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By C. L. Jiang

The role of iron ions (Fe2+ and Fe3+) in the flotation of both ore-and coal-pyrite with ethyl xanthate was comparatively investigated. The complete/partial depression of ore-and coal-pyrite in neutral to weakly alkaline solution is due to the formation of ferric dihydroxy ethyl xanthate between xanthate and the oxidation products of pyrite, ferric and ferrous ions. With xanthate as collector, coal-pyrite was found to be nonfloatable above pH6. In the presence of iron ions and between pH6-9.5, the flotation of ore-pyrite was significantly depressed. Ferrous ions have a stronger effect on pyrite flotation than ferric ions in neutral to weakly alkaline solutions.

Jan 1, 1996

By D. J. MacKinnon, Kazi E. Haque

Ammonia present in a variety of mine/mill waste waters was almost completely oxidized to nitrogen by chloride mediated electro-oxidation. A closed circuit operation of preconcentration of ammonia on a suitable adsorbent (e.g. zeolite or a resin) followed by brine stripping of ammonia and electrolysis of the strip liquor seems to have sound technical, economic and environmental merits. The removal of ammonia, cyanide, cyanate or thiocyanate from a mine/mill waste water (e.g. gold mill), either individually or collectively, is also feasible by chloride mediated electro-oxidation technique. Further R&D investigations are necessary for the development of a closed circuit operation for the removal of ammonia, cyanide and thiocyanate; and also to obtain technical data for process cost estimates

Jan 1, 1996

By E. Forssberg

Studies have been carried out with the High Pressure Roller Mill, HPRM, to produce calcium carbonate minus 10 micron. This paper presents the optimization of the specific grinding force of the HPRM system for a maximum energy utilization when limestone is ground. In addition, experimental tests of producing carbonate minerals using the HPRM as a pre-crusher are described in this paper.

Jan 1, 1996

By J. A. Innes

"""The oxygen, next uniting with the carbon, sent up an ever-increasing stream of sparks and a voluminous white flame. Then followed a succession of mild explosions, throwing molten slags and splashes of metal high up into the air, the apparatus becoming a veritable volcano in a state of active eruption.""IntroductionHenry Bessemer F.R.S(An autobiography, 1905)Thank you Mr Chairman for the opportunity to speak: at this, the opening session of your International Symposium on the subject of ""Injection in Pyrometallurgy"". Judging from the list of papers to be presented over the next three days, the Symposium promises to provide a most valuable addition to our existing knowledge base in what is now an extremely active area of R&D investigations. Whilst we have obviously come a long way since Sir Henry Bessemer's pioneering experiments of the mid-19th century, there is still much for us to learn.Most importantly, the Symposium offers a further opportunity to acknowledge the many significant technical contributions made in this field by the Organising Committee's special guest, Professor Howard Worner - one of this country's most respected research leaders.When first approached to give this talk I had two areas of concern. Firstly, I was not entirely clear just what injection metallurgy was meant to cover. How should the overall scope of this particular subject be defined?My second concern related to Howard Worner himself - a man for whom I have the highest personal regard and who, in fact, played a most influential role in respect of shaping my own career. Having already spoken about Howard's achievements on earlier occasions, I wondered what I could sensibly add.Notwithstanding these personal reservations, I am delighted to be here with you this morning. If my thoughts on the meaning and scope of injection metallurgy appear to be slightly off-course, and if Howard should perhaps recognise some repetition in my remarks, then I hope I can be forgiven."

Jan 1, 1996

By Jonathan Peck, Jim Gray

"While the mine developer looks for bigger and better orebodies in countries offering lower risks to development capital, the opera-tor of existing mines is looking for bigger and better ways to use his existing resources. Mining operations today utilize a variety of stand-alone systems for planning and managing their operations. In both small and large mines, payroll, accounting, inventory, planning, and engineering requirements are met using a combination of manual and computer-based systems.Technical advances and new enabling technologies are changing how mines are doing business. PC-based systems are allowing small operations to join the larger mines in using advanced computer-based systems. Advanced monitors are being used in maintenance to track, predict and correct the health of production equipment. Production monitoring systems are used to measure the performance of operating equipment and personnel in real time. This detailed information on how much, where, when, and by whom is being used for proactive management and planning. Ultimately, this information can be used to optimize and control the machines’ activities, eventually leading to robotic and autonomous operation of mining equipment.As the use of technology increases in mining, specific information objectives are being met but other problems are being created. The life cycle of technology is small, and as current systems are replaced by newer ones, integration problems and additional end-user training are created. In addition, onboard monitoring systems can create large volumes of data, data which are frequently archived without being analyzed. Mine operators are also duplicating efforts applying new technologies in an effort to be more competitive, but in doing so are creating interfaces which are only compatible with their own facilities. As system development moved from the centralized mainframe computer to the PC environment, the fragmentation of these systems became more pronounced.To efficiently continue in adapting and utilizing advancing technology, the mining industry needs to develop a system architecture that readily integrates as many sub-systems as possible. This will provide a framework for existing system integration and design guide-lines for future development. The Total Mining System (TMS) concept will allow a network of stand-alone functional modules to be readily integrated with minimal effort. This paper will discuss some of the current technologies cur-rently in use in some surface mine operations.In addition, a description of the information system and communications requirements that will be needed to integrate these components in the future, will be discussed."

Jan 1, 1996

By Y. Z. Zhang

Electrochemical oxidation of arsenopyrite in ferric sulphate media in the absence and presence of bacteria T jerrooxidans has been investigated for the purpose of understanding the dissolution chemistry of arsenopyrite and the bacteria attack mechanism. Mixed potential, polarization resistance measurements, polarization curve, cyclic voltammetry experiments were conducted in a ferric sulphate medium of 10g/L FeH, temp.25-35°C, pH 1.5-2.5 in the absence and presence of bacteria Tjerrooxidans, respectively. For the anodic process, a two-step reaction sequence is suggested by the electrochemical measurements. The initial step at a low potential is described by:

Jan 1, 1996

By V. M. Torres

An empirical correlation to detennine laboratory mill grinding time has been developed. Grinding samples to 90 ± 5# below 147 micrometers was required for a flotation testwork at Companhia Vale do Rio Doce (CVRD) Research Center. The initial samples were all below 1 mm in size with different size distributions and work indices (Wi) ranging from 13 to 23 kWh/st. Grinding curves were determined for some initial samples. A correlation was developed between percent retained on 147 micrometers at a standard time and the time required to grind each sample to the required size. This correlation was then used to grind all samples, based on the preliminary grinding model. Finally, a statistical analysis with the size distribution of all samples was performed. The success of using the correlation was confirmed and an equation was determined using the data set.

Jan 1, 1996

By Animesh Jha, Chris Dometakis

"Without the use of a flux, only a poor dispersion of ceramic phase can be achieved. A molten-flux-assisted ceramic phase dispersion technique for producing aluminium alloy metalmatrix composites has been developed. In this paper, we report the physical chemistry for the dispersion of TiB2 in molten aluminium. In particular, aspects of the interfacial energy and the thermodynamics of the dispersion reactions are briefly discussed for enhancing the volume of dispersion phase in the molten metal and for controlling their morphology. This investigation also addresses the role of molten flux in the fabrication of AI-alloy mmc using a casting technique. The morphological aspects of the dispersion are explained on the basis of the classical theory· of nucleation.IntroductionMetal matrix composites (MMCs), have long been recognised as an important class of material due to their greater wear resistance, specific stiffness and temperature capability when compared to conventional monolithic alloys. Particulate reinforced composites produced by melt casting techniques have been amongst the first MMCs to achieve commercial market viability. The advent of melt mixing techniques such as the Duralcan™ process have enabled low cost, easily fabricated composites based on the AI-SiC and AIAlz0 3 systems to be produced. In this process, uncoated ceramic particles with diameters 10ltm and larger, are incorporated into conventional monolithic alloys with reinforcement levels up to 25 volume percent. The AI-7Si-SiC metal-matrix composites have good wear resistance, high strength, low density and high thermal conductivity. The combination of these physical and mechanical properties has become a major attraction for the fabrication of light-alloy composite disc rotor brakes for the automotive sector2. However, in silicon-free alloys, SiC is thermodynamically unstable above the composite melting point and is extensively attacked by the melt to form aluminium carbide3 :"

Jan 1, 1996

By Robert Matusewicz

Ausmelt Technology has been applied to the recycling of spent pot liner (SPL) generated from primary alnminum production. The process is centered on the Ausmelt furnace, in which the SPL is converted under high temperature, oxidizing conditions to an HF containing gas stream and inert slag. fluorine is recovered from the SPL as HF gas and is concentrated and used to manufacture AIF) for recycle to the aluminum smelters. Approximately 87% of the fluorine can be recovered and converted to AIF), with the remainder being effectively tied up in the by product slag. Cost projections show that the recycling process will be competitive with other processes for SPL. The production and recycling of AIF) provides available credit that significantly offsets the operating cost of the facility. Ausmelt Technology for recycling of SPL is currently being marketed in North America by Ausmelt Technology Corporation in Denver, Colorado, and in the rest of the world by Ausmelt Limited of Dandenong, Australia.

Jan 1, 1996

By Yong Kuk Park

The horizontal cold chamber die casting process can produce a wide range of near-net shape, non-ferrous castings with small dimensional variation, excellent surface finish and very complex geometries. However, top quality die castings can be achieved only when optimal performance of the cold chamber and plunger is maintained during the molten metal injection phase of the process. Cold chambers (shot sleeves) are known to deteriorate fast and sometimes fail catastrophically because of poor design. Catastrophic fracture and wear due to deformation are leading causes to degrade quality, increase downtime and thereby decrease productivity and profitability. Therefore, a systematic approach to minimize irregular and adverse conditions which prevent an intended injection profile, is highly desirable. To eliminate them, design criteria for shot sleeves were developed using analytical tools and available experimental data. The correlation between design and mechanical failures of shot sleeves was shown by the data obtained from the die casting industry. Also, the relationship between die casting process parameters and deterioration/ failure mechanisms were carefully evaluated.

Jan 1, 1996

By E. H. Cho, Q. Luo

Pittsburgh No. 8 coal, cleaned by conventional froth flotation, was oxidized in a 2-L Parr stirred bench-top autoclave. Autoclave tests were carried out for up to 5 hrs under the following conditions: 150 to 225ºC, 60 to 500 psi 02 and 15 to 60 g of coal per 600 mL of distilled water. The oxidation of coal was evaluated by measuring the total acidic group formed on the surface of the coal and by measuring the adsorption (under standard conditions) of calcium ion from a solution. The degree of oxidation of the coal increased continuously, without much leveling off, with increasing oxygen pressure. With increasing temperature, the oxidation of the coal increased sharply between 150 to 175ºC and then leveled off above 175 °C. The adsorption of calcium was >3% on coal oxidized under the most favorable conditions. The adsorption of calcium on coal increased sharply with increasing equilibrium pH. The loss in Btu was found to be sensitive to oxidation temperature. This study concluded that the optimum oxidation of coal is achieved over 3 hrs at high oxygen pressures (e.g., 500 psi) at ~170ºC. This study also concluded that, when measured in terms of calcium adsorption, Btu loss and reaction time, the oxidation achieved in an autoclave is far superior to that achieved in a fluidized bed.

Jan 1, 1996

By M. Manrique

Various pyrometallurgical methods for treating Ilmenite and Zircon concentrates are reviewed. Laboratory experiments, using a thermal plasma reactor, have been performed to evaluate: the conversion of ilmenite to TiC or TiC-Fe and the conversion of zircon to ZrC or ZrC-SiC. Results are examined and possible processing routes are identified.

Jan 1, 1996

By D. Bruce Wilson

The reaction of oxygen and solid aluminum produces the well-known surface coating of aluminum oxide, Al2O3. Thermodynamic properties and kinetic mechanisms of this reaction are extensively documented. Less well-defined are the corresponding liquid phase reaction and reactions which would be characterized. as 'burning' of aluminum. This paper reviews the solid aluminum-oxygen reaction as a foundation for discussing the flammability of aluminum in oxygen-enriched atmospheres. Appropriate thermodYDan3ic analysis and kinetic reaction mechanisms are developed. Available models of aluminum burning are reviewed and evaluated, The appropriate information for design of engineering applications of aluminum in oxygen atmospheres? is summarized.

Jan 1, 1996

By André Piché

"Over the last ten years, several developments have been undertaken to conceive a machine capable of carrying out simultaneously all the mining tasks in hard rock deposits: cutting, mucking, hauling, ground support and dust control.The main advantages of continuous mining over conventional drill and blast is the elimination of the cyclical nature of the actual methods. Other advantages sought are improved stability of mine openings, higher productivity, lower costs, and a cleaner and safer mining environment. Noranda has con-tributed to these developments in a major way. As a member of HDRK, Noranda participated in the development of two mechanical continuous mining machines; the TM60 and the Wirth. Noranda also undertook a development of its own based on the utilization of electricity to break rock. This technology is called plasma blasting (PBT). The concept of plasma blasting is illustrated in Figure 1.When the operating voltage is reached (18kV), the energy is released through a high current switch (500k A) into a coaxial powercable. It is then delivered to the tip of an electrode inserted into a drill hole which is filled with an electrolyte (water). When the energy reaches the electrolyte, it is instantaneously transformed into a high temperature, high pres-sure plasma that produces a shock wave capable of breaking rock(1).After initial testing of the plasma blasting technology in the lab and in the feld, two experimental platforms were constructed. The first one, a test bench, was erected at the Noranda Technology Centre in Pointe Claire, Quebec.(2)The second one is a rock breaker prototype based on a standard diesel-powered carrier (Fig. 2). Each platform was equipped with a 300 kJ pulsed-power module.In 1993, the rock breaker prototype was used for an extensive series of tests in the field. During that campaign, over 700 oversized boulders were blasted. The results of the tests demonstrated that more durable components for PBT were needed. The test bench was then used to successfully develop and test long-lasting components (probe, switch, cable, connector) that can be adapted to industrial platforms leading to the commercialization of the technology."

Jan 1, 1996

There has been some confusion over the selection of discount rates when performing stochastic simulations of a project's net present value (NPV) using risk- adjusted discounting techniques. Some argue that lower discount rates should be used when performing stochastic valuation simulations. This creates higher NPV values and improves the attractiveness of a project. Others argue that the discount rate should not be lowered for these simulations. This paper exposes the source of this confusion. It demonstrates that stochastic simulations do not remove the risk inherent in a project and, therefore-do not improve a project's value to the risk-averse investor. Risk-adjusted discount rates should, therefore, not be adjusted downward when performing stochastic NPV simulations. Stochastic simulations are, however, shown to he useful in several aspects of project valuation.

Jan 1, 1996

By B. J. Jody

At Argonne National Laboratory, we have been developing a potentially economical process to recycle automobile shredder residue (ASR). We identified three potentially marketable materials that can be recovered from ASR and developed technologies to recover and upgrade these materials. We built and tested a field-demonstration plant for recycling polyurethane foam and produced about 2,000 lb (907 kg) of recycled foam. Several 300-lb (I36-kg) samples were sent for evaluation and were found to be of marketable quality. We are also preparing for a large-scale test in which about 200 tons (181 tonnes) of ASR-derived fines «0.25 in. [<0.62 cm]) will be used as a raw material in cement making. A major cement company has evaluated small samples of fines prepared in the laboratory and found that they meet its requirements as a substitute for iron ore or mill scale. We also produced about 50 lb (23 kg) of recycled acrylonitrile butadiene styrene (ABS) from obsolete automobiles and found that it has properties that could be readily upgraded to meet the specifications of the automotive industry. In this paper, we briefly discuss the process as a whole and summarize the results obtained from the field work on foam and fines recycling.

Jan 1, 1996

By Carlos A. Nunes

V-AI alloys have been used commercially to produce pure vanadium by Electron Beam Melting (EBM), as well as to obtain Ti-based alloys (ex. Ti-6AI-4V). The aluminothermic reduction of vanadium pentoxide (V205) is the primary method to obtain these alloys. Concerning the obtention of pure vanadium, earlier studies have indicated alloys presenting Al content between 10 and 15wt% as the most suitable alloys for direct EBM. In the present work we investigated the aluminothermic reduction of V205 in order to define process parameters for the obtention of V-AI alloys with composition in the previously mentioned range. It was studied basically the effect of excess AI, CaO addition and reaction atmosphere (air, argon) on the alloy composition (AI, 0, N). In addition, microstructural analysis of selected alloys by SEM (BSE images) and EPMA (WDX) were also performed.

Jan 1, 1996

By Curtiss O. Ehrsam, M. Naseem Mian

Alaska’s Red Dog Mine is strengthening its position within Cominco’s “Vision 2000”strategic plan by continually improving quality and quantity of production while reducing costs. Red Dog has evolved into a stable and mature operation, after six years of milling experience. A high grade, partially oxidized orebody in the severe Arctic environment, along with competing producers in a volatile metals market, are the continuing challenges facing Red Dog. The Red Dog Mine is striving to meet these challenges with emphasis on operator training combined with creative systems development and increased production. This paper describes developments in operations along with future plans.

Jan 1, 1996

By M. P. Fahey

A significant amount of silca is recovered in the rougher stage of anionic flotation of Florida apatite. This recovery, in the past, has been attributed to both entrainment and cation activated flotation. This study shows that by using a transport factor, it is possible to determine the contribution of each mechanism towards silica recovery. Further, it is shown that the concentration of cations in the conditioning water significantly affects both the amount of silica recovered due to entrainment and true flotation. Further confirmation of this phenomenon was obtained by Ca++ doping of the conditioning water and by using a sodium silicate depressant.

Jan 1, 1996

By D. E. Roberts

Over 425 million used automotive oil filters are discarded in the United States each year. Estimates prior to this research claim that 10% are recycled with the remainder typically being landfillcd. Surveys conducted with ferrous scrap users and oil filter processors as part of this research reveal that at least 15% are currently being recycled as ferrous scrap. Oil filter scrap is not being used by many operations because of concerns with scrap consistency and quality. These concerns stem from trials conducted in the infancy of the oil filter recycling movement. Consistent scrap quality depends both on the content of the used oil filters and the processing technique used to produce the scrap. Technology has advanced since the first recycling trials were conducted by steelmakers. Several different types of scrap are available, including pucks, bricks, cubes, and shred. This research conducted at the University of Missouri-Rolla investigated the content of used oil filters and compares the recyclability of different oil filter sizes and designs. Filters vary by application and vary between manufacturers for a particular application. An understanding of the scrap itself as well as the concerns and problems of both oil filter recyclers and oil filter processors is necessary to increase the number of used oil filters being recycled.

Jan 1, 1996