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By John L. Hostetler

GALFAN, the Zn-5% Al-mischmetal hot-dip galvanizing alloy is coated onto steel sheet, wire, and tube using high-speed continuous galvanizing lines. Factors critical to producing high quality GALFAN are reviewed, The relationship between minimum mischmetal content in the GALFAN alloy and furnace dewpoint will be described. The relationship between peak annealing temperature and furnace dewpoint will also be shown. Typical suategies for operating multi-purpose hot-dip galvanizing lines including GALFAN will be described. A recent development has allowed preparation of steel smp for GALFAN coating using aqueous fluxes rather than high temperature annealing. This allows production of GALFAN-coated smp without over-ageing of the steel, and allows high steel strengths and hardnesses to be obtained. The principles of this process will be described.

Jan 1, 1992

By E. K. C. Chanda

The best use of available reserves to give good metal recoveries relies on short term mine production scheduling.-The aim is usually to produce a plan to guide mining in specific areas that will enable mine operations to deliver the budgeted tonnes and grade to the mill and keep within the long range mine plan. Thus, short term production scheduling is an important aspect of the open pit mine planning function. Since the 60's increased attention has been paid to effective production scheduling as a means of improving the economic viability of existing mines. Hence, mine scheduling scheduling systems have been evolving rapidly during the last two decades. These systems include manual techniques, computer based simulation, mathematical programming and more recently Computer Aided Design (CAD). Some general drawbacks of the current scheduling systems are that firstly, the costs of acquiring and using them are not at all insignificant especially for small to medium sized pits. Secondly, there is an inherent trial-and-error aspect in these systems. Thirdly, they tend to be suited for specific orebody geometries, hence lacking the necessary generality. For instance, the use of computer programs for planning open pits to mine stratiform orebodies raises problems which are not usually met when massive orebodies are considered. There for, a need exists to develop simpler but effective short term pit scheduling procedures suitable for stratiform type orebodies, considering their geometry and geology. This paper describes a PC- based model designed to assist the planning engineer in optimizing the short term production schedule in open pit mines with stratiform orebodies. The model is based on a combination of linear goal programming and deterministic mining simulation. The orebody model is made up of ore and waste mining regions where winning and and/or stripping are taking place. These shovel regions form the basic planning elements in the model. This approach does not require the laborious preparation and use of a regular block model. The computer program consists of main modules: (i) Data capture - processes the raw data into the required format for mine planning. (ii) Precedence mining constraints - checks the status of each shovel .region at the beginning of a given scheduling period with regard to geometrical mining constraints such as undercutting. (ii) LP- Optimization - provides an optimal selection of ore shovel regions which do not violet geometrical constraints for mining in the period, the objective, being to maximize the contained metal equivalent in the blended R-O-M ore and at the same time to minimize deviations in grade and tonnage from the call values. (iv) Post LP-Simulation - enables the user to smooth out the LP solution in order to adjust it to a practically executable plan and simulates mining of ore and waste for the period. Shovel allocation to selected ore and waste shovel regions, unit operations and depletion of reserves are executed in this module. Preliminary testing of the model for monthly production scheduling using data from Nchanga OPen Pit on the Zambian Copperbelt indicates that it can be a useful planning tool and gives acceptable results.

Jan 1, 1992

By Y. S. Roditis

A new method for interpolating a block model is proposed, where both the diamond drill holes (DHs) and blast holes (BHs) data are used. Combining these data types poses a geostatistical "class size" problem due to the different statistical properties of the densely populated BHs and the sparsely populated DH data. This paper discusses how linear regression was used to adjust the DH values prior to the interpolation to account for the "class size" problem which is inherent to the procedure. The correlation between the BHs and the DHs is found. The DHs are then corrected based on the regression line. Each block that falls within a certain range of influence of a blast hole is assigned a different code and is interpolated with the combined BH and regressed DH data set. Blocks that fall outside the range of blast hole influence are interpolated using the original DH data set. A comparison against other methods, indicate a 12% improvement over using DHs only and a 2% improvement over using BHs only.

Jan 1, 1992

By G. J. Trezek

The use of polysilicates for treating heavy metals in soils and mining sludges is discussed. Results of the treatment are given for soil contaminated in a metal scrap yard operation and for copper mining processing sludges. The types of metals of concern are arsenic, lead, copper, nickel, cadmium, and zinc. The application of the treatment is predicated on the mixture and relative concentrations of the metals as well as the material matrix. Reductions in soluble concentrations (STLC or TCLP) of one to two orders of magnitude can be achieved with relatively small additions of silicates and cementitious materials.

Jan 1, 1992

By Gary R. Adams

Coating thickness control is typically difficult with touch-up solders for galvanized steel, and corrosion properties and abrasion resistance are sometimes poor. This paper reports on progress in ILZRO-sponsored research to develop an improved touch-up solder. Encouraging results were achieved in torch soldering trials with zinc-tin based alloys. Mouldability and coating thickness control were achieved over a practical working temperature range in which the solders consisted of a viscous mixture of solid primary zinc phase particles in a liquid zinc-tin eutectic matrix The mouldability was dependent on the microstructure of the starting material, and optimum structures could be obtained through control of casting solidification rates and/or by the addition of small amounts of copper. Hardness and preliminary corrosion test results showed potentially good mechanical and corrosion behaviour. The absence of toxic materials ensures environmental friendliness. Comprehensive performance testing is continuing on selected experimental zinc-tin-copper touch-up solders.

Jan 1, 1992

Develop a safer, more effective, and more efficient method to control fires in abandoned coal mines and waste banks. Maintain the costs of this new method at less than or comparable to conventional AMI fire control methods. How It Works Cryogenic extinguishment of subsurface fires is a method of heat transfer. Bureau-designed injection equipment produces a pumpable slurry of liquid nitrogen and solid particles of carbon dioxide. Liquid or gaseous carbon dioxide from a pressurized tank flows to a bell-shaped nozzle where the change in pressure causes the carbon dioxide to form a granular snow. The solid carbon dioxide is mixed with liquid nitrogen. A jet pump is used to move the slurry through the delivery lines and into a simple injection probe. At injection, the nitrogen vaporizes and the carbon dioxide sublimes. This phase change produces a cold gas (-180° C) that, as it expands and moves in all directions, removes heat and also displaces oxygen. This combined process inhibits the combustion process and lowers the temperature below the reignition point. When the liquid nitrogen and solid carbon dioxide are converted to gases, the expanding gas acts like a piston, forcing warm air out of the porous bed, Although smoke and hot gases arc forced from the burning coal, generally there is no significant increase in the odor associated with burning coal.

Jan 1, 1992

The Annual General Meeting of the Johannesburg Branch of The South African Institute of Mining and Metallurgy was held at the Johannesburg Country Club on Tuesday, 21st July, 1992. Big turnout at Lunchtime Lecture The re-introduction of Lunchtime Lectures by the Johannesburg Branch of the South African Institute of Mining and Metallurgy met with resounding success when more than 100 delegates packed the Standard Bank auditorium in Simmonds Street to hear Dr Zach de Beer, leader of the Democratic Party, give his views on the state of the nation.

Jan 1, 1992

By Haase W. C

The content of this paper will identify recent developments in walking dragline technology including utilisation of planetary swing dnves, high voltage generators, unique bucket configurations and increased machine capacity resulting from changes to front-end geometry. The benefits to mine operators for increased performance, reduced cost, improved availabilities, simplified maintenance, and ease of operation will be identified and discussed. The feasibility and application of the technology as a retrofit on existing equipment will also be covered in the presentation. All the technology being presented has been recently commissioned into operating Australian mining operations and will be presented from a practical, as well as theoretical perspective.When the Marion 8000-Series Dragline was introduced in the early-1970s, it quickly became the industry standard for high productivity and availability. Features like outboard bearing propel, four-chord deep section boom and the over/under fairlead have proven their superiority in thousands of hours of round-the-clock operations in a variety of tough digging conditions worldwide. Marion has currently sold 31 of these 8000-Series Draglines into the Australian mining community.

Jan 1, 1992

By F. G. Prado

The technology for the extraction of zinc from zinc residues, such as zinc ashes, drosses and metallurgical flue dusts, by way of ammonium chloride solutions is well established, at least at the laboratory and bench scale levels. (3, 4) Zinc is soluble in ammonium chloride solutions in the form of zinc diammine chloride. Its solubility depends upon the concentrations and temperatures employed. The procedure and the equipment required are simple, and they can be applied either to small or large operations. As a by-product, zinc diammine chloride is produced with extremely low impurities in quantities which are stoichiometrically proportional to the zinc removed. The technology has been applied experimentally to galvanized steel residues. The dezincing results, including removal performance, energy and reagents required, and by-products are summarily presented in this paper.

Jan 1, 1992

By R. K. Singhal

In 1990, Canada produced 69.4 million tonnes of coal of which some 65 million tonnes was produced by surface mining methods. The two Western Canadian provinces, Alberta and British Columbia produce approximately 55 million tonnes of coal by surface mining. These two provinces also provide the bulk of the metallurgical coal for export. The geological conditions in the Western provinces particularly in the mountain region are complex. The coals are friable and the seams are steeply inclined, sheared, intensely folded and faulted. There may be as many as 15 to 20 coal seams present with true thickness ranging from 2.5m to over 8m. Most of the Canadian surface mines are large (over one million tonnes per annum) using modern mining equipment such as shovels, high capacity trucks and draglines. At present the industry is going through another of its up and down cycles but has continued to make impressive gains in productivity. This has been achieved through greater mechanization, better management practices and a will to succeed in a highly competitive world market. This paper presents an insight into the current status of the Canadian Coal Industry and essentially updates the information given by the authors at previous SME meetings.

Jan 1, 1992

As the theme of the conference is ære-discover Otago' from the minerals point of view, it is also timely. Of the eight million ounces of gold recorded produced from Otago, perhaps a quarter of this came from the goldfields of St Bathans, Vinegar Hill and Cambrians. The most notable among them was the Kildare Hill Mine, which is the so-called Blue Lake at St Bathans today. The bottom wash encountered in this mine contained the famous Kildare lead, which averaged 7 1/2 dwt to the dish, and is still one of the richest leads of alluvial gold known in the world. The richness of this lead, the best encountered in these gold fields, is otherwise stated to have yielded more than 42 ounces of gold to the cubic yard. It should be borne in mind that this equates to about $22 000 per cubic metre, in todayÆs values. I have been told by older residents of this district that in fact about 1 million ounces came out of the Kildare mine and associated workings. In todayÆs values, this would be about 530 million dollars worth of gold. The largest mines in the district were at Surface Hill, Kildare Hill, Nicholsons, Vinegar Hill, the Never Fail claim at Shepherds Flat nearby, and at Cambrians. It would appear that in almost every case, work stopped when the bottom wash progressed too deep down dip of the anticline hills on which it was initially found. The mining methods were sluicing and hydraulic elevating, and although the gold bearing ground did not stop, eventually it exceeded the ability of the mining methods then available years ago, to work it further. When it is realised that the previous mining has removed what is likely to be only a low percentage of the gold resources in these fields, a tantalising situation presents itself today in that mining technology now available will enable another cut to be taken off these fields. As in the past, I believe this will be million ounce plus and multi-million dollar scenarios, where the economic and social benefits will become widespread prizes.

Jan 1, 1992

By K. Darcovich

The wettabilities of agglomerates made from coals of several different ranks were measured by the adhesion technique. Oil levels from 0 to 10% by weight were used. As was expected, it was found that higher-rank coals are more easily oil-wetted and that the surface properties of the agglomerates correlate with agglomeration recovery and ash removal data.

Jan 1, 1992

By C. R. Tinsley

In maybe the world's first in a mine project financing, a US $55 million Rehabilitation Indemnity was given on behalf of the banks in a US $250 million loan to develop the Ranger uranium mine, Northern Territory, Australia. The basis of the financing was an estimate of removal of the tailings and replacement into the pit. The Indemnity was amortized by a sinking fund from the mine's revenues. Such a concept could be valuable for mineral developments in sensitive areas or jurisdictions such as British Columbia or Alaska.

Jan 1, 1992

By M. P. Bohrer

A closed-loop hydrometallurgical process has been developed for treatment of smelter flue dust generated by copper recycling. The process is a semi-continuous operation in which zinc, iron, and copper are first extracted from the dust with a sulfuric acid solution. The lead and precious metals, initially present in the dust, remain as solids and can be recycled to the copper smelting furnace. Cementation with iron and zinc metal purifies the zinc and iron-rich liquid stream prior to spray drying. The spray-dried product, consisting of a mixture of zinc sulfate monohydrate and iron sulfate monohydrate, is a desirable micronutrient additive for use in animal feeds. Treatment of the smelter flue dust in this manner will generate a positive return on investment, as well as mitigate a potential environmental liability.

Jan 1, 1992

By T. R. Wildeman

"At the Big Five wetland, which was built to treat drainage from a metal mine, encouraging results have attributed to sulfate reduction. Cu and Zn were reduced to below detection limits of 0.50 mg/L, Fe was reduced by at least 90% to below 3 mg/L, and the pH was raised from below 3 to above 6. The study showed that treatment was primarily through microbial processes within the substrate and that plants were not needed to insure success.Constructed wetlands can be taken through design and proofing stages, and into operations scale in a meaningful time frame for on-line acid drainage remediation. In staged design, laboratory experiments are initiated to determine reasonable substrate materials for remediation of a particular drainage. When a reasonable substrate is found, bench scale experiments are initiated as the next stage in the design. In these studies, removal efficiency, permeability, and flow are analyzed to identify candidate substrate which will support sulfate reduction and be hydraulically reasonable. Using this design method at one site, an acid drainage of pH 2.5 was raised to a pH of above 7. Total heavy metal concentrations in this drainage exceeded 900 mg/L. In the pilot constructed wetland Cu, Zn, and Fe were reduced by 99%.Determining how well these anaerobic cells operate in the winter is done at the pilot plant site in Idaho Springs, CO. It's been found that over the last four winters, those cells that emphasize anaerobic removal within the substrate have operated continuously and effectively the year round. Winter operation is aided by the fact that the water temperature of the acid drainage is always between 14 and 16° C, and the cell can be readily insulated from the cold. Activity of the sulfate reducing bacteria may decrease during the winter. However, it appears that organic complexation of metals helps to maintain low concentrations of metals in the effluent."

Jan 1, 1992

By Walter G. Steblez

The countries of Eastern Europe are former members of the Council for Mutual Economic Assistance (CMEA). Geographically, they are located in Central Europe (Poland, Hungary, Czechoslovakia) and Southeastern Europe, largely in the Balkans (Yugoslavia*, Bulgaria, Romania and Albania*). It is important to remember that all of the countries of Eastern Europe had central planning imposed on them by the Soviet Union during the years following World War II. "Stalinist" policy for industrial development had three important tenets: • central economic planning, or a nonmarket-based command economy with administratively set prices; • economic priorities that stressed the development of heavy industries such as mining, metallurgy (steel) and heavy machine building; and • self-sufficiency at all costs, which was aimed at abolishing reliance on the world capitalist market, or reducing it to a minimum. Essentially, the system of industrialization that was used in the Soviet Union in the 1930s and 1940s was imposed on Eastern Europe. Organic market economic development in Eastern Europe ceased during this period. The flaws of this experiment became apparent when mineral processing facilities were set up in many areas of Eastern Europe that did not have reliable resources. Poland, Hungary and Romania are good examples of this situation. The Soviet Union became the principal supplier of iron ore and other minerals and mineral fuels, not only to these countries but to the Bloc as a whole.

Jan 1, 1992

By G. Folmo

Allis Mineral Systems' GRATE-CAR agglomeration/induration/reduction process is currently being operated to process ilmenite at Tinfos Titan & Iron KS in Tyssedal, Norway. In this process, balled ilmenite concentrate is fed to a traveling grate where pellets are dried and preheated, using fully oxidized kiln exhaust gas. Hot preheated, semi-indurated pellets are fed directly to a ported kiln where reduction of the ilmenite's iron oxide fraction occurs in the presence of lump coal. The reduced pellet sand coal char are discharged from the kiln to an indirect rotary drum cooler. Cooled pellets and char are screened and magnetically separated prior to their further processing in a downstream smelting operation. The pellets are melted and the titanium dioxide and iron are separated. Operation commenced in late 1986.

Jan 1, 1992

By Peter N. Gabby

In 1990, the Bureau of Mines conducted a mineral resource investigation of the 12.321 acre Black Warrior study area, one of several proposed additions to the Sawtooth Wilderness. No identified mineral resources were delineated. There were 123 lode and placer claims in or adjacent to the study area. There is a known hot spring adjacent to the study area, but presently no geothermal leases are pending. Lode mines in pr adjacent to the Black Warrior study area have produced 4,022 tons of ore from which 1,981 oz of gold and 811 oz of silver were recovered. None of the vines are currently active. During the field study 125 rock samples were taken. Significant gold assays and favorable geologic characteristics at seven properties indicate that gold occurrences and resources with byproduct metals may exist in the study area. Two other sites yielded anomalous gold assays; however, sage favorable geologic characteristics are lacking. Presently, identified gold resources are being delineated by drilling programs in the nearby Atlanta and Rocky Bar mining districts. These districts have geologic characteristics similar to the Black Warrior area. During the field study 22 placer samples were taken. In most places where an anomalous concentration of gold was found, the stream channels are too narrow for operations other than recreational suction dredges. However. One area is estimated to contain over 2 million yd3 of gold-bearing gravels.

Jan 1, 1992

By E. D. Sehnke

The refractory materials industry provides the largest commercial market for nonmetallurgical grade bauxite. Refractory grade bauxite is prepared from bauxites having low iron, titania, and alkali content by calcining at temperatures near 1,650° C. Although there are substantial bauxite reserves in the world, premium grade bauxite ores suitable for use in refractory applications are limited to only a few specific sources, primarily in Guyana and the People's Republic of China. Consumption of bauxite for refractory use is closely associated with the production and consumption of primary metals, in particular iron and steel. Barring major disruptions within the principal producer nations, sufficient supplies of refractory bauxite will be available to meet world demand well into the next century, and raw material costs will continue to determine the availability of markets for bauxite-based refractory products.

Jan 1, 1992

By Tomás Vargas

The catalytic influence of a pure strain of Thiobacillus ferrooxidans (ATCC 19859) on the dissolution of natural pyrite crystals was studied using electrochemical techniques. The results showed that this microorganism catalyze the leaching of pyrite by both, oxidizing ferrous iron in solution and depolarizing the reduction of ferric ion on this sulfide. In addition, studies of bacterial corrosion under applied potential showed that pitting on the pyrite surface centers on weak sites of the sulfide structure in which bacteria has attached, but occurs only when the ferric iron in solution induces an adequate level of anodic polarization on the mineral.

Jan 1, 1992