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By R. D. Grove, M. F. Elliott, R. L. Weigel

The control of Florida phosphate flotation plants is largely based on the visual observations of experienced operators, both in recognizing good and bad froth conditions and in making judgments about the composition of feed, concentrate and tailing streams. Chemical analyses lag the process by at least two hours and therefore only assist in recalibrating the operators' vision when major deviations occur. An image analysis system has been developed by IMC Agrico Company (IMCA) to improve upon the accuracy and precision of the composition estimation process. It still relies upon the operator taking a representative sample, but provides a measurement in about 15 minutes after that sample is obtained. This paper describes the system and its use and presents comparative results for various process streams.

Jan 1, 1993

By G. F. Raymond

Discussion by G.F. Raymond Knudsen's study presents two curious conclusions: • The kriging of blasthole assays can systematically overstate mill head grades by as much as 21% as a result of unbiased sample variance. • No estimation method is able to reduce this bias to a small margin. The study is based on a simulation using real data and what are presumed to be actual variogram parameters from a real deposit. Although I have no doubt that the first conclusion (21% overestimation) is correct for the author's simulation, I do not believe this represents a realistic mining situation. Over the past 15 years I have done extensive comparisons between exploration drill-hole assays, blasthole assays and mill head grades on seven major open-pit mines, including some very erratic gold deposits. Commonly, nugget effects on blasthole variograms were 10% - 20% higher than on exploration variograms. And in one extreme case, the difference was 50%. Even in the extreme case, ordinary kriging on blastholes agreed well with the mill head grade over the long term. In Knudsen's simulation, the blasthole nugget effect is assumed to be 200% higher than exploration data's. He supports this by variogram plots from each. My guess is that the apparent, large difference between these variograms results from a failure to account for the proportional effect (blasthole assays are likely from a higher-grade area). A simple check would be a comparison of the variance of exploration samples nearest blastholes. As for a nearly conditionally-unbiased estimator of a large random error, the arithmetic mean of all of the data certainly qualifies, provided there is an even data spacing. As a corollary, so does simple kriging, which would include, in this case, a large weighting to the arithmetic mean. Similarly, using a large number of samples with ordinary kriging or indicator kriging would significantly reduce the bias in the case of a large nugget effect for the variogram.[ ] Reply by H. Peter Knudsen Raymond questions two conclusions in the paper. First, he wonders whether a 21 % overestimation represents a realistic mining situation. I agree that 21 % is high, but overestimation in the range of 10% to 15% is certainly common in my experience. Furthermore, several years ago I consulted on a gold mine that was experiencing a 45% overestimation due, predominantly, to poor blasthole samples: In further questioning of the 21 % value, Raymond wonders whether the nugget effect of the blastholes is really so much larger than the nugget values of the exploration data. It is consistently larger throughout the deposit. In my experience with six Nevada gold mines, the high nugget value is not unusual. In fact, for some reason, nugget values for blasthole samples are typically about 0.0005 (opt squared). I am of the opinion that this high nugget effect observed at many gold mines is predominantly due to the inherent inadequacies of the blasthole sample and subsequent sample preparation. The second conclusion Raymond questions is the inability of the estimators tested to reduce the conditional bias. In fact, the conditional bias is extreme with the polygon estimator and greatly reduced by ordinary kriging. However, it was not eliminated. Raymond suggests using simple kriging, or perhaps a larger number of samples, to reduce the conditional bias. The technique of simple kriging may be less affected by the random errors in the data, but I did not test the technique. Using a larger amount of data presupposes that too few samples were used initially. In ordinary kriging and indicator kriging, the screen effect comes into play and ensures that samples beyond the second screen are given zero weight. Hence, increasing the sample size does not change the estimates nor the conditional bias. The main point of my paper is that the random unbiased errors (a fact of life in blasthole samples) cause a conditional bias in our estimates. The mechanics by which the conditional bias is introduced are nicely explained by Springett. My paper simply shows that the bias is also present when working with linear estimators, such as ordinary kriging, and even with nonlinear estimators, such as indicator kriging.[ ]

Jan 1, 1993

By J. W. Evans

Mathematical modeling has now become a standard technique in the development of new technology and the improvement of existing technology in the processing industries. Physical modeling has a longer history but a smaller following at present. The paper reviews some examples of the application of both types of modeling in non-ferrous metal extraction, particularly within the copper and aluminum industries. The objective is to show that well founded models can lead to results that have practical consequence in scaleup, design and operation.

Jan 1, 1993

By Samyguin VD, Filippov LO

The aim of this paper is to emphasise the importance of knowing of the rate of the elementary flotation acts (EFA) - attachment and detachment. By studying the simplest linear model notion of the column flotation, the results of the nonlinear simulaton of flotation separation in the column with lengthwise upward mixing show two principal different types of separative mass-transfer in the column. The first is, the case of a small EFA intensity, almost without the detachment. The second is, the case of a big EFA rate, when the process is close to a local attachment-detachment equilibrium. There is also an attempt to estimate the EFA rate for three different kinds of quartz particles, floated by cation collector in the laboratory column apparatus.

Jan 1, 1993

MODELLING FOR DESIGN AND CONTROL AT KALGOORLIE NICKEL SMELTER Modelling at KNS has been driven by a need to have better tools to answer questions about control, design and optimisation of the plant. This paper describes a number of modelling tools developed for use at KNS and how the development of modelling tools fits with a design and control strategy. In the area of control, a thermodynamic model has been developed to allow process parameters to be calculated. The model allows for the automatic selection of data from a laboratory data base, desired operating set points are input and the operating parameters are calculated. The model has the ability to adjust the burner efficiency and the furnace heat loss depending upon conditions. To assist with the testing of proposed furnace design changes, various mathematical models of the burner and shaft have been created using PHOENICS. These models are particularly well suited to combustion heat transfer and flow aspects of both the burners and shaft. Validation of these models have been based on novel sampling and measuring techniques in the shaft and also by using scale and cold models. Overall plant energy and cost structures can be analysed using a flowsheet simulation, developed to evaluate potential alterations to the plant flowsheet. This model system allows the global evaluation of process changes.

Jan 1, 1993

By R. S. Kramer

A bulk compositional chemical analysis often provides incomplete information to help the mineral processor when faced with the problem of removing troublesome contaminants in low concentrations. Michigan Tech has developed a unique approach for addressing this problem. A combination of Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), and image analysis was successfully used to characterize the species responsible for phosphorus contamination of less than . 05 weight percent in iron ore. An automated routine acquired the chemical signature of each particle on a back scattered electron image. The few particles containing phosphorus were identified from the hundreds of particles examined, and the phosphate phases present were easily characterized.

Jan 1, 1993

By I. Iwasaki, X. Cheng

A series of batch flotation tests was performed on chalcopyrite-quartzite, on pyrrhotite-quartzite and on chalcopyrite-pyrrhotite-quartzite mixtures. Pulp potential measurements in the flotation tests with single sulfide minerals indicated that each sulfide mineral had its own optimal potential range for flotation. When these results were used to select the potential ranges for the separation of the two minerals from their mixture, their flotation responses changed, and the selectivity of separation was adversely affected. A possible mechanism involving surface alteration through galvanic interaction is discussed, and a method to improve the selectivity of flotation separation is proposed.

Jan 1, 1993

By D. M. Bodily, M. D. Deo, E. M. Whitney

Field data from coalbed methane wells indicate a significant variation in composition as a function of flow rate and time. In particular, San Juan Basin wells have displayed an increase in C02 concentration over time. Prediction of gas quality is critical to the economic evaluation of any coalbed project. Previous models have forecast only pressure and production profiles, ignoring compositional variations. In this study a multicomponent model that incorporates binary isotherms for methane and carbon dioxide has been developed. An extended Langmuir isotherm is used for the adsorption representation and a constant separation factor (similar to relative volatilities in distillation) describes the phase distribution of the species. This separation factor depends both on the surface characteristics of the coal and on the adsorbing species. The chromatographic separation equations have been superimposed on Darcy's law flow. The formulation allows decoupling of the pressure and compositional partial differential equations. The equations have been cast in dimensionless form and solved for pressures and compositions. It is observed that the composition of the preferentially adsorbed C02 increases at the wellbore as a function of dimensionless time. The dimensionless time is directly proportional to the real time and coalbed permeability and is inversely proportional to the gas viscosity, coal porosity and the square of the length of the reservoir. As the separation factor increases, the compositional variation increases. This variation in produced C02 concentration is also greater when the initial C02 concentration in the reservoir is higher. A sensitivity study has been performed to identify the effects of important parameters such as isotherm variables and reservoir characteristics on pressure and composition profiles.

Jan 1, 1993

By R. D. Grove

The control of Florida phosphate flotation plants is largely based on the visual observations of experienced operators, both in recognizing good and bad froth conditions and in making judgments about the composition of feed, concentrate and tailing streams. Chemical analyses lag the process by at least two hours and, therefore, only assist in recalibrating the operators' vision when major deviations occur. An image analysis system was developed by IMC Fertilizer to improve the accuracy and precision of the composition estimation process. It still relies on the operator taking a representative sample, but provides a measurement in about 15 minutes after that sample is obtained. Background The search for a quick and inexpensive technique for estimating phosphate flotation stream composition continues. There have been attempts at using "wet chemistry," nuclearmagnetic resonance, neutron activation, X-ray diffraction and other techniques reported on in the past several years. None of these have yet found its permanent place in the flotation plants of the Florida phosphate industry. IMC attempted to use wet chemistry to provide 7.5-minute estimates of final concentrate insol and tailings BPL. This was aborted after 36 months of plant operation due to the high operating costs for chemicals and an operator. There was also no significant economic improvement in the plant's operation. Another factor was the necessity to limit these crude analyses to only a few process streams, which were insufficient to achieve improved plant operation.

Jan 1, 1993

By Weller KR, Lim IL

The high pressure grinding rolls is one of the few new comminution devices that offer substantial savings when compared with traditional crushing and grinding circuits and with SAG milling. The machine has been well accepted in the cement industry, but mining companies have been more cautious in adopting this technology, partly because of wear and availability problems, and partly because of uncertainties in designing circuits which will deliver the power savings without complicating downstream processing. This paper addresses the latter problem by providing a model structure for predicting power draft and throughput from measurements made with small pilot scale high pressure rolls. Three existing models for predicting product size distributions are assessed and suggestions made for future work. The model structure comprises a power equation, incorporating measurements of torque and rolls speed previously used by the authors. Transport through the mill is assumed to be plug flow. Throughput is governed by the equilibrium gap between the rolls, which is determined both by machine settings and the physical properties of the feed material, including its size distribution. Therefore some form of physical testing in a model machine is required to determine throughput parameters. Results from copper and nickel ore experiments covering a wide range of machine conditions are presented and compared with model predictions. Model assumptions are discussed and directions for future work Suggested.

Jan 1, 1993

By S. W. Cavender

The analysis of the results of metallurgical experiments is often complicated by experimental errors and uncertainty, the complexity of the system being studied, and the confusion of correlation with causation. Consequently, comparative statistics are used to determine if a difference exists between the outcomes of tests, an estimate of this difference, and the precision of the estimate. This paper reviews the use of significance tests and confidence intervals for the comparison of results from two tests, the use of reference distributions, and blocking and randomization techniques to reduce unavoidable sources of variability. These techniques are demonstrated using plant and laboratory data.

Jan 1, 1993

By S. G. Zahony

The Moris gold deposit resides in a massive ridge-forming sulfide-poor epithermal quartz and calcite vein system and consists of a mineable reserve of four million tons of 2.1gm Au/ton. Post-mineral normal faulting along the hanging wall of the main fissure has caused a hogback-like exposure of the vein, allowing for inexpensive opencut mining. The vein formed between pre-Cretaceous(?) phyllitic clastic sedimentary units in the footwall and Tertiary andesitic volcanic rocks in the hanging wall. Part of the ore reserve is hosted in a Tertiary conglomerate that rests unconformably atop the phyllitic footwall sequence. The original unoxidized vein material contained substantially less than 1 gram Au/ton. A four-fold upgrading of gold occurred by enrichment when gold recrystallization took place in the electric fields of oxidizing pyrite cubes.

Jan 1, 1993

By Ajit K. Sinha

"Abstract - Electromagnetic surveys were conducted over the Yava sandstone-hosted lead deposit in Nova Scotia to evaluate the usefulness of such surveys for detecting and mapping sedimentary­ hosted metallic ore deposits. Both transient and multifrequency systems were used for that purpose. The deposit consists of three zones of disseminated galena which also contain minor amounts of pyrite and sphalerite filling the interstices of the sandstone grains. Each zone overlies a basement depression and is separated from the adjacent zone by an intervening basement high. A conductive shale layer underlies the galena-rich sandstone formation at all three zones.Because the concentration of galena (3% to 4% ) and other sulfides is too low to affect the resistivity of the sandstone formations for detection by ground electromagnetic (EM) methods, the strategy for our survey was to look for areas of basement depressions and the presence of conductive shale in those depressions by EM depth soundings. The presence of the galena-rich sandstone formations could be inferred because of the close association of these two features with the deposits in the Yava area. Both transient and multifrequency EM systems were successful in mapping the basement depressions and detecting conductive shale at the three known mineralized zones. The technique, therefore, seems to offer good prospects for mapping similar stratabound sedimentary-hosted sulfide deposits."

Jan 1, 1993

By Paul C. Jones

Summitville is an old mining district located south of Wolf Creek Pass in the southern San Juan Mountains of Colorado at an elevation higher than 3500 m (11,500 ft). The Summitville mine site is about 40 km (25 miles) southwest of Del Norte. The current mine, developed by Galactic Resources Ltd. and its subsidiaries in the mid-1980s, is on the north facing side of South Mountain. The area is drained by Cropsy Creek to the east and Wightman Fork to the north, both tributaries to the Alamosa River. Mining in the Summitville area began in 1870 when James Wightman discovered placer gold on what is now known as Wightman Fork of the Alamosa River. The first vein-type deposits were located in 1873 on South Mountain near the current Summitville Mine. Mining began in the district in 1875 and continued sporadically through 1942. Major mining episodes occurred from 1875 to 1894 and from 1926 to 1942. Total gold production from the mining district through 1949 totaled 7.5 t (240,000 oz). An additional 7.7 t (249,000 oz) were produced during Galactic's tenure. Natural degradation of the outcropping sulfide-rich veins in the area and the early mining activity, including development of the Reynolds, Dexter and Iowa drainage tunnels in the late 1890s, have polluted the streams draining the area with heavy metals and acidic water. Names of the various tributaries to Wightman Fork, such as Iron, Alum and Bitter Creek, testify to this natural pollution. This degradation has reduced, or killed, aquatic life in several area creeks, including Wightman Fork, for many years before recent mining activity.

Jan 1, 1993

By F. M. Doyle, Jun Li, Milton E. Wadsworth, E. Peters

The Raman spectroscopic technique was used to study electrochernically oxidized pyrite in-situ. It was found that Raman-active sulfur oxidation products could be detected after a proper potential was applied to the pyrite electrode for a threshold period of time. There existed a minimum potential below which sulfur could not be observed. However, when the applied potential exceeded a certain limit, the intensity of the sulfur spectra decreased. The minimum potential at which sulfur could be observed changed with solution pH. For both acid (pH 2.7) and weak alkaline (pH 9.2) solutions, the minimum potential was 0.8 V/SCE, whereas for neutral (pH 6.5) solutions the value was 0.4 V/SCE. In strong alkaline solutions (pH 12.5) surface sulfur oxidation products could not be detected at any potential.

Jan 1, 1993

By B. L. Gibbs

The mining industry is constantly in a state of flux -boom or bust; mine openings and closings. Part of the reason is the nature of ore deposits -they are there or they are not. Once they are mined, they are reclaimed and the move is on to the next deposit. Risks are usually high, and payoffs can be great or not so great. Many factors go into making a property payoff, and mining companies are continually searching for ways to remain profitable as long as possible. Computers and the people who can make them work are one of the ways available to improve productivity and ensure this happens. Computers have been used in the mining industry for the last 30 years (and more in a few cases). During the past 10 years, the explosion of micro-computing has changed how many mining companies do their work.

Jan 1, 1993

By Ullrich Kammer

Metaleurop's secondary lead smelter at Oker produces 60.000 mtpy of lead and lead alloys. More than 8O2 % of the raw materials are spent lead acid batteries. The other 2O2 % consists of drosses, ashes, scrap lead, type metal, sludges, etc., and is processed in a short rotary furnace (SRF). Also, industrial batteries not fitting in the battery scrap treatment plant are processed in the SRF provided with gas/oxygen-burner. Till Sept. 199O2, a soda ash slag was used in the SRF-smelting similar to the rotary kiln-smelting at Oker. Facing the future problems of handling and dumping soda ash slag, Harz-Metall GmbH has improved SRF-smelting with a non¬hazardous slag, insoluble in water, easy to dump and cheap in fluxes. This slag is based on a CaO-SiO2 -Fe0-type. Aim of the slag smelting is to be within the temperature range of 2 1100° and 1200°C - the eutectic line of Olivine in the corresponding ternary system. Since Sept. 199O2 Harz-Metall GmbH has operated the SRF with an "Olivine-type slag" with good results. Although the material is a "leady" slag. HMG is optimistic of using it as a filling material for construction purposes.

Jan 1, 1993

By Eisele TC

Horizontal perforated-plate baffles were shown to improve the cleaning efficiency of a flotation column when processing coal from two sources. The baffles consisted of flat plates with holes large enough to avoid plugging problems, and they improved the washing efficiency by making the flow patterns in the column closely approach plug flow. Tests with varying amounts of baffle open area showed that the optimum was between 30 and 40 per cent open area, which effectively prevented backmixing without seriously reducing capacity. The baffled column had previously been tested under ideal conditions with good results (87 per cent pyrite rejection at 85 per cent combustiles recovery), and so the tests reported here were intentionally run with difficult-to-float coals to determine the benefits of baffling under adverse conditions. For an original coal feed containing 38 per cent ash and 3.23 per cent total sulphur, the baffled column could recover 84 per cent of the combustibles while rejecting 84 per cent of the ash and approximately 54 per cent of the pyritic sulphur. Without baffles, the column recovered 88 per cent of the combustibles while rejecting only 76 per cent of the ash and 45 per cent of the pyritic sulphur. Subsequent tests with a dye tracer showed that the baffles reduced entrainment by approximately a factor of five, while the recovery was reduced by only a few per cent. Overall, the loss of capacity due to the baffles was more than offset by the improvement in product quality.

Jan 1, 1993

By J. A. Bleeck

A discourse on the relationship between industrial minerals and paper production, concentrating on high grade, ultra fine ground calcium carbonate (mean particle size less than 2 microns) and precipitated calcium carbonate. The scope of the paper encompasses four basic areas relevant to the topic: 1. A tutorial overview of the papermaking process with an examination of various industrial mineral components in that process; 2. A discussion of basic technological topics pertinent to the utilization of carbonate in paper with emphasis on the relative aspect. Of natural ground calcium carbonate (GCC) and synthetic precipitated calcium carbonate (PCC); 3. An overview of paper and carbonate market, in both the United State, and Europe with emphasis on (a) current status and future growth trend. Of such market., and (b) discussion of the major influences on growth and development of such market.; and 4. Identification and discussion regarding the principal producers in calcium carbonate markets serving the paper indu.try in Europe and North America.

Jan 1, 1993

By Jr. Raleigh

As part vi the development of the Coal Quality Expert (CQRN) --a computer program capable of predicting the impacts of coal quality on power plant performance, costs, and emissions control--several nationally important coals are being characterized to augment the coal quality database associated with the software. The project is sponsored by the U.S. Department of Energy and the Electric Power Research Institute (EPRI) under the Clean coal Technology Program. Since 1989, CQ Inc. (a subsidiary of EPRI) has characterized seven bituminous coals from Alabama, Illinois, Kentucky and Oklahoma and six sub-bituminous coals from the Powder River Basin (PRB) in Montana and Wyoming. Coals from the PRB region--being burned more frequently in Midwestern and southern power plants to reduce emissions of sulfur oxide compounds--can sometimes contain significant concentrations of potentially toxic elements. Although no limits were imposed on air toxics emissions from fossil-fuel fired utilities by the Clean Air Act Amendments of 1990, future regulations may be implemented at the conclusion of Federally-mandated emissions studies. One possible result is that any increased utilization of coals, including those from the PRB, may depend on the potential for removing toxic trace elements prior to combustion.

Jan 1, 1993