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By Gang Qi

The solubility of nitrogen in pure molybdenum was measured over the temperature range 2173 to 2473 K and up to one atmosphere (101 kPa) of nitrogen gas pressure. Both thermochemical and kinetic aspects of this phenomenon were considered in this study. The solution of nitrogen in molybdenum may be expressed by the reaction 1/2N2(g) = {N} (Mo,s), for which the standard Gibbs energy is given by the expression {A}G° = 78,500 + 27.36T Joules/g atom N. The formation of molybdenum nitrides, specifically Mo2N, was considered. Attention was also focused on the mechanism of nitrogen solution in molybdenum. Estimates of the diffusivity of nitrogen atoms in solid molybdenum were derived from the kinetic data.

Jan 1, 1991

By R. F. Harig

Designing an underground nuclear waste repository is a complex process. Although many decisions are involved before the design is complete, the first three--what the target horizon is, what the underground boundary is, and where the entry point will be located--are important because they establish the basis for the entire repository design. Even more important than these decisions, however, is the data on which the decisions are based. Because the current data are limited, an aggressive data gathering program is needed during the next design phase to augment information about the intricate interplay among all facets of the repository design and the geologic medium in which the proposed repository is to be developed. Although unique to modern engineering enterprises, the challenges involved in designing a repository in the unsaturated zone are within current technology and engineering practices.

Jan 1, 1991

By James C. Barker

Unverified reports of rare earth element (REE) concentrations in gold placers and radioactive mineral prospects in the Zane Hills were investigated by the U.S. Bureau of Mines as part of the Alaska critical minerals program. REE is reported to occur in dredge concentrates at the Hogatza mine and up to 1.2 pct REE was previously analyzed in alkalic syenite (bostonite) dikes marginal to the pluton. In addition, numerous thorium-rich veins, explored for their uranium content but unevaluated for REE, occur on the western margin of the Zane Hills. The Bureau mapped and sampled all of the reported or suspected REE occurrences. Dredge concentrates contain abundant uranothorianite, a mineral species which incorporates cerium subgroup REE. Bostonite dikes occur in conjunction with a multi-phased zoned alkalic intrusion, however, no significant REE concentrations were found. Thorium-rich veins contain nil to 0.5 pct Y but resource potential is limited by this relatively low grade, the ultimate low tonnage potential, and the lack of uranium as a major economic element. The Zane Hills exhibit attractive exploration targets for uranium deposits, primarily in a sedimentary form. Gold may be found peripheral to the pluton in both placer and lode deposits. Resource potential of REE, however, appears limited to a placer by-product of REE-Zr-Ti that is recoverable only during large scale gold placer mining. Placer exploration of the lower Wheeler and Dakli Creeks is suggested.

Jan 1, 1991

Acid generation from reactive sulphide mineral tailings has become a major environmental problem in the mining industry. Initiation of chemical and biochemical oxidation reactions of the sulphide mineral leads to acid generation. A novel concept of safe disposal and utilization of reactive fine mill tailings is presented in this paper. The paper also presents the results of a preliminary laboratory experimental .study of the concept. The tailings are agglomerated using portland cement as a binder. The cold bonded agglomerates are encapsulated with other chemical additives to act as acid neutralizers, oxygen and ironoxidizing bactericides., The primary. factors influencing the choice of bacterfoides to inhibit the acid generating bacteria are their costs, toxicity and environmental friendliness. The paper discusses the utilization of agglomerated' products as aggregates for underground backfill, or as gravel for surface land cover.

Jan 1, 1991

By Ann M. Hagni

The mineralogical, chemical, microtextural, and particle size character of electric arc furnace (EAF) dusts are being studied by reflected light microscopy, scanning electron microscope-energy dispersive spectroscopic analysis (SEM-EDS) and electron probe microanalysis (EPMA). The dusts consist predominantly of metallic iron, iron oxide, and calcium-iron-manganese silicate phases, together with smaller amounts of iron-manganese-zinc-calcium, iron-calcium-zinc-manganese, and calcium-iron-manganese silicates. The samples vary in their zinc contents. Chlorine occurs in phases containing iron, lead, zinc, manganese, and calcium. The dust particles range greatly in size from 1 to more than 300 ~m, but most particles are about 1 to 6 ~m. Larger particles. about 20-50 um across. also are present. They are predominantly spherical in shape, but some are cenospheres, and others are more angular particles, some of which are broken spheres and cenospheres. Their internal microtextures exhibit evidence of liquid immiscibility, exsolution, skeletal crystal growth, and oxidation react i on rims. Because EAF dusts have been classified by EPA as hazardous wastes, there is heightened interest in the treatment of these dusts to render them non-hazardous. The mineralogy of products of pyrometallurgical treatment of EAF dusts by flash furnace and pyrohydrolysis are currently under study.

Jan 1, 1991

By A. Kevin Beaton, Robert W. Laakso

The desire for dry passageways promotes the NATM as it provides a final support system most suitable for the installation of a waterproofing membrane. Waterproofing during construction is a cost effective way to enhance safety and function as well as increasing the life of an underground structure. The NATM approach utilizes the surrounding mass as an integral element of the "ringlike" support system. At the Pennsylvania Turnpike Commission Lehigh Tunnel No. 2 various rock classifications were determined to require support measures ranging from 2 to 12 inches of shotcrete along with spiling, wire mesh, deformed bar, lattice girders and rock bolts as needed. Field instrumentation and monitoring programmes are a key factor for the success of the NATM. When the support "shell" stabilizes smoothing shotcrete, waterproofing and a final liner can be placed.

Jan 1, 1991

By R. L. Brown

The Buchans mining district is located roughly at the center of the island of Newfoundland and contains some 18 separate mineral deposits. The first of these deposits was discovered in 1905, the latest discovery having been made in 1979. To the present (1983), some 16 Mt (17.7 million st) grading 1.33% Cu, 7.5% Pb, 14.5% Zn, 115 g/ t (3.7 oz per ton) Ag, and 1.4 g/t (0.04 oz per ton) Au have been mined. Mining operations are now largely terminated, but a few hundred thousand tons of economically marginal reserves may be mined in a salvage operation. The Geological Association of Canada Special Paper No. 22, "The Buchans Orebodies, 50 years of Mining and Exploration," contains papers which describe the history, geology, and the application of evolving geological concepts in exploration. Papers by Neary, Swanson, and Thurlow and Swanson in that volume are topical to the present discussion. Successful exploration techniques at Buchans included physical prospecting, utilization of the state-of-the-art geophysical techniques, saturation diamond drilling which was made possible by the high gross value of the existing ore, and, since 1955, diamond drilling directed by fairly well understood geological parameters. The record of discovery started in 1905 when the Buchans River deposit was found by Matty Mitchell, a prospector employed by the Anglo- Newfoundland Development Co., a British company which owned mineral rights over a very large area in the Red Indian Lake-Exploits River drainage system.

Jan 1, 1991

By C. A. Summers

The U.S. Bureau of Mines applied process mineralogy to investigate a lead and zinc deposit located near Story Creek, Colville Mining District, Alaska. Mineralization is hosted by the Kayak Shale in veins, veinlets, and breccia. Sphalerite and galena, with supergene anglesite, occur in symmetrical quartz veins and between breccia clasts. The study sample analyzed 2.11 percent Pb, 5.37 percent Zn, 0.014 percent Cu, and 1.2 oz/ton Ag. Analyses of crushed products showed that 33 percent of the sample weight, and more than 50 percent of the Pb and 65 percent of the Zn, are in the minus 850 um fraction. Liberated grains of sphalerite and galena were found in crushed products finer than 300 um. Beneficiation tests indicate the material is amenable to processing by traditional gravity and flotation techniques.

Jan 1, 1991

By A. Masutomi

Although great strides have been made during the past two decades in the reduction of the severity of accidents and injuries in underground coal mining, the number of accidents resulting in disabling injuries and lost time has continued to increase. Looking ahead to the 1990s, the reduction of accidents and incidents typically found in these latter categories should be emphasized in safety training for underground coal mining. Loss control is an approach which shows promise for applications in mine safety training since loss-control strategies focus on the pre-contact stages of an incident rather than on the incident, itself. Applied to safety training, the heightened awareness of personnel to workplace hazards at the pre-contact stages should result in a reduction of accidents and injuries. This paper explains the concept of loss control and shows how it can be applied in the development of the needs assessment for miner training programs. An example, based on research conducted at the continuous-miner worksite, is provided.

Jan 1, 1991

By U. Lauwers

The influence of different waste materials in sinter blends on the quality and mineralogical composition of a sinter is described. As a result of partial preservation of the original textures of waste materials in the final product the degree of assimilation of the original material in the sinter product can be ascertained. Recycling of waste materials such as dolo char , arc-furnace slag, scrap fmes, mill scale and BOF-mud via the sintering process a saving on costs of raw materials such as flux and fuels, and a reduction on pollution can be achieved. A comparison of a typical sinter with a sinter produced through the utilization of waste materials showed a distinct correlation between certain types of waste material and some metallurgical properties. Dolochar in a sinter blend acts as part of the fuel and flux that are normally added to a sinter mix. Generally dolochar improves the quality of the sinter and decreases the consumption of coke. Other waste materials adversely influence the quality of the sinter. The glass and calcium ferrite content of a sinter when dolochar is used in the blend is similar to that of a sinter produced with only coke as a fuel in the sinter mix. The glass content is lower and the calcium ferrite content is higher, in a sinter produced from dolo char in the blend compared to a sinter produced with additions of other waste materials. Changes in the mineralogical composition are related directly to the metallurgical properties of the sinter product.

Jan 1, 1991

By S. Banisi, J. Marois, A. R. Laplante

"This paper compares the behaviour of gold and ore in the grinding circuit of Hemlo Gold Ltd. Particular attention is given to grinding kinetics, classification behaviour, and liberation. For grinding kinetics, laboratory grinding of gold flakes and silica, 840-1200 um in size (14/20 mesh), was also performed to provide a standard for comparison and to study in a controlled environment the mechanisms of breakage, folding, smearing and impacting.Grinding kinetics were characterized at laboratory scale with breakage and selection functions. The breakage function showed that 75% of gold disappearing from the 840-1200 um class reported to the 600-840 um; this figure is much higher than for silica ( 46%) or most other minerals, and implies that comparatively fewer fine fragments are produced from the breakage of gold flakes, on account of gold's malleability. The selection function of silica was four times that of gold. At plant scale, the ratio of the selection function of ore and gold increased from 6 for at 50-100 um to 20 at 500-1000 um.Observation of original flakes and their fragments with the scanning electron microscope showed that the main mechanism of ""grinding"" from the 840-1200 um to the 600-840 um class was folding rather than actual breakage. This was confirmed by a measure of individual flake weight. The postulated breakage cycle is that relatively globular flakes become increasingly serrated through grinding; they can then regain their original shape through folding and reflattening into cylindrical and spherical shapes, as the majority does; however, some fragments will at this point undergo actual breakage. Photographic evidence is presented to support the proposed mechanisms.Smearing of gold unto silica was observed when silica was ground after a gold, and embedding of silica into gold flakes when gold was ground after a silica. Both mechanisms occur whenever gold and harder minerals are jointly ground, and result in ""unliberation"" of gold. It is postulated that smearing of gold onto other minerals plays an important role in explaining how gravity recovery can increase overall gold metallurgy, especially when used ahead of flotation.Classification of gold in the primary hydrocyclones takes place at a much finer cut-size than ore, 20 vs. 57 um. This and the slower grinding kinetics result in high gold circulating loads in the primary loop, 6700%, and a gold content in the primary cyclone underflow (PCUF) is twenty four times that of the ore. The gold size distribution for primary cyclone overflow is much finer than that of the ore, although they are essentially similar in the PCUF.Liberation, or more accurately ""gravity recoverability"", was assessed with a 7.5 cm (3"") Knelson concentrator. It varied between the thirties for the primary mill discharge and two cyclone overflows, to highs of 89 to 92% for the PCUF and secondary mill discharge, 89 and 92%, respectfully."

Jan 1, 1991

By David G. Chedgy

Noise control is an important consideration in the design and operation of coal preparation plants. It is essential to understand and control noise sources to provide a safe environment for operating personnel. The average noise exposure levels in a typical coal preparation plant generally range between 95 and 100 db. An operator should not be exposed to noise levels of this magnitude for more than 4 and 2 hr, respectively, according to MSHA (Mine Safety and Health Administration) regulations. The major noise sources in a coal preparation plant include noise from impacting the inside surfaces of steel chutes, vibrating screens, coal crushers, pumps, motors, fans, and blowers. The magnitude of noise varies considerably from one situation to another. NOISE EXPOSURE IN COAL PREPARATION PLANTS Noise regulations established by the Occupational Safety and Health administration (OSHA) are accepted by MSHA relative to caal preparation plants. Fig. 14-43 shows a graph of the time of noise exposure in hours per day to which a worker can be exposed for each A-weighted sound level. According to this graph, a worker is permitted to spend 8 hr in a 90-db noise environment, but that time must be halved when the A-weighted sound level increases 5 db. The noise dosage a worker receives is determined by the ratio of the length of time the worker spends in a particular noise environment divided by the length of time he is permitted to spend in that environment. If the worker is exposed to several different sound levels, his total dosage would be the sum of each of the individual dosages. The equation for determining the dosage is: where C is the actual duration of exposure at a given steady state noise level and T is the noise exposure limit for the level present during the time C According to MSHA regulations, the dosage, D, should not exceed one (1) for any worker for a full day of work. As an example of typical plant noise levels, vibratory screens and crushers emanate noise levels in excess of 90 db at a distance of 3 ft (0.9 m) with no material flow. With material flow, noise level increases 1 to 10 db depending

Jan 1, 1991

By S. P. Singh

Drifts are the nerve centre of underground mining. They provide essential communications between primary openings and production areas. In view of their strategic importance in the overall safety, economy and productivity of mines, an empirical approach for blast design during drifting has been proposed in this paper. The approach was developed with the objective of minimum blast damage and provides computerized blasthole patterns for drifting operations. The drift blasting practices and problems in Canadian mines have also been reviewed in this paper.

Jan 1, 1991

By Meili Zhu, Qingpu Shi

High temperature, methane, dust and other disasters are getting more serious with mining depth getting deeper and the development of mechanization in underground mines. An application of a descensional ventilation to a coalface is one of the effective measures to solve the above problemes. The descensional ventilation is an venttilation that an airflow in a coalface wouuld downflow along an inclination of a coalface and the direction of the airflow is the same as coalflow. Since 1960's, the descensional ventilation has been applied to 171 coalfaces in 46 coal mines of 23 coal mine administrations in China, such as Pingdingshan , Zhongliangshan, Pubai, Huangshi coal mine administrations. Among the 171 coalfaces, there were 104 coalfaces taking 60.8% in gently inclined seam. The coalfaces in inclined seam and steep seam were individually taking 18.7 % and 20.5 %. There were 77 coalfaces taking 45 % of the total in low gassy coal mines and coal and methane outburst mine were individually taking 17% and 38%. There were 141 coalfaces taking 82.5% of the total in potential danger of dust explosion. There were 125 coalfaces taking 73.1% of the total in potential danger of spontaneous combustion. Therefore, the descensional ventilation can be used in coalfaces under different conditions in China. The practice at home and abroad shown that the application of the descensional ventilation to coalfaces has obvious results in dust control, temperature control, preventing methane accumulation at top corner angle and control of spontaneous combustion in goaf. To more safely and reliably apply the descensional ventilation to coalface and to provide a way for the development of mine ventilation technology in China, the paper will have discussions on the following problems: METHANE EMISSION AND DISTRIBUTION AT COALFACE WITH DESCENSIONAL VENTILATION Methane emission in a coalface with a descensional ventilation is an argued issue for many years. Base on the coal practice, special similar model tests and researches in China, the followings are our main comments. The Descensional Ventilation can Reduce the Methane, Accumulation at the Top Corner Angle. The measurements in six coalfaces with the downward airflow in Qinhemen Mine, Fuxin Coal Mine Administrations shown that the methane concentration at the top corner angle is often up to l% when the coalface has the upward, airflow. The max. methane concentration at the top corner angle is about 0.49 to 0.7% when the coalface has the descensional ventilation. Therefore, with the descensional ventilation, it basically solved the overlimited gas concentration at the top corner angle which is a potential danger to coal production. Because the direction of upfloating gas is opposite to the direction, of the descensional airflow, the descensional ventilation; could increase a turbulent flow mixing capacity of the methan gas and air, and reduce a possibility of methane; accumulation. Due to an air leakage in goat when the coalface with the descensional ventilation lower than an air leakage in goat when the coalface with the, ascensional ventilation, a less methane quantity will release from goat at the descensional ventialtion. It should be pointed out that due to a higher air leakage at ascensional ventilation and the direction of the air; leakage same to the direction of the natural upfloating methane in goaf, those will cause a large methane; accumulation at the top of the goaf and easy bring about, methane accumulation and overlimited methane concentration at the top corner angle with an ventilation vortexflow at the top corner angle. On the other hand, because the direction of the upfloation force function is upward, the descentional ventilation could minimize as possibility of methane accumulation at top corner angle in coal with the descensional ventiltion.

Jan 1, 1991

By J. J. Moore

Combustion synthesis or self propagating high temperature synthesis (SHS) reaction systems are discussed with respect to thermodynamics and kinetics. In particular, tile effect of the process parameters, ego particle size, AHf, ignition and combustion temperatures on these self sustaining reactions is discussed. Combustion theory is used to investigate the effect of the overall activation energy of the SHS reaction on the combustion front propagation rate and in obtaining a clearer understanding of the transition from stable to unstable propagation. Finally, examples of the application of combustion synthesis to advanced materials processes are made, in particular the synthesis of Ni-Ti -X intermetallic shape memory alloys, TiC-Al2O3 and ZrB2 ?Al2O3 ceramic composite materials.

Jan 1, 1991

By D. H. Dvorak

Two pilot-scale biological reactor systems were installed to treat metal-contaminated water. The reactors consisted of barrels and tanks filled with spent mushroom compost, within which bacterial sulfate reduction became established. Concentrations of Fe, Zn, Mn, Ni, and Cd were lowered by over 95% as these metals were precipitated as insoluble sulfides by reaction with bacterially generated H2S. The chemistry of the reactor systems is examined, and opportunities for maximizing their metal-retaining and alkalinity-generating potentials are discussed.

Jan 1, 1991

Apply state-of-the-art monitoring and computer systems technology to remotely monitor geostructural data and evaluate ground conditions in near real-time. Background Recently, the coal mining industry has progressed dramatically from a labor-intensive industry to highly mechanized and automated systems achieving significantly higher production rates. In underground longwall coal mines, production and face advance rates have increased by almost tenfold in the last 15 to 20 years. With increasingly high advance rates, geologic anomalies which affect rock mass quality are encountered more frequently, far exceeding the current rate at which ground control information can be processed and analyzed. As a result, mine operators find themselves with insufficient time or resources to cope with the rapidly changing ground conditions. To keep up with the technological advancement in mining and the associated ground control problems, the Bureau of Mines is conducting a multi-phase research pro¬gram to implement a computer-assisted Ground Control Management System (GCMS). Research is ongoing at present, but when completed the system will be designed to 1) monitor and evaluate data on rock properties, geologic conditions, and rock mechanics data from underground sensors in near real-time; 2) interpret the analyses to evaluate the interaction between various critical ground control parameters; 3) assess the structural integrity of the mine; and 4) determine failure modes and provide recommendations for control measures, design modifica¬tions, and alternative support procedures. The system will be expanded into its full capability during various phases of this research program.

Jan 1, 1991

By H. V. R. von Rhaden

Systematic quantitative X-ray diffraction analyses performed on diamond-drill cores originating from the Aandenk formation at the Loraine Gold Mine, located in the Welkom goldfield, Orange Free State, South Africa, have revealed the presence of a number of phyllosilicate mineral assemblages which have not hitherto been reported from this region. Rectorite, a regularly interstratified 1:1 mica-montmorillonite "swelling clay", is found to occur together with paragonite, muscovite, pyrophyllite, kaolinite, and chlorite in highly-altered friable rocks. The presence of rectorite in mill feeds may have potentially serious implications with respect to gold recovery. Quantitative X-ray diffraction analysis for phyllosilicates can be used as an aid to correlation, and also to guide the widths of stopes in underground mining. Rectorite has a unique mode of origin, which is discussed.

Jan 1, 1991

By Sun Shao Xian

The Port of Shekou is situated at Shenzhen Bay on the east side of the Pearl River estuary. Geological condition of the site is quite complicated. On top of the sea bed, there is a layer of soft silt 8 - 14 m thick. Under the soft silt, there are intercalated layers of sand, silt and clay. Average surface elevation of the underlying undulatory weathered bed rock is about - 20 m, with a variation of about 10 m. In certain locations, the weathered bed rock is covered with a layer of silt 3 - 4 m thick. This paper gives brief account of three types of wharf structures which are of particular interest, constructed in the last few years: (A) Platform type wharf structure with frontal sheet piling and steel raking pile in the rear; (B) Relieving Platform type structure with steel sheet piling and inclined anchoring HP pile ; (C) Steel pipe pile row supported apron added to a marginal quay. Average construction time of a deepwater berth is about six months.

Jan 1, 1991

By G. M. Li

It is shown that seriously preoxidized arsenopyrite can adsorb a large amount of copper ions as unoxidized one, but without, release of corresponding amount of Fe ions; seriously preoxidized pyrite cannot adsorb copper ions, but with release of a large amount of Fe ions. However, if the minerals are rapidly oxidized with potassium permanganate solution, both arsenopyrite and especially pyrite can adsorb a large amount of copper ions, but still without release of corresponding amount, of Fe ions. Cu adsorption (if there is any) on both oxidized arsenopyrite and pyrite is not based on the Cu-Fe exchange mechanism.

Jan 1, 1991