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By R. L. Nyirenda

The use of ammoniacal ammonium carbonate (AAC) leaching for the treatment of carbon steelmaking EAF dust has been investigated on a laboratory scale. The experiments have been conducted on dust samples obtained from three European steelmaking companies. As received, the dusts were found to be toxic when tested according to current EPA toxicity testing procedures. Toxicity was on account of the leachability of one or more of the following elements: Ag, Hg, Pb, and Cd. Leaching experiments with concentrated AAC solution at 40 " C showed that zinc oxide present in the three dust samples, 60-80% of the total contained zinc, was rapidly solubilized. Data on the dissolution characteristics of Cd, Fe, Pb, Mg, and Mn are also presented. Toxicity tests conducted on residues of the leaching experiments found these to have leachates below past and current EPA toxicity threshold limits.

Jan 1, 1993

By Park McLure, Paul Kunze

Abandoned underground mine workings have been regularly encountered in open pit mining excavations for many years, for the most part without many serious problems resulting. During the last several years however, some tragic occurrences and near misses have resulted when these old workings were intercepted. This paper will report on the problem as it relates to western open pit mining and will describe several techniques that can be used to identify problem areas before they are reached: Utilization of old maps and engineering data, long hole drilling and probing, and the use of subsurface investigation in the form of ground penetrating radar are the detection methods that will be discussed. The paper will describe some possible actions, once potential problem areas are identified. Drilling and blasting crews are usually exposed to the hazards involved when these situations arise because of their "on the ground" working environment. It is therefore appropriate that some of the best methods of dealing with these hazards once they are identified, seems to involve innovative and creative blast designs. The paper will discuss these approaches and describe an example of this aspect of the solution.

Jan 1, 1993

By Chaves AP, Delboni H. Jr

Thermal comminution is an industrial process specially suited to very abrasive material, when contamination with Fe from wearing parts of conventional crushing and grinding equipment must be avoided. It involves an initial step of heating the material to be comminuted, followed by sudden cooling (quenching) and finally by a conventional mechanical process to disassemble the particle aggregates. The thermal step is, in fact, a pre-fracturing process. The heating operation causes changes in phase of the minerals and changes in volume of these minerals and other substances included in pores and cracks. The cooling operation causes thermal shock reversions or the phase transformation and consequent generation of internal stresses, high enough to fracture the solid.

Jan 1, 1993

By R. L. Derick

The Orchard Valley Mine, a large underground coal mine located in western Colorado, experienced a major mine fire during an idled Sunday on June 1, 1986. This mine had extensive problems with spontaneous combustion near the coal outcrop. Spontaneous combustion has been determined to be the probable cause of that fire. Preparing for a mine emergency was an on-going task. Once the emergency occurred, much of the preparation work was implemented and aided in controlling the situation. Later, the successes and shortfalls that arose from that emergency were analyzed for future course of action. This paper summarizes the activity that led up to the major fire, the handling of that emergency, the lessons learned, and the changes implemented.

Jan 1, 1993

By Harry Deitzer

Within the industrial marketplace barium sulfate has an established role as a filler or extender pigment for use in a wide array of applications. The focus of this paper is to outline a number of these applications and in each one characterizes those features of barium sulfate which provide value. Following this is a discussion of the process techniques which have been used to develop value from a selected class of barite ores found in southern Missouri. It is appropriate to define some terms which may help in clarifying some concepts as presented. Use of the term barium sulfate refers broadly to the chemical compound BaSO4 Barite will generally refer to the naturally occurring barium sulfate ores and their properties. Barytes, whether bleached or not, will refer to barite ore made suitable for industrial applications.

Jan 1, 1993

By J. D. Miller

Air-sparged hydrocyclone (ASH) flotation is a high-capacity flotation technology originally developed in the Department of Metallurgical Engineering at the University of Utah for processing mineral resources. However, the technology has been found to be useful in industrial waste processing, in the recycle of secondary resources, and in remediation of environmental problems. For example, areas in which the ASH technology is expected to have potential application include cleaning of waste coal fines, air stripping to remove volatile organics from drinking and process water, water disinfection by ozone or chlorine sparging, dispersed oil removal from water, and contaminated soil remediation. Recently, the ASH has been studied extensively for deinking flotation in the wastepaper recycling industry and has been shown to have excellent efficiency/capacity. In fact, a 20-million-dollar plant has been in operation since June 1992. The ASH technology can provide a specific capacity hundreds of times more than that which can be achieved with conventional flotation equipment and in certain instances is expected to provide superior separation efficiencies when compared to other technologies. The design and principles of ASH flotation are described. Experimental data for fine coal flotation, volatile organics stripping, and deinking flotation for paper recycle are presented and discussed. Finally, other potential areas of application for environmental technology are considered.

Jan 1, 1993

Many of the deeper ore reserves in current gold operations as well as new gold deposits consist of refractory ore types. As process development for these mineralizations remains time-consuming and costly, minimization of exploratory testwork and the early identification of feasible process routes is critical. Since most of the processing parameters are related to the mineralogy of the ore (Marsden & House, 1992), thorough mineralogical analyses during exploration and development phases have become a technical and economical requirement. The determination of mineralogy-related processing parameters and especially the gold mineralogy is even more important for these ore types because refractory gold ores consist of many transitions from partially leachable to totally refractory. In addition to sulfide and gangue encapsulation, various other refractory conditions may exist. Together with accessory mineralogical detriments (e.g., alteration/ slimes, reagent consumers, scale formation, mineral preg robbing) they may complicate process selection and hamper optimal plant operation.

Jan 1, 1993

By V 9. 0 / 300 dpi

In the time period from the early 1980's to the present, longwall roof support technology has evolved tremendously. Chock supports and caliper shields were replaced by 2-leg or 4-leg lemniscate shields. The lemniscate linkage for which the support is named offers numerous advantages to the sup-port both as a fabricated structure and to its performance in the mining application. The hydraulic system, which is the dynamic element of the roof support, was essentially unchanged in early lemniscate shields with the exception of the complexity of additional hydraulic circuits to power a canopy tilt cylinder and canopy side-seals. The control of these fluid-powered functions was provided by direct manual control of valves energizing individual functions onboard the roof-support or the adjacent roof-support. This control valve-gear was comprised of multiple individual valves arranged in a "bank" or integrated into a single hydraulic distribution block with a single operating handle to select any independent function.

Jan 1, 1993

By T. J. Durbin

At some surface and underground mines, control of ground-water inflow involves significant costs. These costs include the capital costs for installing a dewatering system, power and other costs to operate and maintain the system, and costs to treat and dispose of the water that is collected. To minimize these costs, design of a dewatering system utilizing wells has been formulated in terms of a nonlinear operations research problem using quadratic programming. Using this formulation, the locations, depths, pumping rates, and pumping schedules of wells are selected so as to minimize the total costs of the dewatering system.

Jan 1, 1993

By D. A. Norrgran

The recent development of rare earth permanent magnets has revolutionized the field of magnetic separation. The advent of rare earth permanent magnets in the 1980's provided a magnetic energy product an order of magnitude greater than that of conventional ferrite magnets. This has allowed the design of high-intensity magnetic circuits operating energy free and surpassing the strength and effectiveness of electromagnets. New applications and design concepts focused on the mineral and metal processing industries have evolved. This technology also led to the development of various magnetic separators specifically designed for mineral processing applications. Applications which were not previously considered are now being applied to primary mineral upgrading and recycling and secondary recovery.

Jan 1, 1993

By Kal V. S. Sastry

Conventional iron ore balling circuits exhibit undesirable surging behavior which is known to result from uncontrolled occurrence of the mechanisms of nucleation, coalescence and layering. This study was undertaken to investigate the mechanism of pellet growth by layering. Several laboratory experiments have been carried out to delineate the effect of feed moisture content and feed quantity. This paper presents an analysis of the experimental results and a simple model to describe the layering process.

Jan 1, 1993

By David Loomis

Unlike previous gold mining booms in Nevada's Great Basin, the current boom includes a serious commitment to mine reclamation. Many of the smaller mines began reclaiming in the late 1980s but met with limited success due in part to poor soil characteristics. Public land managers and the mining industry began looking for ways to improve reclamation success. One promising technique is suggested by an ongoing research project using sludge biosolids, the solid residue of municipal waste water treatment. During the 1980s, limited space in landfills led municipal governments to search for alternate ways to dispose of their biosolids. The cities of Reno and Sparks, NR and the US Bureau of Land Management (BLM) searched for ways to combine these needs to everyone's mutual benefit. Yet barriers remained. The federal government had major concerns about potential bioaccumulation of metals and contamination of drinking water from the land application of municipal biosolids. The barriers were lifted late in 1991 when an interagency task force led by the Environmental Protection Agency (EPA) issued a new federal policy on the use of biosolids on federal land. The policy encouraged biosolids as a soil amendment to reclaim degraded minelands and invited federal agencies to develop biosolid pilot projects. In response, BLM enlisted the help of American Resources Corp. (ARC) and the University of Nevada, Las Vegas for a pilot study at ARC'S' Butcher Boy Mine near Wadsworth, NR. Although biosolids have been used in mine land reclamation in the eastern United States for 20 years, before this pilot study, none had been used on public lands in the arid Great Basin. Land application of biosolids improves soil conditions by improving nutrient uptake, increasing water retention, permitting easier root penetration and enhancing soil fertility. Biosolids increase ecosystem productivity and can lead to significant improvements in the structure and diversity of plant and animal communities. Thus, land application of biosolids promotes biodiversity.

Jan 1, 1993

By J. E. Urosek

In October, 1990, a fire started in a large underground coal mine in Western Pennsylvania. During fire-fighting activities, an explosion occurred and all personnel were evacuated. Safe re-entry into the mine was not possible and the mine was sealed. Recovery efforts began in January, 1991 and continued until March, 1991, when permanent underground seals were installed between the fire area and the mine openings. This paper describes an extensive atmospheric monitoring program conducted by the Mine Safety and Health Administration (MSHA), Pittsburgh Safety and Health Technology Center (PS&HTC) including the analysis of mine fire gases, natural ventilation, fan pressure and air quantity distribution.

Jan 1, 1993

By J. H. Hill

The globalization of mineral markets and intense competition in downstream mineral-consuming industries such as transportation, agriculture, and construction are requiring raw materials suppliers to innovate, improve quality, invest in new technology, and control costs. Mineral specifications are becoming more refined, and pressure to improve products is felt from increasing numbers of competing producers, substitute materials, customers, and regulators. As a result, engineered mineral products are becoming more like manufactured ones in terms of cost structure, differentiation, and the importance of market driven, customer specific product development. Engineered mineral products are defined as those where the costs of refining and upgrading outweigh those of conventional mining activities (blasting, crushing, classification, haulage etc.), and where close control of physical and chemical parameters is required for customers' processing and manufacturing applications. This includes industrial minerals such as calcium carbonate, kaolin, mica, specialty oxides, talc, and some metal powders. It excludes most metals and bulk commodity materials such as gypsum, lime, sulfur, and soda ash. Engineered mineral products are utilized in common household goods, and are at the forefront of industrial materials engineering in plastics, ceramics, composites, glazes, coatings, and construction materials. As a group, they introduce interesting questions to the minerals firm. Advanced materials or basic? Diversify or specialize? What are the implications of advanced materials and for mineral markets, and most importantly, where can the producer look for long-term value, volume, and profits?

Jan 1, 1993

By James L. Hendrix, R. Y. Wan, David W. Kappes, Jinrong Zhang, M. C. Fuerstenau, Terence E. Albert

A sulfidic flotation tailings ore, containing 1.14 gpt Au and 242.53 gpt Ag, was treated by low temperature chlorination roasting followed by cyanide or chloride leaching. Eighty per cent of Ag was recovered by cyanide leach when the ore was roasted at 350°C with 50 kg/ton calcium chloride. About seventy per cent of Au was made cyanide amenable by chlorination roasting at 400°C. A better Ag recovery, ninety per cent or over, was achieved by chloride (NaCl+HCl) leach. However, Au recovery was very poor by chloride leach. Ferric chloride, calcium chloride, and cupric chloride were compared as chlorinating agents for their effect on Au and Ag recovery. The study found that low temperature chlorination roasting is very effective for recovering Ag associated with stibnite and stannite. The best chlorinating agent for the test ore was found to be calcium chloride. Parallel roasting-leaching tests indicated that chlorination roasting was far superior over oxidation roasting for both gold and silver recovery.

Jan 1, 1993

By T. R. A. Davey

Previous publications on the application of EIETSIM include the modelling of an electrolytic zinc plant and a copper flash smelter. In the present case METSIM has been used to model the desilverising of lead by the reagent zinc, whereby a silver-zinc intermetallic compound is formed, and floats out of the lead. This compound has a variable composition, depending upon the ratio of dissolved zinc/silver in the lead bath. Its solubility in lead decreases with falling temperature. A number of variations and modifications of the Davey Desilverising Procedure are modelled, and applied to a wide range of silver contents in lead bullions at several plants. METSIM uses both feed- back and feed-forward controls to simulate plant conditions, and a logic control to distinguish between different phases in the Zn-Ag system. Use is made of extensive (previously unpublished) fundamental data on the ternary Pb-Ag-Zn system, and of plant data, to establish certain operating parameters.

Jan 1, 1993

By S. Yabe

The reinforcement of the annual copper production capacity to 330,000 metric tons has been attained at Saganoseki Smelter & Refinery in 1991, which is one of the largest and most efficient custom smelters in the world. Many operational improvements and technology developments have realized the increase of smelting and refining capacity without adding main facilities to the existing process. The blister copper refining and anode casting process is composed of two 400 tonnes anode furnaces and one double-wheeled casting machine with the capacity of 80 tonnes per hour. The great innovations in this process such as the finding of essential issue on the extending of anode-mould life and the development of a new anode-mould casting machine have raised the operation efficiency by 14% Now, the process is producing 38,500 tonnes per month of best quality anode in well- controlled working condition, and anode productivity per worker increased by 52%. The progress in extending anode-mould life, the mechanism of the new anode-mould casting machine and the increase of efficiency in butane reduction, that were the principal parts of many technological improvements, are described in the present paper, including some operation results.

Jan 1, 1993

By Larry J. Hulbert, Louis J. Cabri, John L. Campbell, Gilles Laflamme, Chris G. Ryan, Soey H. Sie, Rolando Lastra

"Abstract- The mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon Territory, is complex and the metals of interest are contained within fme-grained minerais which vary in size and mineral associations from sample to sample.The major Ni carriers are pentlandite and violarite; the major Cu carrier is chalcopyrite. About 700Jo of the major Ni carriers and 78% of the major Cu qmier will be liberated at a grind of 80% -'}f,.7 J.Uil (-500 mesh) for typical low-grade gabbro (West zone, sample No. 1). For typical ""clinopyroxenite"" (West zone, sample No. 2) and typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3) the liberation would be 71""lo and 65% for Ni, 74% and 60% for Cu, respectively. Fine grinding, however, cannot liberate the Ni contained in silicates and pyrrhotite, estimated to total24.5% for typicallow-grade gabbro (West zone, sample No. 1), 15% for typical ""clinopyroxenite"" (West zone, sample No. 2), and 12% for typical ""clinopyroxene-rich peridotite"" (East zone, sample No. 3).The principal Pt carrier (sperrylite) varies considerably in grain-size between samples and fme grinding, required to liberate the major Ni and Cu carriers, may be counterproductive in samples where sperrylite is relatively coarse-grained, as sorne would then be unrecovered (e.g. sample No. 1). In addition, sperrylite in samples No. 2 and No. 3 is closely associated with magnetite.Palladium occurs in diverse ways. It occurs in the form of several Pd minerais (e.g. sudburyite, testibiopalladite, merenskyite), as a replacement for Ni in several tellurides, antimonides and tel­ lurantimonides (e.g. melonite), or as very low concentrations in pentlandite (up to 34 ppm), chal­ copyrite (up to 9 ppm), and pyrrhotite (up to 5.6 ppm). Palladium minerais and Pd-bearing minerals are strongly associated with chalcopyrite in sample No. 1 and will thus report to a Cu concentrate. However, 22% of the total Pd is in solid solution in pentlandite in this sample and will thus report to the Ni concentrate. In samples No. 2 and No. 3, less Pd occurs in solid solution in pentlandite, and the PGM are distributed mainly among pentlandite, chalcopyrite, and magnetite in sample No. 2, and among pentlandite, pyrrhotite, chalcopyrite, and magnetite in sample No. 3. Therefore, the feasibility of magnetic concentration should be investigated for samples like No. 2 and No. 3, in order to improve Pt and Pd recoveries.Rhodium was found to occur as rare hollingworthite, in sparse cobaltite (up to 2.7%) and, as low concentrations in chalcopyrite (to 10 ppm) and pentlandite (to 12 ppm) by proton microprobe. Iridium occurs in hollingworthite (up to 7.8%) and very rarely as the native metal or in an undefmed Re-Ir-Os-Ru alloy. Ruthenium was determined by proton microprobe analyses to occur in pentlandite (up to 13 ppm) and chalcopyrite (up to 10 ppm), in addition to rare laurite and Re alloy."

Jan 1, 1993

By F. F. Peng

Fine Coal Cleaning Processes including froth flotation, aggregative flotation or oil agglomeration, depend upon the wettability of coal particles in the aqueous solution. The wettability of coals of various ranks, hydrocarbon oil treated coals and oil-agglomerates have been measured using film flotation, induction timer, and froth flotation. Various hydrocarbon collector dispersion techniques are used to alter the surface wettability of coal particles. Change in wettability behaviors, measured by flotation responses, due to various ranks with or without of hydrocarbon collector modification are explained in terms of surface chemistry modifications as analyzed by induction time, film flotation as well as DRIFT Spectroscopy. The relationship between the wettability of coals and collector treated coals, and floatability are discussed.

Jan 1, 1993

By David G. Dixon

A general, unsteady-state model for leaching of one or more solid reactant species from a non- reactive, porous, spherical pellet is derived in dimensionless form for the interpretation of leaching data, and for use in the design of coarse-ore leaching processes. The effects of diffusion rate, chemical reaction rate, variable reaction order, and competition between multiple solid reactants are examined using the concept of the effectiveness factor. It is shown that the model is capable of simulating both "reaction-zone" and "heterogeneous" kinetics, depending on the choice of three dimensionless parameters. Results of batch leaching tests of artificial ore pellets are presented, and their relationship to the model is discussed.

Jan 1, 1993