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By Luísa Maria Abrantes

Environmental control is becoming more and more stringent. As conventional processes for zinc production are pollutant routes, alternative methods have become an important subject of research. In this regard, the leaching processes have aroused a considerable interest, namely the electrochemically induced approach. The behaviour of zinc concentrate ore in the leaching processesses is influenced by several parameters. Chloride concentration and leaching solution pH, time and temperature of reaction were studied in order to evaluate their influence on the zinc recovery. The efficiency of the leaching process for zinc extraction is performed by factorial design. The experiments were carried out by 23 and 22 factorial designs of the factors. Results show that all factors, except for the time of reaction have a significant influence on the optimisation process, within each experimental region.

Jan 1, 2001

By S. Stoyanov, M. Cross

"Silicon components containing transistor circuitry are at the heart of electronic products such as computers, mobile phones, etc. These components are connected to printed circuit boards (PCB's) using solder material that acts as the conductor for both electricity and heat. During the lifetime of a product it will undergo many thermal cycles where the chip becomes hot during product operation and then cools when the product is switched off. At the product design stage engineers undertake thermo-mechanical simulations to predict the thermal stress in the solder joints due to this thermal cycle and to ensure that the stress magnitude will not result in early fatigue-type failure. The design engineer's aim is to identify component parameters which ensure that the solder will survive beyond a certain number of thermal cycles.The aim of integrating computational mechanics and optimization tools together is to speed up dramatically the design process. From viewpoint of a design engineer in the electronics manufacturing sector, these tools can be used to quickly estimate key design parameters (i.e. material properties, product dimensions, etc) that will guarantee the required product performance. In this paper a modeling approach coupling computational mechanics techniques with numerical optimization is presented and demonstrated. The integrated modeling framework is obtained by coupling the multi-physics framework - PHYSICA - with the design optimisation tool- VisuaLDOC. Thermo-mechanical simulations are presented that predict the creep strains in solder material. Different numerical optimization procedures: Direct and Response Surface based optimization plus Design of Experiments, are tested as a part of this modeling framework."

Jan 1, 2001

By Adam Powell, David Dussault

"Electric Field-Enhanced Smelting and Refining is a process for driving the reaction between carbon in hot metal and iron oxide in slag, for example, in a steelmaking reactor. This process involves inserting electrodes into the slag and metal phases, such that the overall reaction FeO + C -> Fe + CO is separated into two half-cell reactions: Fe2+ + 2e· -> Fe at the cathode in the slag, and C + O 2 • -> CO + 2e· at the anodic slag-metal interface. Without the electrodes, the reaction is very slow, but with electrodes, the additional surface area available to the ferrous ions for reduction accelerates the reaction even without any applied bias. When a bias is applied to the electrodes, the electric field across the slag further accelerates the overall reaction.With or without applied bias, the process is first-order in the ferrous ion concentration, and limited by ferrous ion transport to the cathode. To complicate matters, as the liquid iron is reduced at the cathode, the Mullins-Sekerka instability leads to formation of dendrite-like liquid iron fingers which grow into the slag. Because of this, the design of the cathode can have a significant effect on the overall process kinetics, and understanding of the dynamics of these fingers and of their effect on mass transfer is necessary for the intelligent design of the overall process and the cathode in particular.Toward this end, a detailed mesoscopic two-phase slag-metal model is presented here which describes multi component diffusion in the slag and fluid flow in both phases in the vicinity of the cathode. Diffusion in the slag is driven by chemical and electrical potentials. The phase boundary is modeled as a diffuse interface using a phase field approach. Because this electrochemical reaction occurs at high-temperature, the kinetics of charge transfer and adsorption through the double layer are fast relative to transport, permitting the use of simple linear reaction kinetics. This also eliminates the need to discretize the double layer, with the result that charge neutrality may be assumed everywhere in the domain. Introducing electric field dependence of the gradient potential and well height coefficients in the free energy function allows the model to capture electrocapillarity at the interface."

Jan 1, 2001

The Cooperative Research Centre for Mining Technology and Equipment (CMTE) is funded by the Commonwealth Government, by its mining research members Ñ the Universities of Queensland and Sydney and the CSIRO1, and by its industry members Ñ BHP Coal, RioTinto R&TD, Hamersley Iron, Mining Technologies Australia, Pasminco, Shell Coal, WMC Resources, Advanced Mining Technologies, and Aberfoyle. The Centre conducts work aimed at improving the competitiveness of the Australian mining industry. The current work is focused in four areas: new mining and drilling systems, geological sensing, automation, and equipment maintenance and reliability. This paper describes much of the work in these program areas that relates to metalliferous mining.

Jan 1, 2001

By A S. Lund

Optimisation of the underground mining production process benefits from informed decision making during the process of explosive rock fragmentation. Selection of the most appropriate bulk explosive products for underground production blasting is an area of endeavour that offers significant economic upside if correctly and thoroughly undertaken. The explosive selection process is facilitated by a clear understanding of:the physical and detonic properties of the alternative explosive options available; the response of different rock masses to these different explosive options; and the importance of maintaining a clear focus on desirable blast outcomes in order to enhance value creation aspects of the mining production process. The level of understanding of these issues is raised through the application of measurement and modelling technology, quantifying the effects of blast design (and implementation) on process outcomes. Homestake Darlot and DynoConsult applied a range of dynamic blast measurement and outcome modelling techniques in order to explore the relationship between rock properties, explosive properties and mining process efficiencies. A campaign of vibration and explosive Velocity of Detonation (VoD) measurement produced feed data for use in vibration and fragmentation modelling during the extraction of one of the major stoping blocks at Darlot Gold Mine. The paper describes the use of these tools and discusses the understanding gained concerning the limitations and capabilities of, and the reconciliation between, a selection of analysis and modelling approaches.

Jan 1, 2001

By Gordon Revey

Over ten million pounds of explosives are used daily to blast rock in mines, quarries and construction projects throughout the United States. Despite the immense volume of explosives used, serious incidents involving the legal use of explosive materials are rare. Unfortunately, when incidents arise they are well publicized, whereas the great majority of blasting projects-even the most challenging ones—quietly occur without incident or public recognition. Although unfair, media coverage focuses on incidents and/or accidents, and as a result skews the public’s perceptions of our industry. These negative perceptions about blasting profoundly effect our work. Most apparent are the community groups who organize to fight blasting work. However, other impacts are more insidious and have long-term effects on our industry. For instance, planning engineers or government agencies often prohibit blasting to avoid the public’s adverse reaction or because of general fear of blasting impacts. Ironically, as regulations and specifications continue to curtail our industry, the net effect is an increase in the cost of rock excavation. As taxpayers, we suffer needlessly by paying more for government funded construction projects. As blasting professionals we are additionally penalized through loss of work.

Jan 1, 2001

By J P. van Dyk

A new crude ilmenite beneficiation process was recently proposed that allowed for the preparation of a smelter grade ilmenite from ilmenite with elevated chromium content. Magnetising roasting was not utilised in the process. As part of this circuit an ilmenite low susceptible reject stream was produced that had a low magnetic susceptibility. In this article a magnetising roasting process was investigated to beneficiate this material. Tests were conducted on material produced by pilot scale simulations on a typical South African East Coast heavy mineral reserve. The results obtained were compared to those published in literature for crude ilmenite. The small-scale experiments were used to define approximate operational limits for the oxidising roasting of a low susceptible ilmenite low susceptible reject stream, although industrial roasting conditions may differ significantly from those obtained in laboratory units. In a next phase these results will be confirmed on pilot plant scale.

Jan 1, 2001

By M Freeman

In a visionary move, the Planning Commission and the Ministry for Planning in Western Australia decided to invite three extractive industry quarry operators, local government councils and State Government departments (Minerals and Energy, Environmental Protection, South West Development Commission) to contribute jointly to study the impacts of blasting on areas surrounding basalt quarries in the Bunbury region of WA. The results of the study will help establish suitable zones in which land uses will be controlled under a proposed Greater Bunbury Region Scheme and in local planning schemes, to minimise conflicting land uses. This paper discusses the blasting program conducted to characterise and model the vibration behaviour of the rock under the effects of pilot-scale and full production blasting, and highlights some of the benefits achievable when a thorough blasting impact program and assessment is conducted at the planning stages of land-use establishment.

Jan 1, 2001

By S. Viswanathan, A. S. Sabau

"Dimensional changes between a pattern die and its corresponding investment casting part occur as a result of complex phenomena such as thermal expansion/contraction and hot deformation (elastic, plastic, and creep) during the processing of the pattern material (wax), mold material (shell) and solidifying alloy. Determining the pattern tooling dimensions is crucial to the dimensional control of the investment casting process. To date, computational methodologies have not been applied to the prediction of dimensional changes in investment castings.This paper deals with the evaluation of wax pattern dimensions, which is one important factor in determining pattern tooling dimensions in investment casting. Cerita 29-51, an industrial wax, is considered in this study. The wax pattern dimensions are determined by considering its thermo physical and thermomechanical properties, restraint of geometrical features by the metal die, and process parameters such as dwell time, platen temperature, injection pressure, and injection temperature.IntroductionThe investment casting process involves making a disposable wax pattern by injecting wax into a metal mold, building a ceramic shell mold around the wax pattern by the application of a series of ceramic coatings to the wax pattern, dewaxing the ceramic shell mold, and casting the alloy into the shell mold. Dimensional changes between the pattern tooling and its corresponding cast part occur as a result of thermal expansion, shrinkage, hot deformation, and creep of the pattern .material (wax), mold material (shell), and solidifying alloy during the processing [1]."

Jan 1, 2001

By J. Lobel, M. Bourassa, J. A. Kozinski, B. Peng

Non-isothermal kinetics studies of the reduction phenomenon of electric arc furnace (EAF) dust generated in stainless steelmaking have been carried out. The dust was mixed with carbon as a reducing agent and dolomite as a binder to form pellets. A Thermo-Gravimetric Analyzer (TGA) was used to determine the weight loss of pellets heated at an average rate of 40 K/min. up to a temperature of 1500°C. The degree of metal reduction was calculated by considering the pellet weight loss, and evaporation of moisture, dust, zinc and lead at high temperature. The reduction process was divided into three different steps. The first covers the 300°C to 760°C temperature range (from 7 to 18 min.), the second step ranges between 760°C and 980°C (18 to 24 min.), and the third covers temperatures above 980°C. Each step is characterized by different chemical reactions. Non-isothermal reduction kinetics equations were set up to describe each step. The kinetics parameters such as apparent activation energies and frequency factors were established. It was found that the first step was chemically controlled, while the second step was diffusion-controlled. Reduction behaviour in the third step was strongly dependent on the initial carbon content in the pellet. Chromium oxide (CrO) could only be reduced in this last step. High temperatures and higher initial carbon content favoured the reduction of CrO.

Jan 1, 2001

By G. Glinski, K. A. Pericleous

"Recent advances in new computational modelling techniques such as Lattice-Boltzmann and Dissipative Particle methods offer the prospect of simulating complex fluids such as colloidal and dense suspensions in industrial processes. They are referred to as mesoscopic methods since they lie between molecular dynamics at a microscopic atomistic scale «lO-9m) and traditional macroscopic CFD methods (> 1O-2m). The models behave like a 'coarse-grained' gas consisting of fictitious interacting particles, which are much larger than the real molecules of the actual fluid they represent. Inter-particle forces are set so that the collisions collectively mimic the phenomenological transport properties and flow of the underlying fluid at a macroscopic scale.Much of the developmental work to date has focused on laying theoretical foundations based on thermodynamic and kinetic theory. Successful applications include predictions of macroscopic transport properties of complex fluids and flows in porous media and filters. With the constant increase in computational power, these mesoscopic methods are now sufficiently developed to determine their suitability to simulate complex fluid flows in real industrial processes. This work describes the application of meso scopic methods to the stencil printing of solder pastes in the assembly of electronic components. The aim of this work is to assess the ability of these methods to study the transport mechanisms of individual solder particles suspended in the flux solvent as they enter and fill the micro-apertures of a stencil. This paper demonstrates the coupling of such mesoscopic methods to continuum CFD methods to predict the flow of dense suspensions (i.e. solder paste) in industrial processes."

Jan 1, 2001

By K. G. Wang, M. E. Glicksman, P. Crawford

"We formulate the mathematical solution to late-stage multi particle diffusion in finite systems. The transition from finite system behavior to that for an infinite system is established. Large-scale simulations are reported regarding the dynamics of phase coarsening. Even in the case of a small volume fraction (Vv = 10-4), the particle size distribution is broader than that for the well-known Lifshitz-Slyozov limit at zero volume fraction. We also report the first simulation studies of extremely low volume fraction, for which corresponding experiments, as well as other simulations, do not exist at present for comparison. However, in the case of moderate volume fractions (Vv = 0.1), the fiucutations in the volumetric growth rate of particles are extracted from our simulations. These simulations provide additional insight into the statistical nature of diffusion interactions, including multiparticle stochastics during microstructural evolution.IntroductionPredicting microstructure evolution in alloys remains one of the cornerstones of materials science. Phase coarsening is a common process in microstrucural evolution that leads to a decrease in the excess total interfacial energy of the system. The system typically consists of separate and identifiable units, or domains, such as second-phase particles distributed in a matrix. During phase coarsening, larger particles grow at the expense of small particles. Over time, this ""competition"" results in an increase in the average size of the particle population, and in a concomitant decrease in the number of particles.Particle size and microstructure of many cast alloys depend on similar coarsening processes. Indeed, properties of these materials, such as strength, toughness, ductility, and electrical conductivity, depend on the material's average particle size and particle size distribution (PSD). Understanding and controlling microstructures in two-phase systems are clearly of widespread technological importance."

Jan 1, 2001

By A. J. Williams, T. N. Croft, M. Cross

"The computational modelling of extrusion and forging processes is now well established. In this work a novel approach is described which utilises finite volume methods on unstructured meshes. This technique can be used to solve simultaneously for fluid flow, heat transfer and non-linear solid mechanics and their interactions. The approach involves the solution of free surface non-Newtonian fluid flow equations in an Eulerian context to track the behaviour of the workpiece and its extrusion/forging, and the solution of the solid mechanics equations in the Lagrangian context to predict the deformation/stress behaviour of the die. Some preliminary examples of this approach will be discussed.IntroductionThe computational modelling of extrusion and forging processes is now well established. Within the last 20 years the finite element method has become the most commonly used technique to simulate metal forming processes [1]-[4]. The Lagrangian and Eulerian type of formulation have been the two major approaches to this problem.Lagrangian methods are efficient and suitable for handling non-linear problems in which small strains prevail, boundary conditions do not change with the course of deformation, and where mesh distortion is not a critical factor in the analysis. Unfortunately, the above points are essential to any accurate metal forming analysis. The problems of mesh distortion and element entanglement pose a serious drawback on the use of such methods. Some automatic remeshing techniques have been developed for Lagrangian finite element analyses of metal forming problems [5]-[7]. However, these methods are not robust and efficient enough to remedy the mesh distortion problems in general. An alternative is to update the mesh manually but this is not always possible, and even when it is feasible it involves major interaction by the user. In addition, remeshing is usually applied to the whole domain which is not necessary and increases CPU time. The complexities associated with remeshing also affect the ability to parallelise the code."

Jan 1, 2001

By A. V. Tarasov, V. M. Paretsky

"A mathematical model of the low-temperature (soft) nickel oxide reduction (SNOR) in a tubular kiln has been developed including an equation describing changes in the nickel oxide content of the solid material along the length of the kiln; an equation describing the changes in the content of reagents ensuring nickel reduction (i.e., hydrogen and carbon monoxide) in the gas phase along the kiln length; as well as the temperature along the kiln length. The kinetic relationships used for the development of the model had been determined based on experiments conducted specially for this purpose. Model investigations were conducted to determine the distribution of such parameters along the length of the kiln as the contents of metals oxides in the solids, partial pressure of hydrogen and carbon monoxide, variations of the temperature depending on the SNOR process conditions, including the kiln rotation speed. Based on the data obtained, a simplified regression model of the reducing roasting process was developed.IntroductionAt the SeveroNickel complex (Russia) a technology has been developed and is being introduced on a commercial scale for low-temperature (soft) nickel oxide reduction (SNOR) in tubular kilns.The SNOR process has a number of advantages, the main of which are the higher degree of metallization and higher chemical activity of reduced nickel oxide attributable to the lower fusion of the surface of the grains of reduced material due to lower process temperature (800-1000°C) and improved reducing ability of the gaseous phase. However, the fact that the process is conducted in a gaseous phase sets higher requirements to the consistency of its composition necessitating careful continuous monitoring and control of the main process parameters."

Jan 1, 2001

Australia has a long history of underground mining. Even withadvances in open cut mining equipment, techniques andeconomics, many orebodies are still best mined by undergroundmeans. In addition, modern exploration tools are æuncoveringÆorebodies that are at increasing depths. South African mines arecurrently producing from below 3 km, and developing down to5 km depths û it is likely that Australian mines will also becomemuch deeper over the next 20 years. One of the most significanttechnical challenges in deep mines is the problem of heat.Community expectations and legislated standards continue todrive operations towards improving the working conditions inmines. The hazards and costs associated with chronic hotworking conditions (heat illness, poor safety, poor productivity,higher operating costs and poor morale) are also becomingincreasingly recognised (Brake, Donoghue and Bates, 1998). Theexposure of miners to many other occupational hazards has beenreduced over the past 50 years. However, despite air-conditionedcabins greatly reducing the heat stress on mobile plant operators,there are still many Australian mine workers subject to levels ofthermal stress that existed a century ago. There are severalreasons for this, including a frequently-poor understanding of thephysiology of working in heat by mine management, no agreedmining code of practice for working in heat, the lack of a robust,practical-sized instrument to measure heat stress, the costpressures on the industry and, to some extent, deep-seatedtraditional management and worker practices. Howeversignificant progress has been made in many of these areas (Brakeand Bates, in press), with the net result that there is likely to be a trend towards installation of refrigeration of some form in manyAustralian mines in the future. This will add directly to the costof operation, but will also have direct and indirect benefits,including cost benefits. It should also be noted that Australia isnot at the forefront of adopting practices to manage temperaturesin the workplace: South African metal mines usually haverefrigerated cooling, and Canadian mines spend large sums onheating, with heating costs (averaged over a full year) of up to$A1 per tonne mined (Bandopadhyay et al, 1997). The history of mine refrigeration dates back to 1919 when thefirst plant was installed at Morro Velho, Brazil. By 1965, the totalinstalled capacity (worldwide) reached about 100 MW(R)i. Since 1965 the growth in mine refrigeration capacity has beenexponential, with a doubling every six or seven years (Howes andNixon, 1997). South Africa is by far the largest user of minerefrigeration, with over 300 refrigeration machines installed. This paper discusses the key design issues associated with theapplication of refrigeration in underground metal or coal mines.Whilst the emphasis is on large, surface plants, small, surface orunderground refrigeration plants can also be very effective in thecorrect application and many of the principles of design andoperation are the same.

Jan 1, 2001

By K. Ono

A new process for extraction of titanium metal from its oxide is demonstrated. In this process, row material to be reduced is titanium oxide synthesized from ilmenite. The reducing agent is the Ca+CaCI2 two-phase mixture. TItanium is elaborated in the medium consisted of liquid Ca, Caq and solid TI02 at the temperature range 1200 to l300K by means of mixing mechanically the ingredients in the reactor into a smooth paste. Fluidity of the feed which enables continuous scheme depends on the CaCl2 content. The oxygen level of the reduced titanium is the range 500 to 1000 mass ppm varying with the operational conditions. The Ca+CaCI2 reducing agent is taken out from the electrolysis of CaC12 at 11401(, and this CaCl2 is produced by aqueous chemistry conversion using Cl2 gas recycled from the electrolysis.

Jan 1, 2001

By W. G. Davenport

This chapter examines three minor influences on flash smelting's industrial oxygen and oil requirements, i.e.: (a) recycle of molten converter slag to the flash furnace (b) gangue oxides and carbonates (e,g, Ah03, CaC03) in the flash furnace feed (c) minor sulfides (e.g. NiS} in the flash furnace feed. It then examines the. sensitivity of our flash furnace calculations to previously ignored aspects of smelting chemistry -Cu, S and Fe304 in slag and 0 in matte.

Jan 1, 2001

Determining the environmental consequences of green field projects is becoming an increasingly important component of new projects. Feasibility studies are regarded by potential investors as incomplete if a comprehensive Environmental Impact Assessment (EIA) has not been completed. These EIAÆs need to meet various local and international requirements in order to achieve bankability. Heavy mineral mining projects are often located in ecological sensitive coastal zones, and bring with them a suite of social impacts in the mainly developing countries within which they are usually located. This paper draws on experience gained in undertaking EIAÆs for heavy mineral mining projects in Kenya, Mozambique and South Africa, and uses these case studies to identify potential pitfalls. Important lessons include the need to initiate the EIA process as early as possible in the project, in order to develop management systems to mitigate the environmental impacts of exploration. Close and on-going consultation with affected communities is also seen to be critical to the success of the EIA. Proactive participation on the part of the environmental consultants with the project team and all interested and affected parties (IAPs) is important. An EIA commissioned later in project planning makes it difficult for the EIA to contribute in a positive manner to the project. Early engagement with environmental consultants allows the environmental assessment to develop from a report to an actual process, and to become fully integrated with project planning. The proviso is that an initial æfatal flawÆ assessment is required to identify any potential æshow stoppersÆ, in order to meet one of the important objectives of EIA, namely an assessment of whether or not the proposed project is the preferred development intervention in the study area. For more controversial proposals this may require the commissioning of a Strategic Environmental Assessment (SEA), which circumvents some of the limitations of the project level EIA. Whilst confidentiality is a constraint to full disclosure, an open participatory approach to public consultation is essential to add credibility to the EIA process and to gain, at least, the acceptance of the process from the majority of IAPs. Full disclosure is encouraged by organisations such as the International Finance Corporation, who acknowledge that good public consultation costs a lot of money, but bad public consultation costs a lot more! An open approach to disclosure presents understandable difficulties for proponents, as they are required to give up some of their control over the project, and to trust the social scientists engaged in the process. However, independence in the EIA process is critical to its success. This paper will highlight these and other issues by drawing on five case studies to identify lessons learnt, and explore the above themes in more detail.

Jan 1, 2001

By G. W. Harris, P. Mousset-Jones, J. Daemen

"To minimize ore dilution induced by blast movement in surface mines, it is necessary to quantify such movement. This will enable more accurate location of the grade boundaries beneath the surface of a blasted rock pile before excavation. A method has been developed and tested to accurately measure the direction and magnitude of subsurface blast movement. This technique uses a cesium vapour gradiometer and a real-time, differentially corrected GPS system to locate pre- and post-blast position of magnetically enhanced target objects placed within blastholes inside a bench. The procedure developed does not require the blasted rock to be disturbed, and the movement information is available within a sufficient time to allow for modification of the selective mining boundaries for each surveyed blast. It was found that the maximum depth of target detection was 18 m, with the overall accuracy being measured as ±1 m (horizontally) and ± 1.2 m (vertically). IntroductionOre dilution is a critical concern for many mining operations. In some instances, it may be the cause of considerable mineral loss. Where the mineralization is finely grained, sedimentary and disseminated in nature, and exhibits no clearly defined visual ore/waste boundary, there is a heightened possibility for ore grade dilution. In most modern open pit gold mines, it is economically desirable to minimize dilution in the production process through the practice of selective mining by defining pre-blast ore digging boundaries, called digging polygons, on the preblast bench area. The polygons’ positions are defined by sampling the production drill holes, with the resultant assay and survey data being used to estimate the areas of specified grade content within the bench. Once the ore is blasted in the bench, the pre-blast locations of these digging polygons are flagged as designated areas on the broken ore pile. The purpose is for the loader operator to be able to recognize which areas of blasted rock are to be sent to the appropriate processing facility or to the waste dump."

Jan 1, 2001

By Steve Klein

Weak rock is an important consideration in tunnel design and construction due to the difficult ground conditions that are often encountered. Nevertheless, when conditions are favorable high advance rates can be achieved leading to economical tunnel construction. Successful construction of a tunnel in weak rocks depends on correctly anticipating the behavior of these unique materials. The objective of this paper is to provide guidelines that can be used to accurately classify the performance of weak rock in tunnels.

Jan 1, 2001