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By W. C. Hirt

Selective flocculation was used to produce superclean zinc concentrate with minimized silica contamination. Research was carried out on a flotation concentrate from the Jersey Miniere Zinc Company (JMZ) in Gordonsville, Tennessee. The material was first dispersed with sodium silicate and then causticized tapioca starch was used to selectively flocculate the sphalerite, leaving the silica in suspension. This technique has been applied commercially to iron ore beneficiation but has never been used for processing zinc. The feed material assayed 0.45% Si02. Use of 0.56 kg/tonne (1.13 lb/st) of sodium silicate and 0.070 kg/tonne (0.141 lb/st) of causticized tapioca starch resulted in 98.2% zinc recovery in a purified zinc concentrate assaying 66.0% Zn and 0.24% silica. The present target level for silica contamination in JMZ zinc concentrates is 0.3% Si02. This work has shown that selective flocculation offers a potential method for cleaning flotation concentrates, particularly where low silica products are required.

Jan 1, 1993

By L. W. Beckstead

In a conventional zinc refinery plant, zinc concentrates were roasted at 950°C. The calcine was ground and leached in a series of leaching vessels using sulfuric acid. The pH in the first leaching vessel was maintained at 2.5, while the pH of the solution exiting the last vessel was about 5.4. The leached residue typically contained (in percent) 0.1 Ag, 0.2 As, 0.7 Cd, 2 Cu, 15 Fe, 10 Pb, and 15 Zn, and it was classified as hazardous material according to the EP-toxicity test. In order to make the residue non-hazardous, and to recover most of the metal values from the residue, a brine leach process was developed. The process consisted of leaching the zinc leach residue in CaCI, brine solution at pH 2 for 1 hour at 90°C. Silver extraction was about 95 percent, while lead, copper, cadmium, zinc, and iron extractions were about 80, 50, 50, 30, and less than 0.5 percent, respectively. More extreme conditions of acidity could have been used in the leaching stage to increase zinc dissolution, but iron dissolution would have significantly increased which would have complicated subsequent recovery steps. The leached and washed residue passed the EP-toxicity leach test and could be disposed as non-hazardous. Silver, copper, and lead in the leach solution were recovered by zinc cementation, while zinc and cadmium were recovered by sulfide precipitation. The resulting solution can be recycled in the process after magnesium precipitation.

Jan 1, 1993

By B. Devulapalli

A mathematical model of the industrial hydrocyclone based on fluid dynamics is a better alternative to the currently existing empirical models. The swirling-flow velocities are determined by solving the Navier-Stokes equations with an appropriate turbulence model. The solution of the momentum-balance equations yields the flow field inside the hydrocyclone which determines the particle trajectories, and subsequently the classification curve. The essence of the model is that the physical dimensions of the hydrocyclone and the slurry characteristics can be incorporated, and the influence of these parameters reflects on the flow predictions. The predicted tangential and axial velocities in a 250-mm hydrocyclone are in good agreement with the laser-Doppler velocimetry measurements. Finally, the predicted classification curves show good agreement with experimental data measured on a KREBS Dl0B hydrocyclone.

Jan 1, 1993

By C. L. McKenzie

American Girl Mine is located in the Cargo Muchacho Mountains in the southeastern Imperial Valley of Southern California. Production from the current open pit mine and heap leach recovery system began in early 1989. Previous mining and gold recovery took place commencing in 1987 at the Padre Madre site, situated adjacent to the American Girl site to the southwest. In mid-1990, a 790-tonne-per-day underground gold mine and mill went into production. Approximately 6,500 troy ounces of gold per month are recovered from the combined open pit underground mine operation. Copper in the form of Azurite [Cu3(CO3)2(OH)2] and Malachite [Cu2CO3(OH)2] are abundant in the mined ores (Henshaw, 1942). The high solubility of these minerals in caustic cyanide solutions has a negative impact on carbon adsorption and electrowin processes. This paper presents the results of monitoring programs, process chemistry, and control changes introduced at American Girl Mine to abate production complications in the refinery and measures taken to minimize solution gold losses in the adsorption circuit(s).

Jan 1, 1993

By B. J. Arnold, C. D. Harrison, R. A. Lohnes

More than 544 Mt (600 million st) of coal are handled annually for use by this country's coal fired power plants. Coal is transported in various ways: overland conveyors, railcars, trucks and barges. It can travel short distances or thousands of miles, picking up moisture, freezing or drying. When the coal is received at the power plant, environmental problems with fugitive dust and further handling problems can arise. To ensure that power plant availability is not jeopardized by coal handling problems, the Electric Power Research Institute's (EPRI) Coal Quality Development Center (CQDC) developed a research program aimed at addressing utility coal handling problems. The program has identified key areas, and is investigating the cost and cause of coal handling problems as well as the solutions to these problems. The ultimate goal of the program is to develop a "handleability index" that utilities can use in their coal specifications or hardware for a utility's sampling system to predict handleability and determine if a coal shipment should be accepted.

Jan 1, 1993

By S. L. Jung, T. L. Nichols, K. Prisbrey

The problem was to evaluate the on-line detection of rock properties through acoustic emission sensors. Acoustic emission sensors, when attached to crushers, grinders, and roof bolters, are robust, economical, and relatively maintenance free. Our objective was to relate acoustic emissions to rock fracture mechanisms, including micropore closures, linear elastic deformations, and crack propagation. We evaluated acoustic emissions from steel jacketed rock cores during indentation tests. In addition we attached sensors to the rotating shaft of a rock bolter drill. A back propagation neural network "learned" rock fracture characteristics and rock type with 99% classification accuracy. A neural network's calibration and computational abilities suggest better acoustic emission sensor capabilities.

Jan 1, 1993

In 1874 a stockman, JE Wright of Foxlow Station, recognised copper mineralisation when he was about 12 kilometres south of the station. The find was on the banks of the Molonglo River. Several small mines were soon operating along the ridge above the river, and the village of Captain's Flat was established.One mining company established in the 1880s was Lake George Mines. It's name was to remain synonomous with the name of the town until mining and treatment ceased on 11 March 1962.

Jan 1, 1993

By Joseph Rosta

The gold and silver review did not arrive in time for publication in the May issue. Gold The gold market generally was listless in 1992, although investors returned to the metal in the fourth quarter. The gold price declined for the second year in a row, averaging $11.05/g ($343.76/ oz), 5.2% lower than the $11.65/g ($362.44/oz) seen in 1991. The average price has declined more than 23% since 1987, when gold averaged $14.36/g

Jan 1, 1993

By J. A. Brierley, Arpad E. Torma, Victor C. Storhok, C. L. Brierley, Batric Pesic

Chemical and electrochemical studies were performed during bioleaching of cobaltite concentrate with Thiobacillus ferrooxidans. The two principal minerals present in the concentrate were pyrite and cobaltite (CoAsS). During chemical studies, the effect of pH on dissolution rates was examined under uncontrolled and pH-controlled conditions. It was found that in the pH range 1.5-3.0 there was no pH effect if the initial pH was not controlled (maintained). When the initial pH was controlled, the leaching of Co, As, and Fe depended strongly on pH. Electrochemical studies were performed by using cyclic voltammetry and constant potential techniques. A sequential reaction mechanism was proposed for dissolution of cobaltite.

Jan 1, 1993

By Derek G. Cieplinski

Regenerative conveyors with complex conveyor profiles place unusually stringent demands on the starting drive control. Depending on the nature of the conveyor loading, the drive must either provide a positive driving force to overcome conveyor friction and gravitational forces if the belt is empty or the inclined sections are loaded, or it must provide a retarding force to resist the gravitational load of decline sections to control the acceleration rate. This paper discusses the requirements of regenerative conveyors, reviews the working principals of fluid couplings, and examines their interaction by means of a case study of a 1700 m long regenerative conveyor utilizing a fluid coupling with a proportional brake control to provide controlled starting and stopping under all load conditions.

Jan 1, 1993

By Michael J. Feltes

In mining operations, conveyors hold one of the most important keys to productivity. Sudden belt or belt-splice failures and extended repair downtimes can contribute to low material-handling system availability. Consequently, operations and maintenance personnel should have a thorough understanding of the available splicing and repair alternatives and how each method can affect the productivity and cost-effectiveness of their operation. The two primary methods of joining belt ends - vulcanization and mechanical fastening - affect the likelihood of sudden failure and repair times in different ways. The time-honored method of vulcanization remains popular in many conveyor-intensive underground and above-ground mining operations around the world. At first, vulcanization may seem attractive because, when done properly by trained and experienced craftsmen, it can match the original belting fairly closely and give the splice a smooth, continuous surface with no edges or seams to invite snagging.

Jan 1, 1993

By Wilhelm Wendt

About five years ago we showed that it is possible to use the spectral in- formation in the light emitted by the off-gas flame of a PS converter for on-line production control. Very recently measurements have been performed using improved optical equipment and data evaluation software, resulting in both improved accuracy and the establishment of new optical process parameters. Using the optical signals the slag heats could be stopped at a predetermined Cu content of the white metal with an accuracy of +0.2% Cu m the range 74-78% Cu. A good correlation was found between the slag composition and optical data, providing a possibility for on-line monitoring of the SiO2 content of the slag. The measurements indicate the possibility of predicting the optimum end-point of the copper-making stage and having real time information on the impurity removal. Factors influencing the optical parameters, such as blowrate, Pb content, temperature etc. will be discussed.

Jan 1, 1993

By A. Rios

ENAMl's Paipote Smelter commenced operations in 1951. At present, it processes 230,000 tonnes/year of green feed in a conventional smelter, which comprises one reverberatory furnace, two Hoboken, one Peirce-Smith converters and one rotary anode furnace. The feed is composed of 83% copper concentrate and 17% metallic copper precipitates, which results in a feed average grade of 32% of copper content. The final products are 75,000 tonnes/year of copper anodes and 48,000 tonnes/year of sulphuric acid. At present, the plant is undergoing a modernization to expand the smelter capacity to 300,000 tonnes/year of green feed and increase the sulphuric acid production to 100,000 tonnes/year. This will be achieved with the installation of an El Teniente Converter and an expansion in the acid plant. The work began in November 1991 and is scheduled to be in operaton by March 1993. The paper provides an overview of the modernization plans and results achieved to-date.

Jan 1, 1993

By Liu Chunpeng

The new technological process developed is by means of thermal plasma arc smelting to obtain high grade Ni matte directly from Ni-Cu concentrates containing 6-7% nickel and 3-8% sulfur. In comparising with conventional smelting and converting processes the plasma arc smelting process has many advantages over conventional processes, such as lower energy consumption, lower capital investment and free from SO, pollution by transforming the sulfides into elemental sulfur with microwave irradiation under controlled oxygen potential, moreover, the process is simple and easily controlled due to less magnetite troubles in the operation. Therefore, this new technological process can be used as an alternative way to conventional process for Ni-Cu concentrate smelting. The main economical technical index is summarized in Tabal 1. Table 1 Main Ecnomic-technical Index

Jan 1, 1993

By Wayne C. Stewart

Freezing of high pressure air lines and pneumatic equipment has been a recurring problem in the Thompson Smelter. The particular severity during the winter of 1989-90 resulted in costly process disruptions and repairs. A process improvement team with representatives from operations, engineering and both maintenance supervision and the shop floor was established to develop solutions. Their mandate included process evaluation, design, equipment and in-plant commissioning. In 1990, upon recommendation of the team, we installed three Refrigerant/Desiccant air dryers with a total capacity of 20,000 S.C.F.M. to service the Smelter. This paper discusses processes and process improvements associated with this installation.

Jan 1, 1993

By D. W. Mitchell

Planning today for what hopefully will never happen is one of the surest ways to decrease the chance of it happening. As Napoleon proved and Ian Mitroff wrote, "The heat and stress of battle is the worst time to make decisions of strategic importance." Mitroff also wrote, "The value of a plan is not that it will ever perfectly match reality, but going through the process of planning speeds the process of recovery. It allows the organization to emotionally work through the worst before it actually happens." This paper concentrates on things miners must consider; on the need for plans to be like a belt conveyor strong enough to carry the load, flexible enough to stretch a little; on the criticality of throwing away fax machines and telephones, and having certain officials at the scene rather than back in head-quarters; on the training of fire brigades and mine-rescue teams; on having company-controlled chromatographs; on having people who can look at trends rather than numbers. Some of the things in this paper might anger some readers; for that, I can only ask them to consider first the problem not their position.

Jan 1, 1993

By Frank E. Chase

Retreat mining is one of the most hazardous operations conducted underground. One of the keys to miner safety and an efficient recovery of the reserves is to design adequately sized production pillars to prevent pillar squeezes, excessive pillar spalling, severe floor heave, roof falls, and pillar bumps. Currently, few pillar design approaches are available which consider the abutment pressures generated by the gob. The Bureau of Mines is developing a method called Analysis of Retreat Mining Pillar Stability (ARMPS) to aid in the design of retreating sections. Back analysis of 42 case studies indicates that ARMPS can be helpful in predicting stability during retreat mining operations.

Jan 1, 1993

By Larry A. Haas

The U.S. Bureau of Mines, in cooperation with Cleveland-Cliffs, Inc. (Hibbing, MN), investigated ways of enhancing the quality (compressive strength, after-tumble and reducibility) of domestic acid and fluxed magnetite pellets by modifying the oxygen content during the preheat and induration periods of the firing operation . Oxidation of magnetite was best accomplished when sufficient oxygen and time were available before the peak induration temperature was reached. The rate of magnetite oxidation increased directly with the gas oxygen content during the preheat period at 7000 C and above. With 30 pct ( or more) O2 and a preheat rate of 2000 C/min, most of the magnetite was oxidized during the preheat period. With laboratory tube and mini-pot furnace tests, oxygen enrichment during the preheat period improved the pellet properties more in the simulated grate-kiln tests than in the simulated straight-grate tests. The longer induration period with the grate-kiln test resulted in more sintering of the residual magnetite and its reaction with the silicon compounds. When flux was present in the pellets, calcium silicates and calcium and magnesium ferrites were formed. More calcium ferrite was formed when the magnetite was oxidized early and less iron was present in the fayalitic calcium silicate slag.

Jan 1, 1993

By A. B. Mayer

A generic task summary for design and implementation of hydrogeology programs at open-pit mine operations is presented as a guideline for management. Rigorous assessment of the local and regional hydrogeologic system is necessary to plan dewatering activities and to address environmental concerns. Dewatering activities include calculation of dewatering requirements, design of dewatering systems and evaluation of dewatering-water disposal areas. Environmental concerns include calculation of dewatering and water-disposal impacts, mitigation of soil and ground-water contamination and acquisition of water rights. Three-dimensional numerical models are commonly used to support these analyses. A thoroughly developed hydrogeology program provides an interactive basis for dewatering feasibility decisions and for support of environmental permits and regulatory compliance.

Jan 1, 1993

Large deposits of eudialyte, a low grade zirconium bearing mineral, occur on the Southern Coast of Greenland in the Ilimaussaq intrusion. Various processes were tested in the laboratory to recover eudialyte from these ores, including flotation, leaching, gravity and magnetic separation. A combination of dry and wet magnetic separations has the advantage of simplicity and the least environmental impact for the location. This paper summarizes the results of laboratory testwork to develop a two-stage treatment process to recover the eudialyte by magnetic separation.

Jan 1, 1993