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By Z. R. Llanos

This paper presents a review of industrial and experimental processes for the recovery of molybdenum, vanadium, nickel, cobalt and aluminum from spent hydrotreating or hydrodesulfurization catalysts. Numerous processes have been developed in a laboratory and pilot scale. However, worldwide, there are only four well established commercial facilities currently in operation. The installed capacity of these facilities exceeds the availability of spent catalysts and may be sufficient to assimilate future increases of spent catalysts. Despite liability risks; significant quantities of spent catalysts are still being landfilled. Changing regulations that may affect the future handling and disposal of spent catalysts are also reviewed.

Jan 1, 1995

During the last few years the quality requirements on roads and railroads have become more accentuated due to the desire to minimise maintenance costs. This has, in turn, led to increasing requirements in the preparation of ballast materials and pavement aggregates. As the access to natural gravel in northern Europe is decreasing (due to lack of availability or by law restrictions) the use of crushed rock material is becoming more and more important. The aim of this paper is to derive and describe a universal method for the prediction of particle size distributions from compressing crusher machines such as jaw- and cone-crushers. Based on a closely defined physical model, expressions which define the size reduction process are derived. Conditions for simplifying assumptions are clearly outlined. The choice and mix of breakage functions is a central subtopic iò the analysis of the crusher machine processes. Known breakage functions are reviewed and evaluated. A new concept for determination of a true breakage operator which is related to physical properties of the crusher device and the size distribution of the feed material is introduced. Finally experimental tests are compared to numerical calculations. The method described in the paper can be a useful tool when designing crushing plants or when optimizing the output of compressing crusher Machines.

Jan 1, 1995

By S. Tyson

The American Coal Ash Association, Inc. (ACAA) is an organization of producers and marketers of coal combustion byproducts. Since 1968, the goal of ACAA has been to gain recognition and acceptance of ccbs as an engineering material on par with competing virgin, processed and manufactured materials by advancing ccb uses that are technically sound, commercially competitive and environmentally safe. The use of ccbs is affected by local and regional factors including production rates, processing and handling costs, transportation costs, availability of competing materials, seasonal adjustments, and the experience of materials specifiers, design engineers, purchasing agents, contractors, legislators, regulators, and other professionals. An annual, survey of coal-burning electric utilities is conducted by ACAA to determine the quantities of ccbs produced and used in the USA. In 1993 approximately 88.5 million tons of ccbs were produced in the form of fly ash, bottom ash, boiler slag and byproduct from flue gas desulfurization (FGD). Approximately twenty-two percent of the combined production of these byproducts was used, while the remaining portion was deposited in disposal areas. The major markets for ccbs include cement and concrete products, structural fills, road-base layers, mineral filler in asphalt, grit for snow and ice control, blasting grit and roofing granules, grouting, coal mining applications, and waste solidification and stabilization.

Jan 1, 1995

By D. U. Gustafsson

After half a million meters drilled with Wassara we are now confident that ITH hammers powered with simple water will become an established product for production drilling. Today four drill rigs in LKAB Malmberget equipped with Wassara drill about 25 000 m per month of 4 1/2" holes. In Kidd Creek, Canada, Was sara is used for production drilling in stopes with good results. The first Wassara 6" hammer has drilled a 36 meter long, completely straight horizontal cut hole for drifting in the LKAB Malmberget Mine. Main advantages are about doubled penetration rate, very good air quality and improved hole cleaning which facilitates stabilized drilling. Disadvantages are resistance to new technology and, in some cases, the increased use of water.

Jan 1, 1995

By Orlando C. Gaspar

The textures of the ores, the fine mineral intergrowths, the complex distribution of the deleterious minor elements, and the low base metal contents in some ore types, pose many technological problems to the beneficiation of the volcanogenic massive sulphides occurring in the Iberian Pyrite Belt. In particular fine intergrowths of the base metal sulphides with pyrite impose extremely fine liberation sizes (Kao=15 to 25um). The mineralogical, textural and metallogenic studies have provided an understanding of the distribution of vertical and lateral metal zoning in the ore bodies. Mapping of the ore types, carried out by mine geologists, and the metal zoning patterns computed from data base have shown that ore types are distributed as ore lenses, and that vertical and lateral base metal zoning exists in several orebodies. Since ore processing efficiency is affected by ore textures, and because the same mineral often shows different textural features, a relationship between the textures of the feed ores and those of the middlings must be established for all ore types defined at the deposit scale. For supplying, on time, the information needed for the optimization of the concentration processes, empirical methods of determining the mineralogical and textural characteristics of the several ore types have been developed.

Jan 1, 1995

By J. D. Miller

Fluid flow phenomena and therefore the flotation efficiency of air-sparged hydrocyclone (ASH) flotation are strongly dependent on the operating and design variables such as air flow rate, slurry flow rate, underflow and overflow opening areas, percent solids in the feed, reagent levels, particle size, ASH length, etc. Time-averaged multiphase flow characteristics, as deter-mined by x-ray CT and described in a previous publication, are used to understand and explain the steady-state ASH flotation of quartz. A detailed parametric study of quartz flotation by a nominal 2-inch diameter air-sparged hydrocyclone (ASH-2C) revealed the influence of these variables on the flotation response which is discussed in terms of the multiphase flow characteristics. Thus, a phenomenological description of quartz flotation has been established to assist in the further development and utilization of the ASH technology.

Jan 1, 1995

By Jean-Michel Rendu

That you are giving the Daniel C. Jackling award to me is a great personal honor. But more significantly, it is a recognition that geostatistics has come of age. And since I am considered by many as belonging to an older generation of geostatisticians, I thought that it would be fitting that I reflect on where geostatistics came from and where it might be going. First, though, let me propose a definition of geostatistics. Etymologically, paraphrasing Webster's definitions of "geo" and "statistics," it is "a branch of mathematics dealing with the collection, analysis, interpretation and presentation of masses of numerical data taken from the earth." This definition is most appropriate in the context of mining geostatistics. It includes both classical and spatial statistics. It emphasizes the earth aspect, or the analysis of geologic features. And it should remind the practitioner that geologic input is a critical part of all geostatistical applications. In the 1910s, statistical methods were already used to analyze geological data. However, the origin of geostatistics, as we know it today, is best set in the late 1940s, when H.S. Sichel recognized the lognormal distribution of sample values in the South African gold mines. In 1951, Daniel Krige observed that "it can be expected that the gold values in a whole mine will be subject to a larger relative variation than those in a portion of the mine." In other words, samples taken close to each other are more likely to have similar values than if taken farther apart. This observation is the foundation on which spatial statistics, which characterizes values defined in a multidimensional space, is built. However, the 1950s were marked by studies based on classical, as opposed to spatial, statistics. It was only in the 1960s that the need was recognized to model the similarity between sample values as a function of the distance between samples and that the semivariogram was defined. A theoretical framework was developed by Matheron that supplied an elegant mathematical explanation to the empirical observations made by Krige. Matheron coined the term "kriging" in recognition of Krige's pioneering work on the geostatistical evaluation of mineral deposits. As soon as this theoretical framework was developed, it was possible to bring geostatistics to the academic world. The "Centre de Geostatistiques" was founded in Fontainebleau. Numerous students were trained there, disciples eager not only to improve the theory and develop more sophisticated mathematical tools, but also to spread the new faith throughout the world. Expansion of geostatistics exploded in the 1970s, arguably the most fertile decade if it is judged by the frequency of theoretical breakthroughs, the number of original publica-

Jan 1, 1995

By Abdullah Arik

Verification of computer generated reserve models is essential since the computer does not automatically check the validity of methods and assumptions selected by the user and their results. For the computer to do model verification would require an expert system which would perform tests on the model and determine if the model is valid. Since such an expert system is not available, it is up to users to verify the models they develop.

Jan 1, 1995

This paper reviews the issues of mining machinery automation with special emphasis on underground applications. Automation is desirable because it offers the following advantages: ò increased safety by reducing human exposure to hazards of underground mining; ò higher productivity; and ò reduced wear of equipment. In spite of these advantages and in spite of numerous attempts over the past several decades, mining automation has been a difficult proposition, partly because no two mining operations are exactly alike and these operations are carried out in an unpredictable environment. This is the main difference between automation in factories and in mines and that is why mining automation has been lagging so far behind factory automation. Automation is possible only when the machine 'knows' its workspace. In a factory, this workspace can be 'described' to the machine because it is sufficiently controlled. In a mine, the environment undergoes continuous change and the only way the machine can 'know' its workspace is through real-time sensing.

Jan 1, 1995

By I F. Bell, K P. Hammerschmid

Well planned and executed environmental management plans can reduce life-of-mine operating costs and the need to deal with major environmental issues at the time of mine closure. With proper planning during the exploration, feasibility and execution phases of a project, final closure costs can be reduced. The reduction of closure costs should be considered during exploration and initial feasibility studies and when process facilities, waste rock dumps and tailings impoundments are designed. During the mining of the resource, closure cost reduction will depend on effective and efficient environmental management plans for ongoing land clearance, segregation of mine waste materials, management of mine site water and workshop wastewaters, and the establishment of progressive rehabilitation strategies. These issues are the responsibility of planning, production, technical support and maintenance personnel at an operating site. The successful implementation of environmental plans will ensure that all impacts are reduced and that closure issues with major cost implications are addressed prior to closure of the mine.

Jan 1, 1995

By M. J. Sanzotti

This paper examines the potential for controlling longwall-induced subsidence by pneumatically backstowing the void created by mining with waste rock, and having the process scheduled as a unit operation of the mining activity. Based on a review of background literature, interviews with representatives of various mining companies, public-interest groups, and state and federal regulatory agencies, a hypothetical case-study evaluation of pneumatic stowing in a southwestern Pennsylvania mine site was conducted. The study indicated that current stowing technology cannot keep pace with the production potential of U.S. longwall systems. Further, at the case-study mine site, concomitant stowing would reduce subsidence by only 50% of that incurred during full longwall caving, the longwall coal production rate would decrease from 4000 tons per shift in the non-stowing case to 1500 tons in the stowing case, and a preliminary cost analysis reveals that pneumatic stowing would add $5.25 to $10.50 to the operating cost of producing a ton of coal at the case-study site.

Jan 1, 1995

By E. R. Slatick

The northern and central Appalachian coal basin in the eastern United States has been the source of about two-thirds of the nation's coal output during the 20th century. This region includes parts of Pennsylvania, Ohio, Maryland, West Virginia, Virginia and eastern Kentucky. It covers about 130,000 km2 (50,000 sq miles) of the Appalachian coal basin and ranks as one of the world's most important coal production regions (Fig. 1). The coal industry's heyday in northern and central Appalachia has passed. This was due to competition from other fuels and low-sulfur coal produced in the West and because of the declining use of coking coal for steelmaking. Nevertheless, the region still plays a vital role in US coal production. It currently produces about 40% by weight of the nation's coal (its share is about one-half when measured by the energy content of the coal), contributes substantially to electricity generation and serves as the mainstay of US coal exports.

Jan 1, 1995

By A. D. Davis

A ground-water flow model was developed to simulate the post-mining recharge rate at the Belle Ayr surface coal mine in the Powder River Basin near Gillette, Wyoming. State regulations of Wyoming require that reclaimed lands should provide a rate of recharge that approximates the pre-mining rate. Steady-state calibration and transient simulations showed that the post-mining recharge rate in backfill is at least five centimeters per year, exceeding the original infiltration rate of 0.4 centimeters per year to shallow, overburden aquifers. Major reasons for the increase include the flat topography of reclaimed areas and decreased spoil density. It is expected that the backfill will disaggregate and settle over time, eventually resulting in a nearly constant recharge rate less than five centimeters per year but somewhat greater than the pre-mining rate.

Jan 1, 1995

By Frank E. McCall, John K. Marshal, Fred Garcia

Since the advent of longwall mining systems in the United States, mine operators are increasingly relying on methane drainage techniques to supplement the ventilation system. The most commonly used technique is the vertical gob borehole. The number and spacing of vertical gob boreholes per panel is generally based on experience and underground conditions. To design a more efficient methane drainage systems, mine operators must accurately determine methane gas produced. Thus, mine operators must monitor gas flow and methane gas concentration on every vertical gob borehole on active panels at least once or twice during each 8-hr shift. As the mine grows, it is possible to have more than one operating longwall and many vertical gob boreholes. Thus, daily visits to each vertical gob borehole site can become very time consuming. During weekends when methane gas concentrations typically drop because there is no mining activity, borehole sites may not be visited. To obtain accurate gas flow data, a gob borehole monitoring system was designed and constructed by the U.S. Bureau of Mines (USBM). Gas flow, methane gas concentration, gas temperature, barometric pressure, and vacuum pressure of the exhaust fan are the parameters collected by the system. The system also includes circuitry for automatic shutdown of the exhaust fan and an alarm system before an unsafe condition is created. Telemetry components were also integrated into the system to allow for transmission of borehole data to the mine office. As a test, the system was installed and operated on a vertical gob borehole for six months. Test results indicated that intermittent measurements with hand-held instruments from vertical gob boreholes were always higher than gas flows measurements made by the gob gas analyzer system. This paper describes the system components, operational characteristics, and the results of the test program.

Jan 1, 1995

By C. G. Anderson

Historically, the treatment of orebodies for recovery of valuable constituents presents many processing challenges. In a time of heightened environmental awareness, the constraints placed on processing complex orebodies are becoming more and more pronounced. As such, established technologies are limited in their ability to fill the needs of these emerging sources of raw materials. A prime example of this is in processing PGMs from primary sources. Normally, this type of material is found in a nickel-copper-iron sulfide matrix. Typically, these materials are processed by established pyrometallurgical means. However, other options should be considered. Hydrometallurgical processes are available which offer advantages over pyrometallurgical methods. One of these is the nitrogen species catalyzed sulfuric acid pressure leach used industrially by Sunshine Mining and Refining Company. In 1990, laboratory work was undertaken in cooperation with Stillwater Mining Company to test PGM matte materials from the Columbus, Montana smelter. The initial results were very positive, and they led to a design to recover PGMs in a high grade residue and to recover nickel and copper as valuable products. Handling the iron and other wastes in an environmentally safe manner was also successfully investigated.

Jan 1, 1995

By Gregory S. Parker

The explosives community has seen tremendous technological advances during the past several decades. When this industry was in it's infancy and even past, Powder Monkey's defied the odds by relying on daring and cunning to unleash the power contained in nitroglycerin and black powder. Unlike the manufactured improvements, there has been little in professional evolution amongst the blasting fraternity unless provoked (for the most part) by the government. It is the intent of this author to advance the cause of an industry wide training and certification program, uniform in nature and broad-based enough to be voluntary, giving states whose outstanding programs are already in place, the opportunity to provide input. In creating this type of atmosphere, grandfathering, reciprocity and accessibility would be paramount. With ISEE taking a firm leadership role during the inception and NICET's involvement in the administration, the idea postulated here is intended to spark interest and debate, bringing the inception of such a program to the forefront.

Jan 1, 1995

By J. M. Pugliese

The U.S. Bureau of Mines is developing designs and estimating costs for vertical in situ copper mining wells as part of its in situ mining research program. Conceptual designs and estimated costs for "deep" 1100 m (3600 ft) recovery and injection wells in an undisturbed copper ore zone are presented. Within a single in situ copper mining well, multiple perforated well completions and associated costs are discussed for two ore zones between depths of 370 m (1200 ft) and 550 m (1800 ft). The order of well specifications for designing these wells is explained.

Jan 1, 1995

By M. S. Celik

Salt-type minerals are usually floated with anionic and cationic collectors. Flotation of a number of systems has been reported to remarkably increase above the concentrations where surface precipitation of collector-metal salt is initiated. Some studies attribute this phenomenon to heterocoagulation of oppositely charged collector colloid and mineral particles. In this study, examples are given on boron minerals to demonstrate that the high flotation region occurs when particles, colloidal precipitates and bubbles acquire a similar charge which induces Van der Waals interactions resulting in hydrophobic bonding.

Jan 1, 1995

By Stanislaw Nawrat, Waclaw Dziurzynski

An increasing concentration of coal production, especially in the circumstances of intensive methane inflow makes the coal mine managing staff apply new techniques of safe mining. It paves also the way for scientists to develop new directions of investigations and implementation of state-of -the- art technical solutions. Simultaneously, it could be noticed that the funds assigned for expansive 'En situ ' investigation are continuously decreasing. Better and better results are reached when applying computer technique in calculations of the parameters of ventilation process. Recent theoretical and experimental investigations of air and gas (methane) flow in longwall areas with caving, combined with the implementation of methane drainage system allowed to create, a mathematical model and consequently to elaborate a computer supported numerical simulation of discussed phenomena. The mathematical model has been modified and the simulation program was prepared in such a way that the software is convenient for a user looking for an optimal solution. The paper presented the methodology of optimal choice of following parameters: - ventilation system - rate of flow through the wall. The procedure takes into consideration keeping a safe level of concentration methane in air flowing through the longwall as well as the criterion of maximum methane concentration within the methane drainage pipe line. Results of variant computer simulation regarding the longwall with caving are shown in graphs and tables.

Jan 1, 1995

By C. L. Lin

A PC image-based on-line coarse particle size analyzer has been developed to measure particle size distributions under plant situations where overlapped particles are being transported on a moving belt conveyor. Although previous testing had shown satisfactory performance of this image-based system for separated particle size measurements (the non-overlapped case), it was necessary to modify original algorithms in order to solve the overlap problem and make the system suitable for plant operations. On-site testing has been conducted at a large copper concentrator in the southwestern U.S. for further investigation of the overlap problem.

Jan 1, 1995