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By J. W. Tsai

Both diamond crystals and diamond films were grown on silicon and copper substrates using a methane/hydrogen gas mixture as a precursor with thermal CVD techniques at low pressure environment. In addition to diamond particles, other crystalline phases including graphite and aluminum silicon carbide were observed on the substrate surface. ?The grown materials were analyzed with X-ray diffraction, electron microscopy, Auger electron spectroscopy and optical microscopy. Most synthesized diamond crystals were twinned. The flow rate of reactant gases, substrate nature, substrate temperature, decomposition temperature of the precursors, total pressure of reaction chamber, methane/hydrogen ratios and other possible parameters were varied during the growth processes, and the significant effects of these factors on nucleation and growth rate were evaluated.

Jan 1, 1989

By Warren L. J, Horsley R. R, Meagher L

Mineral concentrators often use process water that is very saline and/or hard. In this paper the effect of increasing concentrations of sodium chloride and calcium chloride on the rheological properties of 70 wt% quartz suspensions (d5o - 10.6 ¦m) is reported. The apparent viscosity at 100 s t in 5 mol dm -3 sodium chloride solutions (approx. 300,000 ppm) was nearly 500 times the viscosity of water without salt or particles present. Part of the increase in viscosity is caused by aggregation (coagulation) of the suspension.

Jan 1, 1989

By G. M. Wilemon, B. J. Scheiner

The Bureau of Mines conducted investigations on extracting phosphate values from fine-particle wastes generated during the mining and beneficiation of phosphate ore by leaching dried wastes using a H2SO4-methanol mixture. Although phosphatic clay waste contains up to a third of the phosphate originally present in the ore, recovery of these values represents a significant challenge due to the fine grain size of the material, the particles averaging less than one micrometer in diameter. Waste samples obtained from two Florida producers yielded phosphate extractions of 71 and 84 pct, respectively, when leached under ambient conditions and at a stoichiometric acid ratio of 1.4:l. Elevated temperatures did not improve the amount of phosphate extracted. Undesirable A12O3, Fe2O3, and PlgO impurities were largely rejected; higher grade wastes gave acids that meet established industry impurity standards and lower grade samples yielded acids that marginally fell short of the standard. Separation of the crude acids from the insoluble residues was accomplished via vacuum filtration through either filter paper or commercial filter cloths. Both filtration rates and solids retention were improved by the addition of 0.5 lb/ton of poly(viny1 acetate) (PVAc) or poly(ethy1ene oxide) (PEO) to the methanol-acid slurries. These results show potential for substantially increasing the reserves of an important domestic resource.

Jan 1, 1989

By J. A. Voigt

In an effort to determine the optimum conditions for preparing high purity, fine particle size high temperature superconducting oxide powder, we have investigated how calcination conditions influence the conversion of a chemically prepared hydroxycarbonate precursor powder to YBa2Cu307. We find that the precursor can be converted to phase pure YBa2Cu307 in either oxygen or synthetic air (20% 02. 80% N2) at 850°C. This temperature is substantially lower than the temperature (>900°C) normally used for the calcination of mixed-oxide powders. The lower calcination temperature prevents particle sintering and maintains the desired fine particle size. Powder processed in synthetic air shows a low degree of crystallinity indicating it may be more sinterable than the highly crystalline powders produced when an oxygen atmosphere is used. Intimate contact between powder particle surfaces and a flowing gas atmosphere promotes the reaction between the BaCO3 component of the precursor powder and the Y and Cu constituents.

Jan 1, 1989

By I. Tinto

"IntroductionEnvironmental pollution problems, caused by gases or effluents, by high noise levels or from air borne dust, are placing increasing demands of the operators, from statutory authorities, and from the general public, to adopt more stringent dust control measures. This requires that a successful plant dust control program be an integral part of any plant operation. While a successful environmental program is a key factor in maintaining productivity and good labour relations, anticipation of future environmental regulations during the plant design phase can avoid the high cost of plant upgrading, or dealing with pulmonary conditions in the work force in subsequent years.Particulate removal, conventionally called dust collection, involves the removal of coarse- and fine-particulates from the airstream. Although generally limited to that required for contro!Hng plant generated air emissions, particulate control equipment also has a wide application for air cleaning and filtration inside the plant, as well as for recovery of usable products.In the late 1950s and early 1960s the public became more concerned with the problems of air pollution. This increasing concern was stirred by an awareness of the extremes to which water pollution had progressed in many of the rivers and lakes, by increasing perception of air pollution as detected by visible smog and harsh chemical odors, by the alarming rate of increase of smog plagued cities and communities, and by specific incidents where ill health could be traced to specific episodes of air pollution. Particle size is perhaps the most important single factor affecting particulate control. Large particles (over 5 microns) constitute the major mass fraction of most sources of emission and economical control equipment dqes exist for their efficient control. However, while these larger particles frequently represent the source of soiling and unsightly smoke plumes, they are not a major health problem as they tend to settle relatively quickly, are more easily scrubbed from the atmosphere by rain, and are not able to penetrate the respiratory system. By far the most important form of particulate air pollution is the fine particulate, (below 3 microns) which is harmful to the pulmonary system. The adverse effects caused by this particulate matter on human health are for the most part related to injury to the surfaces of the respiratory system. Particulate material in the respiratory tract may produce injury itself, or it may act in conjunction with gases, altering their sites or their modes of action. A combination of particulates and gases may produce an effect that is greater than the sum of the effects caused by either individually (i.e. synergistic effect)."

Jan 1, 1989

By Robert B. Parsons

"This article is based on a paper presented by Jim Scott at the 1988 annual convention of the Prospectors and Developers Association of Canada. The paper suggests a number of factors that might be taken into account in negotiating royalty terms.IntroductionRoyal ties are a part of mining life in Canada. They are used by many kinds of individuals in many kind s of situations. Prospectors commonly take royalty interests back when they transfer claims to development companies. Mining companies disposing of undeveloped (or sometimes even developed) properties are often paid at least in part by royalties. Royalties are even used by institutional investors with no other connection with the resource industry.Such different royalty holders have different investment goals, different cash flow requirements, and different risk / return preferences. These differences have given rise to a number of different royalty types. These types range from the simplest cents-per-ton royalty (where the operator pays a royalty at a fixed rate per ton milled) to net smelter return or ""NSR"" royalties (where the royalty is based on a percentage of the operator's NSR) all the way to net profit interest or ""NPI"" royalties (where the royalty is based on the operator's bottom-line net profit),The fundamental difference between the many royalty types is in the risk / return relationship. The cents-per-ton royalty, for example, is relatively risk-free. Of the many economic factors which affect a mine, the only one which will affect the royalty holder is the amount of ore physically milled. On the other hand, the potential for significant gains under a cents-per-ton royalty is also very limited. The royalty holder will not share in any increases in the market price of the end product or any cost reductions achieved by the producer."

Jan 1, 1989

By Jennifer S. Riefenberg

The U.S. Bureau of Mines conducts basic and applied research related to predicting, eliminating, and/or controlling rock bursts in underground hard-rock mines and coal bumps in underground coal mines. An important element in this research is the development of a reliable and efficient microseismic source location technique. This report presents the results of a Bureau study to develop and evaluate a new algorithm to locate microseismic events based on the Simplex method, a powerful linear programming technique. The technique was tested on both field data and simulated data. Microseismic event source locations obtained with this new Simplex-based algorithm were shown to have less error than those locations obtained using a least squares method. It was concluded that the Simplex approach to source location of microseismic events can be used effectively in microseismic monitoring.

Jan 1, 1989

By J. C. Rhodes

The demand for good white minerals for many industries including paint and plastics have made it necessary to import high grade industrial minerals from various parts of the world. Some of the calcium carbonate, barite and talc minerals are from China, Mexico, Jamaica and Haiti. These materials can be processed by custom processors. The custom processor can provide a service to the Industrial Mineral owner. The imported materials can arrive in various feed sizes from lumps (3"-6") down to 325 mesh. The materials can also be in various size shipments or container loads. The economics for importing should be investigated thoroughly. The two factors just mentioned can influence the quantity of material to be processed. These two factors can also influence the total cost for each end product.

Jan 1, 1989

By Ryokichi Shimpo, Akio Fuwa

"The process-measurements of copper smelters in Japan were investigated for the summary of the latest technique and for the fundamental study of process control. The smelters investigated are those employing flash smelting furnace and P.S. converter, one reverberatory furnace and P.S. converter, and one continuous smelting converting furnace (M.I. process). Respective process is then considered, consisted of several reactors of different functions. The measurement methods were summarized in each reactor, including the measurement points. The methods of chemical analyses of the samples in each reactor were also investigated.IntroductionAn investigation on the process measurements, chemical analyses, and system control in copper smelters in Japan were carried out for understanding and summarizing the technique of the pyrometallurgical copper smelting operations. The typical seven processes in six copper smelters were investigated in the period from 1985 to 1987. The smelters investigated were Touyo Smelter of Sumitomo Metal Mining Co., Ltd., Kosaka Smelter of Dowa Mining Co., Ltd., Saganoseki Smelter of Nippon Mining Co., Ltd., Tamano Smelter of Hibi Kyodo Smelting Co., Ltd., Ashio Smelter of Furukawa Co., Ltd. and Naoshima Smelter of Mitsubishi Metal Co., Ltd. They include five flash smelting furnace and P.S. converter systems, one Mitsubishi continuous smelting and converting process (M.I. process), and one reverberatory furnace and P.S. converter system.The investigation was performed by making inquiries about the measurements, chemical analyses, system control, and their future prospects to the engineers in each smelter and by summarizing up in each item. The system control and future prospects were summarized in another paper titled ""Process Control Scheme of Copper Smelting Processes in Japan and Future View."

Jan 1, 1989

By C. S. Ek

Tests have been performed to recover silver and lead from residues produced after a super-hot leaching in a zinc hydrometallurgical plant operating with jarosite precipitation. When this residue is leached in ammoniaammonium sulfate or in diethylenetriamine solutions, lead dissolution is not complete and its recovery from the aqueous solutions is either difficult, due to the operating conditions, either expensive due to the amount of added reagents. In both cases, silver is partly dissolved, partly left in a new residue still containing lead and baryum sulfates. The best treatment seems to include a selective flotation producing first a silver concentrate assaying about I % Ag, then a 50 % lead concentrate collecting the baryum salts, and a final quartz-gypsum tailing. Metal recoveries can reach 50 % and 80 %, respectively.

Jan 1, 1989

By R. S. Dennen

A ground penetrating synthetic pulse radar system has been used by the Bureau of Mines to probe into a coal pillar to locate hidden structures or anomalies. Two types of velocity tomographic reconstruction methods, direct matrix inversion and iterative, were used to obtain a velocity image of the interior of the pillar. The reconstructed image showed the existence and location of a relatively low velocity material within the pillar. Core samples were taken from the pillar in a region surrounding the low velocity material. Analysis of the cores showed the presence of a clay vein coinciding with the low velocity material imaged in the tomogram.

Jan 1, 1989

By Concentrator Staff

"IntroductionA brief literature search will reveal that the information available concerning rod mills and ball mills is quite extensive. This type of equipment is used to treat every element from antimony to zinc. The size and capacity of individual mills, the number of units employed, and the configuration of the equipment within a concentrator add another dimension to the possible scope of this discussion. It would be impossible to treat this volume of material with any degree of thoroughness.It is the intention in this paper to describe the simplest and generally the most typical circuit wherein a single rod mill and ball mill operate in parallel. Some of the subject matter will not be entirely applicable to every installation. However the principles should be generally relevant to most applications.Typical Circuit DescriptionFigure 1 illustrates the arrangement of the equipment associated with a rod-ball mill circuit.Ore is extracted from a fine ore storage bin (1) the capacity of which is large enough to allow .continuous mill operation independently of the mine and crushing plant production schedules. A number of feeders (2) may be employed to control the flow of ore to one or more feeder conveyor belts (3). In larger tonnage operations several such conveyors are employed at least one of which will be equipped with a variable speed control to allow adjusting of the amount of feed reporting to the rod mill. A rod mill feed conveyor (4) accepts all of the ore from these feeder belts for ultimate transfer to the rod mill. This conveyor is normally equipped with a weightometer (5) to monitor the flow rate of ore to the rod mill and ultimately to allow control of this flow. Typically these conveyor belts would be equipped with feed deficiency switches which would give a remote alarm of the fact that no ore is present on the conveyor. The conveyor belts are protected by underspeed monitors which will provide a remote alarm and automatic shutdown of the conveyor in the C'.'~nt that belt slippage occurs. Finally the belts are protected by monitors which will alarm and shut down a belt if it is not running straight in the idlers."

Jan 1, 1989

By John S. Timmons, Eivind B. Jensen

The Henderson mine is an underground panel-caving molybdenum mine located in the mountains of central Colorado. All development and primary production operations are performed using diesel-powered, rubber-tired mobile equipment. The growth in manpower and equipment was rapid in the five years following the July 1976 start-up, reaching about 250 machines and 2000 people to produce 9 Mt/a (10 million stpy) of ore. However, due to dramatic improvements in productivity, production is currently at a rate of 8.1 Mt/a (9 million stpy) with about 570 people and a much smaller equipment fleet. The mine's high degree of mechanization and accompanying maintenance costs have focused increased attention on the maintenance function as a cost center with potential for improvement. To realize some of that potential, several approaches to equipment maintenance have been adopted. None of these stand alone effectively, though, and their success relies on their working together in the overall program. The approaches that characterize the equipment mainte¬nance philosophy at Henderson are described here. Preventive maintenance The value of preventive maintenance as an alternative to breakdown or emergency repair is widely accepted in industry. When production began in 1976, few people at Henderson had experience maintaining diesel-powered, rubber-tired equipment. Other company operations such as its previous Urad operation and the Climax molybdenum mine near Leadville, CO used rail and Blusher technology. A maintenance consultant was hired to establish a formal preventive mainte¬nance program. The initial program contained four different preventive maintenance services, "A," "B," "C," and "D." Each was keyed to a different operating interval. • "A" service was the most frequent. It was a quick, general inspection and greasing of all fittings. •"B" service added a more detailed inspection. • "C" service included changing all filters and most fluids, such as engine oil. • "D" service was originally designed as a comprehensive inspection and testing of major component systems over a period of 24 hours during which the equipment was removed from operation. It was believed that most problems uncovered by the inspection could be reported and scheduled for repair at some later date, with only critical repairs being done during the service. In addition to these scheduled preventive maintenance services, a schedlle of minor and major rebuilds at intervals of 2500 to 5000 hours was established.

Jan 1, 1989

By R. A. Walker, G. Scheltgen, T. Javorsky, G. Blackwell

"Recent engineering advances in open pit rock mechanics have resulted in improved pit wall slope design and improved operating procedures in the event of a major wall instability. At the other end of the spectrum, on the scale of single bench failures, considerable discretion is left to the mine operators as to how potential problems are handled. The usual alternatives are either to operate with caution beneath potential hazards, or try to bring the unstable rock down. In specific cases it may be advantageous to attempt to stabilize rock structures for reasons of access and operating safety.A t the Brenda Mines open pit a prominent structure on the north wall had caused recurring bench-scale wedge failures when exposed on each mining level. In spite of operating precautions a shovel was hit by a rockfall causing significant damage. The first section of this paper describes the investigative, design, and stabilization methods which permitted subsequent mining beneath the structure to proceed without incident. Emphasis is placed on the personnel and equipment resources available at the mine site which were used to minimize costs and which would be available at most operating mines.The second section describes an ongoing research project that utilizes radio telemetry to transmit slope monitoring data. As part of this project the wedge structure was instrumented so that it could be continuously monitored with the aid of a computer. The application demonstrated the potential of 'micro- chip' technology to remote data collection and processing as related to rock structure monitoring, slope stability and safety."

Jan 1, 1989

By M. Leroux, S. R. Rao, J. Kim, V. Gervais, J. A. Finch, G. Labonté, N. Macminn, M. Ounpuu

Collectorless flotation of sulphide minerals from Lyon Lake ore (Mattabi Mines Ltd.) has been studied both in the laboratory and plant. Among the four major minerals chalcopyrite showed the greatest response to collectorless flotation, followed by galena. Flotation of sphalerite and pyrite was minimal. Collectorless flotation was influenced by pulp potential and pH. Experiments using different gas compositions showed collectorless flotation was promoted when the pulp potentials were greater than about 0 mV (SCE). The study of the effect of depressants showed that SO2 at pH < 8.0 depresses both galena and chalcopyrite but at pH 9.5 flotation of chalcopyrite recovers. Use of NaCN preferentially depressed chalcopyrite compared to galena. Preliminary results from plant tests at Mattabi Mines Ltd. confirm that collectorless flotation occurs and that it is preferential for chalcopyrite and to a lesser extent galena. Practical implications of collectorless flotation in plant practice are discussed. A critical factor will be silver recovery.

Jan 1, 1989

By Alan P. Prosser

The heap leaching of gold ores by cyanide solution was simulated by computer program. The program uses only basic m1neralogical and chemical data; no process testwork data, such as column leach results, are required. The simulation can be used to forecast the consequences of various changes before and during the testwork, design and operation stages of a particular ore-process system. Also, data about the state of different parts of the heap at various times help create an understanding of what is happening. The effects of mineralogical and process variables on the overall performance of the ?heap leaching process are illustrated. Comparisons are made to column leach tests and production data. The potential of the simulation strategy is discussed for making better use of operating experience and for suggesting specific research objectives. It has become clear that more attention should be paid to other metals that dissolve in the solution.

Jan 1, 1989

By Thomas J. Ferree

"IntroductionThe objective of this chapter is to provide important criteria relating to the operation and maintenance of spiral concentrators and Reichert cones, so that optimum performance can be achieved and maintained in a mill circuit. Little space will be devoted to the theory of the forces of separation or the technical details of the devices, as that in(ormation is available from other sources. The discussions in this chapter will be presented in a manner that should be interesting and useful to anyone who may be exposed to these methods of gravity separation. It is most important for the reader to understand that each application of the equipment should be considered on its own merit, as no two suites of minerals respond exactly alike in mineral processing circuits. The information herein should be useful as a guide toward increasing the metallurgical efficiency of the processes, irrespective of the type of minerals being concentrated.It is highly recommended that certain tools be made available to the personnel responsible for metallurgical performance of the spirals and cones; these include a set of standard type laboratory screens, a medium quality petrographic microscope, and a vanning plaque or gold pan. These devices, when used in conjunction with a basic understanding of the mill circuit, provide immediate knowledge on the characteristics of any sample in the mill circuit. The information gained by visual evaluation of sized fractions of products can solve many of the basic problems of mineral beneficiation, and at the same time increase the interest of the non-technical personnel associated with the plant operation. There are many problems associated with obtaining satisfactory performance from a mill operation. Many of the problems have to be solved using a technical approach. Some of the problems, however, can be solved with practical knowledge and common sense. It is hoped this chapter can provide a guide to both techniques."

Jan 1, 1989

By George A. Savanick

The U.S. Bureau of Mines has patented and transferred to industry an abrasive-enhanced water-jet rock drill. This drill incorporates three novel components: a collimator, jet deflectors for cutting clearance, and an unpressurized swivel, which rotates at 1,000 rpm while passing 20 gpm of an abrasive slurry flowing at 1,000 ft/s. Drilling occurs through the action of a 10,000-psi, 2O-gpm water jet into which is entrained 72 lb/min of abrasives. The pumps, hoses, and fittings are those commonly used in the water-jet-cleaning industry. Only inexpensive, common sandblasting abrasives are used. This drill can cut through hard rocks with moderate-pressure jets; e.g., rocks with a compressive strength of 73,000 psi can be drilled with a 1O,OOO-psi abrasive jet. In addition to drilling holes, the drill can cut deep, narrow kerfs; collar a hole at any angle; drill through rubble; and chamber holes. The development of the abrasive jet drill is a significant advance in the state of the art of hard-rock drilling. The Government of the United States has licensed the abrasive jet drill patent to Weatherford Water Jetting Systems.

Jan 1, 1989

By N. Dave

"IntroductionIn the mineral processing industry, certain minerals such as uranium, thorium and vanadium, etc., are selectively extracted with high degree of purity from solutions containing variety of other impurities by solvent extraction process. This separation process consists of bringing two immiscible or partially soluble liquid phases in contact, where mass transfer of one or more components takes place by ion exchange under certain controlling parameters such as pH, salt concentration and temperature. The processes taking place are primarily physical because the solutes being transferred are ordinarily recovered without chemical change. For efficient extraction more than one stage is required and the solutions are recycled counter currently through other stages. A multi-stage counter current solvent extraction plants essentially consist of four circuits namely: extraction, water wash, stripping, and solvent scrubbing. In extraction circuit the desired mineral is extracted at a certain pH from an aqueous solution onto an organic solvent by bringing them in contact with mixing in large mixer-settler units. The mixed solutions are allowed to settle and separate into component organic and aqueous phases in horizontal settlers by providing sufficient residence time. The solutions are then moved counter currently to other units- the aqueous from the underflow and the solvent organics from the overflow of the settler. The solution streams coming out of extraction circuit are loaded organics and barren aqueous or raffinate solution. The loaded organics are washed with water in a water wash circuit to remove transported impurities from extraction circuit. In the stripping circuit, the desired mineral is stripped selectively from the solvent phase back into an aqueous phase with a stripping agent at a selected pH. The solution stream leaving, stripping circuit are stripped organics and pregnant strip (aqueous) solution. The stripped organics are scrubbed off other loaded impurities with a conditioning solution in, scrubbing circuit and the cleaned solvent is re-used in the extraction circuit.A typical solvent extraction plant for uranium extraction and purification at Agnew Lake Mine is described in this chapter."

Jan 1, 1989

By O. Neves, C. G. González Beca, M. C. Sol Pereira, H. Sousa Vale, R. A. Guedes de Carvalho, M. N. Sampaio

"As sulphide ores are usually concentrated by flotation , the material is very finely ground <37um), wet and impregnated with the chemicals used in flotation. These conditions are favourable to the development ofchemical reactions which are largely influenced by atmospheric conditions (temperature, humidity, wind, etc.) as well as by the geometry of the piles.Physical and chemical properties of a chalcopyrite concentrate were determined by laboratory tests. The knowledge of these properties was considered necessary in order to establish a correct design of the storage and handling operations of the sulphide ore concentrates obtained by flotation.The properties studied in this work were: transportable moisture limit, flowability, effects of vibration, hygroscopicity, ""caking"", chemical alterations by humidity, oxidation and self-heating (auto-ignition, dry and wet oxidation, self-heating by humidification and its prevention).INTRODUCTIONIn order that the handling and the transport of a powdered material may be carried out correctly, it is necessary to know certain physico-chemical characteristics. Transportable moisture limit (TML), apparent density (both aerated and compacted), compressibility, angle of repose, angle of spatula, cohesion and angle of slide(l-4) are characteristics (among the flowability parameters) worth knowing.Moisture content of the powdered material is fundamental, because if this is too low heavy losses will occur when the product&apos;s particle size is very small, if it is too high, separations between solid and liquid phases may occur. In the latter case, the centre of gravity of the system may change suddenly and cause accidents, mainly if transport is by sea or by river."

Jan 1, 1989