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This chapter presents an overview of fatal and nonfatal injuries reported to MSHA during 1986-1995. Reportable injuries follow the criteria for reporting specified in 30 CFR 50. These criteria are listed in appendix A. The data used for these analyses came from the MSHA accident, injury, and illness data closeout files for the years 1986-1995. The MSHA data are described in appendix A and methods used in data analysis in appendix B. There may be slight discrepancies between the figures presented here and other presentations of MSHA data for the following reasons: (1) injuries to nonemployees have been excluded from analysis; and (2) injuries identified by MSHA after the files were closed out are not included. Within the MSHA data, there are differences in reporting requirements for operators and contractors. Contractors are required to report only those injuries that occur during certain categories of work (described in appendix A). For this reason, data on injuries among employees of operators and contractors in the MSHA database should not be considered directly comparable. As discussed in the "Introduction," the MSHA data on fatal injuries differ from the CFOI data (chapter 1) because of varying definitions used for the mining industry. As compared to the CFOI data, MSHA data exclude injuries that occurred off of mine property and include injuries occurring at mills and processing plants on mine property. Tables 4-1 through 4-9 and figure 4-1 provide comparisons of injury frequencies and rates among the commodities. These comparisons are followed by sections 4A through 4E, which provide more detailed tables and figures for each commodity separately. The method used to calculate injury rates is described in appendix B. Since denominator data for occupations (lob titles) were available for 1986 only, estimates of rates by occupation for the entire 10 year period are based on extrapolation from 1986 data. For this reason, estimates of injury by occupation should be interpreted with caution. Fatal Injuries A total of 1,078 fatal on-the-job injuries were reported to MSHA during the 10-year period 1986- 1995. The average annual fatal injury rate for all commodities combined during this period was 30.9 per 100,000 full-time equivalent workers. Mine operators accounted for 908 (84%) of the fatalities and had an average annual fatal injury rate of 28.2 per 100,000. While mine contractors comprised only 16% (n = 170) of the total number of fatalities, their average annual fatal injury rate was 2.3 times higher than that of mine operators (65.0 per 100,000). Table 4-1 presents the number and rates of fatal injuries by commodity for operators and contractors. Contractors in metal, nonmetal, stone, and sand and gravel are grouped together, since MSHA data on employment were not available for rate calculations for these commodities separately. The highest average annual fatality rate for the period, 66.5 per 100,000, occurred among metal and nonmetallic mineral mining contractors, followed closely by coal contractors (63.1 per 100,000). Among mine operators, the highest average annual fatal injury rate was in coal (38.9 per 100,000); the lowest was in nonmetal (14.3 per 100,000). Table 4-2 shows the average annual fatal injury rate by type of operation for each commodity for mine operators only. Of commodities with underground mines, all except stone had higher fatality rates at underground than at surface operations of these mines. The highest fatality rate for any operation occurred in surface operations at underground stone mines (124.5 fatal injuries per 100,000 workers). Stone had the second highest fatality rate for underground operations at underground mines (77.9 per 100,000). The highest rate for underground operations at underground mines occurred in metal (87.6 per 100,000). Table 4-3 shows the number and rate of fatal injuries by U.S. Bureau of the Census occupational groups (described in appendix D) for the 10 occupation-commodity groups with the highest fatal injury rates. These data should be interpreted with caution because the denominator used in calculating the rates was based on an extrapolation from data for the year 1986 only, as described in appendix B. Extractive occupations are represented in this group for three commodities: coal, metal, and sand and gravel. Construction trades are included for coal, sand and gravel, and nonmetal. The distribution of fatal injuries by commodity and work activity for mine operators is presented in table 4-4. A description of the work activity categories is in appendix C. Overall, the leading work activity at the time of injury was using or operating tools and machinery (26.4%) followed by constructing, repairing, and cleaning (24.0%), vehicular operations (18.8%), and materials handling (12.6%). The distribution varied by commodity. The largest percentage of fatal injuries occurred while operating tools and machinery in both coal and stone; during vehicular operations in metal; and during constructing, repairing, and cleaning activities in nonmetal and sand and gravel. Table 4-5 shows the distribution of fatal injuries by commodity and MSHA accident classification for mine operators. A description of the MSHA accident classifications appears in appendix E. The largest proportion of injuries overall occurred during powered haulage (28.5%). The

Jan 5, 2000

This surveillance report summarizes data on work-related fatal and nonfatal injuries, illnesses, and hazardous exposures in the mining industry for the 10-year period 1986-1995. The term "surveillance," as used in public health, may be new to many readers of this report. With regard to occupational safety and health, the goal of surveillance is to describe the occurrence of work-related injuries, illnesses, and known hazardous exposures; to identify new hazards that may occur due to the introduction of new technology or other factors; and to assess the effects of preventive measures designed to improve worker safety and health. Surveillance provides an overall picture, which can be used to focus resources on areas most in need of prevention programs or further research. Surveillance generally requires the use of multiple sources of data, all of which have their own strengths and limitations. Surveillance in the U. S. mining industry is complicated by the fact that U.S. national data systems that provide information on mining are based on two different definitions of the mining industry. One is established by the Mine Safety and Health Administration (MSHA), the other by the Standard Industrial Classification (SIC) System [Office of Management and Budget 1987] and the 1980 U. S. Bureau of the Census (BOC) Classification System [U.S. Bureau of the Census 1982]. The mining industry as defined by MSHA is based on the regulatory jurisdiction of that agency. Reporting requirements for injuries, illnesses, and workplace exposures are stipulated under the Federal Coal Mine Health and Safety Act of 1969 and the Federal Mine Safety and Health Amendments Act of 1977. Of note is that the oil and gas extraction industry falls outside of MSHA jurisdiction. The Occupational Safety and Health Administration (OSHA) was charged with enforcement in the oil and gas industry under the Occupational Safety and Health Act of 1970. Under the SIC, the definition of mining covers the extraction of naturally occurring minerals, including liquids (petroleum), gases (natural gas) and solids (coal, metal, and nonmetallic minerals). Exploration and development of mineral properties are also included in the SIC definition of the mining industry. The SIC was developed by the Office of Management and Budget for use in classifying establishments based on the type of economic activity in which they are engaged and serves as the industry classification standard for all establishment based Federal economic statistics. This classification is important for occupational safety and health surveillance because it also serves as the industry classification system for all data on work-related injuries and illnesses collected by the U.S. Bureau of Labor Statistics (BLS). The U.S. Bureau of the Census uses an industry coding scheme similar to that used by the SIC. For the mining industry, the categorization is identical in both systems. Death certificate data made available by the National Center for Health Statistics (NCHS) are categorized under this system. Death certificate data are particularly important for surveillance of mortality from work-related illnesses. Key differences between the SIC/BOC categorization system and the MSHA system can be summarized as follows: • MSHA excludes the oil and gas industry, which is classified as part of the mining industry under SIC/BOC. • MSHA excludes work that is done off of mine property; work off of mine property is included under SIC/BOC if it is performed by an establishment falling into one of the SIC/BOC mining industry codes. • MSHA includes mine-associated mills and processing plants; these are classified under the manufacturing industry, rather than mining, according to the SIC/BOC coding structure. Since the data collected by MSHA and the data collected by BLS and NCHS using the SIC/BOC classification system are both important sources of information on the mining industry and in many cases serve different purposes, data from both systems are presented in this report. In general, data using the SIC/BOC system are comparable across U.S. industries and should be used when comparing mining to other U.S. industries. Much of the data in this report are presented in the form of frequencies or rates. A frequency provides only a count of the number of cases without providing any information about the risk of occurrence. Rates provide an estimate of the risk of injury or illness. The reader is cautioned, however, that rates based on small numbers can be unstable; thus, any inferences should be drawn with care. In this report, no rates are presented for groups in which there were fewer than three cases. The incidence of most injury and illness conditions differs by age, sex, and race. For this reason, data in many surveillance reports are adjusted for these demographic factors. It was not possible to do this for most of the rates in this report because information on demographics was not available. With the exception of the proportionate mortality ratios (PMRs), all data presented are unadjusted. A detailed account of the sources of data is in appendix A. The methods used in data selection and analysis are described in appendix B.

Jan 5, 2000

By Ron Light, Doug Applett

"HistoryThe Nanisivik mine began operation in October 1976 as the world's most northerly metal mine and the first permanent industrial project in the Canadian High Arctic. Located 700 km north of the Arctic Circle on Baffin Island's Strathcona Sound, exploration by Texasgulf Inc. between 1957 and 1970 had outlined the ore deposit. In 1974, Nanisivik Mines Ltd. was formed with Mineral Resources International, the Government of Canada, Metallgesellschaft and Billiton being shareholders, and Strathcona Mineral Services Ltd. providing project management. In 1996, Breakwater Resources purchased the mine from Alberta Energy Corporation Limited which had recently acquired the assets of then owners Conwest Exploration Ltd.Ore DepositThe main ore deposit is very flat, approximately 80 m in width and varying in thickness from 3 m to 16 m. The length of the deposit is approximately 3000 m with satellite zones located on the perimeter of the main zone. The economic mineralization is sphalerite with minor galena and silver. The sphalerite and galena are coarse grained and associated with pyrite as the main gangue component with minor inclusions pf dolomite and calcite within the deposit. The deposit being hosted in a permafi·ost environment creates a number of challenges. Dry drilling is employed in room and pillar production drilling. The permafrost aids in the stability of both the pillars and the back."

Jan 1, 2000

By Noritaka Horii, Katsuyoshi Kakinuma, Hiroshi Yamamura

"ZrO2 and Y2O 3-doped ZrO2 gel film were obtained by spin coating of sol from Zr-n-propoxide, n-propanol, acetylacetone, nitric acid, and water on a silica glass as a substrate. ·Dried gel films crystallized to monoclinic, tetragonal, cubic and their mixed phases, depending on the chemical composition of sol, .firing temperature, and coating cycles. ZrO2 films with highly preferential orientation were successfully obtained from a solution containing a large amount of n-propanol. The highly oriented ZrO2 film was found to have high transparency compared with non-oriented 'films. Electrical conductivity of 8 mol% Y2O 3 doped ZrO2 film was also measured.Introduction3 mol% Y2O 3 doped ZrO2, which has a tetragonal symmetry is ·well known to have a strong mechanical property and a high toughness. (1) On the other hand, 8 mol % Y 2O 3-doped ZrO2 is high oxide-ion conducting material and is applied to oxygen sensor, oxygen pump, and solid oxide fuel cell (SOFC). (2) Sol-gel methods using metallic alkoxide are widely applied for synthesizing ceramics such as high-purity fine particles, thin film, and fiber. (3) For ceramics films, many reports have been made on SiO2, (4) TiO2, (5) and PZT. (6) Several case studies have been done on zirconia film based on the sol-gel method, (7) - (11) but very few on preferentially oriented film and on systematic Y zO3 doping. Almost zirconia ceramic· films reported were prepared by means of dip-coating. Kamiya et al. (12) and Ganguli et al (13) converted zirconia into fiber. Sol from Zr alkoxide is usually very unstable, and a stabilizing agent such as glycol or ß-keton is used beforehand (7) (14)."

Jan 1, 2000

By Fumio Hashiuchi, Yushiro Hirai, Masatoshi Maeda, Toshihiro Nagata

"Increase in the copper smelting capacity at Saganoseki Smelter & Refinery was attained through various improvements in the PSconverters and the flash furnace. Two of the major innovations in the converting process were: a new operational technology which avoids increase in the copper content in the converter slag even when higher copper grade matte (65%) are treated in the slag making stage and a technology which shortens the operational interruption time which is caused by coolant charging. The latter was realized by introducing a new automated coolant charging system with which it was made possible to charge the coolant without stopping the blowing into the converter. These improvements brought about a remarkable increase in · the production capacity per converter and an annual production of 450,000 tons of copper without adding new furnaces was made possible. In addition, good results have been obtained of the tests with modified tuyeres to further increase the production.IntroductionIn a bid to renovate its Saganoseki Smelter & Refinery and to establish a leading production unit in terms of global competitiveness, Nippon Mining & Metals undertook major restructuring efforts since 1994. One of its themes was the shift from· a two-flash furnaces operation to a single-flash furnace operation. The shift was successfully completed in 1996 while maintaining the production at the same level (330,000 tons per annum of copper). Then, the productivity was enhanced to 450,000 mtpy without adding new furnaces through technological and operational improvements. It is now planned to increase the smelting capacity further to 470,000 mtpy this year.Some technological and operational improvements in the matte converting process and the new plan resulted from the tests with modified tuyeres are presented in this paper."

Jan 1, 2000

By Jose M. Gomez-Vega, Osamu Takai, Atsushi Hozumi, Hiroyuki Sugimura

"Ongoing research is reported aimed at improving the properties of mesoporous silica-based coatings on various substrates for optoelectronic or medical applications. Tetraethylorthosilicate (TEOS) was selected as the silica precursor, and amphiphilic triblock copolymers poly( ethylene oxide)- poly(propylene oxide)poly( ethylene oxide) as the surfactant micellar template or structure-directing agents. Cetyltrimethylammonium chloride (CTAC) was also used as a control agent. The effect of the templating agent and type of substrate (glass, Si, and Ti) on the mesoporosity, particularly on the alignment of the mesochannels, has been investigated. Three · different treatments (thermocalcination, photocalcination, and solvent extraction) have been also studied to remove the organic templates.IntroductionThe fabrication of mesoporous silicate-based materials through the utilization of a sol-gel process, where cooperative organization of organic and inorganic species takes place, provides a versatile approach to nanoscaled structures with potential applications in fields such as catalysts, optoelectronics, biomaterials, etc. Compared to conventional low molecular weight surfactants, self assembly of amphiphilic·block copolymers can result in mesostructured materials with larger pore sizes (up to 30 nm).1 Most of the synthetic strategies use silicon alkoxides as the silica precursor, although non-silicate metal alkoxides, e.g; Ti, Zr, Al, and B, have been also used to obtain different mesoporous materials, or even mixed metallic oxide systems. 2 Recently, Yang et al. 3 • 4 were able to synthesii:e a great variety of mesoporous metal oxides ID nonaqueous media using inorganic precursors (metal chlorides) and block copolymers as structure-directing agents."

Jan 1, 2000

By Fuxing Yin, Akira Sato, Yoshiaki Ohsawa, Kohji Kawaharai

"INCRAMUTE alloy (nominally 45Mn-53Cu-2Al wt. %) has a specific damping capacity as high as 0.4, through a solid-solution and aging treatment. The damping behavior of the alloy is highly temperature-dependent and shows a peak near room temperature. The inadequate strength in the high damping condition restrains the practical application of the alloy, as structural components. Ferromagnetic MnB particles are dispersed in the alloy during induction remelting the matrix alloy in an argon atmosphere. Surface modification of the MnB particles by mechanical alloying (MA) and suitable control of the addition process cause a homogeneous distribution of MnB particles in the alloy. In the composite containing 2 wt. % MnB particles, temperature dependence of damping capacity is improved, and higher damping capacity is still retained in the temperatures over 60 °C. Meanwhile, the Young's modulus and tensile strength were also increased by about 20%. The roles of the MnB particles in improving both damping behavior and mechanical properties were also discussed.IntroductionMany viscoelastic materials, such as rubbers, polymers and plastics, have the superior ability to damp vibration and noise. However, in the applications as structural materials the high damping capacities of materials are pursued upon the satisfactory mechanical properties, especially those at elevated temperatures. Damping alloys are finding more and more applications in structures where noise and vibration ·should be ·eliminated. Specific damping capacity (SDC), defined as the ratio of the energy dissipated to the maximum vibration energy stored per cycle, is usually used to evaluate the damping capacity of alloys. INCRAMUTE damping alloy, developed by the International Copper Research Association, Inc., has a nominal composition of 45Mn-53Cu-2Al in weight percent. The high damping· microstructure of this alloy is obtained through the solution treatment at 820 °C followed by a water quench and aging at 400°C for 10 hours followed by cooling to room temperature [1]. With the heat treatment, a SDC peak ·vs. temperature of as high as 0.4 was observed in the alloy at the strain amplitude of about 10-3 while a tensile strength of about 500MPa was sustained."

Jan 1, 2000

By Eddie C. Chou

Phelps Dodge, Inc. (PD) is currently developing a lateritic nicke/Vcobalt deposit in Madagascar. Hazen Research, Inc. provides technical assistance to PD to investigate recovery processes for nickel and cobalt. Various process options were evaluated in laboratory experiments and pilot plant operations. The process selected for the feasibility study consists of feed preparation, high-pressure acid leach, countercurrent decantation wash, sulfide precipitation, sulfide dissolution, solvent extraction, ion exchange, and electrowinning. Among these unit processes, high-pressure acid leach, sulfide precipitation, and sulfide dissolution are applications of pressure technologies. Process development work and design criteria for commercial operations of these unit processes are presented in this paper. Concerns related to scaling in the high-pressure acid leach and the sulfide precipitation processes are discussed. Corrosion of various metal coupons under these environments was examined.

Jan 1, 2000

By K. Eto, H. Akiyama, T. Iwamoto

The Hikoshima smelter carried out an expansion project in 1997 and increased its production from 59,200 t/y to 71,000 t/y. The leaching process and the casting process had production capacities of 84,000 t/y, but because of the electric power situation in Japan, the production capacity in the electrolysis process was limited to 59,200 t/y to justify the production cost. Electrolysis was the bottle neck of the plant. In order to eliminate a part of this bottle neck, and considering the electric power situation in Japan, a way to increase the production during the time when the electric power rate is low was sought. In practice, we increased the number of cells by 36, and further improved the operation procedures in the cellhouse. For example, we improved the working efficiency of the cells, improved the productivity during the night time, decreased the unit power consumption and improved labor productivity. Accordingly, this paper describes the recent operations at the Hikoshima plant.

Jan 1, 2000

By Peter Stiaszny, Andrej Samoilov, Yuri Titovets, Gottfried Hribernig, Nikolai Zolotorevskii

"The model has been developed to simultaneously predict both transformation product portions and mean ferrite grain size from the same common · principles as a result of the austenite decomposition during any cooling path of dual phase steels. The transformation products considered are polygonal ferrite, pearlite, bainite and martensite. The model is based on the classical equations of nucleation-growth theory and also contains some empirical parameters. The chemical driving forces for nucleation and composition of elements at the phase interfaces are derived by computation thermodynamics. The empirical parameters related to the model were determined on the basis of a series of austenite transformation dilatometric curves and grain size measurements for continuous and interrupted cooling of several steel types. The model is aimed to predict phase transformation in the complex cooling conditions of the run-out table of the hot strip mill at YOEST-ALPINE STAHL LINZ GmbH as a part of the computer aided system for prediction and on-line controlling of the mechanical properties of hot-rolled strip.IntroductionThe term ""dual phase steels"" is used to refer to a steel consisting essentially of a dispersion of martensite in a fine-grained ferrite matrix. These steels are of increasing technological interest since they provide a better combination of strength and ductility than any other conventional steel sheet material. The strength is important because it offers an opportunity to produce lighter components, while good ductility is needed to permit easy forming of components. It is generally recognized that martensite plays an important role in determining the strength level of dual phase steels. A full understanding of the role played by the phases in determining such characteristics requires investigating in more detail how to optimize the martensite level of such steels, while maintaining good ductility remains the subject of continued research in the industry."

Jan 1, 2000

By D H. Laubscher

The in situ rock mass rating system û IRMR - leading to the mining rock mass rating system - MRMR - for jointed rock masses has been used (and abused) in mining operations around the world for the past 27 years. Despite the recent development of elaborate design procedures and computer-aided design packages, MRMR remains one of the most versatile and practical mine design systems available. It is important to realise that the rock mass classification system should not be replaced but rather complemented by more sophisticated and detailed design procedures. The classification system is not only the æcrudeÆ method used for initial assessment (as described in some geotechnical literature) but also in many respects a very effective and practical engineering tool. MRMR could, and should be used during the entire stage of mine life as an integral part of the design process. The objectives of this paper are to illustrate using practical case histories from the past decade, some of the pitfalls of the MRMR classification system, to clarify certain misconceptions in its application and update its mining application.

Jan 1, 2000

By Keiji Okumura, Jiayi Shan, Jian Yang, Masamichi Sano

"A new method of deoxidation and desulfurization of molten iron with magnesium vapor has been developed. An immersion tube, which was filled with pellets of the mixture of magnesia and carbon powders, was put into the molten iron. Magnesium vapor produced by carbothermic reduction of magnesia inside the tube was injected directly into the molten iron with argon carrier gas. The effects of temperature and carrier gas flow rate on deoxidation and desulfurization were investigated. A mathematical model of the reactions was developed. The rates of deoxidation and desulfurization were controlled by mass transfers of magnesium vapor in the gas-phase and oxygen and sulfur in the liquid-phase. This method may offer high efficiency for magnesium deoxidation and desulfurization of molten iron.IntroductionMagnesium is a strong refining agent in steel-making processes1 • At steelmaking temperatures, magnesium has a very low solubility in liquid iron, and a very high vapour pressure2 • Deoxidation and desulfurization with magnesium take place essentially through the interaction of magnesium vapor with oxygen and sulfur dissolved in molten iron, and magnesium can change chemical composition of nonmetallic inclusions3 • However, addition of magnesium to the steel bath is dangerous and does not give high efficiency in the refining process4 • Furthermore, as a refining agent, the price of magnesium is higher than aluminium and CaO fluxes. In the present study, a new method of the deoxidation and desulfurization of molten iron was developed using magnesium vapour in-situ produced by carbothermic reduction of magnesium oxide. Pellets made of mixture of magnesia and carbon powders were charged into an immersion tube, which was made of alumina or graphite. The magnesium vapor was injected directly into the melt. The effects of pellet mass, experimental temperature and carrier gas flow rate were studied on the refining rate. A mathematical model of the refining reaction was proposed on the basis of the experimental results."

Jan 1, 2000

By Barend Botha, Trevor Davids

The presence of an extensive soft siltstone layer in the middle of the inter-burden sequence of rocks at Syferfontein Colliery in the Republic of South Africa prompted tests to determine the effect of different mid-column decks of inert material in the siltstone layer. The objective was to achieve significant cost savings in explosives use whilst not degrading dragline productivity. An important factor that had to be considered was that the initiation systems available in South Africa are not accurate enough to ensure simultaneous initiation of explosives decks in a blasthole. A number of inert materials were tested including ash, drill cuttings, river sand and crushed stone. It was found that the ash, drill cuttings and river sand did not effectively attenuate the shock wave and that the risks of sympathetic detonation or partial disruption of one or the other explosives deck in a blasthole was high. This became much worse when the inert material was saturated with water. Crushed rock was the most effective in attenuating the shock wave, but this material was very expensive to use because it had to be imported onto the mine.

Jan 1, 2000

The history and milestones in the evolution of support systems utilised in the mass-mined chrysotile mines of Shabanie and King are discussed in detail. The use of block caving, false footwall or sublevel caving mining methods brings with it some major support problems, which are exacerbated, in our low rock strength mining environments. The paper discusses the various support elements and systems that have been used successfully or otherwise in these operations. Some predictions for the future of rock reinforcing in our ground conditions are highlighted, in relation to geomechanics, levels of mechanisation and production risk analysis.

Jan 1, 2000

By Hiroshi Nakajima, Kotobu Nagai, Toshihiro Hanamura

"Low carbon ferritic steel bars with ultra-fine grain structure was developed through a warm rolling for the first time by the present authors. They show better low temperature toughness than conventionally hot-rolled plates. Hence, the brittle fracture surfaces in Charpy tests were examined in terms of the effective grain size of fracture, compared with those of conventional QT steels. The ductile-to-brittle transition temperatures were in good accordance with those for the QT steels if referred to the effective grain size of fracture: · However, the size was a few times that of the ferrite grain. This means the grain refining is not yet fully utilized from the viewpoint of low temperature toughness. The anisotropy of· the impact properties and the annealing effect of highly dislocated structure on the toughness are also discussed in the present paper.IntroductionFor structural materials, both high strength and good toughness are required. Well-known approaches for obtaining better toughness for steels are as follows:1) Grain refining2) Addition of Ni3) Thin plate effect by cracking parallel to the rolling direction prior to crack propagation4) Contribution of metastable austenite.Among them, only the grain refining can raise the strength and improve the toughness. And it is well known that the finer the ferrite grain size, the lower the ductile-to-brittle transition temperature. For example, in the case of 0.11 carbon steel, the transition temperature decreases linearly to in d 1/2 [1 ]. However, these have been told in the regime of coarse grain size that is larger than 10 µm in diameter. There ~as .been no study dealing with the low temperature toughness in the regime of ultra-fine grain size with a diameter in the order of 1 µm."

Jan 1, 2000

By B. Mishra

The major waste product of the alkaline extraction of alumina from bauxite [Bayer Process] is known as red-mud. Approximately, a ton of red-mud is produced for every two tons of bauxite that is mined. The red-mud produced from Jamaican bauxite is rich in hematite, alumina and titanium oxide. It has been shown that over 90 wt. pct. alumina can be recovered from red-mud by soda-ash sintering and caustic leaching. Hematite can be carbothermically reduced with a degree of metallization of over 94 pct. At this stage, the product could be charged through the tuyeres in an iron blast furnace or smelted to produce pig iron. The mineralogical characteristics of the reduced product are not amenable to magnetic separation for iron recovery. The problems associated with the use of reduced red-mud as an alternative to direct-reduced iron [DRI] has also been discussed. Special attention has been paid to lower the alkali content of the reduced material. If smelted, the concentration of titanium oxide in the slag will be significantly high justifying its recovery by an acid-leach process. This paper describes the successful efforts of iron and alumina recovery.

Jan 1, 2000

By Jun Sugiyama, Hiroyuki Sano, Toshiharu Fujisawa, Hideki Takeuchi, Chikabiuni Yamauchi

"The solid .state electrotransport (SSE) is one of the most promising methods for the elimination of gaseous impurities from chemically active metals, such as rare earth metals. . In the present work, the SSE process was applied for the oxygen removal from praseodymium. The SSE factors, such as effective valence, were measured under the various temperatures, electric field intensities and initial oxygen contents, and the effects of those conditions on the SSE process were discussed. Furthermore, the solubility of oxygen in .solid praseodyillium was also measured·, by using the SSE method and metal-oxide equilibrium method.IntroductionWhen a direct current is passed through a solid alloy, not only electrons but also solute atoms are transported as charge carriers toward the anode or cathode. This phenomenon is referred to as an electrotransport or electromigration. The solid state electrotransport (SSE) is the application technique, based on this principle, to the pUrification of the solid metallic materials.Rare earth metals are used for various functional materials, such as magnetic, optical or electronic materials, therefore their high purity metals are required [l ,2]. However, rare earth metals are chemically active and have a strong affinity with gaseous elements (e.g. oxygen, nitrogen, hydrogen and carbon). In many cases, eliminating operations of gaseous elements have not been always made commercially, because these impurity elements could not be eliminated by usual treatments applied to the purification of ·common metals. As an alternative method, authors have proposed the· application of the SSE process to the elimination of gaseous impurities from rare earth metals. Investigations have been carried out on the yttrium-oxygen and neodymium-oxygen systems and the results were already reported[3,4]."

Jan 1, 2000

By D. Maurice, W. D. Riley, J. A. Hawk

"The increased penetration of wrought aluminum into the automotive market is stimulating a need to separate wrought aluminum from cast aluminum because of: a) the additional value of scrap wrought alloys and b) the increase in the total amount of aluminum automotive scrap will outstrip the demands of secondary aluminum foundry industry. The availability of clean fractions of wrought and cast aluminum and incidentally, a clean cast magnesium fraction will allow increased recycling of aluminum used in the automotive industry.Hot crushing has been tested previously and proposed as a means to separate cast from wrought alunrinum product. The underlying concept is that when a mixture of cast and wrought aluminum is thermally processed and then subjected to crushing action, differences in toughness between wrought and cast aluminum alloys will become more pronounced. Hence, it should be possible for conditions can be established such that the cast material fragments, while the wrought material, having lost much less of its toughness, merely deforms. The two types of product could then be separated by simple sizing methods.In this paper we report on the testing of this concept. We were unable to replicate the results which originally demonstrated proof of concept. Possible reasons for this are discussed, as well as the possibility that the original results may not be as desirable as the current results for subsequent sorting."

Jan 1, 2000

By Kensuke Sassa, Shigeo Asai, Norihisa Waki

"A new method for separating inclusions from a molten metal using a high magnetic field has been proposed. The principle of this method based on the magnetization force has been confirmed in experiments of separating intermetallic compounds imitating inclusions from molten Al-Si-Mn-Fe and Al-Si alloys. In order to measure a magnetic susceptibility, the Gouy's method has been so modified by using a super-conducting magnetic as to work in a high temperature up to 1473K. A theoretical expression for the magnetization force, which is indispensable to evaluate the magnetic susceptibility, has been derived. The magnetization forces acting on intermetallic compounds which were used in the magnetic separation were measured over the range of liquidous to solidous temperatures and the magnetic susceptibilities of the intermetallic compounds were obtained from measured magnetization forces by use of the theoretical expression.I. IntroductionRecent developments in the technology of super-conducting magnets have given rise to the circumstance that a high magnetic field over a relatively large space is readily available without liquid helium. Then, it has been found that a high magnetic field provides magnetic effects to nonmagnetic substances and various interesting phenomena have been reported in the broad science fields of physics, chemistry and biology1). ""A science related to a high magnetic field"" in which many fields are transversally viewed from the standpoint of a high magnetic field2 ) is going to be established. In particular, new phenomena and functions brought by the science related to a high magnetic field are also useful for Material Science and Engineering so that the creation of Materials Science and Engineering related to a high magnetic field"" has been conceived 3).Now, when a substance regardless of being magnetic or nonmagnetic is put in a magnetic field, it feels a magnetization force, which is familiar to such a force that a magnet attracts iron. The force is in proportion to the product of magnetic field strength, its gradient and susceptibility so that a precipitated substance can be separated from a molten metal based on the difference between susceptibilities of a substance and a melt. This is a basic principle of the magnetic separation. So far the application of the magnetic separation has been limited to the separation of ferromagnetic substances from a nonmagnetic medium. A high magnetic field, however, has enabled to separate nonmagnetic substances from a nonmagnetic medium.In this study, a new method to separate inclusions from a molten metal using a high magnetic field has been proposed. The principle of the method was verified by experimental works and the feasibility on the elimination of inclusions in steelmaking processes has been studied"

Jan 1, 2000

By D. A. Horne, V. R. Daiga

Certain steel mill wastes contain significant amounts of zinc oxide due to the use of galvanized scrap during the steel making process. Typically electric arc furnace (EAF), and basic oxygen process (BOP) flue dusts contain 20 to 30% zinc oxide and 40 to 50% iron oxides, along with smaller quantities of lead and cadmium. These materials can be recovered from the flue dusts by using a proven rotary hearth furnace (RHF) process. By-products of the recycling operation include a crude zinc oxide fume, which is captured in a baghouse filtering system, and sponge iron that may be recycled into the steel making operation. Crude zinc oxide properties plus the operating experience from two commercial RHF installations utilizing MR&E's DRyIron™ Process will be presented.

Jan 1, 2000