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By M. S. Moats

The treatment of oxidized residues of zinc with high iron content continues to present a technical challenge in both the steel and zinc industries. Two main problems are commonly identified and include high treatment costs and environmental concerns about contaminated, iron-bearing residuals. A new approach to this problem is described in which selective separation of the iron and zinc into salable products may be potentially feasible. The waste material is first leached to give a solution having an approximate concentration of 110 g/l Zn, 15 g/1 Fe and 40 g/1 H2SO4 and other impurities such as Pb, Cd, Cu and Sb. A suitable organic, such as D2EHPA, is used to load the majority of the iron. The aqueous phase is then acceptable for zinc electrowinning after standard solution purification. The novel step in the flow sheet is the efficient recovery of the ferric iron from the organic solvent using a solid metal to reduce the iron to the ferrous state. The Fe+2 is easily stripped into an aqueous phase in a relatively pure form, suitable for use in water treatment. Process parameters and possible flow sheet designs are described and discussed.

Jan 1, 1995

By M. Rieber

The recent history of the mercury market results almost entirely from U.S. Government actions. Its derived demand has been curtailed by U.S.E.P.A. mandates; its supply has been augmented by U.S.D.L.A. controlled stockpile releases. The resultant prices have altered its market structure, impacted mercury mining, refiners and recyclers, and affected international production and markets. From a marketplace product mercury is rapidly becoming a disposal problem. Other minerals may follow in its wake. This paper reviews developments in demand, particularly in relation to environmental constraints. Supply side impacts are considered. The impact of stockpiles, both as a market overhang and as a potential supply is reviewed. Government stockpile disposal activity is emphasized, but the size, estimated disposal rate, and quality of the private stockpiles are considered, as is the potential availability of additional material from shut-in mines.

Jan 1, 1995

Blasting in Norwegian mines is often carried out by contractors who tend to look for the cheapest solution, without concern about fragment quality. The requirementsfor a contractor are usually only related to the maximum size of boulders and the quantity per month. Even when the owners of the mine are responsible for blasting, very little effort is made to optimise the blasting process. This paper presents test methods which were used and results from small-scale and full-scale blasting tests. In the small-scale tests, cubes 500 x 500 x 500 mm of four different rock types were blasted in a chamber, using two types of dynamite explosive. The velocity of detonation (VOD) for the dynamite explosives was 3000 m/s and 6000 m/s respectively. Three cubes of each rock type were blasted with each type of explosive, and a total of six cubes of each rock type was used. The entire muckpile (approximately 350 kg) was- sieved and weighed after each blast and fragments between 8-16 mm were tested for impact values and flakiness. The results of these tests clearly showed improvement in fragmentation the closer the acoustic impedance ratio of the explosive (VOD x density) over the rock (Cp density) was equal to one. The results also showed that the quality of the fragments (in terms of impact values) tends to be better when the cubes are blasted with the high velocity dynamite.

Jan 1, 1995

By N. Menad

Thermal treatments of five different types of non-ferrous metallurgical wastes, under controlled atmosphere, were carried out at temperatures lower than 800 °C. The aim of these treatments was to reduce the toxic elements content and to increase that of valuable metals in the residue. <Best results were obtained by their treatments in air or hydrogen or successively both of them. Simple treatments using air or hydrogen of three samples allowed the elimination of more than? 95 % of their toxic elements and&apos; almost doubled their valuable metals&apos; concentration. For the rest two samples, combined treatment was necessary for their efficient decontamination and the concentration of valuable metals, in the treatments residue, to a reasonable value. Most of the solids issued from these treatments can be recycled in .the current non-ferrous metallurgical processes.

Jan 1, 1995

The use of controlled recirculation can be dated back to the early 1930s. Although this method has been applied in many mines since then, a generalized comprehensive network analysis is still lacking. This paper presents a unique approach in which the ventilation network with a controlled district recirculation is divided into two subsystems: a main subsystem and a recirculation subsystem. The subsystems are analyzed individually and the results and their relationships are then integrated into discussions of the total ventilation system. The analysis of the recirculation subsystem is facilitated by introducing a non-dimensional parameter A, which represents the ratio of the air quantity for the working face to that for the subsystem. As a result, fan and regulator pressures and air power for various recirculation arrangements can be effectively expressed as a function of A and the subsystem air quantity. Numerical examples are included.

Jan 1, 1995

By Joseph C. Milbourne

Tetra Technologies CCIX? (continuous countercurrent ion exchange) system has been involved in a wide range of uranium concentration, separation and purification applications over the past 40 years. Uranium ion exchange applications have ranged from the treatment of copper heap leach solution containing 5 parts per million of uranium to the treatment of high strength sulfuric acid solutions containing several thousand parts per million of uranium. The flexibility and the countercurrent mode of operation and other unique features of the CCIX? have resulted in successful uranium recovery from these solutions and many others.

Jan 1, 1995

By Larry Schneider

"0 ne of the incentives that led to the development of non-electric shock tube initiation systems was the desire within the industry to improve detonator safety. And to the extent that nonelectric initiators are immune to the hazards of stray current and radio frequency energy found on normal blast sites, an advancement in safety has been accomplished. However, as a cautionary note, it is important to realize that there are still many hazards associated with any initiation system. While some of these hazards may differ from those associated with electric detonators, others are identical to those associated with any type of initiation system. For instance, contrary to what some uninformedblasters may believe, lightning remains a hazard when using nonelectric initiation as well as electric initiation."

Jan 1, 1995

By M. Akser

Ilmenite, rutile, and zircon deposits of commercial importance have not been reported to-date from Turkey. However, information from recent reconnaissance activities indicates the possibility of an economically viable heavy-mineral deposit along the Black Sea coast of Turkey in the vicinity of Ormanli, northwest of Istanbul. Consequently beach and sand dune samples were collected from that area for additional analysis. Laboratory methodologies, designed to simulate standard industrial heavy-mineral plant practices, were used to analyze and evaluate the samples. Based on the analyses, and current market needs, none of the deposits in the Ormanli area qualify as a commercial heavy-mineral deposit.

Jan 1, 1995

By Xinghui Meng

The recovery of platinum and palladium from automotive catalysts has been investigated by leaching in iodide solutions with oxidants including oxygen and iodine in an autoclave. An ammonium salt was presented in a neutral leaching solution as a key leaching reagent to achieve high recoveries of the platinum group metals (PGM). The effect of temperature, and concentrations of oxidants and of ammonium salt on the recovery of PGM was examined. Under the experimental conditions studied, the recovery of platinum and palladium was found to be greater than 95%. An economical assessment of this process has also been examined and discussed.

Jan 1, 1995

By P. K. Kaiser, D. D. Tannant

"A support system for large ground convergence conditions or burst-prone ground must contain holding elements (rockbolts, cable bolts, etc.) that are strong yet capable of sustaining large deformations, i.e., they must absorb as much energy as possible. Steel wire rope anchored in a borehole by a friction bolt provides these desired yield characteristics if the frictional anchorage is placed deep enough into the rockmass, i.e., in non-yielding rock or beyond the expected depth of rock ejected during a rockburst. Pull-out tests were conducted on wire ropes anchored by inflated Swellex bolts to assess the feasibility of this support concept. The test results demonstrate that a Swellex bolt generates a frictional anchorage that allows the wire rope to slide at high loads and to absorb significantly more energy than either a Swellex bolt alone, or a cement-grouted cable.The rope/friction bolt combination can be engineered to provide the desired energy absorption and allowable deformation by varying the installed lengths of the friction bolt and the rope. For yielding rope support, the contact length between the rope and Swellex bolt must be short enough to ensure that the rope can slip well before its tensile capacity is reached. A safe maximum overlap length is about one metre for the wire rope used in this testing. When used as support in the backs of drifts, a swaged button on the ropes end must be used to ultimately mobilize the full rope capacity thereby protecting against gravity-driven falls of ground."

Jan 1, 1995

By C. A. Young

The remediation of cyanide (CN-) and nitrate (NO)-) anions in mine and agricultural waters by various photolytic methods has been reviewed and investigated. Photolytic methods such as direct photolysis, homogenous photolysis, and heterogeneous photocatalysis are briefly described and compared. Results and discussions show that each method has certain advantages and disadvantages. For each method, Eh-pH diagrams prove useful for determining reaction mechanisms. Preliminary results obtained for cyanide oxidation and nitrate reduction show that homogeneous photolysis can be superior due to faster kinetics than the other methods. The photolytic methods were individually, not simultaneously, tested and compared. Differences in concentrations of products were obtained and attributed to differences in photoconversion efficiencies and other inherent characteristics of .the photolytic methods. Various reaction mechanisms are proposed in accordance with the literature as well as measurements obtained from solution analysis using ion selective electrodes and ion chromatography .

Jan 1, 1995

By C. Patrick

Annually, the U.S. coal industry generates and must dispose of over 200 million tons of coal refuse, expanding a major environmental problem. The purpose of this research was to investigate the feasibility of utilizing coal refuse as an aggregate in concrete. This paper reports on findings of the initial phases of a project to determine the viability of replacing traditional concrete blocks, used for under-ground ventilation stoppings, with refuse blocks. Refuse was collected from three active preparation plants in Eastern Kentucky and used as the primary aggregate for concrete cylinders. The refuse fell within ranges normally observed for size consist, moisture, and ash. Stress-strain analyses yielded compressive strengths of the refuse cylinders from 59% to 77% of the control group strengths. Low variability within groups while significant differences between groups were found. On-going determination of effects of weathering on the refuse cylinders is being conducted and will be completed in early 1995. The research results are favorable for the future direction of the overall project objectives.

Jan 1, 1995

By Shuguang L, Jing S

Computer controlled truck dispatching systems is a newly-developed technical system in surface mines with shovel-truck technology. The real time dispatching criteria, as the core of optimal truck dispatching software, are analysed and a new criterion, complex dispatching criterion, is put forward. Dispatching criteria previously proposed include: 1. `Earliest Loading&apos; (EL) - to assign a truck to the shovel at which the truck can be loaded earliest. 2. `Max Truck&apos; (MT) - to assign a truck to the shovel at which the truck will have the shortest waiting time. 3. `Max Shovel&apos; (MS) - to assign a truck to the shovel which has been waiting for the longest time. 4. `Minimum Saturation Degree&apos; (MSD) - to assign a truck to the shovel at the branch where the truck flow saturation degree is minimum. 5. `Minimum Saturation Degree with Truck Cycle time consideration&apos; (MSDTC) - as the MSD principle, with the truck travel cycle also considered. 6. `Fixed Dispatching&apos; (FIX) - to assign trucks to fixed shovels. A system simulation model has been set up for truck dispatching system analysis. A few surface coal mines have been selected for case studies. Equipment waiting times and shift production of the system are obtained as the main outputs of the model. Simulation results show that each dispatching criterion has its own applicable range, no one can absolutely dominate the others. For example, when under-trucked, EL and MT criterion can obtain higher production than the MS criterion; when over-trucked, it is vice versa; while for MSD criteria, better results can be obtained no matter how the truck numbers fluctuate. From the view point of shovel output balance, large fluctuations occur for EL and MT criteria, while a good balance can be obtained for other criteria. In the light of dynamic change of mining system conditions, a single dispatching criterion is not necessarily reasonable. A complex dispatching criterion has been put forward to seek the complex optimum effect. Taking the advantage of each dispatching criteria, the dispatching result of a complex dispatching criterion dominates over individual dispatching criterion and a comprehensive optimum effect can be reached.

Jan 1, 1995

By Andrea B. Baldwin

In recent years, federal and state regulatory agencies have tightened air emission standards. Two of the acid gases, hydrochloric acid (HCI) and sulfur dioxide (SO2), are under heavy scrutiny for reduction. . Most traditional scrubbing systems, i.e. wet scrubbers and spray dryers, meet the standards but they typically are high in capital cost, have significant space requirements for equipment, and are difficult to maintain. Dry sodium injection (DSI) is a alternative technology that has been shown to be effective in HCl and SO2 removal while being the inverse to the problems listed with traditional systems. This paper covers the mechanics of dry injection scrubbing using the most effective sorbents, sodium bicarbonate and mechanically-refined trona (natural sodium sesquicarbonate). It presents DSI performance data for Chambers Medical located in Hampton, SC. This facility incinerates local medical and municipal solid waste. Chambers Medical has used mechanically-fined trona for HCl and SO2 removal since late 1991.

Jan 1, 1995

By Ritter K-C, Sturgul J. R, Filess T

The proposed Lihir open pit gold mine is located on Lihir Island in New Ireland Province, Papua New Guinea. The mine will be located within a volcanic caldera, part of which forms the adjacent Luise Harbour. Kennecott Corporation started engineering design work in 1988 and ended in 1993 when a Feasibility Report was submitted to the Papua New Guinea government by RTZ/Kennecott. The project will be managed by the Lihir Management Company. The mining operation will produce approximately 350 Mt of waste and 62 Mt of low-grade ore over the life of open pit mining. Landforms and traditional land use by Lihirians preclude storing mine waste and some of the low-grade ore on land close to the mine site. The mine waste will be composed of hard rock and soft soild like material which cannot be safely used to construct large land waste repositories by truck dumping. Submarine disposal by bottom discharging barges is the only safe disposal method. The barges will also be required to construct a waste platform along the shore for stockpiling low-grade ore. A simulation model of the waste handling system was written in GPSS/H¦ to assist engineers in selecting the optimum size and quantity of barges and loading docks by analysing the interaction between excavators, trucks and barges. The simulation model was written in enough details to model the various functions that will be encountered during mining. Input parameters allowed for variations in the size and number of trucks, shovels, barges and loading docks. Variations in loading, hauling, and dumping times were from user specified distributions. In order to visualise the interaction between the components of the waste mining operation, the simulation was animated using Proof AnimationT""&apos;. It is believed that this is the first application of an animated simulation study for a mine still in the planning stages.

Jan 1, 1995

By Carl C. Nesbitt

A process has been developed to recover and recycle metals from wastes of brass foundries which contain copper, zinc and lead in various quantities. Tests were conducted to evaluate several leachants, including sulfuric acid, ammonia, hydrochloric acid, cyanide and acetic acid, and to determine the optimum leaching conditions, such as air flow rate, initial copper ion concentration, temperature, and agitation strength. Sulfuric acid containing copper sulfate with dissolved oxygen is the most successful leachant. More than 99% of the copper and zinc originally present in the waste was dissolved, while only 0.5% of the lead entered the solution after 14 hours of leaching. The leaching mechanisms of copper, zinc, and lead are proposed. The copper and zinc can be recovered from the solution by electrolytic processing. The unleached residue may be converted to a lead carbonate which can be converted to litharge at 400-450°C and to massicot at temperature above 500°C by calcination.

Jan 1, 1995

By M. S. Klima

Tests were conducted to investigate the potential for recovering anthracite from preparation plant tailings. Samples were collected from tailings streams or slurry ponds of several anthracite cleaning plants. A washability analysis was conducted on each sample. The use of gravity-and surface-based cleaning processes for treating the 28x200 mesh tailings material was examined. Simulations were performed for various cyclone staging arrangements using published partition data for both water-only and dense-medium cyclones. Froth flotation testing was done on both precleaned anthracite and tailings material. Grade-yield curves were determined for various conditions.

Jan 1, 1995

By Omar A. Muhtadi

Brohm Mining Corporation, in conjunction with Geobiotics, Inc. has nearly completed a pilot heap biooxidation test on sulfidic ore from the Gilt Edge Mine near Rapid City, South Dakota. Some results from the pilot testing have shown the correlation between the extent of biooxidation and the increase in cyanide gold recovery seen in the laboratory. Bench scale testing showed approximately a 1: 1 correspondence between percent biooxidation and percentage increase in gold recovery. The economics of large scale biooxidation were also evaluated in terms of increased gold recovery versus the time and cost of biooxidation. In the pilot test, the rate of biooxidation became limited by the acid water neutralization system. Later in the test, measures were taken to overcome this problem. Results from bench scale column bioleach testing showed that the Gilt Edge sulfide ore is quite amenable to biooxidation with a substantial increase in gold recovery with just partial biooxidation. Direct cyanide gold recovery of 51 % on ore crushed to -3/8" was enhanced to 82-85% after oxidation of37% of the sulfide as measured by iron. Laboratory experiments also showed that the slow rate of biooxidation of this ore could be accelerated by removal of metal sulfate build up from the leach liquor. The combination of these normally non-toxic metals became inhibitory to biooxidation if not removed by the neutralization circuit.

Jan 1, 1995

By W. M. Cross

Optical fibers have revolutionized the telecommunication industry, because of their ability to transmit large amounts of data over long distances. Without optical fibers many of the communication technologies on which business, industry and research rely would be impossible. In addition to their use as communication devices, optical fibers are often used as sensors. Despite the great promise that optical fibers have for the development of many types of remote sensing devices, few remote sensing devices have been built for use in the mineral industries. This paper will describe the use of optical fibers as sensors for surfactant adsorption at mineral surfaces.

Jan 1, 1995

By V. Rastogi

Acid rock drainage is the result of exposure of sulfidic materials, such as pyrites and sulfidic ores, to air and water. The oxidation of these sulfides is catalyzed by more than a million times by the bacteria Thiobacillus jerrooxidans and close families. Inhibition of these bacteria can mitigate 98% or more of the acid loading generated. This can be achieved by the use of certain surfactants that are selectively bactericidal to the lithotropic acidophilic bacteria. Bactericides are used in two ways. As periodic or continuous treatments for prevention of acidification of material actively handled and moved, and in controlled release form for reclamation where treatment sets up a change in site microbiology to replace Thiobacillus jerrooxidans with heterotrophic bacteria and creates a stable site without need for further treatments. Use of bactericides begins with laboratory testing of the site material to qualify the site for bactericide treatment and dosage determination. Site specific treatments are designed for active sites and reclamation. Once acid production is controlled, solubilization of metals is correspondingly reduced. Results and economics of use from active and reclamation sites are presented.

Jan 1, 1995