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By M. Bai

The influence of mining on the hydro-geomechanical environment is greatly constrained by alternating mining geometries. The limiting magnitudes of surface subsidence and groundwater flow over the mining area, as a result of geometry changes, can be reasonably predicted through a coupled finite-element model introduced in this paper. Verification of the model has been tested using real and conceptual case studies which reveal that changes in strata conductivities are strongly related to the strata deformation induced by mining. The greatest modification of hydraulic conductivities occurs within the caving or severely fractured zones. The study indicates that narrowing the panel face width will substantially reduce both the intensity and extent of mining damage to the overlying strata, limit surface subsidence and constrain the change in hydraulic conductivity to a reduced scale and smaller extent, particularly as mining depth increases.

Jan 1, 1993

By Ron Jessulat

"IntroductionBrunswick Mining and Smelting Corp. Ltd. is a IO 500 tid base metal producer. Development is carried out by Jarvis Clark MJM-21 3-boom development jumbos, using Tamrock E400, 410 and 550 pneumatic drills. Typical drift size is 13 ft by 18 ft with a 12-ft advance per round. Blast holes are 1 ½ in. in diameter while reamed holes are 3 in. in diameter. AN/FO is the principal blasting agent, being loaded by C-I-L model60R intermediate loader. The detonators are NONELS and DETINELS. Sulphide dust explosions occur during blasting when dusts from certain minerals such as pyrite and pyrrhotite are ignited by name from the detonating shots. The result is a secondary unwanted explosion with a characteristic shock wave and name front that are very destructive to mine services such as ventilation ducting, electrical cable, and ventilation control doors.A typical reaction in the Brunswick orebody occurs according to the chemical formula:4FeS 2 + IIOs-2Fe2O3 + 8SO2 + 3458--(Enright , 1988)The hematite (FeO3) is deposited as a red dust in the blast area while the toxic sulphur dioxide gas (S00 contaminates the underground workings . The presence of S02 gas disrupts production until it is purged from the area by the mine ventilation system or dissipates slowly in those areas where the vent ducting has been melted by the name front or torn down by the shock wave.Sulphide dust explosions exact a high economic toll. Direct costs in damaged materials and wages are probably exceeded by the value of lost production and disruption to the mining cycle. In addition, the health and safety concerns associated with sulphide dust explosions cannot be ignored."

Jan 1, 1993

By Hans von Michaelis

There has been a renaissance in gold and silver extraction and recovery that has taken place over the last fifteen years, since the price of gold was freed from the $3510~ level. Despite major advances in such areas as carbon adsorption processes for gold recovery, refractory gold ore treatment, crushing and grinding, process control, etc., there still remain several gold and silver mineral processing frontiers. Frontiers related to environmental management present significant challenges especially in the USA. More than ever it is appropriate to optimize total economics by adopting a "systems approach" that integrates mining, mineral processing and environmental management.

Jan 1, 1993

By Y. K. Rao

In the carbonyl process for the refining of crude nickel CO(g) reacts with nickel in the 310-370K range producing nickel tetracarbonyl, Ni(C0)4(g). Iron and cobalt impurities also form gaseous carbonyls but their partial pressures are low. The carbonyl is led to a decomposer plant wherein the gas disproportionates in the 500-600K range depositing pure metal on nickel pellets that move countercurrent to the gas-flow. This system serves to illustrate the fundamental principles involved in the vapor phase mass transport of elements, against temperature-gradient, under the influence of chemical potential gradient. Unlike in the crystal growth, the source is at a lower temperature (say 350K) whereas the seed is in the hot-zone (say 550K) of the closed ampoule-type reactor. By assuming virtual gas-solid equilibria in the end zones, with diffusion of gaseous species between them acting as a slight perturbation, the quasi-steady- state mass-transport rates are computed for a range of CO-pressures and temperatures.

Jan 1, 1993

By A. D. MacPhail

The Highland Valley Copper partnership was formed in July 1986 and was the logical result of a mine with a large ore reserve but no adequate mill, and a mine with a large, modem mill but dwindling ore reserves. The original partners -Cominco and Lornex -were joined in January 1988 by Highmont Mining Co. which contributed a two-line concentrator. During 1988/1989, the Highmont mill was moved 7.5 km to adjoin the Lornex mill, forming what is now called the Highland mill, with a current nominal capacity of 130 000 tonnes per day. The mine is located 220 km northeast of Vancouver, British Columbia and is close to four communities in which personnel make their home: Logan Lake, Merritt, Ashcroft, and Kamloops. The map in Figure 1 2.2 shows the general area. Kamloops is a major service centre and is serviced by two railways, two major roads and a regional airport.

Jan 1, 1993

By H. T. Mulryan

Talc is used as an essential ingredient in a wide variety of plastics applications ranging from polyester body patch compounds through polypropylene automotive, appliance, and household furniture components to high performance parts made from liquid crystal engineering resins. The paper focuses on polyolefin applications; the three tier market for talc in polypropylene; the effects of various talcs in typical compounds; and trends in each market segment. Emphasis is given to emerging markets, examples of which are polypropylene compounds which mimic higher cost resins, and polyethylene films, customer requirements for talcs for these purposes are discussed.

Jan 1, 1993

Since the 1989 Loma Prieta Earthquake in the San Francisco Bay Area, the California Department of Transportation (CALTRANS) has accelerated seismic upgrading of their bridges. Many structures can be improved with the simple addition of hinge seat restrainers. Others require modification of column bents and superstructure to column connections. Often, footing retrofits are necessary, which require the addition of tension/compression elements (compression piling and tiedowns anchors) to resist overturning moments substantially larger than those originally used for footing design. These footing retrofits may include doweled reinforced concrete footing extensions or new pile caps which transmit forces to either driven steel or drilled concrete piles. In some cases, installation of these traditional piling elements is expensive, impractical or impossible due to: low overhead clearance, ground obstructions, high water table, noise or vibration sensitivity, or the inability to laterally expand the existing plan dimensions of the footing. In the latter case, one practical option is to attach small diameter drilled and grouted tension/compression piling elements (Pin Piles) to the existing footing. The footing may be strengthened with dowels and added concrete thickness or there may be a reduced shear span due to the installation of larger or jacketed columns. A reduction of elements is available with a Pin Pile alternative, particularly when the selection of traditional standard piles is governed by the reduced tension/uplift capacity available from the traditional elements, since Pin Piles exhibit superior uplift performance.

Jan 1, 1993

By C. L. Karr

Researchers at the U. S. Bureau of Mines have developed a technique for producing adaptive control systems using fuzzy logic and genetic algorithms. These controllers can be used to efficiently manipulate complex systems in real-time. Furthermore, they can achieve an acceptable level of control despite limited feedback in the problem environment. The control systems that result from the implementation of the Bureau-developed technique are able to recognize when changes have occurred in the problem environment, evaluate the magnitude of these changes, and alter the strategy being used to control the problem environment. Fuzzy logic is used to provide the controller with a rule-base that mimics the "rule-of-thumb" approach generally adopted by humans in the area of process control. Genetic algorithms are used to provide the controller with the adaptive capabilities necessary for the control of complex time-varying processes popular in the minerals processing industry. The effectiveness of this technique is demonstrated on a laboratory pH titration system. The pH system includes a changing setpoint, titrants with varying concentrations, and the possible addition of a buffering solution.

Jan 1, 1993

By Li YQ, Yoon RH

The photoresponse of natural mineral pyrite and galena electrodes has been studied in aqueous solutions on freshly fractured surfaces (some fractured in situ) using moderate overvoltages. When fractured in situ, the electrode potential of both minerals instantly drops several tenths of a volt. Pyrite exhibits a spontaneous anodic photocurrent at fracture, which indicates upward band bending (depletion layer) on the n-type electrodes. The negative surface charge responsible for the depletion layer is believed to arise from a surface state that is intrinsic to pyrite surfaces, possibly modified by hydroxide ion adsorption. The flat band potential, Vty, of pyrite is at approximately -1.0 V (SCE) at pH 9.2 but to reach V(b, pyrite has to be cathodically decomposed. In contrast, galena assumes the flat band potential at fracture. Subsequent polarisation of galena at potentials positive of Vth produces an anodic photocurrent (upward band bending) and polarisation negative of Vro a cathodic photocurrent. Most of the galena electrodes studied were degenerate n-type and at potentials negative of Vtb, no cathodic photocurrents are observed, indicating the bands cannot be bent downward, consistent with the Fermi level at the surface merging with the conduction band edge near Vn,. Several were close to intrinsic, with the photocurrent changing sign near Vn,.

Jan 1, 1993

By M. C. Furerstenau

Adsorption behavior of various surfactants on sulfide minerals is very much affected by the nature of the surface of the mineral. Since sulfides are naturally meta-stable, oxidation occurs when they are exposed to air, especially in aqueous environments. As a result. oxygen assumes a major role in sulfide flotation. Mechanisms of adsorption of various thiol collectors on sulfide minerals have been reviewed. The electrochemical behavior of various sulfide minerals has also been reviewed. Flotation behavior of galena, chalcocite, sphalerite, pyrite, chalcopyrite and pentlandite has been presented together with the. flotation of copper sulfide- nickel sulfide ore.

Jan 1, 1993

By C. Patrick

Longwall face-to-face transfers can cost over $100 per minute in lost production potential and $100,000 for personnel and supplies. Such high cost makes extensive planning and control of the transfer process a critical necessity for the economic feasibility of longwall operations. This paper reports operations research techniques used for the analysis and modeling of longwall face-to-face transfers. Transfer data has been collected from companies who operate over 30% of the total U.S. longwall faces. Comprehensive sequence networks of existing longwall transfers were developed; simulation models of transfers under varying conditions were generated; and, the economics of general transfers and time-cost tradeoffs in the transfer procedure were investigated.

Jan 1, 1993

By Chander S

Properties of surface films on chalcopyrite and pyrite differ due to variations in the mechanism of oxidation of the two minerals. In the case of chalcopyrite the first step in the oxidation is the release of iron as ferric ions, which hydrolyse depending upon conditions prevalent in solution. The iron oxide/hydroxide layer formed by hydrolysis of ferric ions is quite porous and easily detachable from the surface of chalcopyrite. When the surface oxide layer is detached a sulphur-rich layer is exposed making chalcopyrite hydrophobic. The thickness and properties of the sulphur-rich layer determine its flotation response, both in the absence and presence of collectors. In the case of pyrite, on the other hand, iron is released as ferrous ions which require much higher pHs to hydrolyse. These ions remain adsorbed on the surface of pyrite making the surface hydrophilic. When the iron species are complexed with chelating agents such as ethylene diamine tetra acetic acid, pyrite was hydrophobic. Siderite forms in the presence of carbonate ions, which might be present in several flotation systems. Siderite nucleated on isolated sites at the surface. The presence of such a precipitate is likely to influence the interaction of pyrite with various reagents thereby altering its flotation behavior. To determine the mechanism of oxidation, kinetics of oxidation of chalcopyrite and pyrite was studied using several electrochemical techniques, namely, cyclic voltammetry, polarisation and impedance spectroscopy. Floatability of the minerals was investigated by measurement of contact angles on mineral electrodes and by Halimond tube flotation. Impedance spectroscopy was especially useful for estimating various properties of surface film for both the minerals. Properties such as charge transfer resistance, porosity, and capacitances of the surface films on the two minerals are compared under several conditions of oxidation. These properties were found to be a strong function of the rate and the extent of oxidation.

Jan 1, 1993

By J. R. Palmes

Three coal samples, selected out of eight with well characterized surface properties, were used in flocculation tests and synthetic mixture of coal and silica was used in the selective flocculation experiments. Coal wettability and flocculant type were found to have a strong effect on the flocculation results.

Jan 1, 1993

By A. E. Petersen

The United States Bureau of Mines conducted research on high-intensity magnetic separation methods for upgrading tantalum concentrates from Alabama. Process flow sheets were studied to maximize tin removal and minimize tantalum loss. Using laboratory-scale equipment, concentrates were produced which contained over 65% combined Ta2O5-Nb2O5. Up to 78% of the tin was recovered as a byproduct, containing about 70% SnO2. Only 1 to 5% of the tantalum reported with the tin byproduct. The producer subsequently incorporated high-intensity magnetic separation into its process flow sheet to provide concentrates for the National Defense Stockpile.

Jan 1, 1993

By E. (Walt) van Walsum

The MPTM was first applied in the U.S.A. in 1950 as described by Lewis, W.E., 1951. The method was then abandoned in the USA and rediscovered some 20 years later in France where it was greatly improved and widened in its scope of application. It was subsequently successfully introduced to Italy and Spain. The technique, at its present stage of development, provides solutions to tunneling in soil and in the softer rock types, which often were troublesome geological environments for tunneling. When used in conjunction with drilling-and-blasting, over break, excessive vibration, noise and fissuring of the rock can all be avoided. When used as an alternative to the New Austrian Tunneling Method (NATM), the MPTM provides safe, full face tunneling in stead of multiple headings, excavated sequentially; in addition, surface settlement can be virtually eliminated. When used as an alternative to a TBM, the method's flexibility and low capital cost make it attractive. This attractiveness is enhanced when ground conditions are erratic or when the length of tunnel to be excavated is limited. The method holds promise for tunnels of large cross section, to be excavated in soft ground or rock with unconfined compressive strengths of less than 80 MPa (11 600 psi). While in itself not new, recognition and development of the method's potential are. Further development work, aimed at increasing the range over which the MPTM can be applied, is in progress.

Jan 1, 1993

By I. S. Parrish

One of the most common errors uncovered while performing a reserve, or resource, audit is not in the geological modeling or grade problems due to poor sampling, prepartion or assaying. The error most commonly found is in tonnage or, more specifically, in the tonnage factor - that factor applied to volume to derive tonnage. Tonnage factors In the metric system, the tonnage factor is the density, or specific gravity. Specific gravity (Sp.g.) is defined by Dana (1947): • "The specific gravity of a mineral is the ratio of its density to that of water at 4° C (39.2° F). • "Density is the mass of the unit volume or weight of the body divided by the weight of an equal volume of water." When Sp.g. is multiplied by the metric volume it yields metric tonnes. In the English system, the tonnage factor is usually expressed in cubic feet per short ton (cu ft/st). When the volume in cubic feet is divided by cu ft/st, the resulting figure is in English short tons. Table 1 gives the cu ft/st factors equivalent to specific gravities from 1.6 Sp.g. to 5.8 Sp.g. The table is based on the following equation: cu ft/st = 0.9072 divided by Sp.g. times 0.02832 The blase attitude that most geologists have toward tonnage factors is echoed in the prevailing definitions of Reserves and Ore, as provided by the US Securities and Exchange Commission (S.C Form S-18), Canadian National Policy 2A and the SME Proposal for Reporting Terminology (SME February 1991). In each case, it is stated that "quantity" (SEC, SME), or "tonnage" (Can.2A), "is computed from dimensions revealed in...." etc. Unfortunately, "dimensions" do not directly yield tonnage. Dimensions must be factored by density to derive tonnage.

Jan 1, 1993

By P. J. Stewart, S. Tracy

This presentation describes the operation and features of the WCC Carbon Reactivation Kiln. Particular emphasis is placed on minimizing carbon losses, corrosion resistance, fuel efficiency and the fate of mercury during reactivation in the multiple-tube vertical retort. Detailed laboratory work indicates that there is complete vaporization of mercury in the kiln, no refluxing in the upper sections and distinct advantages in using this type of kiln when sizing collection equipment.

Jan 1, 1993

By Bruce W. Downing, Philip G. Claridge

"The availability of environmental data is a major concern in the development of an exploration project through the permitting and feasibility stages. The collection of these data should ideally start very early in a major exploration program. Although a large proportion of the environmental data can also be used for exploration purposes, (e.g. stream-sediment, soil, and rock analyses), environmental sampling will rarely have been initiated at an early date. For the Windy Craggy project, a major environmental concern is the potential for generation of acid rock drainage from waste-rock piles. The project is reviewed with respect to the environment of the deposit, deposit geology, mineralization and reserves, the sequence of exploration activities to the present, the potential for the development of acid rock drainage, the geochemistry and water quality, and the integration of exploration and environmental databases and their application to environmental planning. IntroductionIn the classical sense of exploration of a mineral deposit, the efforts throughout exploration are routinely directed at confirming the existence of the deposit and defining its extent, grade and continuity. Environmental issues are usually tackled separately, possibly by different personnel at a later date. When that is the case, an opportunity is lost to build, from an early date , a comprehensive database that (I) will satisfy the needs of conventional exploration and environmental monitoring, and (2) is usable as a predictive tool for environmental impact assessment.The concept of environmental geochemistry is not complex. The availability of environmental data is a major concern in the development of an exploration project to the feasibility and permitting stages. The collection of data should ideally start very early in any major exploration program. In many cases a significant proportion of the geochemical exploration data gathered early in the life of a project will also be used later for environmental purposes (e.g. stream-sediment, water, soil, and rock analyses). Rarely, however, will the data gathered in a geochemical exploration program provide information as complete as that attainable if environmental objectives had been considered in scoping the work.A knowledge both of local and regional geochemical processes can lead to a better understanding of environmental impacts. This understanding is the basis upon which good environmental management practices may be built. Geddes Resources Limited has undertaken a major study of the natural environment in the Windy Craggy area which includes geology, surface and underground waters, soils, stream sediments, glaciers and geomorphology (Geddes Resources Limited, 1990). This paper deals with the building and integration of the exploration and environmental databases."

Jan 1, 1993

By W. H. Strickland, R. H. King

Ultrasonic ranging sensors are inexpensive, have no moving parts, have no lenses to clean, are normally small and unobtrusive, and can measure distances through moderate amounts of dust, smoke, and humidity, so they are well suited to underground mines. In the work reported here, conducted by the U.S. Bureau of Mines, researchers tested ultrasonic ranging sensors for their abiity to define rib line features for computer-aided navigation of underground mine mobile equipment. The investigation began with laboratory tests of field of view, angle of incidence, intersensor variation, and ranging accuracy of the individual rangers in a ring array produced by Denning Robotics of Wilmington, MA. The results showed that the sensors have good accuracy and low variability. Additional experiments at AMAX's Henderson Mine showed the sensors could accurately and reliably measure the distance to mine features, including convex and concave corners and rib intersections. The results showed that when used properly, the ranger data are accurate enough for reliable mine vehicle navigation When used incorrectly, ultrasonic rangers do not provide the anticipated data. Therefore, this report explains the principles of ultrasonic range measurement, describes the ranger's strengths and weaknesses, and explains proper ranger use and data analysis.

Jan 1, 1993

By Robert E. Moore

Synthetic spinel is proving to be a highly effective refractory for specific applications, but its cost limits applications. Formation of spinel from a raw material such as diaspore or bauxite could provide a simple and less costly starting material. In the study reported here, finely ground (-325 mesh) diaspore from Missouri and bauxite from Guyana and China are combined with hard burned MgO (-325 mesh) in appropriate proportions to yield spinel and spinel with secondary phases. A classical sintering and dilatometer study was completed, followed by a microstructure study to determine completeness of the reactions and morphologies of the reaction products.

Jan 1, 1993