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By Hiromichi Ohta

Precise thermal properties of molten materials are essentially required for analyzing the metal production process. These properties are also important as a clue to consider the dynamic structure of liquid materials. However, it is difficult to obtain the precise thermal diffusivity values of molten oxides at high temperature because of the experimental uncertainties arising from the bubble formation or the severe separation of radiative and conductive heat components. Recently a novel laser flash method has also developed for measuring thermal diffusivity of molten oxides at high temperature. In this new technique, the sample is melted in a metal crucible and heated to the desired temperature. A single laser pulse is flashed on the bottom of the metal crucible and the infrared ray irradiated from the same bottom surface is measured for obtaining the temperature decay, from which the thermal diffusivity of the liquid sample can be estimated. The usefulness and validity of this new laser flash technique have been confirmed by obtaining the thermal diffusivity values of silicate melts in the wide temperature range between 773 and 1673 K.

Jan 1, 2003

By Steve Kral

It seems that mining has been in the doldrums for awhile. Except for gold, metals prices remain depressed. And economic conditions in the United States and around the globe have put governments in a financial bind. This affects new building and infra-structure repairs, which, in turn, have a major impact the building materials industry. Add to that the severe environmental and regulatory restrictions placed on the mining industry in developing new mines and expanding existing ones. It’s enough to make a mining engineer/geologist/metallurgist go sell real estate. So why do those employed in the mining industry stay in the business and remain optimistic? Many of them will say that they have been through down cycles before and know that an upswing is in the offing. They also know that society will always need the commodities they produce. And they love the challenge. The challenge in mining’s case is producing commodities as cheaply as possible, in an environmentally sound manner and improving the quality of life in the communities where they work.

Jan 1, 2003

By F Pavloudakis

The installation of on-line analysis systems in the open-pit mines of the Public Power Corporation SA (PPC, the state-owned electricity entity of Greece) is considered to be the key-parameter for performing improved quality control and blending/homogenisation of the produced lignite. In order to investigate the accuracy of these systems under the site-specific conditions of the Greek lignite deposits, a research project was carried out. This was necessary since there is lack of experience in using on-line analysers in mines that produce a fuel of such a poor and largely fluctuating quality. After thorough market research, a dual energy gamma ray transmission on-line ash analyser was installed in Kardia mine of Ptolemais û Amynteon Lignite Centre, which is located in West Macedonia, Greece. The initial results obtained after the realisation of a series of dual-comparison trials (ie using two series of reference values that allow three-way comparisons) pointed out several problems that obstacle the achievement of high accuracy on-line measurements. More specifically, the measurements obtained by the analyser were higher than the concentrations determined by the two laboratories when the ash content was lower than 12 per cent (in wet basis). On the contrary, when the ash content was higher than 12 per cent, the measurements of the on-line analyser were lower than the concentrations determined by the laboratories. In other words, the range of the measurements obtained by the analyser was narrower than that corresponding to the lab analyses results. Therefore, the use of this on-line analysis system under the site-specific operating conditions of Kardia mine does not guarantee improved quality control of the lignite fed to the mine-mouth located power plant. Most probable reasons that explain the above-mentioned problems are the following: The frequent and widely ranging fluctuations of the chemical and mineralogical composition of the lignite transported by the conveyor belt, especially as far as its calcium content is concerned. This result from the nature and the origin of the mineral matter co-excavated with the lignite, which varies from calcareous marls to sands and clays rich in aluminium and silica minerals. The fluctuations of the lignite quantity transported by the conveyor belt. The change of the linear concentration of iron contained in the fabric of different belt parts.

Jan 1, 2003

By A Bouazza, J Kodikara

In this study, 23 samples of leached ash (LA) were collected from an ash pond at Loy Yang Power Station and geotechnically characterised. The samples were collected at various depths and locations within the ash pond on two separate occasions in order to account for the full variability. The LA within the ash pond at Loy Yang Power Station (LYPS) was found to vary in texture from silt to sand, depending on the location from where the sample was collected. Samples collected near the ash pond inlet discharge point, for instance, contained more than 50 per cent sand sized particles and were subsequently classified under the Unified Soil Classification System (USCS) as silty sand (SM). Further downstream of the inlet discharge, the LA became progressively finer and was classified accordingly as elastic silt (MH) when the sand content became less than 50 per cent. Basic geotechnical testing revealed that the LA from Loy Yang Power Station was generally acceptable as a landfill cover material. The permeability of LA, however, was generally too high for prescriptive covers, (ie resistive covers that generally rely on the impervious nature of the material to control percolation). Alternative covers, generally rely on the store/release function of a capillary or monolithic barrier to prevent percolation into the landfill. Subsequently, a material that can maintain a high water storage capacity while at the same time, readily allow infiltration and evapotranspiration is required for an alternative cover. Sandy silt and silty sand are optimal soils for alternative covers, as they do not yield water to gravity forces, but do give up most of the water in their pores when subjected to high-matric suction (Kavazanjian, 2001). The effectiveness of alternative covers is ultimately assessed using computer models, such as UNSAT-H and HYDRUS-2D, to rigorously perform water balance calculations. Prior to using a computer model to determine the highest possible percolation in the worst climatic conditions, it is necessary to select the most appropriate materials. This paper suggests a method to screen available materials for use as an alternative cover material on the basis of the soil water characteristic curve (SWCC).

Jan 1, 2003

By David McGregor, Ashoke SenGupta, Jerry Darlington

The stability of bentonite clay suspensions against flocculation in the presence of certain anionic polymers was investigated. These polymers included a purified sodium lignosulfonate, a sodium oxylignosulfonate, a potassium salt of humic acid, and a sodium polyacrylate. The polymers differed from one another in molecular weight as well as in carboxylic, phenolic, and sulfonate group contents. The scope of this study is in evaluating the extent of thinning achievable in a bentonite clay suspension in the presence of these anionic polymers under varying electrolyte concentration, presumably as a result of deflocculation of the clay platelets by the polymers. Under certain conditions of polymer dosage and electrolyte concentration, the lignosulfonate seemed to have flocculated the clay suspension, while the other polymers served fairly well as a deflocculating/dispersing agent. The lignosulfonate, however, showed some deflocculating ability when the electrolyte concentration of the suspending medium (water) was increased by adding sodium chloride to the clay suspension. Among the four polymers tested, the polyacrylate was found to be the most effective in deflocculating clay particles, followed by the humate and the oxylignosulfonate.

Jan 1, 2003

By Subagyo

The condition of slag in a pyrometallurgical reactor is vital to ensuring control of the process. A new technique based on multivariate image analysis (MIA) of digital images has been developed to provide an online measurement of important slag characteristics, such as the presence of exposed metal, the presence of solid phases, and temperature. This paper shall describe the technique and provide some results from analysis using industrial plant data.

Jan 1, 2003

When mining of ilmenite deposits wet process of preparation is traditionally used. But this method needs large volume of water. The problem of water deficiency is characteristic of many regions of the Republic of Kazakhstan. The Satpayevskoye ilmenite deposit is situated in the East Kazakhstan, its location has problems with water, and the mineralogical composition of rock is unfavourable: rocks contain up to 40 per cent of clays. That is why designers made a decision to use dry process of preparation for processing of these ores. Offered scheme and equipment selection are presented in this paper.

Jan 1, 2003

"Developed by CRIRSCO, IRT is a document that draws on the best of the CRIRSCO-style reporting standards. These reporting standards are recognised and adopted world-wide for market-related reporting and financial investment.The IRT is not an international reporting code and does not supersede existing national reporting standards. Rather it is a guideline that encapsulates the content of these standards for the benefit of the international mining industry and its various stakeholders.The template is a 'living document' that is continuously updated and improved as new national laws, rules, codes and guidelines are created or amended.The International Template is advisory only and where national codes already exist, these will take precedence. The International Template is intended to assist those countries that either do not have a reporting code or whose code is outdated, to produce a new code consistent with international best practice. It also provides a consolidated version of national codes that reflects their compatible international components and may thus be used in comparisons with other international reporting systems. The word 'Template' is used advisedly to indicate that this document is a model for code development and does not in itself constitute a 'code' which implies that it has legal or other regulatory force.From this point forward, the Template includes words that imply a mandatory action, such as ""requires"", ""applies"", ""must"" etc. This is to enable the Template to be easily adopted by countries and organisations wishing to do so, and does not imply that the Template itself is a mandatory reporting standard.INTRODUCTION2 In this edition of the International Reporting Template (""The Template""), important terms and their definitions are highlighted in bold text. The guidelines are placed after the respective Template clauses using indented italics. They are intended to provide assistance and guidance to readers for interpreting the application of the clauses in the Template.Indented italics are also used for Appendix 1 — 'Generic Terms and Equivalents"", and Table 1 —'Check List of Assessment and Reporting Criteria' to make it clear that they are also part of the guidelines for the application of the Template.Appendix 1 contains a table of generic terms and their equivalents, designed to avoid unnecessary duplication or ambiguity in the textAppendix 2 provides Rules of Conduct for Mineral Resource and Mineral Reserve estimators that may be considered in addition to the Codes of Ethics or Practice normally applying to members of professional institutions."

Jan 1, 2003

By Craig Haase

A. Introduction

Jan 1, 2003

By D B, M A. Sares, D W. Coulter, D C. Peters

This presentation discusses NASA-funded research on the ability of hyperspectral remote sensing to map diagnostic acid rock drainage (ARD) mineralogy that adversely affects water quality within watershed and to determine the relative contributions of natural ARD sources of metals and acidity to that drainage. Ground-based reflectance spectroscopy, combined with water chemistry, is used to identify mineralogical and chemical variations throughout a watershed. Integrated with hyperspectral data acquired from airborne remote sensing platforms, such as the NASA Airborne Visible Infrared Imaging Spectrometer (AVIRIS) sensor, a methodology has been developed that should improve environmental assessments and tracking of impacts on and from drainages. Phase I of this project focuses on a drainage basin (Lake Creek), tributary to the upper Arkansas River in central Colorado, which is impacted by natural acid rock drainage from areas of high-sulfide hydrothermal alteration. This project builds upon research and inventory efforts by the Colorado Geological Survey (CGS) to identify hydrothermal alteration that is the primary source or is contributing to acidic and toxic drainage in Colorado. This presentation will cover ground and airborne hyperspectral remote sensing techniques and results and water analyses for seasonal high-flow and low-flow conditions in Lake Creek. Identifying correlations between mineralogy, especially mineralogy that can be identified through airborne remote sensing, and water chemistry is a key focus of this project. Of particular interest are low-pH iron phases such as jarosite, ferrihydrite, schwertmannite, copiapite, and transitional amorphous phases as well as AlOH phases from higher, although still acidic, pH environments which are observed to mix with the iron precipitates within the streams draining from the hydrothermal systems. Drainage in the Lake Creek watershed derives from the Grizzly Peak caldera (Oligocene), which exhibits extensive hydrothermal alteration. Alteration types include silicic, quartz-sericite, quartz-sericite-pyrite, advanced argillic, and argillic. By understanding the chemistry of a naturally impacted drainage and its relationship to the surrounding geology, the project goal is to allow more efficient and complete identification of such sources in mineralised terranes through remote sensing technology.

Jan 1, 2003

By Karl J. C. Harries

"14.1. INTRODUCTION1The boilerplate of an agreement is not a single provision, but a series of provisions that are expected in “every agreement”. They are sometimes also referred to as the “lawyer’s provisions”. Many businessmen consider the boilerplate to be superfluous and, to some extent, window-dressing by the lawyers – even legalese. They will often offer advice to the effect that it can “pretty well be ignored”. Such advice could not be more wrong.Most boilerplate provisions are essential parts of every agreement. Some may be part of a “standard package” and may have little relevance to the agreement at hand, but these are the exception rather than the rule. The exceptions should not be treated as justification for giving all these provisions short shrift. The boilerplate should receive the same review, consideration, and negotiation as the provisions that set forth the business deal. It is often these provisions that make the deal work or that are turned to at the time of disputes. If they are inadequate, as they sometimes are (unfortunately, some draftsmen are also loath to review or update their standard boilerplate provisions or to tailor them to the deal at hand), they can create problems, rather than offer solutions. Such problems can be costly and time-consuming for the parties to address. Inadequate or incomplete provisions may ultimately be one of the reasons for the parties to turn to the courts to settle their differences. On the other hand, good boilerplate provisions can help keep them out of the courts.One of the principal objectives of an agreement should be to provide procedures, or mechanics, for implementing agreed principles and for the parties to follow to settle their differences, real or perceived, without going to the expense and disruption of a lawsuit. An agreement should aim to keep the parties away from the courts, not serve as a springboard to the courts. It must nevertheless be acknowledged that, if there is a major falling-out among the parties to an agreement, the chances are that, however carefully the provisions of that agreement have been negotiated and drafted, the parties will end up before the courts or some other adjudicating body."

Jan 1, 2003

By H. Y. Sohn

The purpose of this article is to analyze critically and quantitatively the effect of chemical equilibrium on the overall rates of fluid-solid reactions. It is shown through a mathematical analysis that a reaction with a small equilibrium constant (a positive standard free energy of reaction) is more likely to be rate-controlled by pore diffusion or mass transfer than a reaction with a large equilibrium constant. The overall reaction rate of the former also tends to be slow. Furthermore, the apparent activation energy of such a reaction approaches the standard enthalpy of reaction (Mf'), rather than the true activation energy of the chemical reaction. The Law of Additive Reaction Times developed by the author is shown to apply to equilibrium-limited fluid-solid reactions and to be useful in quantitatively analyzing the behavior of such reactions.

Jan 1, 2003

By D Michaelsen, S Miller

The Grasberg Mine is a copper and gold open pit mine operated by PT Freeport Indonesia (PTFI) and located in the high equatorial mountains of the Indonesian province of Papua. The climate is alpine/subalpine with little seasonal variation in temperature or rainfall. The daily average temperature ranges from about 2¦C to 14¦C and the annual rainfall in the vicinity of the mine and overburden stockpiles is about 4000 mm to 5000 mm. Mining of the Grasberg open pit will continue until 2014 at which time approximately 2750 Mt of overburden will have been produced. Current overburden production rates are 200 Mt per annum. The current mill rate is 230 000 t/day from the Grasberg pit (190 000 t/day) and the underground operations (40 000 t/day). The acid rock drainage (ARD) issues associated with overburden from the Grasberg operations were identified early in the mining operation. Almost all overburden placed to date has been Potentially Acid Forming (PAF). Laboratory testing has identified four main overburden types: limestone and non-acid forming (Green waste), PAF low capacity (Blue waste) and PAF high capacity (Red waste), and Heavy Sulfide Zone (HSZ), which contains greater than 20 per cent pyrite. Waste type block modelling indicates that at least 30 per cent of the overburden production from 2003 to the end of Grasberg pit operations will be limestone. Strategies are being developed to maximise the beneficial use of limestone through strategic blending and placement for ARD mitigation and control.

Jan 1, 2003

By Steve Vaughan

Canadian Regulation and Reporting Requirements High reporting standards are essential in developing and sustaining a strong confident capital market. As of February 1, 2001, technical reports on mineral exploration and mining work, must conform to the standards of the Canadian Securities Administrators (CSA) National Instrument 43-101. Only a ‘qualified person’ may supply the technical information on which a news release is based and must verify that the final version of the release is accurate.

Jan 1, 2003

By Rob Morrison, Peter Cameron

"Many products and technologies have been developed from outcomes of research projects carried out by the Julius Kruttschnitt Mineral Research Centre (JKMRC). When these products and technologies are applied to the design and optimisation of blasting, comminution and separation, improvements in profitability can be realised.In 1970 Alban Lynch promoted two practical ideas to improve plant operations:• Ore and equipment properties can be separated allowing experience with one type of ore or equipment to be transferred to other types of ore and equipment. If this experience was encapsulated in a mathematical model, then these properties could be combined and used to simulate (ie. to design and to optimise) complete mineral processing circuits.• Many problems associated with scale-up from laboratory to industrial equipment could be eliminated by experimental work on full-scale equipment in the plant.Many JKMRC research projects have focussed on the development of models of unit operations in mineral processing and their application to process simulation.Models of comminution and classification developed at the JKMRC have been used since the early 1980's. Ore characterisation techniques developed to support these models are licensed world wide through JKTech. The application of comminution modelling techniques to blasting, which optimises the process feed size distribution is used in Mine-to-Mill® projects. The advances in the understanding and modelling of froth flotation over recent years have provided the opportunity for integrated ore characterisation and process optimisation from resource to product.JKMRC project outcomes often provide proven opportunities for the mineral industry to improve performance and productivity. JKTech was established in 1986 to commercialise and market the most promising outcomes and thus ensure their continuing availability to the mineral industry.They include:• Commercial software (JKSimMet, JKSimBlast and JKMetAccount).• Monographs (Comminution and Blasting).• Technologies (Mine-to-Mill® and flotation optimisation).• Hardware products (JKFrothCam, JKJetLift® and the Mineral Liberation Analyser).This paper summarises these technologies and their benefits."

Jan 1, 2003

By F Shi, W Valery

WMC Fertilizers (WMCF) operates a Beneficiation Plant at Phosphate Hill in Queensland, Australia. The plant consists of two-stages of crushing, followed by a wet scrubbing and desliming circuit. Ore is then fed to a tertiary crusher and a milling/classification circuit, with the final product going to a swing-lift thickener and storage tanks. From the slurry storage tanks, the phosphate rock is fed to a horizontal belt filters which dewater the phosphate rock ahead of a hemi-hydrate phosphoric acid plant. The water soluble recovery of phosphate in the phosphoric acid plant is dependent on the moisture content in the filter cake, as this governs the wash water addition to the hemi-hydrate filters. Since commencement of operation, the moisture content of the filter cake fed to the phosphoric acid plant has been higher than design reducing the phosphoric acid plant recovery and at times reducing the throughput through the phosphoric acid plant. The moisture content in the filter cake can be decreased by reducing the generation of fines in the milling and classification circuit (classified as û38 micron material). This paper identifies the causes of fines generation in the Phosphate Hill beneficiation plant. It discusses the options that were assessed to minimise fines generation, and outlines the results to date of circuit changes undertaken at Phosphate Hill.

Jan 1, 2003

By Anatoly N. Vinogradov, Vyacheslav A. Tsukerman

The North-West Russia for 70 years is one the main producers of Cu, Ni, Co, Al, P, REE, Zr, Ti, Ta, Nb, Fe ores and other minerals in the Europe. The largest mining companies locates in the Murmansk region, and they extracts about 100 mln. tons of ores and damps up to 250 mln. tons of waste annually. Nevertheless an environmental situation in the region is stable due to rational management and treatment of wastes on a base of the Noosphere Concept for Nature-using suggested by Vladimir Vernadsky. The Concept was performed practically in the Fersman’ scheme of “non-waste mining and metallurgical complex”, published in the monograph “Minerals of the Kola Peninsula: current status – analyses – prognoses” (1941) and served till now as a sort of “Bible” for industry managers lightening a strategy for an industrial “trophic chain”. The recent status of this scheme is shown on the picture below, and one can see that our concept is coincide with modern ideology known as the “Industrial Ecology”. Moving along this mainstream in the Kola Peninsula since 1929, when the first mining company “Apatit” was established, we provided the water close circuit in mineral dressing plants, hydrometallurgical treatment of slag and tailings, productions of building materials and adsorbents of wastes. The innovation set of technologies designed by the Kola Science Centre allow recently to involve tailing damps in re-exploitation as the technogenic deposits of valuable raw materials for fertilizers, tanning and cleaning agents, pigments, concretes and etc.

Jan 1, 2003

By W. K. Rankin

Achieving continued economic growth with social equity within the natural limits of the Earth's eco-systems is the major issue facing the world today. The material and energy needs of the world cannot be met with the current ways of addressing this issue. The need for metals, an important class of materials, will continue into the future because their unique properties make substitution by other materials impossible in many applications and this need will continue to be met from primary metal production and recycling. However, the recycling rate will increase and the usage pattern of metals will change to reflect the environmental impact of their production and use. Pyrometallurgy has an important role in meeting the metal needs of the future since some metals can only be produced pyrometallurgically; the energy required to produce some metals pyrometallurgically is significantly less than by other methods; most metals are most efficiently recycled pyrometallurgically; and the release of harmful and toxic elements into the biosphere can sometimes best be controlled through pyrometallurgical processing. The development of strategies for pyrometallurgical processing for the future lies in the recognition that sustainable development calls for large step improvements in value delivered per unit of environmental impact over the entire supply chain. Pyrometallurgists can respond to this challenge by contributing to reducing the environmental impact of meeting metal needs using three broad strategies: "end-of-pipe" approaches to convert emissions into benign materials for storage or disposal; flowsheet redesign to limit or eliminate emission production; and improved recycling technologies. A number of examples are discussed to illustrate how the sustainability driver is already influencing the technological development of pyrometallurgical processes, and how these will develop further as the sustainability driver strengthens.

Jan 1, 2003

By A Geldenhuis, M Hagger, J Maree

Disposal of mine water is a worldwide problem occurring in the coal and gold as well in the metal ore mining areas. Since southern Africa is a (semi) arid region, mining effluents should be treated to qualities such that they can be used for agricultural purposes or that they can be discharged in river system. Studies have shown that partly treated acid mine water can be used for irrigation. A copper mine in Botswana plans to use 5 M/d of treated mine effluent for the irrigation of agricultural product. The results of this study showed that when applying the biological sulfate removal technology the produced sulfide precipitated the metals in the mine effluent, such as nickel, Zn and Mn, to metal sulfide (MeS).

Jan 1, 2003

This paper presents an overview of the current status of mine water management in South Africa. The regulatory framework within which mine water management operates is set out, based on the principles and policies embodied in the relevant legislation. The status of the gold and coal mining industries, with regard to water management, is presented on the basis of studies that have been undertaken to develop water and salt balances for these industries. While the data is not available to quantify the status of ARD in South Africa, the range of typical mine water quality problems faced by South African gold and coal mines is presented. The status quo, problems and challenges relating to mine water management are presented and discussed. It is shown that, while there have been major strides in the last decade, and mine water management and treatment in South Africa has moved onto the forefront of mine environmental management, important problems still persist. There is still a significant amount of improvement required, particularly in the field of prediction of water quality deterioration and the application of such predictions to the identification of management actions that can be applied to prevent or minimise mine water pollution in the shortmedium- and long-term.

Jan 1, 2003