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By J. Wiebmer

Some thoroughbred racehorses are great routers (distance runners), others are sprinters. Some racehorses perform best on turf, others on dirt, and some in mud. To be a winner, you have to choose the right horse for the course. It's no different when looking at an electric cable shovel, a hydraulic shovel/excavator, or a wheel loader. Each loading tool has its own zone of application. To be a winner, you have to choose the right horse for your course.

Jan 1, 1993

By Sridhar Seetharuman

Sulfur and oxygen dissolved in nickel and cupronickel melts can be removed as gaseous oxides of sulfur by a vacuum treatment. Presented in this paper is a new matched thermochemical diagram that permits direct evaluation of the equilibrium partial pressure of SO, as a function of temperature over an alloy of specified composition. The matched thermochemical diagram consists of a central plot which shows the integral Gibbs' energy of mixing for the binary system S-O2, at different temperatures. The central plot is flanked on either side by terminal plots of the chemical potentials of oxygen and sulfur, as functions of temperature, for different alloy compositions. By projecting the chemical potentials of oxygen and sulfur from the terminal plots on to the central diagram, the equilibrium pressure of SO2,can be directly read on the nomograms on the central plot at different temperatures. The matched thermochemical diaerams are - useful in assuring the efficiency of vacuum refining.

Jan 1, 1993

By N. Arbiter

Evidence for the floatability of sulphide minerals without collector is analyzed and it is shown that results obtained with ores, in contrast to those with single minerals or mineral mixtures, depend on many additional variables, some identified and others not. Because of the prevailing low levels and costs of collectors for most sulphide ores, it is unlikely that collectorless flotation will have commercial applications, so that continued research on the subject may be justifiable on theoretical but not on practical grounds.

Jan 1, 1993

By J. W. Matousek

In the flash smelting of copper sulfide concentrates, the course of reactions from the burner tip, through flame "burn-out" (the point of oxygen depletion), to settled matte and slag is of particular interest in understanding the mechanisms of the process. Numerous reaction sets can be proposed to describe the chemical changes that might be taking place, but from outside the furnace no one set offers an obvious advantage in explaining the actual processes involved. Only a combination of mathematical modeling and flame and bath sampling can achieve this result. This paper shows that flash smelting, while still reasonably orderly, is a more complex process than suggested by the technical literature.

Jan 1, 1993

By M. S. Riyaz Ulla

The Hutti Greenstone belt, located in the northern side of Dharwar Craton, India, contains several promising gold fields. It is predominantly composed of meta-volcanics with minor intercalations of meta-sedimentaries. Alkali-SiO2 and Zr-P2O5 diagrams, immobile element trends, and an iron-rich trend on the AFM diagram indicate that the volcanic suite is low-potassium tholeiitic basalt. The lower Mg number, MgO-TiO2, MgO-Ni, and Ni-Zr plots reveal that the basalt was derived from a fractionated, highly evolved magma generated by 10-20% melting of the mantle at 1100°C and 5 kb pressure. The chemical variations suggest that the Hutti metabasalt represents volcanic arc rocks generated at a converging plate margin.

Jan 1, 1993

By Eric R. Bauer

The ground control aspects of extended depth-of-cut mining are presented in this U.S. Bureau of Mines report. A trend analysis of extended cut approvals was performed. A comparative review of roof fall fatalities for extended and nonextended cut mining is included. Current ground control guidelines for extended cut approval are summarized. The problems and concerns of this extraction system are addressed, and typical extended cutting face operations are described.

Jan 1, 1993

By T. A. Lloyd

The use of tank cells over the years has provided a means for low cost, space efficient, extra capacity in existing flotation circuits. In some cases, new plants have selected tank cells as the machine of choice. Typical tank cells use high efficiency impellers for mixing, which results in low power draw. Unfortunately, these mixers have poor aerating characteristics that compromise metallurgical performance. This has all changed with Outokumpu's new flotation concepts. Outokumpu has recently developed the HG or High Grade flotation cell that can provide higher recovery with better selectivity while maintaining the simple operation of conventional cells.

Jan 1, 1993

Room-and-pillar mining at White Pine started in 1953 from a sub-outcropping orebody that gently dips to 1000 m depths in a distance of about 6 km. High horizontal stresses were recognized in the mid-1960s which had obvious stability impacts when viewed in combination with the increased overburden stresses. Modifications in conventional room-and-pillar design were introduced through the years on a trial-and-error basis to help overcome stability and resource recovery problems. These modifications were based on pressure arch concepts using pillar yielding and/or pillar recovery, and on mine layout orientation to minimize stress impacts. While some of these modifications were successfully applied in some areas, they failed in others. Through the years, visual observations played a major role in panel design with contributions from stress measurements and analyses. However, the down slide in the copper economy during the 1970s and early 1980s resulted in a loss of interest in the application of these concepts. This paper reviews ground control problems and presents the results of recent stress measurements and computer analyses. They shed light on the importance of using yield pillars and mine layout orientation to control stresses at depth.

Jan 1, 1993

By James T. Staley

Quenching and aging are critical processing steps used to produce precipitation hardenable aluminum alloy products. This work describes personal computer programs that employ models to predict certain properties after quenching and aging and graphically display them. One of the programs allows the user to predict the attainable strength and toughness of aluminum alloy products after an arbitrary quench. Another program simulates the changes in strength and electrical conductivity occurring during second-step aging alloy 7050-T7X products as a function of thickness, furnace temperature set point, and furnace characteristics.

Jan 1, 1993

By J. E. Murphy, R. Y. Wan, K. R. Sandgren, M. C. Fuerstenau

As part of a U.S. Bureau of Mines program to evaluate alternatives to sodium cyanide in gold leaching, three organic nitrile compounds were tested for their effectiveness as gold lixiviante. The organic compounds examined were malononitrile, acetonitrile, and cyanoacetamide. The reagents were tested on an oxide ore, two carbonaceous ores, and a eulfidic ore. Acetonitrile and cyanoacetamide were shown to be ineffective gold leachante. Malononitrile was the most successful of the organic lixiviants. On an oxide ore, malononitrile performed shilarlyto sodium cyanide with extractions of around 80 pct. For carbonaceous "preg-robbing" oree, sodium cyanide was completely ineffective while malononitrile extracted 24 pct of the gold. When using a resin-in-leach technique, extraction with sodium cyanide increased to 60 pct and the extraction with malononitrile increased to 80 pct. On the sulfide ore, sodium cyanide and malononitrile performed similarly with 80+ pct extraction as long as the pH of the malononitrile solution wae maintained above 10.5. Malononitrile is six times less toxic than sodium cyanide as measured by LD, levels. Therefore, malononitrile has a significant advantage over eodium cyanide, but its high cost and undemonstrated usefulnees make it unlikely to gain acceptance.

Jan 1, 1993

By R. G. Reddy

The effect of solid particles on viscosity behavior of Na2O-O-B2O3-SiO2 melts of composition XSio2/XNa2o =0.5 and in the temperature range of 900- 1150 K was studied. Samples were analyzed by X-ray diffraction and optical microscopy. The results showed that a crystalline phase (NaBO2) was formed and its amount increases with decrease in X,, from 0.50 to 0.25. The experimental viscosity values were compared with the predicted values using our viscosity model developed earlier. At low temperatures, for low content of B2O3 , the experimental values exhibits a large deviation from the predicted values. It was concluded that the deviation was due to the formation of solid particles in the molten slags. The existence of these solid particles increased the viscosity values significantly. A new viscosity model was developed to include the effect of solid particles.

Jan 1, 1993

By E. vanHuyssteen

A method of establishing the relationship between the mineralogy of a sinter and its subsequent processing behaviour in a lead blast furnace is demonstrated. It involves: 1) analyzing the Zn-spinels, hardystonite, larsenite, Pb-silicates, Pb-arsenates, Pb-(Ca)-sulphates and other femtes with an electron microprobe; 2) determining the extent of elemental substitutions in various mineral structures; 3) establishing a sequence in which the various phases formed during sintering. In this manner the relationship between the bulk chemistry of a sinter formulation and the speciation of elements into various phases in the sinter can be established. Specifically, the-substitution of Mg for Zn in hardystonite significantly influences sinter production. Mg substitution releases Zn into the surrounding matrix. This Zn reacts with the Pb-silicate to form larsenite thereby reducing the amount of Pb-silicate available for anhydrite digestion. Excessive amounts of residual anhydrite thus result if the sinter formulation is based solely on the CaO/Si& ratio.

Jan 1, 1993

By J. R. B. Lima

The present work emphasizes the selection in the separation of the apatite/calcite by the direct anionic flotation versus the double flotation, with a reverse second stage of the Jacupiranga phosphate ore. The double flotation would allow the obtaining of two concentrated solutions: one of them mainly constituted by a calcium carbonate material (CaCO3) and the other one, phosphatic (apatite). The calcium carbonate concentrated solution is used for the production of cement. The presence of phosphatic material in the calcium solution is not desirable, phosphor being a harmful element to cement. On the other hand, smaller quantities of calcite in the phosphate concentrate would represent a substantial economy in the processes of production of phosphated fertilizers. These processes make use of sulfuric acid to the solubilization of the apatite and the presence of calcium material consumes acid. Also that, when carbonates are solubilized, unwanted products are formed resulting in losses in the process and diminishing the quality of the fertilizer produced. These characteristics are discussed in the paper and are compared to another Brazilian phosphate ore, the reverse route of which can be considered more adequate. The results are discussed according to recent discoveries, and special emphasis is given to the use of corn starch and its crucial role in promoting the selection in the direct flotation process.

Jan 1, 1993

By R. S. Farinato

Thionocarbamate flotation reagents have enjoyed a niche position in the recovery of copper sulfides and activated sphalerites since their introduction in the mid 1950's (Harris, 1954). Thionocarbamates containing an allyl group (-CH2- CH=CH2), introduced recently Lewellyn, 1985; Nagaraj, 1988; Avotins, 1991), are used commercially as collectors for copper sulfides and activated sphalerite. Laboratory flotation tests and plant usage have demonstrated that allyl-containing thionocarbamate collectors exhibit certain unique properties that distinguish them from the corresponding dialkyl thionocarbamates. Spectroscopic (FTIR, XPS) and wettability studies of N-allyl iso-butyl thionocarbamate (AIBTC) and its saturated analog N-propyl iso-butyl thionocarbamate (NPIBTC) adsorbed on copper at pH 9 were performed in order to investigate whether there were any fundamental reasons for these differences. Flotation tests were carried out on chalcocite, copper ore and an activated sphalerite.

Jan 1, 1993

By J. R. Goode

The first part of this paper comprises a general discussion on refractory gold ores and their mineralogy processing methods now in use are reviewed and test procedures for the important methods are discussed. Factors determining the selection of a process are outlined. The paper includes a survey of production plants using pressure oxidation, roasting and biological oxidation to process refractory ore. The status of processes under development is briefly reviewed.

Jan 1, 1993

By P. Legast

Serpentinite minerals are available in large quantities from asbestos mining activity. The granular or fibrous serpentite, at temperatures greater than 700°C, will recrystalize into olivine, forsterite and enstatite. These minerals have been used and studied for decades and are environmentally safe. The thermal process changes the composition and properties of the original mineral. Therefore, the substitution of the original mineral cannot simply be made and the applications for these new synthetic minerals need to be redeveloped. The two original mineral forms allow a wide range of new synthetic raw materials which can be adjusted to specific applications or custom needs.

Jan 1, 1993

By Jean M. Kenney

Frequencies of haulage-related accidents in metal and nonmetal surface mines for the years 1988 through 1990 were investigated and compared with those of non-haulage-related accidents. This study was part of the U.S. Bureau of Mines program to improve mining haulage safety. Data were obtained through the U.S. Bureau of Mines Accident Data Analysis (ADA) program. The chi-square test was used to compare frequencies of haulage-related and non-haulage-related accidents for each of the following variables: degree of injury, age, total number of years of mining experience, and shift time. Significance was determined for degree of injury between haulage-related and non-haulage-related accidents. Age of injured did not vary significantly between haulage-related and non-haulage-related accidents, but total number of years of mining experience was found to be significant. Shift time for the accident proved to vary significantly between haulage-and non-haulage-related accidents. Events causing injury for haulage-related accidents were tabulated, and the most frequent determinants of haulage-related accidents were identified. Accident descriptions for both fatalities and permanent disabilities were studied, and the primary causes of these accidents were identified. These findings suggest that haulage-related jobs are among the most dangerous when considering accidents experienced by all workers in the metal and nonmetal surface mining work force.

Jan 1, 1993

By John J. Sammarco

This report details the testing and evaluation of a modular azimuth and positioning system (MAPS) to provide navigational information for a continuous mining machine. Vehicle navigation is part of the U.S. Bureau of Mines research program in computer-assisted mining serving as a tool to increase mining health, safety, and productivity. The Bureau is investigating other navigation systems, but MAPS seems to have the most promise. MAPS was installed on a continuous mining machine. An operator used the machine to cut coal while researchers collected machine and MAPS data. A comparison of MAPS data for xy position and data obtained with an electronic transit showed an increasing error for MAPS. After 30 min of operation, the easting position error was -0.02 m, and the northing position error was 0.019 m; after 60 min of operation, the easting position error was -0.19 m, and the northing position error was -0.26 m. Modifications to MAPS software and to the operational procedure of the machine significantly reduced this error by a factor of 3.7. Researchers continue to reduce these errors.

Jan 1, 1993

By M. C. Williams

As the flaws in the population balance model (PBM) comminution model are examined more deeply, further errors and problems were discovered. The Levenberg-Marquardt algorithm for systems of constrained non-linear equations was used to solve the dynamic PBM grinding equations to obtain the grinding selection and breakage rate functions. The fact that the PBM model equation Inverse Problem is degenerate or underspecified is demonstrated. Multiple solutions to the same PBM equations are provided. It is shown that there is no unique solution to the Inverse Problem unless additional constraints are provided or assumptions are made such as the Arbiter-Bhrany normalization assumption. The severity of the non-uniqueness problem for dynamic grinding is demonstrated. Each solution to a dynamic PBM, while giving the same prediction for a given grinding time interval, gives different solutions or predictions for mill composition for other grinding times. Actual experimental grinding data was assessed to determine the functionality of mill selection and breakage functions.

Jan 1, 1993

By Michael R. Norland

Surface and subsurface stabilization of mining-related wastes through revegetation depends upon the physical, chemical, and biological condition of the waste following mining. Mining disturbances can significantly alter the soil physical, chemical, and biological characteristics of a site, reducing or eliminating mycorrhizal fungi from the soil. Mycorrhizae are economically and ecologically important because they can alleviate environmental stresses caused by lack of proper soil condition and because they are vital to stabilization of mining waste by increasing plant survival and biomass through increased nutrient and water uptake. This report discusses some of the ecological factors that may affect mycorrhizae-plant associations on mining-related wastes and provides general information on mycorrhizae inoculation technology.

Jan 1, 1993