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By Harry D. Lewis

Gilsonite is a lustrous black material that can be easily crushed into a chocolate-colored powder. It is a solid but relatively soft, lightweight hydrocarbon that visually resembles the volcanic glass obsidian. It was once thought to be a type of coal, but because it is thermoplastic it melts rather than bums. Gilsonite is found in commercial quantities only in the Uinta Basin of eastern Utah and western Colorado, where it forms vertical, nearly parallel veins of varying depth, width, and length. Gilsonite from different veins has different properties, most notably variations in softening point and solubility. These differences result in its use in a variety of industrial applications. Gilsonite's earliest commercial uses were in varnishes, buggy paints, and beer vat linings. Eventually it came to be used in more than 160 products ranging from inks to explosives. It is exported from the United States to most industrialized countries throughout the world. Today, due to competition from synthetics and other hydrocarbon products, its use has narrowed to several specific industries. Although sold mostly as a commodity, current research is focused on applications for gilsonite as a value added product. Historical Overview The discovery of gold in California and the dawn of the mining era in Nevada, Colorado, and Utah around 1850 brought a wave of prospectors to the western United States. One of those pioneers, Samuel H. Gilson, is generally credited with a major role in the discovery of gilsonite. The material now known as gilsonite was discovered several times from the late 1860s through the mid-1880s. It was William P. Blake who, after receiving samples of the material, wrote a paper in 1885 describing "a new variety of asphaltum from the Uinta Mountains." He termed the material uintaite. Although Sam Gilson was not the first to discover the mineral, he was an-inventor who used gilsonite in products that he patented. It was his conviction that the substance was of great value, which caused some to refer to it as gilsonite. The term Gilsonite became the registered trademark of the American Gilsonite Co., and it continues to be in use today. When the first company was formed to mine this substance in 1886 it was named the Gilsonite Manufacturing Co. This firm acquired many gilsonite mining claims and marketed a varnish made from the material. It was the unusual properties of gilsonite varnish that attracted the attention of Adolphus Busch of the Anheuser-Busch Brewing Co. In 1889 Anheuser-Busch bought out Gilson's interests and formed the Gilson Asphaltum Co. Busch had been importing asphalt from Sicily for use in lining beer barrels and saw gilsonite as being more readily available and cheaper. Although gilsonite did not work well in this application, Busch did acquire a large number of mining claims in the Uinta Basin. In 1903 the parent firm of Gilson Asphaltum financed the building of an 85-km railroad from near Grand Junction, CO, to Dragon, UT, to haul gilsonite ore to market. Underground mining was initially centered near Dragon and then later at Bonanza, UT, as different veins were mined. The railway was abandoned in 1937 in favor of truck transportation. In 1938 Gilson Asphaltum changed its name to Barber Asphalt Co., the predecessor of Barber Oil Corp. In 1946 Barber Oil teamed with Standard Oil of California to form a partnership, American Gilsonite Co., which today has its operational headquarters at Bonanza, UT. Barber Oil investigated many new uses for gilsonite, including the making of petroleum derivatives such as gasoline. This work led to the construction of a 116-km pipeline to carry slurried gilsonite to a refinery in Colorado for the production of gasoline, fuel oil, and coke. Pipeline operations began in 1957 but stopped when the economics of competing with petroleum became unfavorable, and the refinery was sold in 1973. In 1981 Standard Oil (later Chevron) became the sole owner of American Gilsonite and remained so until 1991, when it sold its interest to Stratford Enterprises Co. of Tulsa, OK. The companies have since been merged and now operate under the name American Gilsonite Co. with headquarters in Salt Lake City, UT. American Gilsonite continues to be the world's largest miner and supplier of the mineral. The American Asphalt Association was formed in 1902 by former stockholders in Gilson Asphaltum. This company mined various gilsonite claims until it was dissolved in 1953 and its properties were sold to American Gilsonite and Gordon S. Ziegler and Associates. The Utah Gilsonite Co. was established in 1920 and mined several claims until 1952, when its holdings were sold to Gordon Ziegler. Several other gilsonite mining ventures have been pursued in Utah, although they were significantly smaller in scale than those described above. There are currently three companies which mine gilsonite resin in Utah. They are American Gilsonite Co., Ziegler Chemical & Mineral Corp., and Lexco.

Jan 1, 1994

By R. S. Krarner

Fly ash, a by-product of coal burning power plants, poses a major problem for the utility industry since most fly ash must be landfilled. These quantities may represent as much as 20% of the total material going into landfills. A major problem with fly ash utilization is that although the ash consists of useable components, ash composition can vary depending on the types of coal burned and plant operating conditions. Ash is first characterized using SEM, image analysis, and chemical methods. Processing techniques were developed to separate ash into various components including cenospheres, magnetic spheres, carbon, and clean ash. These products are again evaluated for various utilizations before being used to produce valuable products such as mullite, activated carbon, fillers in plastics, and concrete.

Jan 1, 1994

By P. A. Hendricks

This U.S. Bureau of Mines (USBM) report identifies and evaluates factors responsible for metal/nonmetal (M/NM) underground mining accidents involving mobile equipment. Information regarding the occurrence and severity of the accidents, the type of equipment involved, the primary and contributing causes, and preventive measures is included. The goal of this report is to provide information that will aid mine operators and safety managers in the recognition of hazards associated with operating mobile mining equipment in an underground mining environment.

Jan 1, 1994

By Richard A. Heckman

Destructive Thermal Technology (DTT) is used in the management of various waste streams. DTT includes Destructive Distillation, Pyrolysis and Classical Incineration. Recent work has more clearly defined the differences in these technologies based upon a more rigorous thermochemical approach. The U.S. Environmental Protection Agency (EPA) has chosen Classical Incineration as the Best Developed Available Technology (BDAT) for the management of hazardous organic wastes. Municipal Solid Wastes (MSW) and Sewage Sludges (SS) are also managed using Classical Incineration. Three environmental problems plague the use of Classical Incineration. Destructive Distillation, on the other hand, avoids these problems. It is an environmentally benign DTT for managing a wide variety of organic waste streams, including hazardous wastes. Thermochemical analysis of the available data on the performance of three types of DTT will be discussed.

Jan 1, 1994

It has been reported previously that dolomite samples from different locations showed varying flocculation behavior with Poly(ethyleneoxide) (PEO). In this study it is determined that palygorskite associated with the Florida dolomite samples is responsible for their flocculation with PEO. A detailed characterization of the dolomite samples from different locations and its relevance to flocculation with PEO is discussed.

Jan 1, 1994

The accurate estimation of ore reserves along with capital and operating costs are two key components to the successful outcome of any feasibility study. In recent years, there have been many project failures caused by improper estimation of ore reserves. The accurate estimation of ore reserves for any deposit relies heavily on understanding its geology and underlying assumptions unique to the estimation techniques being used. The assumptions unique to commonly used traditional and geostatistical reserve estimation technique will be reviewed. The shortcomings of the estimation techniques and their possible impact on a given project's economic outcome will be discussed. The latest developments in geostatistics in overcoming existing reserve estimation problems will be presented.

Jan 1, 1994

By Bill Morgan

This paper discusses the economic zones of application for several different types of earthmoving equipment: dozers, wheel loaders in load-and-carry applications, wheel tractor scrapers, articulated trucks, rigid-frame trucks and wagons. Only the medium to large pieces of equipment were considered. From this chart (Figure 1), you can see the size range, in tons of carrying capacity, of Caterpillar equipment and the specific models analyzed.

Jan 1, 1994

By W. B. Carter, A. T. Hunt, G. W. Book

"Combustion Chemical Vapor Deposition (CCVDSM ), an open air, flame assisted CVD process, is under development. The CCVD process produces non-line-of-sight, epitaxial deposition. Materials deposited include YBa2Cu3Ox' Y2BaCuOx, BaTiO3, Y2FesOI2, ZrO2, yttria stabilized ZrO2 (YSZ), partially (yttria) stabilized ZrO2 (PSZ), and amorphous silica. Two modifications of the CCVD process are being studied. Liquid fuel CCVD deposition, involves the combustion of an organic solvent that contains dissolved reagents carrying the desired coating cations. Gaseous fuel CCVD deposition uses a flammable gas as fuel. A non-flammable solution containing dissolved reagents is either aspirated into the flame or mixed with the fuel gas as an aerosol prior to its combustion. Substrates to be coated are held near the flames' ends.IntroductionThin films and coatings can be deposited using a wide variety of techniques including chemical vapor deposition (CVD). CVD is ""a materials synthesis process whereby constituents of the vapor phase react chemically near or on a substrate surface to form a solid product.""lIn conventional CVD processing, gases carrying coating constituents flow into a reaction vessel where deposition occurs onto a heated substrate. The deposition process is often conducted at reduced pressure. Both cold and hot wall reaction chambers are used. Heat can be provided by a resistance furnace, rf induction, or high-intensity radiation lamps. Plasma, microwave, photo, laser, RF, and electron-enhanced CVD processes have been developed. The necessity of using a reaction vessel limits the substrate size and affects coating economics. Although most CVD depositions are performed as batch processes, continuous deposition can be accomplished with the use of appropriate hardware.The chemical vapor deposition of thin, dense oxide films has been accomplished in the open atmosphere with a flame assisted process. The process is called combustion chemical vapor deposition (CCVDSM).2 Two modifications of the CCVD process have been developed. The liquid fuel CCVD process involves the combustion of an organic solvent in which reagents (containing the coating cations) are dissolved. The gaseous fuel CCVD process uses a flammable gas as fuel. In this modification, a non-flammable solution containing dissolved reagents is either aspirated into the flame or mixed with the fuel gas as an aerosol of small droplets prior to its combustion. Substrates to be coated are held near the flames' ends."

Jan 1, 1994

By Lloyd R. Nelson

The feasibility of producing low carbon (LC) ferromanganese (FeMn) by lime-'ore' melt refining of high-grade ferromanganese silicon (FeMnSi) was investigated. Thermodynamic simulations demonstrated significant benefits in moving from a single-stage ladle operation to a two-stage counter-current reladling operation (to emulate the commercial Penin Process). The theoretical alloy silicon content was predicted to be refined from 1.57 to 0.005 per cent silicon, at a 6.2 per cent higher manganese yield (yield predicted to increase from 82.3 to 88.5 per cent). Extension of this counter-current refining principle, to a multistage Counter-Current Reaction Launder (CCRL) was investigated using the Slag Metal And Gas Klnetics (SMAK) software to model the mass transfer kinetics of the multicomponent coupled reaction system. Simulation results suggested that commercial production of 50 000 tonnes per annum (tpa) of refined LC FeMn, containing less than 0.5 per cent silicon, at manganese yields of up to 90 per cent, should be feasible in a compact CCRL (7 m long by 0.7 m wide).

Jan 1, 1994

By Gerald R. Smith

Because of continuing concerns regarding the effects of cumulative quantities of materials in the environment, the Bureau of Mines has initiated a series of studies to evaluate, to the fullest extent possible, all aspects of the materials flow sequence fur selected commodities. Although tungsten and its compounds do not pose a significant health hazard to the environment, they do represent valuable resource materials to which appropriate conservation considerations must be given. The present study includes a description of recent trends in the consumption, loss, and recycling of tungsten-containing materials in the United States during the period 1974 to 1991 and an estimation of the cumulative loss of tungsten to the environment since 1910. Obsolete tungsten is recycled primarily as cemented tungsten carbide components that have been used in cutting and wear-resistant applications. The quantity recycled, as a of annual U.S. consumption of tungsten, was estimated to have increased from 10% in 1974 to 341a in 1991. An estimated 58% of the 148,000 metric tons of primary tungsten consumed since 1910 was lost to the environment through means such as dissipation, discard, and dilution.

Jan 1, 1994

By H. Suharyono

The results of an experimental study of polymer-induced flocculation of clay suspensions in continuous, stirred-tank reactors are presented. The effects of polymer dosage, mixing time and mixing intensity are shown to be generally similar to those observed for equivalent batch systems, but flocculation appears to be generally less effective in the continuous process. Settling rates are lower and supernatant turbidities are higher for the continuous system. It is postulated that non-equilibrium effects due to simultaneous polymer adsorption and floc growth can be exploited so as to enhance flocculation in batch systems. The nature of the continuous process, however, offers less opportunity for taking advantage of such effects. Conditions in a continuous flocculation system inherently lead to a closer approach to equilibrium.

Jan 1, 1994

By M. H. Lin, S. Kou

"Czochralski pulling has been a very widely used process for growing single crystals for electronic and optical applications. Dopant segregation can significantly degrade the quality and yield of single crystals. We have used the floating-crucible technique for segregation control in Czochralski pulling, our floating crucibles being unique in that the melt passageway is very long. As such, dopant back diffusion is suppressed, even when the cross-section of the melt passageway has to be relatively large to help the melt go through or when the pulling rate is very low. Single crystals of model materials K-doped NaN03 and Pb-doped Sn have been grown with very uniform dopant concentrations. IntroductionSingle crystals of electronic and optical materials are often doped with a small amount of impurities to develop required physical properties, e.g., P and B in Si for n-type and p-type semiconductors, respectively, and Nd in YAG lasers. Dopant segregation can result in nonuniform physical properties, thus degrading the quality and yield of the resultant crystals.Figure 1 is an illustration of the conventional Czochralski process for crystal growth. Several techniques have been developed to control dopant segregation in Czochralski pulling, including the push-pull technique (1,2), the drop-pull technique (3-7) and the floating-crucible technique (8-13). The first two techniques require precise sensing devices and feedback control systems to keep the feeding rate equal to the pulling rate. The last technique is simple since the feeding rate is automatically equal to the pulling rate."

Jan 1, 1994

By H. Kamarudin

The behaviour of cassiterite-sulphosuccinamate flotation system was examined in the light of zeta potentials measured by micro-electrophoresis method. It was observed that sulphosuccinamate substantially affects the zeta potentials of cassiterite, lowering its i.e.p. to pH 2.5 and indicating a specific adsorption and/or chemical interaction. The optimum concentration for flotation, as seen in micro-flotation tests, was found to be associated with the most effective lowering of the zeta potentials, the optimum pH being 3.0. The effect of cations in the pulp was examined for the presence of ferrous, ferric, aluminium and lead ions. The ions ferric and aluminium were observed to create an intense effect of increasing the potentials to positive side, possibly due to adsorption of cation hydroxy complexes, as indicated by their respective species distribution diagrams.

Jan 1, 1994

By Kazuyoshi Kawami, Fumihiko Sumiya, Kunihisa Katsuyama, Yuji Ogata, Koichi Kurokawa, Yuji Wada

When explosives are detonated in the borehole where there is an air gap between the explosive charge and the borehole of inner wall, the shock cave in an air gap travelling ahead of the detonation front sill be generated. This shock wave is called the precursor air shock wave (PAS). The explosive is precompressed by the PAS, and as a result of that the detonation failure occur on occasion. This phenomenon is well known as channel effect.

Jan 1, 1994

By C. Flores

It is well known that manganiferous silver ores containing manganese intimately associated with silver are not amenable to conventional extraction methods. The segregation process has been applied primarily for recovering copper from oxidized and oxide-sulfide ores. A new alternative process combining segregation roasting followed by flotation to recover silver from refractory manganiferous silver ores, was studied using a 23 factorial experimental design. Laboratory investigations have been conducted on a manganiferous silver ore analyzing 0.02% copper, 0.09% lead, 0.33% zinc, 12.55% manganese and 187 g/ton silver to study the effects of additives salt, coke and copper oxide on silver recovery. Results indicate that 79.3% silver recovery can be attained in the absence of copper oxide and 88.4% when the copper oxide content is 1.5% at '750°C, 2% salt and 1% coke and 30 minutes of roasting time. It was concluded that doping with copper oxide improves silver recovery.

Jan 1, 1994

By G. Ahuja

Tests were conducted to investigate the effects of cyclone geometry, operating conditions, and particle size on magnetite classification. The effects of these parameters on the partition curve for narrow size fractions were studied using a 25mm diameter cyclone cleaning -150 µ m coal. Additional tests were run to investigate the effects of geometry and operating conditions on the slurry, solid, and water splits. The relationship between the relative density of the underflow stream and the relative density of separation was also investigated. This paper presents the results from this study.

Jan 1, 1994

By I. Martinez-Dominguez

In September 1992, mining in Mexico was opened again to foreign investment by President Salinas-de Gortari, after thirty years of "Mexicanization" of mining industry which limited foreign participation up to a 49 % (or 34 % in case of national reserves) on a Mexican mining corporation. During said period mining in Mexico was controlled by four or five big mining companies and besides mining production was focused mainly on silver, lead, zinc, copper and fluorspar. Suddenly in middle of a big crisis on Mexican mining industry due to low prices of minerals in the world and also in a period on which it seems that mining industry in the United States and Canada has been condemned to die for environmental reasons, it appears a new Mexican Mining Law to permit foreigners to participate in mining in Mexico' trough Mexican mining corporations that they may control up to 100 %

Jan 1, 1994

By D. R. Spears

The U.S. Bureau of Mines has had an ongoing interest in developing new reagent schemes for floating Stillwater, MT, chromite ore. Previous reagent schemes have been unsuccessful in achieving complete separation, primarily because little is known about the surface chemistry of the minerals in this ore. In order to design a rational reagent scheme, a study of the binding of various functional groups (R = -H, -OH, -CO2H, -NH2) on the two components (chromite and forsterite) of the Stillwater chromite was undertaken. Electron Paramagnetic Resonance (EPR) Spectroscopy was used to determine the adsorption isotherm, from a cyclohexane solution, of spin-probes which contained the functional group of interest. This was complemented by studies of the saturation surface coverage of the spin probe on the two minerals. In each case, more sites existed on chromite than forsterite; however, the forsterite sites were more strongly binding for each functional group. The results are discussed in terms of their implications for flotation.

Jan 1, 1994

By Patrick R. Taylor

Sub-micron sized boron carbide powders have been synthesized in a non-transferred arc thermal plasma reactor. Precursors for this synthesis are boric acid or boron oxide powders and methane. The powders produced were characterized in terms of size, shape and purity. Methods to increase the purity of the product were evaluated and included hot water leaching to remove unreacted oxides and controlled temperature, air roasting to remove excess carbon. Theoretical results are also presented on the thermodynamics and mechanisms of the synthesis reactions.

Jan 1, 1994

By A. P. Paiva

Studies focused on the recovery of precious metals by solvent extraction have recently increased. either to devise suitable solvents or to clarify the involved extraction mechanisms and kinetics. In this work, a comparison of the performance exhibited by triphenylphosphine (TPP), bis-(penty1thio)-ethane (BPTE) and triisobutylphosphine sulfide CI"I'BPS) in the extraction of silver from acidic chloride media is carried out. Extraction and stripping isotherms involving the three extractants are presented together with the results obtained on the selectivity of silver extraction against high contents of iron, copper and lead. Attempts to clarify the mechanism of silver extraction by TIBPS were performed by studying the distribution coefficient dependence on ligand and chloride concentrations. The effect of temperature on extraction and stripping is also considered. The interfacial tension for the system, measured with different concentrations of extractant in the organic phase, is analysed.

Jan 1, 1994