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By Sergey Komarov, Manuela Diaz, Sano. Masamichi

"Mixing time, bubble behavior and absorption rate of gas injected into a liquid bath through rotary L-shaped lances have been studied by cold models with an effort to improve refining characteristics of metallurgical processes. Two kinds of the rotary lances were tested, namely the single-hole lance and the multi-hole lance. The effects of gas flow rate, bath depth and rotation speed were examined.It is found that when gas is injected through the rotary lances, the mixing intensity and the gas absorption rate are larger than that for the gas injection through stationary lances. The effect of rotation speed decreases as the bath depth and the gas flow rate increase.The multi-hole lance produces much smaller bubbles, which lead to an increase in the volumetric mass transfer coefficient by 3-4 times as compared with the single-hole lance. However, the effect of rotation speed is smaller for the multi-hole lance. The obtained results are explained in terms of the bubble coalescence and fragmentation, the rate of which depends on the departure bubble size and the power supplied to the liquid bath.IntroductionIn recent years, there has been a growing interest in the development of gas injector for metallurgical processes. The majority of the previous work was focused on modification to the injector design to improve mixing and to increase the of chemical reaction rate. These two goals can not be necessarily achieved by the same way. Bottom nozzles and stationary immersed top lances, which have been widely applied to steelmaking processes, are effective for the bath mixing, but have a limit to decrease in the bubble size. This results from a vigorous coalescence occurring between the bubbles when they rise in the molten bath as a bubble swarm.One of the ways to ensure the small bubble size and the effective bath stirring is the gas purging through rotary injectors. A number of studies have been undertaken to improve the refining characteristics by using rotary injectors. All of them are related to aluminum refining. The SNIF equipment (The Spinning Nozzle Inert Flotation) has significantly improved the quality of aluminum products at National Luxemburg Aluminum [1]. Rotary injectors made in the form of a disc have been applied to the Alcoa 622 [2] and the GBF processes [3]. A study of the gas injection by a rotary impeller has been carried out by C. Leroy and G. Pignacelt [4]. All researchers note the significant improvement in removal of sodium, calcium, hydrogen and non-metallic inclusion."

Jan 1, 1996

By R. J. Miller

Mechanized Roof Supports (MRS) have dramatically improved safety and productivity of retreat pillar mining in coal. Due to low capital cost and greater flexibility, retreat panels have in some cases approached the productivity of a longwall. Because of improved safety and rapid set-up time when compared to conventional timbering, MRS are driving a return to retreat pillar mining in many situations. This paper describes how panel layout can be optimized for safety and operational efficiency when using MRS for retreat pillar mining of coal. The potential for significant unit cost reductions will also be addressed.

Jan 1, 1996

By M. Nilmani, J. Sofra

The transverse distributions of the solids discharge velocity and mass flux at the discharge end of vertical and inclined lances were measured in order to detennine the transverse distributions of the axial momentum flux, which is a dominant factor influencing the penetration behaviour of particles into melts during submerged injection. The effects of gas velocity (10 - 30 m/s), solids loading (5 - 10), lance length (0.15 - 1.0 m), lance inclination (vertical downward - horizontal) and particle density (2500 - 8900 kg/m3 ) were investigated, while the lance diameter and particle size were fixed at 10 mm and 220 µm respectively. The particle velocities and mass fluxes were measured by image analysis of particles illuminated in a laser-generated light sheet aligned vertically through the axis of the lance at the discharge point. The particle discharge velocity profiles for vertical downward flows were synunetrical about the centre-line of the lance, with the maximum velocities occurring at the centre-line. The velocities increased with increasing gas velocity, increasing lance length and decreasing particle density in accordance with previous observations. The transverse mass flux profiles were also synunetrical for vertical downward flows, however at the lower gas velocities the peaks in the profiles were displaced from the centre-line of the lance by a fractional diameter of about 0.15. The particle discharge velocity profiles become increasingly asynunetric as the lance orientation was changed from vertical to horizontal, with higher particle velocities present near the top wall of the lance. The mass flux profile also became asyrrunetric as the horizontal orientation was approached, however in this case, the profile became biased towards the bottom of the lance. The effect was much more pronounced for a gas velocity of 10 m/s than for 30 m/s, showing the relatively stronger gravitational influence as the velocity was reduced.

Jan 1, 1996

This paper provides a summary on the use of the POL YCOM high pressure grinding roll (HPGR) for increasing extraction in copper leaching. The energy-efficiency and significant hydrometa1lurgical benefits of the HPGR result in better acid-curing, higher solution application rates, improved copper extraction from various copper minerals and better recovery from high acid consuming ores. The HPGR's metallurgical features such as micro-fracturing, better liberation of disseminated and veinlet copper, increased oxygen and lixiviant penetration lead to higher copper extractions than achieved by conventional crushing. Flowsheet options, operational characteristics and applications for various copper ores are outlined.

Jan 1, 1996

By C. M. Wai

"Metal species in solid and liquid materials can be extracted by supercritical carbon dioxide containing a suitable ligand. This in situ che1ation-supercritical fluid extraction technique offers several advantages over conventional solvent extraction including minimization of organic liquid waste generation and exposure of personnel to organic vapors. One unique feature of this technique is that metal species can be removed from solid materials directly using supercritical carbon dioxide as a solvent. Several ligand systems including dithiocarbamates, B-diketones, organophosphorus reagents, and macrocyclic compounds have been tested for metal extraction in supercritical carbon dioxide. This novel extraction technique may have important applications for metal recovery and mineral processing.IntroductionSupercritical fluid extraction (SFE) offers several advantages over conventional solvent extraction including the minimization of organic liquid waste generation and exposure of personnel to organic vapors.[1] The high diffusivity, low viscosity, and T-P dependence of solvent strength are some attractive properties which make supercritical fluids excellent candidates for extraction and recovery of organic compounds from solid materials [2] Carbon dioxide is a gas of choice for SFE because of its moderate critical constants (Tc = 31 °·C and Pc = 73 atm), inertness, and availability in purified form. After extraction, the fluid phase is depressurized to separate organic solutes from CO2 gas and the gas can be recycled for repeated use. The SFE technology has been applied to industrial scale operations such as the preparation of decaffeinated coffee and hop extracts."

Jan 1, 1996

By L. L. Tavlarides, N. V. Deorkar

"Recovery/Recycling of metal ions from industrial process waste streams is a preferred alternative to disposal by conventional techniques. This paper presents methods for preparation of inorganic chemically active adsorbents to be used in fixed bed adsorbers. Methods for immobilization of chelating agents on the inorganic supports are discussed. The prepared adsorbents are characterized to determine coverage density of functional groups, effect of pH on metal ion removal efficiency, regeneration efficiency and uptake capacity. Results from the laboratory scale and bench scale experiments are presented here.IntroductionRemoval of heavy metal ions from processing wastes in various industries is an important problem. Waste streams in electroplating, electronic, catalyst preparation and hydrometallurgical industries contain metal ions such as copper, nickel, chromium, lead, tin, cadmium, silver, gold and platinum. One major concern for the non-ferrous metal industry is secondary recovery of precious metals and cyanide from cyanide leachate from smelter residue and hydrometallurgical waste streams.Recovery methods recently considered include evaporation, electrolyte metal recovery, reverse osmosis (1), adsorption, ion exchange (2,3), membrane separation (4,5) and Solvent extraction. These processes have met with various levels of limited success. The use of liquid ion exchange molecules to selectively extract metal ions for on-site treatment of these waste streams is currently receiving substantial interest (6,7). This interest seems from an awareness of the advances made in the development of commercial extractants for metal ion separation in hydrometallurgical industries (8). However, separation by solvent extraction processes is generally considered to be economical in the range of aqueous metal ion concentrations from 0.01 to 1.0 mol/lit (9). In order to exploit the selectivity of chelating agents, the idea of immobilizing chelating agent into a solid matrix has attracted growing attention in recent years. Many supports such as inorganic oxides, organic polymers, cellulose powder and polyurethane foam can be used for immobilization of chelating agents. Over the last decade, considerable efforts have been directed toward attachment/introduction of chelating agents into a polymer matrix (10,11). Inorganic supports as compared to polymer supports provide high mechanical strength, chemical and thermal stability, and high reaction rates due to open pore structure. On the contrary, organic resins shrink and swell, thus affecting mass transfer (12). Many of the disadvantages of polymer supports can be excluded by the use of inorganic supports. Innovative use of immobilization techniques can produce inorganic chemically active adsorbents with comparable capacity, stability and reaction rates. Consequently, the objective of our program is the development of inorganic chemically active adsorbents to be used in a fixed-bed unit operation as an alternative heavy metal ion recovery process. Methods of preparation of inorganic chemically active adsorbents, (ICAAs) characterization and applications are discussed in this paper. A brief summary of the results from laboratory scale studies and bench scale studies is presented."

Jan 1, 1996

By Cecil Harriss

Philip Environmental Services Corporation's (Philip's) innovative fluidized bed thermal desorption system recovers mercury from contaminated soil. Referred to as the Thermal Recycling System, Philip has constructed a mobile thermal desorption system that has a processing rate up to five tons per hour. The system includes a continuous-feed system, all radiant heat, inert gas atmosphere, hot gas filter, two-stage cooling, and a water treatment system. Based on treatability studies, the processed soil can meet cleanup objectives as low as two milligrams per kilogram and passes the mercury toxicity characteristic leaching procedure test.

Jan 1, 1996

By Jozef S. Stachula

"INCO Limited operates eleven under-ground mines in the Sudbury area. The mines are located on the rim of the Sudbury Basin, an oval with the axis in the range of 27 km and 60 km. The ore dips to at least 3000 m below surface. The ores are mined primarily for nickel and copper. Total ore production from underground is in excess of 55 000tonnes per day.Over 40 surface fans have been installed since the late 1960s. All of the fans are adjustable pitch, axial flow units. A major factor influencing ventilation design in the last 30years has been the introduction of diesel equipment underground. Volumes per fan have ranged from 60 m3/sec. to 330 m3/sec., with motors from 100 hp to 2500 hp.Fans of the axial flow type have been commonly used for main fan installations at Canadian mines for many years. The standard arrangement has been to mount these fans horizontally, i.e. with the fan shaft and the long axis of the housing horizontal. This is a natural arrangement for an underground fan, but for a surface installation, a vertically mounted fan has definite advantages.The surface area taken up by a typical vertical fan installation is generally about one quarter that of a horizontal fan of the same capacity (Rutherford, 1957). This is not a problem with isolated fans and fat surface out crop sites, but where the installation is to be near existing buildings, or where there are poor surface soil conditions, space and cost considerations greatly flavour vertical fans."

Jan 1, 1996

By D. E. Wakefeld

"My first reaction to Joanna LaForte’s discussion paper is that she has quite properly assumed that I would like the process of equitable participation between aboriginal landowners and mining companies to be a fast process. On the other hand, I have been a business lawyer long enough to know that the past experiences of the parties will have a significant effect on how they will proceed at any one time.In my article, I was trying to convey the importance of responding to the wishes, aspirations and fears of aboriginal communities in Arctic regions without land settlements. I agree that if it is necessary to wait for governments, the process will be quite slow. My article did point out that often aboriginal communities and mining companies who have become comfort-able that a project is in their mutual interest regard the government(s) involved as their common enemy. I agree that the education and training of aboriginals should “expedite the negotiations and end the power struggles equitably”. Also, I did not mean to suggest that the elders distrust of changes in traditional land use was solely due to concern for alienation and separation from their offspring; however, I suspect it is one reason for their caution. I also agree with this author that establishing opportunities that enable the young aboriginal community members to remain in the north and avoid the problems that await them in southern urban culture should be a common concern of the mineral developer and the Arctic aboriginal community.When this author suggests I am “overly concerned about how much land the aboriginals will control, how educated they may become, how ignorant they are of mining procedures, how objections from aboriginals will escalate expenses, etc.”, she attributes to me as “concerns” matters that were intended to be general information for my readers. My references to the increased land holdings and the improvement in education of aboriginal peoples was intended to deter mining companies from any attempt to be inequitable in their dealings with aboriginal communities."

Jan 1, 1996

By E. H. Christiansen

Gem-quality red beryl in the Wah Wah Mountains of southwestern Utah formed as a post-magmatic mineral in a topaz rhyolite flow. Unlike topaz, this beryl occurs along fractures in devitrified rhyolite, rather than in lithophysal vugs. The flow occupies a graben and perhaps a significant paleo-drainage. Beryl occurs at medial depths within the eroded flow, about 170 m below overlying mafic lava flows. Both beryl-bearing fractures and the host rhyolite show an unusual amount of argillic alteration compared with other topaz rhyolite flows. Alteration may be related to the incursion of surface water along shrinkage fractures within the flow. Whole-rock concentrations of CaO within the host rhyolite are very low (<0.01 % to 0.18%) compared with other topaz rhyolites and Be concentrations (about 20 ppm) are about average. Low Ca activities prevented fluorite precipitation and allowed Be transport as fluoride complexes. Beryl probably grew at subsolidus temperatures (-300-650°C), but above the temperature of kaolin development (200-300°C) as fluoride-rich vapors, released by devitrification, encountered fractures and mixed with vapors derived from surface water flowing through the fractures. Beryllium fluoride complexes reacted with water vapor, silica minerals, alkali feldspar, water, and Fe-Mn oxides along fractures to produce red beryl. Continued reaction of the cooling flow with surface water at lower temperatures probably produced a boiling, more acidic fluid that produced the argillic alteration. Consequently, eruption of low-Ca topaz rhyolite followed by entrance of surface water into medial portions of a devitrifying and still hot lava flow appear to be critical factors that led to red beryl formation.

Jan 1, 1996

Profiled on these pages are the eight RMCMI 1996 Scholarship Award winners. All eight winners were present as guests of the Institute at the June convention in Durango, Colorado. Each received recognition at the Institute Awards Luncheon Monday, July 1. 1996. Each state vice president sewed as the host for the collegiate winner and his firm provided travel and hotel expenses. In addition to receiving a plaque from the Scholarship Chairman, Alan Czarnowsky, each winner receives $1,000 tuition credit for the coming academic year, as well as transportation hotel lodging and meals at convention as guests of the Institute. Because this is a continuing award, the winners from the previous year also receive a $1.000 tuition credit in their senior year if recommended by the dean of the college or university and are full time students. A resident from each of the eight RMCMI member states is selected from among Board approved institutions. Criteria for these awards to be made in the spring annually is that the recipient (1) Is a full time sophomore student who will use the tuition credit during the junior year. (2) Be both a U.S. citizen and a resident of the member state. (3) Maintain good academic standing, be pursuing a degree in a mining related field and have an expressed interest in western coal as a possible career path. The scholarship program includes curricula other than in the mining departments, but in engineering disciplines, such as geology, mineral processing and metallurgy. Contributions to this worthy project are tax deductible to each individual RMCMI member or his firm. Through annual donations of $100 or more, the Patrons of the Institute fund the scholarship program. A listing or current donors is found elsewhere in this book. Donations to this worthwhile program are payable to RMCMI Scholarship and may be mailed to the RMCMI Office, 3000 Youngfield Street, Suite 324, Lakewood, Colorado 80215. Profiles of the 1996 Scholarship Winners follow. [ ] ARIZONA WINNER Michelle Begaye New Mexico Tech - Socorro. New Mexico Michelle Lisa Begaye plans to work in a mine near her Navajo Reservation after graduation. She would like to continue teaching the young in her community as she has been doing for the past few years. As a volunteer with the Natani&apos; Trails, she takes at-risk students on wilderness experiences such as rafting, repelling, etc. Active in school, she played the trombone, was in speech and drama, played softball, and was the first female to play football as a right and left tackle. A member of National Honor Society in High Shool, she also made the Dean&apos;s List at Navajo Community College. Michelle will pursue a degree in Environmental Engineering when she transfers to New Mexico Tech this fall. [ ] COLORADO WINNER Nicole Albert Colorado School of Mines - Golden. Colorado Nicole is pursuing a BS in Mining Engineering with a Minor in Mineral Economics - and has already proven her serious intent with her many activities related to mining. She is a member of the Society of Women Engineers; Society of Mining, Metallurgy and Exploration; and has participated in two different projects related to mining, one of which was to clean up a mine tailings site. Nicole enjoys hunting, camping, fishing, softball and horses. Growing up with her father, working at a surface coal mine, sparked her interest in this industry.

Jan 1, 1996

By L. Henry Smith, David C. Arthur

"The Williams Mine is Canada’s largest gold producer, with annual production of 450 000ounces from 2 300 000 tonnes of ore. Highly mechanized and automated underground mining practices are employed in order to achieve and maintain high levels of productivity and minimize costs.The mine ventilation system is modified to include a new vent raise and variable pitchvane-axial fan. This addition allows several fan installations underground to be decommissioned. A substantial net savings in installed horse power is achieved.Heating costs associated with under-ground ventilation air are a significant portion of mine operating costs. Air heating costs are substantially reduced by recovering heat from upcast exhaust air, minewater and compressor cooling circuits. This waste heat is used to supplement propane fired air heating systems for underground ventilation air. An additional benefit is the availability of a heat sink for summer cooling of the compressors.System design, energy savings data and payback calculations are presented."

Jan 1, 1996

By J. K. Brimacombe

"Nearly all the easy things have been investigated in injection metallurgy. Water models have been used exhaustively to study mixing, gas distribution and flow in submerged jets. Mathematical models have been developed with their restrictive boundary conditions to quantify submerged gas jet behavior. While being valuable tools to our understanding of injection metallurgy, there is an obliqueness to their application. What we need now are measurements and modelling on the actual systems, hot and unfriendly, where gas meets liquid at temperatures above l000°C. This is where the challenge lies.AN APPRECIATONThere are those who follow the trail and there are those few who blaze new trails in search of novel concepts and processes. With his restless, inventive mind, Howard Womer is a trail blazer without doubt. Decades ago, he was a pioneer in the pursuit of continuous steelmaking with the WORCRA Process and, today, he is developing new processes for the treatment of waste. He is not only an inventor but has been a professor at the University of Melbourne and was the first Director of Research at BHP. He has influenced the lives of many people, including myself; with his achievements and humanity. Therefore it is most fitting that this symposium should be held in honour of Howard Womer, a luminary in the metallurgical world for over half a century.BACKGROUNDGas injection has been an integral part of pyrometallurgical processes since the early days of Bessemer, then of Pierce and Smith. Today, of course, one cannot imagine pyrometallurgical processes without submerged gas injection to effect reactions for metal extraction and refining, to provide mixing and to inject solids into molten metal, slag or matte. Spurred on by new developments like tonnage oxygen and argon production, the Savard-Lee concentric tuyere and porous plugs, new steelmaking processes have emerged; and now solids injection is changing copper extraction processes. The ingenuity of the extractive metallurgists who drove these developments is inspiring for they have applied gas injection to transform pyrometallurgical processes. Humankind has been the beneficiary.' Today these processes are safer, more efficient, cost effective, less energy intensive and more environmentally friendly."

Jan 1, 1996

DIVERSITY There are plenty of examples to show that diversity has been the fundamental downfall of many organisations, particularly when you consider the international position. What about core business, the return of companies to key competence directions and market focus. The stockmarket for instance defines groups and companies in key groups of core business. The expectation is that companies toe the line and do not diversify across their areas of defined expertise. In essence, the market has given notice that the requirements are to focus and stick to our core business. So what right does the conference have to suggest that diversity is the key to prosperity. Hasn&apos;t the organiser read the book, studied the history, listened to the market - obviously not. Have they got it wrong, My feeling and belief is no - the organisers have got it right. However, the matter is not as simple as first perceived. What is Diversity, or Diversification as I would prefer? Is it a product position? Is it a geographic position? Is it an expansion or change in services offered? Does a gold mining company diversify into copper or diamonds or aluminium or nickel? Does a gold miner in Australia diversify into China or Kazakhstan or West Africa? How do the two relate? They don&apos;t. A successful company will always possess a &apos;core competence&apos; not so much a &apos;core business&apos;. The best example of this is the service company extraordinaire - McDonalds. They don&apos;t sell hamburgers or french fries, they sell a service, a convenience, a lifestyle. The core business is hamburgers and if McDonalds were to diversify further into new styles of hamburgers, I suggest to you they would fail. But if McDonalds were to diversify into other products based on their &apos;core competence&apos;, provision of service, then I would suggest to you they would be very successful. The service procedure, service machine, service system, the formula, stava the rnnetant the nrnrlnrte -

Jan 1, 1996

By Tomio Tsuchiya

A construction method of bored steel H piles enclosed in soil-cement columns was developed by modifying steel H piles from the driven pile method and soil-cement walls from the earth retaining wall method, the latter of which produces cut-off walls and reduces noise and vibration during construction. In this method, as shown in Figure 1, rich mix cement paste is injected into the bottom of a borehole which is pre-excavated by a casing auger, then a steel H beam is inserted before it hardens. Since the high vertical resistance of piles created with this method has already been confirmed by loading tests, we have been investigating the applicability of this method for piles used to temporarily support building loads for top-down construction on raft foundations until the raft foundation is completed. However, in the loading tests, the bearing capacity at the lower end of the pile was measured by loading from ground surface on test piles which had friction cut to eliminate the shaft friction resistance. In other words, the loading tests neglected the effect of overburden pressure of soil above the lower end of the pile. To investigate the effect of the overburden pressure on the bearing capacity at the lower end of the pile, loading tests were carried out on a bored steel H pile of lm diameter (test pile) bored in a compacted sandy soil layer with N-value of 100 to 250 at each stage of a three-step excavation. The results show no significant change in the bearing capacity at the lower end of the pile when the depth ratio of the pile is in the range of 5.7 to 22.7.

Jan 1, 1996

By C. G. Anderson

The treatment of concentrates for the recovery of the precious metals imposes many processing and environmental challenges. Hydrometallurgical technology for recovery of values from refractory precious metal materials has been developed at Sunshine Mining and Refining Company. Historically, conventional pyrometallurgical methods have been used for to recover values from refractory precious metal materials. However, enhanced environmental awareness has worked to constrain typical refractory material processing methods. This hinders and limits the ability of established smelting or roasting technologies to fill the needs of new sources of refractory materials. An alternative is to treat refractory precious metal bearing materials by hydro metallurgical techniques. These methods are considered more environmentally appropriate since they do not produce gaseous pollutants like sulfur dioxide. Industrially, Sunshine Mining and Refining Company employs hydrometallurgical technology to process refractory precious metal materials. The Sunshine antimony leach uses a mixture of sulfur and caustic under ambient pressure and boiling conditions. The Sunshine oxidation leach uses a mixture of sulfuric acid and a minimal amount of sodium nitrite under relatively mild oxygen pressure and temperature conditions. These conditions result in a nitrogen species catalyzed sulfuric acid pressure leach. Since hydrometallurgical technologies provide industrially proven processing options for many types of refractory precious metal containing materials, their usage should be considered. Ample work has been conducted to prove the effectiveness of Sunshine refractory processing technologies on various materials. This has included platinum group metal materials, refractory gold concentrates, silver materials and indium materials. In some cases, complete process flowsheets have been designed to recover both base and precious metals from these materials and to treat the generated waste streams in environmentally sound manners.

Jan 1, 1996

By Mark Hollingworth

"There is general consensus that as the world continues to change at an ever-increasing pace, companies must continually adapt their operations in order to remain competitive. Those that change fast enough, survive; those that don’t, perish quickly. Today, we hear that it is not worth the time preparing corporate business plans as they are out-of-date before the ink is dry. Within the corporate environment of the 1990s, we must “think” strategically, be a “learning organization”, keep our costs low, focus on our core competencies, stay as flexible as possible and create value. So-called “sustainable competitive advantages” can be obsolete before a patent is issued — if its even worthwhile patenting the advancement. This is industry in the 1990s.Now, while all this radical change has been underway in the global industrial environment, what have Canada’s universities been doing to keep pace with the change affecting one of their major stakeholders? Have they adapted their products and services to suit the new market conditions? Have they built closer links to industry to try to understand how better to serve this important client? Do they welcome industry input as to how to redefine their mission, objectives, strategies or their course contents? Do their students graduate with skills ideally tailored for the global mining industry? In the era of communication, can they write high quality reports in English, never mind speak French or Spanish?In an effort to provide Canada’s engineering faculties with a “blueprint” for the future, the Canadian Academy of Engineering pre-pared a report entitled “Engineering Education in Canadian Universities”, published in August1993, which concluded with the following recommendations:"

Jan 1, 1996

By R. DasGupta

The dissolution behavior of gold in ammoniacal solutions at 75°C has been investigated. The variables investigated include concentration of lixiviants, pH of the solution and various oxidants. The anodic dissolution of gold was studied in the absence of oxidants using the potentiodynamic polarization technique. The cathodic reaction of oxidants was studied on a platinum electrode. Tafel polarization tests were also performed to determine the dissolution rate. The overall dissolution of gold in ammoniacal solutions was examined using a mixed potential theory. A comparative study on the role of cupric am mine, oxygen, hydrogen peroxide, sodium hypochlorite as oxidants for the dissolution of gold in ammoniacal solutions has been carried out.

Jan 1, 1996

By G Eastwood, C Joyce, P Ryan, G M. Johnston

Over the years, predictive techniques for Acid Mine Drainage (AMD) and the natural processes affecting acid generation have received considerable attention. Less emphasis has been placed on the sampling strategy and the integration of testwork results with the geological data base. The sampling strategy employed and the development of a geological model to determine the spatial distribution and volume of acid producing material are often crucial for developing cost-effective containment and mitigation measures. The geological model provides a link between the occurrence, timing, destination and placement of mined waste rock. Careful and accurate interrogation of a comprehensive geological database provides this linkage. The AMD testwork program at Cadia in NSW has been designed to identify the temporal selective handling requirements that will be required during operation. Sampling involved collection of representative combinations of all waste rock types identified within an extensive geological database. These samples were subjected to static, kinetic and accelerated weathering predictive tests. Preliminary results have been used to construct a waste block model for the deposit that identifies the quantity and distribution of acid producing material. Integration of the block model with the mine scheduling determines when the material will be mined.

Jan 1, 1996

By Bailey S, Avraamides J

Laboratory-scale experiments were conducted in a mechanically stirred aeration vessel to determine the rusting abilities of aerated water in the presence of various catalysts compared to the industrially used ammonium chloride. The catalysts used were tartaric acid and citric acid, firstly by themselves, and then in later experiments mixed with ammonium chloride. From these experiments it was found that leaching of iron from reduced ilmenite in the presence of either tartaric acid or its sodium salt was much slower than in the presence of ammonium chloride. Citric acid or its sodium salt also give a slower rate of leaching than the ammonium chloride system, but citric acid and its sodium salt mixed in equal proportions produced a rate of leaching approximately twice as fast as the standard ammonium chloride system. When tartaric acid was mixed with ammonium chloride the leaching rate was found to be equivalent to the leaching rate of the same amount of ammonium chloride alone, thus indicating that tartaric acid made no contribution to the leaching in this svstem_

Jan 1, 1996