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By R. L. Nyirenda

One of the problems with ammoniacal-ammonium carbonate leaching of EAF carbon steelmaking flue dust is that zinc present in spinel phases is not leached. This paper presents results of test work in which prior to leaching, EAF dust was reduced with CO containing gas to decompose the spinels into zinc oxide and iron bearing phases, mainly metallic iron and wustite. From such reduction products, the amount of zinc leached increases but the iron co-leached becomes extensive. The effect of various leaching parameters such as liquor concentration and redox potential on zinc and iron dissolution has been investigated. Supplementary experiments utilizing pure zinc oxide and pure iron phases were also carried out. Results show that the co-dissolution of iron from severely reduced EAF dust cannot be prevented. This is because the wustite phase contains zinc which can only be leached when iron also dissolves. Further, the zinc bearing wustite phase is not totally soluble so that the residue cannot be made zinc free. In the absence of air, dissolution of metallic iron hardly occurred, though in leaching experiments of a long duration its transformation to a spinel structure was observed.

Jan 1, 1992

By Arthur J. Hudson, Lawrence W. Scott

The performance of RETIMET metal foam as a flame arrester on explosion-proof enclosures was investigated by the U.S. Bureau of Mines both in laboratory tests and at the U.S. Mine Safety and Health Administration's (MSHA's) Approval and Certification Center, Triadelphia, WV. The objective of this research was to develop a permissible pressure vent for use on lightweight, vented, explosion- proof enclosures. In laboratory tests, four grades of RETIMET, a stainless steel foam material, were evaluated: (1) 45 NC-7, (2) 45 NC-13, (3) 80 NC-7, and (4) 80 NC-13. Explosive gas mixtures were prepared by a dynamic flow system. Ignition was by a low-voltage arc. Each grade of RETIMET metal foam successfully arrested the flame front in all methane-air tests. To evaluate RETIMET metal foam on large, commercial size enclosures, a multicompartmented enclosure was designed and tested in MSHA's explosion gallery in Triadelphia, WV. Extensive explosion testing revealed that a minimum vent-area-to-enclosure-volume ratio of 11.33 in2/ft3 is required to keep internal pressure rises below 3 psig. The RETIMET metal foam functioned satisfactorily in all tests as evidenced by the absence of external ignitions.

Jan 1, 1992

By D. E. Healy

In 1989, an autogenous grinding task force was formed to study potential autogenous grinding circuits to replace the existing semi-autogenous grinding (SAG) at the National Steel Pellet Plant in Keewatin, MN. Pilot plant test work, performed by the Hanna Research Center (HRC), indicated that fully autogenous grinding with pebble extraction and crushing could be incorporated into the existing circuits. In 1990, one of the existing 10 grinding mills was converted for an in-plant test incorporating pebble crushing. Full-scale test work were conducted in 1990 and 1991. They verified the pilot plant projections with primary mill throughputs from the fully autogenous circuit using pebble crushing being greater than throughput of the existing SAG mill circuits. The plant produces 5 Mt/a (4.9 million ltpy) of iron ore pellets from 17.6 Mt (17.3 million It) of crude taconite. Crude ore is single-stage crushed by gyratory crushers. Primary grinding is performed by 10 semi-autogenous wet grinding mills. Secondary grinding is performed by five ball mills. Induration is with an Allis Chalmers grate-kiln pelletizing system. The primary grinding circuit consists of 108.2-m-diam x 5.5-m long (27 ft-diam x 18-ft) SAG mills. The mills are charged with 127 mm-diam (5 in.diam) steel grinding balls at from 3% to 5% by volume. Ball consumption rate is about 0.55 kg/t (1.25 lbs/lt) of crude ore feed to the mill. Each SAG mill is powered by two 2.6 MW (3500 hp) motors drawing 5450 kW (7300 hp) at 76% of critical speed. The mills are grate discharge with 16 mm (0.6 in.) slotted grate openings when new. The mill discharge is sized on a trommel screen having 4.5 mm (0.2 in.) openings. The plus 4.5 mm (+0.2 in.) oversize material is returned to the discharge end of the mill by a reverse screw auger located in the center of the trommel. The -4.5 mm (-0.2 in.) trommel screen undersize is pumped to magnetic cobbers.

Jan 1, 1992

By Y. Maeda

Non-ferrous smelting furnaces generally install a gas cooling system for treatment of waste gas containing SO2,. From the point of view of corrosion resistance and recovery of waste heat, the high pressure boiler system is the best way to cool gas, however this system requires high initial investment and relatively higher operating costs. Because the feasibility of this boiler system greatly depends on the smelting process and scale, other lower temperature systems, e.g. water-cooled jacket system, are more suitable if the smelting process does not produce enough steam nor generate enough electricity to compensate operating cost. In additton, the water-cooled jacket system is simple in structure and easy to operate. For those reasons, it is applied widely. A new smelting furnace was planned in our factory and it was necessary to install waste gas cooling equipment. In our case, a water-cooled jacket system was more feasible because of the low gas volume and high dust content. It was also expected to operate without maintenance for ten years. On the other hand, some leakage problems with the water-cooled jacket had been experienced in the past. That is because SO2 In the waste gas changed into sulfuric acid which corroded the jacket material. As the first step, several data from actual' usage were reviewed to throw light on the corrosion process, and an appropriate procedure to determine the operating temperature of cooling water was obtained. For the basis of this study, a water-cooled jacket system was newly designed and tested for three months in a pilot plant. After this system's performance was confirmed, it was installed in a new furnace as a commercial plant. After one year of operation, the initial thickness of carbon steel jacket remains almost the same.

Jan 1, 1992

By Chris M. Healey

"Perhaps the single most significant variable in the evaluation of a mining project is the reserve estimate. Many parameters are considered when estimating reserves, among them geology. This paper examines the link between the quality of a reserve estimate and a good understanding of the geological controls for the deposit. A clear understanding of the geometry is essential to the accurate definition of the shape and size of the deposit. This includes the definition of any structural controls as well as the proper interpretation of the stratigraphy. Further when the distribution of grades is erratic and there is consequently a high nugget effect, there are significant problems in estimating the true grade of the deposit.Two Saskatchewan examples are presented, one with good knowledge of the controls and therefore good estimates of reserves, and the other with a poor understanding of the geology and resultant problems in deriving good estimates. In both cases the reserve estimates at various stages in the project development are compared to actual results from underground work. The first example is the Star Lake Mine where just about all the estimates were within 10070 of the actual on both tonnage and grade. The Laurel Lake deposit is discussed to show how problems in interpreting the geological data make reserve estimation very difficult. Laurel Lake has the additional problem of erratic grade distribution."

Jan 1, 1992

By Nicholas Kyriazi, John P. Shubilla

A joint effort by the U.S. Bureau of Mines and the U.S. Mine Safety and Health Administration (MSHA) was undertaken to determine how well self-contained self-rescuers (SCSR's), deployed in accordance with Federal regulations (30 CFR 75.1714), survived the underground environment with regard to both impact damage and aging. This report presents findings regarding laboratory-tested SCSR's from 1982 through 1990. The SCSR's were tested on human subjects and on a breathing and metabolic simulator (BMS). These results indicate that most of the apparatus, if they pass their inspection criteria, perform as expected except for units with manufacturing defects or design deficiencies. However, when the apparatus are carried in and out of the mine daily and stored at the working section, they may suffer abuse. Physical signs of abuse, unless extremely obvious, are frequently not detected by the miners or mine operators. This poses a potential danger to a user in an emergency. Recommendations include improved training in inspection procedures.

Jan 1, 1992

Halide media are considered as suitable alternatives to cyanide for extracting gold and have received much attention lately. The extraction of gold by iodide-iodine mixture has been patented and briefly studied without much attention given to the fundamental aspects of this process. This paper reports recent studies on the kinetics of gold extraction in iodide media, using hypochlorite, iodine and hydrogen peroxide oxidants. The kinetics of dissolution was found to be dependent on the solution pH, reagent concentration and most importantly the iodide- oxidant molar ratio. Without proper control, the gold surface can be passivated due to the formation of solid products. Thermodynamic modelling was carried out to determine the equilibria governing the dissolution process. The formation of AuI solid was also identified as a possible product during the dissolution.

Jan 1, 1992

By Nosa O. Egiebor, Kafui Nyavor

"The effectiveness of sulphuric acid, nitric acid, and hydrogen peroxide pressure oxidation on the cyanide extractability of gold from a double-refractory concentrate is presented. Whileover90% of the sulphide content could be oxidized by either of the two acid pretreatments, only 65% was achieved by the peroxide oxidation. Carbon oxidation by both acid and peroxide pressure oxidation were less than 15%. Although the peroxide pressure oxidation pretreatment resulted in much lower sulphur and carbon oxidation, it gave pretreated residues with decreased levels of preg-robbing activities and higher gold recoveries during subsequent cyanidation, thus indicating some deactivation ofthe preg-robbing carbon during pretreatment with hydrogen peroxide. The refractoriness due to carbon preg-robbing activity was found to contribute more to the refractory behaviour of the concentrate than the occlusion of gold particles by the sulphide mineralization.IntroductionGold ores and concentrates are classified as refractory when a significant portion of the gold content cannot be extracted efficiently by conventional cyanidation, even after fme grinding (Weir and Berezowsky, 1984); (Demopoulos and Papangelakis, 1987). The refractory behaviour of precious metal ores and concentrates is generally attributed to two main factors: The presence of carbonaceous materials which could cause preg-robbing activity during cyanidation (Zaitseva et al., 1973); (Nice, 1971); Scheiner et al., 1971); (Eisele et al., 1983), or occlude gold-bearing minerals (Wells and Mullens, 1973); (Gasparrini, 1983); (Chen and Reddby, 1990), and the occurrence of sulphide minerals which can occlude gold, thus reducing the access of lixiviants (Schwartz, 1944); (Weir et al., 1986); (papangelakis and Demopoulos, 1990); (Michaelis, 1989); (Schweigart, 1965). When the refractoriness is due to a combination of these two factors, the ore or concentrate can be referred to as being ""double-refractory"". Because of the rarity of gold ores exhibiting this double-refractory phenomenon, only a few studies have been carried out on their suitability for pretreatment by existing techniques."

Jan 1, 1992

Site specific geotechnical data, deposit characteristics and method of mining are key factors when assessing an appropriate slope design philosophy. Mining geotechnics should be viewed as an iterative design process linked closely with mine planning, development and operational safety constraints. This case study presents geotechnical investigations for slope design at Macraes Flat Gold Mine using kinematic, probabilistic and economic analyses tempered with knowledge of site specific conditions. The recommended designs not only reduce early waste stripping tonnages but also provide data to optimise final walls.

Jan 1, 1992

By Lynne Bowen

"On the da y shift in Number One Mine at Nanaimo on Vancouver Island, on May 3, 1887, William Griffiths, a coal miner with many years experience, fired a shot to advance the face of the crosscut. A flame ran out for a distance of fifteen feet along the roof and then extended up the slope for ten to twelve feet, and although many would have called this a blowing out shot, Griffiths said it was just a feeder. ""A blower"", he said, ""would have caused an explosion."" 1There was no explosion. Griffiths reported gas and the area was cleared for three hours and then work resumed. When the shift changed at 3:00 p.m., the fireman reported all places clear of gas and the ventilation good.2The ventilation in Number One Mine was the best anyone had ever seen. The air in the mine was almost too cold. The current was so strong that it sometimes blew out the flame on the miners' fish oil lamps. It delivered five to six hundred cubic feet of air for every man and animal working in the mine. The law required only one hundred cubic feet 3The miners considered Number One to be relatively safe. The manager was proud of the mine and its up-to-date equipment"". Recently, there had been reports from France and America about the explosiveness of coal dust, but the manager did not think his mine was sufficiently dusty to be dangerous.5 The dust lay thick on the floor of the mine. Sometimes when a shot was fired the dust rose in great clouds. When a miner was shovelling it, the dust would billow up and be carried off by the current of air. The dust was also in the roof and in the stopings, put there intentionally to fill up the spaces and prevent the accumulation of methane gas."

Jan 1, 1992

By D. E. Ranta, Jean-Michel Rendu

It is generally recognized that geologic input is required for the results of a geostatistical study to be meaningful. However the link between geology and geostatistics is often complex and not well understood. A geostatistical evaluation can be divided into four phases: Background discussions, computation, reserve reporting and reserve audit. Each one of these phases is described, as well as the role the geologist should play during their completion. This role will vary depending on the geology of the deposit being studied, the geostatistical method chosen and the computer hardware and software being used. The geologist's acceptance of the results is needed if the geostatistical model is to have any credibility. The most significant obstacle to a meaningful study comes from the difficulties geologists and geostatisticians often encounter when attempting to communicate with each other.

Jan 1, 1992

By Thomas E. Weyand

Prior to 1975, lead-based paints were commonly used in protecting steel structures. Because of the toxic effects of lead on human health and the environment, their use has been significantly reduced. However, problems with these paints persist when they are removed during normal maintenance by pneumatic blasting with mineral abrasives. Technologies are developed to contain the spent abrasive and paint during blasting operations. This paper reports on A study to identify beneficial reuses for the spent blasting material. Nine samples were gathered from different projects within Pennsylvania. The samples were thoroughly characterized with regard to composition, morphology, and EP and TCLP leach test performance. Potential reuse applications will be reviewed with regard to technical adequacy, economics, and environmental constraints.

Jan 1, 1992

By Batric Pesic

Dissolution of gold with sodium bromate solutions of various compositions was studied by using a rotating disc technique. The role of bromide ion, acid and externally added bromine was examined. It was found that sodium bromate could not dissolve gold in the absence of either acid or bromide ion, or both. When acid was absent, no bromine necessary for gold dissolution could be produced. When bromide ion was absent, formation of soluble gold bromide species, AuBr,-, was not possible. Bromate concentration had a complex effect, and it was dependant on bromide ion concentration. For fixed initial bromide ion concentration, gold dissolution rate increased with sodium bramate concentration increase until certain level, beyond which further increase of bromate concentration decreased the gold dissolution rate. The negative effect of bromate was explained by the depletion of necessary bromide ion. Sulfuric acid concentration effect was a function of initially present bromine.

Jan 1, 1992

By R. H. Hanewald

The INMETCO process has been modified so as to recover nickel. chromium and Iron from a wide variety of metal containing waste-streams. This now includes the recovery of metals from spent acid solutions such as chromic acid etching I1quids. nJcke1 and chromium plating solutions; stainless and superalloy pickling solutions. etc. In addition. hazardous electric furnace stainless steel and. superalloy baghouse bags can be processed so as to recover the valuable metall1cs. A detailed review of the above new recovery techniques w1ll be discussed as well as the current operating methods used at INMETCO.

Jan 1, 1992

By James J. Jessop, Richard E. Thill, Michael J. Friedel

As part of an investigation aimed at improving the health and safety and competitiveness of the mining industry, the U.S. Bureau of Mines evaluated the application of common offset radar profiling, using a 250-MHz ground-penetrating radar (GPR) system, for the detection of fractures in igneous rock. A series of radar reflection surveys were conducted to detect and delineate the extent of fracturing at various granodiorite and gabbro quarries and outcrops located in Minnesota. The application of radar profiling for detecting joints, sheeting fractures, shear zones, and depth to water table was demonstrated to be feasible with minimal processing. Radar reflection interpretations were verified by visual inspection of the rock mass and field mapping of local structure. The radar reflection section provides a simple, rapid, and cost-effective means for mapping of shallow (less than 10 m) small-scale fractures (greater than 0.25 cm) in igneous rock masses (characteristic of velocities between 0.061 m/ns for gabbro and 0.125 m/ns for granodiorite). Depth or distance estimates to fractures are within 10 pct of the actual, and time-shift compensation is necessary only when topographic irregularities exceed 30 cm.

Jan 1, 1992

By G. E. Maryniak

To date, human space exploration has been almost completely dependent on the use of resources carried with astronauts and cosmonauts from the surface of the Earth. The only exception to this has been the harvesting of solar energy to power space stations like Skylab, Salyut and Mir for long-duration missions. This dependence on materials which must be transported into orbit at costs in excess of $5000 per pound is the fundamental limiting factor in space exploration and operations. It is likely that launch costs can eventually be greatly reduced by means of such innovations as true single stage to orbit vehicles, aerospace planes, or serial electromagnetic or laser launch systems. However, the Earth will always remain an expensive source of materials for space construction and for basic commodities such as propellant and life support liquids and gasses. Fortunately, abundant sources of materials exist which are already in space, outside of the Earth's deep gravity well.

Jan 1, 1992

By I. de Jong, G. Van Weert

Silver cyanide adsorbs extremely well on activated carbons. This suggests that the addition of soluble silver salts to trace cyanide containing waste streams should allow efficient cyanide removal with active carbon. Silver losses, however, would make this method expensive and also objectionable, since silver has biocidal effects. When silver impregnated carbon is used, these problems are overcome. Test work has shown that such silver remains on or in the active carbon, that cyanide concentrations can be reduced to the level of detection (< 5 ppb) and that the silver impregnated carbon can be reactivated with equipment similar to that now in use at gold milling operations. Initial results on the type of carbon, the impregnation procedure and the level of silver, and the effect of repeated regeneration are discussed.

Jan 1, 1992

Bitumninous and semianthracite coal reserves underlie about 1,400 square miles of Arkansas, less than 2.7 percent of the state&apos;s total area. These deposits, located near the western border, contain an estimated 2.2 billion tons, of which about half are recoverable. This represents less than one-tenth of one percent of the national reserves. Most of the commercial coal is mined from thin beds that are at least 14 inches thick. In some locations, however, the coal beds can be as much as eight feet thick. Lignite was mined in southern Arkansas before the Civil War. Current estimates indicate that the reserves may be as high as 9 billion tons, which could be used in the state&apos;s coal-fired electric generating plants; however, these deposits are not being mined at present. Because many coal operations in Arkansas are small and the demand for coal is unsteady, the industry employs fewer than 25 miners on a daily basis. Arkansas gained primacy when its regulatory program was conditionally approved November 21,1980, subject to the correction of four minor program deficiencies. The regulatory program was fully approved January 22, 1982. Authority of the state to administer its Abandoned Mine Land Reclamation Program was granted upon approval of the Arkansas Reclamation Plan on May 2, 1983. Arkansas was the first state to assume responsibility for abandoned mine land emergency projects when its Reclamation Plan was approved.

Jan 1, 1992

By Fabjanczyk MW, Guy RJ, Tarrant GC

The design of the reinforcement systems required to stabilise mine roadways has developed through the application of field measurement techniques. These techniques have allowed the level of security of a given opening to be determined from an assessment of the loading within the reinforcement, the extent of roof deformation and experience. The design systems developed are now used extensively in a wide variety of geological environment. Recent interpretative techniques have been developed to improve the level of confidence when designing roadway reinforcement. The techniques are particularly applicable for roadways subject to either weak materials or extreme stress levels. A second area of application is where roadway advance rates and hence the timing of reinforcement placement are critical. The newly developed techniques include both analytical and computational models. The validated computational techniques allow a more rational approach to investigation of the effect of varying reinforcement type, timing of placement and density on the level of stability achieved.

Jan 1, 1992

By Elliot B. J

Flash smelting is a complex and capital intensive technology. Although in use for 50 years the technology is still not well understood from a fundamental point of view and thus uncertainty is evident when significant change to the practice is necessitated. The application of effective design and process simulation tools has significant advantages when process change and improvement is required. Mathematical models have been used to simulate the processes occurring in the shafts of copper flash smelters. The present approach to flash furnace modelling differs from earlier work in that the burners were modelled in detail, the output from the burner model becoming the input to the shaft model. This paper serves as an introduction to the modelling process used to analyse the performance and provide a better understanding of the parameters applicable to the flash furnace at the Kalgoorlie Nickel Smelter.

Jan 1, 1992