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By L M. Foster, J R. Kellett, G A. McMah

The Great Artesian Basin (GAB) contains one of the largest reserves of fresh water in the world. The volume in storage is enormous, being estimated at nearly 65 000 million megalitres (ML). Development of this resource, dominantly for the pastoral industry, began in the late-1800s and quickly accelerated. With exploitation of the resource, artesian pressures declined almost as rapidly. This loss of head is a result of the total discharge from the basin and much of this discharge is waste of water. The waste through uncontrolled bores and inefficient distribution systems still amounts to about 75 per cent of all discharge. However, the volume in storage has hardly been depleted. The major concern is the effect of withdrawal on artesian pressures. Due to the size of the Basin, the relatively flat gradients and low permeability, the movement of water through the aquifers is extremely slow and independent of recharge. Hence, the normal concepts of sustainable yield (ie discharge should equal recharge) cannot be applied to the Basin as a whole as travel times do not allow for the effect of recharge to be seen away from the outcrop areas within management timeframes. The large volume in storage, though, can provide an extensive buffer to the impacts of temporary water needs. This effect should be considered when assessing the acceptability of fixed life projects such as mines and the extracted volumes from their operations. Identifying a sustainable yield involves balancing the acceptability of the economic, environmental and social costs with the associated discharge and fall in head, to arrive at an acceptable balance.

Jan 1, 2003

By C. P. Manning

This paper reports recent progress in the development of a unique metal extraction technology utilizing zirconia-based inert anodes for the electrolytic reduction of metals from their oxides. In this process, the target metal oxide is dissolved in an ionically conducting liquid solvent phase. An extended anode consisting of an oxygen-ion-conducting stabilized zirconia membrane in intimate contact with a catalytically active electronic phase and an inert electronically conducting cathode are inserted into the molten flux containing the oxide. When the appropriate electric potential is applied between the electrodes the target metal is reduced at the cathode and oxygen ions are selectively transported across the stabilized zirconia membrane and oxidized at the anode. When the process is conducted at temperatures between 1200-1400°C, the ohmic resistance drop across the stabilized zirconia membrane is low, and high current densities on the order of I A/cm2 or greater can be obtained. In addition, the process efficiency can be increased further by directly reforming hydrocarbon fuel over the anode. Laboratory experiments at Boston University have demonstrated the technical viability of employing zirconia-based inert anodes for environmentally sound production of metals such as magnesium, tantalum, aluminum, etc., directly from their oxides. Significant progress has been made in the application of this concept to the electrolytic reduction of magnesium at 1300°C. The research topics covered include stability of the zirconia membrane in the selected molten solvent (flux), volatility of the flux, electrochemical characterization of the electrolytic cell, and analysis of the metals produced.

Jan 1, 2003

By Michael Zinigrad

The quality of metallic materials depends on their composition and structure and these are determined by various physico-chemical and technological factors. To effectively prepare materials with required composition, structure and properties it is necessary to carry out a research in two parallel directions: Comprehensive analysis of thennodynamics, kineties and mechanisms of the processes taking place at the solid-liquid-gaseous phase interface during welding processes and development of mathematical models of the specific welding technologies. We have developed unique method of mathematical modeling of phase interaction at high temperatures. This method allows us to build models taking into account the thennodynamic characteristics of the processes, the influence of the initial composition and temperature on the equilibrium state of the reactions, the kinetics of heterogeneous processes, the influence of the temperature, composition, hydrodynamic and thennal factors on the velocity of the chemical and diffusion processes. The model can be implemented in the optimization of various technological processes in welding, surfacing, casting as well as in manufacturing of steels and non-ferrous alloys, materials refining, alloying with special additives, removing of non-metallic inclusions.

Jan 1, 2003

By M. H. Pelkki, R. J. Sweigard, P. W. Conrad, J. M. Ringe, D. H. Graves

Research has shown that excessive soil compaction is detrimental to the establishment of trees in reclaimed soils. Dry bulk density and penetration resistance are two soil parameters that can be used to indicate the level of compaction in reclaimed soils. It is believed that reclamation practices that minimize soil compaction will produce better results when forestland is the intended postmining use. The University of Kentucky has developed reforestation test cells on reclaimed soils at a surface mine in eastern Kentucky to test this hypothesis. Each test cell has been planted with various species of trees. Since 1997, data have been collected at these test cells for soil average dry bulk density, average penetration resistance, average depth to refusal and average survival rate of trees. These data have been correlated to determine the relationship between soil compaction and tree-survival rate. It is believed that these two soil-compaction parameters may ultimately be used to predict tree-survival rates on reclaimed surface mined lands.

Jan 1, 2003

By Mitsutaka Hino

The contents of gangue minerals, such as Al2O3. P2O5, crystalline water and so forth in the iron ore imported to Japan tend to increase year by year. Though the increments of such gangue contents arc approximately 0.1-0.2 mass%, some problems for the blast furnace operation in ironmaking process have already been reported, In order to clarify the mechanism of harmful effect caused by the small increment of gangue minerals, mainly Al2O3. on the blast furnace operation, the dripping behavior of Fe,O-CaO-SiO2-Al2O3-MgO slag from the iron funnel, which simulated the micro-porosity in sinter ore, has been observed with the wide range of basicity, Al2O3, Fe2O and MgO contents. The effect of MgO on the dripping behavior of slag has been summarized in this paper. It was found that the addition of 2mass% MgO resulted in large increase of hold-up on the most of the conditions. When Fe2O content was less than 20mass% and the basicity was lower than 0.8, MgO lowered the hold-up even if the slag contained 10mass% Ah03. Every slag hold-up showed the minimum at the basicity of less than unity on the conditions of constant Fe2O and Al2O3 contents, This trend became remarkable when the slag contained 2 mass% MgO.

Jan 1, 2003

By Zdzistaw MiGzkowski

At KGHM Polska Miedi S.A. a direct flash smelting process is used for smelting of chalcocite concentrate for the production of blister copper. The paper presents a model of complex oxidation process of single concentrate grains smelted at KGHM. The description covers main chemical reactions, phenomena of heat and mass ex-change inside the grains and between a grain and the surrounding space. In the model, two zones describing the course of process inside the grain were distinguished: ? The first one, which moves faster towards the centre of a grain, both organic and carbonate carbon are freed. The process takes place without the presence of oxygen and results in an increase of the temperature in the core of the particle. ? The second zone moves slower into the grain and the rate of the movement is deter-mined by the presence of oxygen. In that zone the sulphur is eliminated and the oxidation of the organic compounds vapours moving from deeper layers of a grain takes place. Based on the results of laboratory tests, the coefficients that describe the oxygen transportation into the grain and decide the progress in the chemical reaction were determined. The paper contains the results of model calculations for single grains reacting in environment of various content of oxygen as well as the results of model calculations for the laboratory reactor system.

Jan 1, 2003

By Mônica Suede Santos Silva

This work describes characterization of the performance of the tundish of a six strand continuous casting unit of the Companhia Siderúrgica Belgo Mineira, João Monlevade, Brazil using physical modeling. Permanent and transient conditions, due to ladle metal composition changes are considered. Pulse and step tracer addition techniques are employed to assess the control variables. For transient conditions the degree of inter-mixing and the minimum residence time are determined with a view to optimize the process especially during the grade changes of steel.

Jan 1, 2003

By P. H. Oliver

"The current theory of how explosives fracture rock offers no explanation for the improvements in fragmentation and the reduction of fly rock and back break which occurs when an adequate inter-row delay time is used. Nor does it explain why fragmentation improves with rectangular drill patterns where the hole spacing may be as much as four times the hole burden.A new theory of rock fragmentation is proposed which builds on the existing theory. It offers rational explanations for the many blast effects which the current theory does not address and the need for adequate timing delays between rows. It improves on the design of inter-row delay timing by defining the length of free-blasted face needed in front of a hole *Retired from Inco Ltd., Sudbury, Ontario when selecting the delay element which will provide an adequate inter-row delay time."

Jan 1, 2003

By Freddie Hunter

An underground mining method for extracting an eight metre (26') coal horizon, containing a sandstone layer. A decrease in the thickness of the rock strata between the number two and number three seams of the Sasolburg Coal Field, has resulted in a total mining horizon approximately eight metres (26') thick. This parting varies in thickness and competency and in some areas is impractical to cut with a continuous miner. In addition, the general mining area is highly jointed. The top seam is first mined to a normal bord and pillar plan with a continuous miner. The bottom seam is then mined by selectively undercutting the stone parting constituting the floor of the top seam. In areas where this parting is between 0.75 - 2.50 metres (29.5" - 98") thick, it is suspended from the primary roof support installed when mining the top seam. Secondary, high extraction retreat mining is then undertaken in the coal pillars adjacent to the suspension supported headings in the bottom seam. Left in-situ, the parting provides lateral support to the pillar sidewalls in both the top and bottom seams, enabling high percentage extraction rates in what was previously thought an uneconomically mineable area. The paper proposed, presents the challenges and practical implications of executing the mining method, including the primary roof control of the top seam and the stone parting between scams.

Jan 1, 2003

"Boston’s Central Artery passes beneath nine active railroad tracks carrying commuter and Amtrak trains into South Station, the City's busiest rail terminal. These railroad operations had to remain in service throughout the construction of the “Big Dig”. The solution was to jack the tunnel under the tracks, rather than build the tunnel by more conventional means.Jacking of utility pipes is fairly common, but jacking boxes as big as a highway had never been done in North America, until the Big Dig came along.Soil freezing was decided upon as a means of stabilizing the soil under the tracks. This allows the tunnels to be jacked into place without soil caving when the soil is excavated at the leading face of the advancing tunnel boxes. Hundreds of pipes were driven into the ground between the tracks. Inside the steel pipes were smaller plastic pipes. A freezing plant near the railroad tracks pumped refrigerated brine into the inner plastic pipes. The brine ran out the bottom of the inner pipe, flowed up to the top inside the outer pipe, and was re-circulated to the freezing plant and back again into the ground. Over several weeks the circulating brine drew the heat out of the soil little by little, and froze the ground outward from the pipes. Soil FreezingThe plan required the construction of jacking pits in which the tunnel boxes could be constructed, and from which they could be jacked forward to their final locations, as described in the accompanying article. Once the jacking pit was built and the tunnel box constructed inside the pit, crews made an opening in the headwall of the pit to allow passage of the tunnel sections, excavated about three feet of the frozen soil, pushed the tunnel box ahead, and repeated the procedure again and again."

Jan 1, 2003

By Supachai Surapunt

The distribution behavior of V A minor elements (As, Sb and Bi) in the smelting stage of the Mitsubishi process were evaluated thermodynamically based on thermodynamic data and operating data. The fractional distributions between the gas, slag and matte phases considered as the degree of vapor saturation of 1.0 are as follows: 53.8, 27.2 and 19% for As, 23.6, 56.6 and 19.8% for Sb, and 91.3, 1.1 and 7.6% for Bi, respectively. Arsenic is mostly distributed to the gas and slag phases. It is effectively eliminated by volatilizing and slagging. Antimony is mainly in the slag phase, which is suitably removed by slagging. Bismuth is easily vaporized to gas phase. The degree of vapor saturation has a large effeet on the distribution behaviors of the three elements between the three phases. The amount of a minor element in the charge has an effect on the distribution of As but no effect on the distributions of Sb and Bi. Increasing matte grade and temperature results in the change of distributions for As and Sb, significantly. The change in the distribution ratio between slag and matte phases also considerably affects the distributions of As and Sb. The distribution behavior of Bi is not significantly changed by the change in matte grade, temperature and distribution ratio.

Jan 1, 2003

By M. Brennan, A. Majumder

"The mineral processing research community has devoted enormous efforts to the modelling of mineral separators over the last 50 years. While many efforts have been made to use only fundamental physics as a basis for the models, fluid flow patterns in separators are not simple while the motion of particle swarms through fluids is extremely complex.Sluices are the simplest forms of the flowing film concentrators and have been used in the mineral industry since at least the 15th century (Agricola, 1556). Flowing film concentrators, in general, still have widespread applications in the mineral industry and their designs vary according to the specific need.Particle separation in a sluice appears deceptively simple, but the separation mechanism has proven complex and difficult to quantify. Separation in the sluice takes place in a flowing film a few millimetres thick. The particles are suspended by turbulent eddies and motion relative to the fluid takes place in socalled hindered settling mode. The difficulty arises because the presence of the particles influences the flow pattern and when the particles are fully transported by the flow, the flowing slurry may not have the same viscosity as water and does not have the same density. For this reason a universal theory which can explain the behaviour of a suspension in a sluice or any other gravity equipment has still not been developed. Few attempts have been made to analyse the mechanisms involved in the concentrating processes of pinched sluices and Reichert cones.Fluid flow behaviour and slurry transportation characteristics in open channels have, however, been active research topics in the disciplines of fluid mechanics, chemical engineering and civil engineering for many years. As a result, an extensive literature is available, which has led to the development of the model described in this paper.In an effort to test the extent to which fundamental fluid mechanics can provide a prediction of particle separation, a study on a simple parallel-sided sluice has been carried out using glass beads at various particle concentrations and flow rates, and the actual particle separation taking place compared to predictions from modelling.The modelling strategy was divided into two parts; the first was to predict the horizontal slurry flow velocity profile and the second to predict the solid particle concentration over the depth of the flow at different flow conditions. The predictions were then validated with measured data sets. This can easily be done if the slurry flow is split at different fractional flow depths so that the mass flow of solids over different flow heights is measured accurately over a fixed period. Mass flow splits can then be calculated by integrating the product of the predicted slurry velocity profile and the predicted solids concentration profiles from the base of the sluice bed to the slurry free surface."

Jan 1, 2003

By M Titley, E Maidens

Many gold deposits were mineralised by fluids and processes that also altered the host rocks. This alteration may often be a useful visual aid that distinguishes barren, low-grade from high-grade regions in a rock mass. Alteration intensity is commonly used in gold deposits as a visual tool, along with face sampling or grade control support, to define oreblocks and guide excavation in underground and open pit mining. However, alteration is not often used at the resource estimation stage. Mineralised lodes are usually defined by geologists using a ægeo-grade envelopeÆ, where a number of constraints are considered, including an (arbitrary) cut-off grade; the ænaturalÆ grade break between high- and low-grades; and geological features including structural, lithological or alteration continuity. The geo-grade envelope is usually thought to satisfy the requirements of stationarity for grade estimation, and is considered a single domain. This paper examines a modelling technique combining gold grade and alteration, applied to the Wallaby deposit in Western Australia, to imbue a greater level of detail to the grade estimation in a region tested by relatively sparse drilling. This was achieved by utilising the correlation of gold grade and alteration, along with the spatial characteristics of the alteration, when estimating grades within a number of lodes. The alteration-driven estimation was utilised in conjunction with an unfolding approach, and the use of probability estimates, to overcome geometric data constraints. This technique allows greater control and most likely provides a more reliable estimate of the mineable resources than a global grade cut-off when visual control is to be a major vector in grade control.

Jan 1, 2003

By F. M. C. C. Vieira

Four mining alternatives for exploiting an ultra-deep orebody were assessed through a multidisciplinary evaluation process which involved: the generation of a 3D geological model; the design and scheduling of life-of-mine layouts; the analysis of anticipated ventilation and cooling conditions; the study of rock-related risks of mining in ultra-deep stress environments; the logistic implications of transporting men, rock and materials; and, lastly, the economic implications of each option. Once results from the integrated mine design assessment were available, mine planners were faced with an important problem to solve: how to identify the optimal mine design alternative when numerous assessment measures and multiple decision criteria needed to be considered simultaneously? To address this ‘multiple-attribute decision problem’ and arrive at the ‘optimal layout for ultra-depth’, a generic decision methodology that uses principles of ‘utility’ was applied. The methodology assumes that ‘single-value risk estimators’ do not account for the inherent variability of real conditions. Therefore, risk estimators were represented by statistical distributions of their incremental changes, where applicable. The stochastic variables, once defined, are used as inputs in the ‘utility’-based layout decision scheme. This ‘utility’-based decision methodology offers a framework for mine design decisions to be made objectively, when complex trade-offs between multiple risk domains need to be considered simultaneously. Upon applying it, one of the layouts emerged as the preferred alternative. Keywords: Utility; mine design; multiple-attribute decision; layout selection

Jan 1, 2003

By J Mar·n, R Anderson, S Strohma, R Harvey

Xstrata is the operator of both Minera Alumbrera Ltd (50 per cent Xstrata, 50 per cent Wheaton River) and Ernest Henry Mining Pty Ltd, (99.99 per cent Xstrata), both copper-gold deposits, using conventional SAG/ball milling at current capacities of 36 Mt/yr and 10.3 Mt/yr respectively. Alumbrera is located in Catamarca Province, in the north west of Argentina. Ernest Henry is located in Cloncurry, north west Queensland, Australia. Both operations started in late 1997, with commercial production achieved in early 1998. Different designs and equipment are in use for both operations, however the evolution of SAG milling performance, although logically related to their specific features, reflect similar trends of consistent increases in throughput. This paper will discuss the main changes to the SAG mill liners in both operations and the results achieved to date. A summary of the operating strategies will be included.

Jan 1, 2003

By A. González

Arsenic is one of the main contaminants present in Chilean copper concentrates and its abatement represents a challenge for the process metallurgy, particularly under the strong environmental requirements in the global community. The possibility to form ferric arsenate directly from a gas phase by means of a heterogeneous reaction between an arsenic gas bearing and iron oxide was studied at laboratory scale. A thermodynamical analysis for the system Fe-As-O-S has been initially made, in order to obtain the stability conditions for the ferric arsenate or other FexAs2O2 type compounds. Experiments were made using an hematite sample suspended in a thermogravimetric device. AS4O6 gas generated from solid AS203 that was passed through the iron oxide sample and its instantaneous weight change was recorded directly. A kinetic study for the AS4O6 volatilization was made to control the gas composition. A chemical control between 300 and 600°C with an apparent activation energy of around 14 Kcal/mol As2O3 was determined. The samples after the reactions were chemically and XRD analysed. Arsenates detected corresponds to complex compounds. Results shows a dependence on temperature and oxygen content in the gas phase. The kinetics for iron arsenates formation is slow, reaching an arsenic capture of 6% after 80 minutes of reaction when an oxygen content of 50% is fed continuously at 800°C and 3,56% As in the gas. Experiences made at the same temperature but under higher oxygen content in a closed reactor, allowed arsenic capture close to 60%. For higher temperatures the capture is considerably lower.

Jan 1, 2003

By Guo Xueyi

The electrochemical couple behavior of manganese dioxide with ferrous/ferric ions in acidic chloride medium was investigated, It was proven that the dissolution of Mn01 is due to the electrochemical couple reaction between MnO2/Mn2+ and Fe2+/lFe3+ in the solution, The driving force for the process originates from the rest potential difference of the two couples. The reduction of Mn02 is controlled by clectrochemical kinetics, whereas the conversion of F e2+ to Fe3+ is limited by diffusion, The factors such as the Mn2+, Fe2+, Fe3+, Cl concentration, pH of the solution and the temperature, have much influence on the kinetics of the couple process, This study will be useful to elucidate the mechanism for the leaching of manganese nodule from the deep ocean as well as manganese dioxide ores in land,

Jan 1, 2003

By Jerome P. Downey

Technologies developed within the field of extractive metallurgy to recover, concentrate, and purify metals and industrial minerals from ores, have served as the foundation for all of the subsequent environmental remediation, materials recycling, and waste management technologies. This paper discusses the application of classical extractive engineering principles to the development of a thermal process for the recovery of mercury from solid wastes. Process development is presented as a series of logical stages, which begin with a thorough characterization of the site-specific waste, move on to bench and pilot scale testing of the process options, and end with a functional process flowsheet. This paper also presents thermodynamic data on many mercury species of interest to the minerals, power, and chemical industries. These data can be used to model the speciation and recovery of the mercury as a function of various process parameters.

Jan 1, 2003

By T P. Hynes

Submarine tailings disposal is conceptually an attractive option for managing reactive mine wastes in coastal regions by virtue of reduced sulfide oxidation under a water cover and no infrastructure to maintain after mine closure. However, the lack of detailed knowledge of metal leaching, dispersal of fine tailings and biological impacts in the marine environment has led to no operating permits currently in effect in Canada. Detailed chemical and ecotoxicological assessments at two historic copper mine sites (Little Bay and Tilt Cove) in the north coast of Newfoundland with tailings disposed in an estuarine to shallow (=100 m) marine environment have demonstrated reduced reactivity of sulfidic tailings when submerged under water. Only non-acute toxicity is detected in biota inhabiting the immediate vicinity (A review of another historic shallow marine tailings operation in the southern tip of Vancouver Island (Jordon River) with a high-energy setting also reveals problems with unconfined tailings dispersal and temporal biological impacts. Documented studies at two deeper (140 - 360 m) marine tailings disposal operations at the northern tip of Vancouver Island (Island Copper) and northwestern coast of British Columbia (Kitsault) again illustrate imperfect predictions of tailings re-suspension and dispersal. At these sites, bioaccumulation of tailings-derived metals appears to be minimal. There is evidence of rapid re-colonisation of the tailings surface by benthos but of different species than the original population. Integrating these observations with reported metal fluxes and biological diversity associated with submarine hydrothermal vents, the risks and benefits of deep-sea (>1 km) tailings disposal are discussed. To determine if submarine tailings disposal in deep, confined basins on the seafloor is environmentally friendly, detailed multi-disciplinary research incorporating physical, chemical, biological and toxicological components will be indispensable.

Jan 1, 2003

By D. Rajkovic

Geothermal sources are exploited in two basic forms, i.e., the primary form of thermal energy and that converted into electrical energy by using an adequate thermodynamic cycle. There is a possibility of applying several processes for the conversion of thermal into mechanical or electrical energy, which depend on the thermodynamic characteristics of the geothermal water. Geothermal sources in Croatia do not contain steam of relatively high temperature, like in Italy, although both countries are nearly in the same position with respect to geothermal belt. Geothermal sources in Croatia are mostly so-called low-temperature geothermal sources with water temperatures lower than 100°C (Cubric and Jelic, 1993). A few of them have been exploited, although the percentage of utilization of their available power is still very small. The low-temperature potential is a major disadvantage when it comes to power generation, since state-of-the-art geothermal power plants require reheated steam or hot water to operate. There is a common belief that the optimum way of exploiting low-temperature geothermal sources is heat generation. Therefore, this analysis is especially aimed at potential users and showing the technical and economical possibilities of using low-temperature sources for conversion of thermal energy into mechanical work and electrical energy.

Jan 1, 2003