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By Skaviniak M

Some better perspectives applying to the exploitation and dressing of polymetallic ores in the Banskfa. gtiavnica-Hod- rusea Ore District are supposed to be achieved after a suc- cessful investigation and proving there the existence of deep-seated mineralization as well as due to increasing de- mand for non-ferrous metals and consequently to higher mar- ket prices of those recently noticed. With respect to the present situation in mining and to the further technical development as well, a several times higher exploitation may be in this region expected, especially in the deeper .eated parts of the deposit. When solving the tasks of a complex economic exploitation over the whole region, consi- derable attention is paid to regional relations and impact studies (due to expected exploitation and ore dressing but also to very difficult problems of dewatering (drainage pro- blems-). It will be first of all necessary to find there an equilibrium between the consequences resulting from the re- naissance of mining industry and environmental requests un- dispensable for the city of Banska 9tiavnica and the other neighbouring towns in the vicinity of mining plants.

Jan 1, 1988

By J. G. Reid

Nickel is second only to aluminium, of all non-ferrous metals, in energy required to convert the ore to metal. Nickel Laterite ores, which constitute the feed source for approximately 40% of world nickel production, are at a particular disadvantage because of the absence of sulphur, as an energy source, in the ore and because lateritic ores general 1 y are not amenable to beneficiation. The dramatic escalation of oil prices which commenced in 1973 and continued for a decade meant that Nickel Laterite refineries using oil as a primary energy source were placed at a distinct disadvantage relative to refineries utilizing nickel sulphide concentrate feeds. By the late 1970's the continuing large difference in oil and coal prices caused Greenvale to consider converting certain high oil consuming areas of the refinery to coal. These investigations confirmed that the areas of ore drying and power generation, which together consumed 50% of total Plant oil requirements, could be economically converted from oil to coal firing. Construction of the coal conversion facilities commenced in October 1980 and the first ore drying air heater came on line in August 1981. Construction was completed with the commissioning of the coal fired boiler in June 1982. This paper outlines the additions required to receive and utilize coal in ore drying and power generation and how the changeover was completed with minimal process disruption.

Jan 1, 1988

By C. M. Diaz

The chemistry of the main unit processes in nickel extractive pyrometallurgy is reviewed. Key re1a ions between smelter feed composition and process selection are discussed, with particular reference to operating conditions, energy requirements and products. The paper a1 so includes a brief discussion of current nickel smelters, based on the results of a recent survey carried out by TMS.

Jan 1, 1988

By Robert B. Parsons

"The Canadian Exploration Incentive Program (CEIP), which was announced by the federal government on May 3, 1988, promises to maintain the viability of flow-through shares as a financing mechanism which has proven to be so crucial to the health of the junior exploration sector. This month, Tax Notes examines, the main features of CEIP, which will come into play on January J, 1989. IntroductionOn May 3,1988, the Honourable Marcel Masse, Minister of Energy Mines & Resources, and the Honourable Gerald Merrithew, Minister of State (Forestry and Mines) announced the Canadian Exploration Incentive Program (CEIP). Under CEIP, the federal government will make cash payments to eligible applicants equal to 30% of eligible exploration expenses. CEIP payments will be available with respect to both mineral, and oil and gas, exploration. In essence, the program will replace the ""mining exploration depletion allowance"" (MEDA) presently applicable to mineral exploration, and the Canadian Exploration and Development Incentive Program (CEDIP) which is presently available to the oil and gas exploration sector.This paper discusses briefly the main features of CEIP insofar as the program will affect mineral exploration. The comments herein are based on the Canadian Exploration Incentive Program Act which received Royal Assent on July 21, 1988, and on a discussion paper which was released by EM&R in May 1988. The bulk of the rules relating to the program will be in the form of regulations which have yet to be finalized. It is understood that EM&R would like to have the regulations in force by October I, 1988, when the oil and gas portion of CEIP becomes effective. (The rules relating to mineral exploration will become effective January I, 1989)."

Jan 1, 1988

By R. E. Blair

The mining and minerals industry has been, and continues to be, at the cutting edge of high technology. Iron and steel built the Industrial Revolution/copper electrified the world/coal tars and petroleum and gas feedstocks developed the organic chemical industry. Industrial minerals now carry forward this tradition. Two, of hundreds of examples of hi-tech industrial minerals are quartz crystal and rare earths. Both demonstrate the international market aspects of mining, processing and finished product trade.

Jan 1, 1988

By Abdulhadi H. M, Soliman S. A

The Western Desert of Egypt is a part of the arid Great Sahara of Africa which extends from the Nile Valley in the east to the Atlantic Ocean in the west. It is covered by a sedimentary sequence of Mezozoic and Teriary rocks. Recently this part of the country (about 65% of its surface area) has attracted an increasing attention in the plan of finding new agricultural and industrial communities outside the crowded Nile Valley. The plan aims to reduce the high population density in the narrow Nile Valley and to cover a considerable part of the increasing food demands in the country of Egypt. Accordingly, the groundwater exploration work in the Western Desert has been remarkably increased in the last decade, however it is still limited compared with the vast area of the Desert. The present work is a part of the groundwater exploration in the 6th October City, a new community located at 40kms west of Cairo. The rock exposures belong to a sedimentary stratigraphic section starting from the Cretaceous in the east to the Pliocene in the west. The Cretaceous outcrops due east are attributed to an almost N-S uplift and forms a thick massive limestone plateau which separates the present area from the Nile Valley. The Teriary section in the west have alternations of different porous formations such as the sands and sandstones which may acquire a good potentiality of groundwater resources. The previous groundwater exploration work included combined geological and geophysical investigations followed by exploration drilling. Although the area lies directly to the west of the Nile Valley, the discovered groundwater is saline and located at deeper reserviores compared with the groundwater in the Nile Valley. This groundwater was described as marine fossile water by the oil companies working in the Western Desert. From the geological point of view, it is believed that the Cretacious massive limestone plateau, in the east, roots to a depth which far exceeds the groundwater levels in the Nile Valley and acts as an impervious barrier between the aquifers in the Nile Valley and the area under investigations.

Jan 1, 1988

By P. Maraboutis

Iron removal by precipitation as jarosite from Fe-Ni-Co sulfate solutions, (synthetic or real, resulting from laterites leaching) has been investigated. Precipitation was carried out at 95 C, and at an initial pH 1.6, which was either kept constant with CaCO3 or Li2CO3 additions, or left to drift with the evolution of the reaction to lower values. The precipitation of K-, NH4- and Na- jarosite was initially examined using synthetic solutions. In all cases, hydronium ions were incorporated into the precipitate as well. Residual iron in solution was lower (0.2-1 g/1) and equilibrium was achieved faster (within 4-8 h) when precipitating K¬jarosite at constant pH, using CaCO3 for neutralization. Nickel and cobalt losses were small. Na- jarosite precipitation was also studied from real solutions with high initial iron content, under constant pH=1.5, controlled with CaCO3 additions, and it was shown that low residual iron concentration in solution (0.3-0.5 g/1) can be achieved again, with relatively small nickel and cobalt losses. The thickening and filtration characteristics of the precipitates were excellent in all cases examined.

Jan 1, 1988

Jan 1, 1988

By J. D. Lowell

The gold content of prophyry copper deposits ranges from less than .05 gmt (ppm) to more than 1.0 got, and most deposits contain on the order of 0.05 gmt Au. Perhaps the highest grade mineralization which has been found in close proximity to a porphyry copper is the Ok Tedi Gold Cap orebody whose grade falls in the 2-3 gmt Au range.

Jan 1, 1988

By J. C. Emerick

Preliminary investigations have shown that wetland-based treatment systems can be an effective and relatively inexpensive control strategy for mine drainage pollution in eastern coal mining regions. This strategy also has potential for western mining regions, although too few systems have been installed in the west to permit general evaluation of the concept for western climates. The construction of prototype systems is encouraged for some situations. Wet-land environments have the capability of removing metals by natural geochemical and biological processes, including precipitation, filtration, ion absorption, and biological uptake and accumulation. Data presented for natural wetlands receiving mine drainage show removal of iron and other metals, and high accumulation of metals in soils and plants.

Jan 1, 1988

By Colin J. Douch

New Zealand has been a significant producer of gold for over a century. Total recorded production is over 850 tonnes. There were three major periods of production: the first and biggest was between 1860 and 1880, the second was between 1895 and 1920 and the third was between 1930 and 1945. After 1945 gold production fell continually until 1980 when the major upward adjustment in gold price led to renewed interest. There have been important new developments in each of the known gold-rich areas: Westland, Otago and Coromandel and exploration for gold in these areas and in previously unprospected regions has reached unprecedented levels. In Westland over 140 gold processing plants are each producing between two and six ounces a day from low-grade placers. A major gold dredging operation will soon be producing over a tonne of gold annually and other new dredges are proposed. There are still vast reserves of gold-bearing gravels in Westland and prospecting is continuing to reveal new resources. In the Reefton area there is renewed interest in gold-bearing quartz reefs which were the source of over a million ounces of gold between 1900 and 1951. New large opencast reserves are now defined.

Jan 1, 1988

By J. P. Sieverson

The Comprehensive Environmental Response, compensation, and Liability Act (CERCLA -commonly referred to as Superfund) was passed into law in December 1980 in the wake of such incidents as Love Canal and the Valley of the Drums. Superfund was originally perceived as a way of cleaning up spills of hazardous substances and/or cleaning up abandoned hazardous waste dumpsites. In February 1981, Michael Cook, EPA deputy assistant administrator for hazardous emergency response, called Superfund "a tremendously powerful law. It could revolutionize the way the environment is protected, but we certainly don't intend to realize the full potential of the law for some time." These words have proven prophetic for Asarco's East Helena Smelter.

Jan 1, 1988

By S. G. Axen

Design of wells for in-situ leaching is based on individual mining operation and ore deposit requirements. Major design considerations are well flowrate, depth, fluid composition, expected well life, mine operating plan and cost. A large variety of downhole equipment, materials of construction, contract services and methods of well completion and stimulation are available. A generalized design procedure which allows the engineer to optimize well design for a particular ISL application is described.

Jan 1, 1988

By X. Shi, V. Vallyathan, N. S. Dalai

"Using. ESR spin trapping methodology, evidence was obtained that fresh quartz dust in a cell-free aqueous medium generated hydroxyl - and possibly superoxide radicals. The hydroxyl radical generation potential decreases on storing of fresh quartz dust in ambient air and on the addition of either catalase, superoxide dismutase, desferoxamine, or DMSO. The role of quartz related radicals in the biochemical mechanism of acute silicosis is suggested from these findings.IntroductionThis report summarizes our electron spin resonance (ESR) detection of oxygenated radical formation by freshly crushed quartz particles in a cell-free aqueous medium, and its inihibition by radical scavengers. This study was undertaken with to elucidate the primary biochemical mechanism involved in the development of silicosis (Farber, 1983; Reiser and Last, 1979; Silicosis and Silicate Disease Committee, 1988). In particular the mechanism by which the quartz particles exert their toxic action on cells and the process(es) by which these actions progress to fibrogenesis are still not well understood (Farber. 1983; Reiser and Last, 1979;). It is generally believed that the action of quartz particles on the cell membrane is the starting point of the silicotic process (Farber, 1983; Parazzi et al., 1968). Thus the surface characteristics of the quartz particles have been the subject of several recent studies (Bolls et al.. 1983; Dalai et al., 1986; Fubini et al., 1987). Recently, We reported that mechanical crushing of quartz under normal atmosphere generates free radicals which decay with time, and that these free radicals are associated with a higher cytotoxicity of fresh quartz dust as compared to aged dust from the same stock (Dalai et al., 1986; Vallyathan et al.. 1988). The formation of Si• and. SiO--type of radicals from quartz particles crushed under atmospheric conditions has also been reported by Fubini et al. (1987). In addition, Gulumian and van Wyk (1987) have reported that quartz particles react with hydrogen peroxide (H202) to generates hydroxyl radicals (•OH) and suggested that this process might contribute to quartz's pathogenicity. However, these authors did not report the effects of metal chelators, so it was not clear as to whether the detected -OH radicals simply resulted from the Fenton reaction involving exogenous metal ion contaminants. Earlier, Marasas and Harington (1960) reported that quartz particles could function as an oxidant in a number of in vitro oxidations, including the hydroxylation of proline and lysine. They postulated that silica dusts, on reacting with water, could release H2O2 which might have the potential to react with various biological constituents and thus cause tissue damage. In fact, Gabor and coworkers (Gabor and Anca, 1974; Gabor et al., 1975) suggested that the cytotoxicity of quartz particles might be associated with the generation of some 'factor or factors possessing the properties of a free radicals capable of promoting the peroxidative chain cleavage of polyunsaturated fatty acid moieties of the phospholipids in the cell membrane. More recently Weitzman and Graceffa (1984) reported that asbestos is able to catalyze the generation of • OH radicals from H2O2. Their later work indicated that lipid peroxidation may be one of the mechanism by which asbestos produces tissue injury (Weitzman and Weitberg, 1985). This is significant because • OH radicals are capable of causing peroxidation by abstracting hydrogen atoms from cell-membrane lipids and initiating lipid peroxidation in lysosomal membrane (Fong et al., 1973). In fact, the formation of oxygenated species in reactions involving quartz was suspected since Kolbanev et al. (1980) reported the detection of H2O2 in the reaction of fresh quartz particle with aqueous medium. The present work was thus undertaken to detect the anticipated formation of some oxygenated, radical species by reactions of quartz in a cell-free media and its inhibition by radical"

Jan 1, 1988

By M. Rieber

In July 1985, as the U.S. copper industry contracted and the Mexican industry expanded, a trans border pollution agreement was signed which included smelter air pollution control in the "Gray Triangle": Cananea, Nacozari and Douglas. Since then the Douglas smelter has been closed, a year earlier than initially required; though its new smelter is operating, S02 collection and acid disposal at Nacozari is yet to come; and the Cananea smelter has been un-touched. Nacozari and Cananea copper mining have expanded while a reduced U.S. copper industry has rationalized to a point of fragile profitability. As a paradigm of U.S. copper competitiveness, this paper attempts to explain the differential fortunes of copper in the two countries, to project the future of the smelter agreement as a function of acid disposal, and to consider the consequences of the politicized application of smelter pollution control in Arizona.

Jan 1, 1988

By J. R. Johanson

Many solids processes that look feasible on paper or even in pilot studies become disasters in full scale. Changes in solids flow characteristics from pilot scale to full scale because of larger so lids contact pressures, thermal shocks or unforeseen temperature excursions often cause full scale solids flow problems not encountered in the laboratory or pilot studies. Fortunately, proper applications of solids flow principals and solids flow property measurement at full scale conditions can anticipate the problems and thus provide an accurate basis for full scale design or existing plant modifications.

Jan 1, 1988

By R. Martinez

The Alligator Ridge Mine was discovered in 1976 by a prospector grubstaked by Amselco Exploration Inc. in eastern Nevada 116 km (72 mi.) northwest of Ely in White Pine County. The mine is operated as a 50-50 Joint Venture by BP Gold, the operator, which is a subsidiary of British Petroleum Minerals America and Nerco Inc., a subsidiary of Pacific Power and Light.

Jan 1, 1988

In this year marking the centennial of the Geological survey of Western Australia, it is appropriate that we should review the value of the contribution of the Survey, and Australian Geological Surveys in general, to the exploration industry. Most geological surveys in Europe and North America had their origins in the first half of the 19th Century when the burgeoning Industrial Revolution was demanding the identification of new sources of coal and iron ore. Australia, as a young nation, essentially dependent on an agricultural and pastoral industry, and with already discovered vast coal resources in Eastern Australia, had, no great need to explore for new mineral resources. However, with the discovery of gold in 1851, the mineral potential of the country became apparent to the whole world and the first Geological Survey in Australia was set up in 1852 in Victoria under A.R.C. Selwyn. After a number of false starts all Australian States had an established Geological Survey by 1900. It is hard to assess the contemporary value of the early work of the Geological Surveys with respect to exploration, almost all major mineral discoveries were made by prospectors and most mining companies had little time for geologists - although the Chamber of Mines in Western Australia in 1910, did recommend that the Geological survey be granted an additional ten thousand pounds over two years to map all existing goldfields and the country between them, and produce a reconnaissance map of the area east of a line between Wiluna and Edjudina as far as the South Australian border!

Jan 1, 1988

By J. S. Martin

The redesign and reinforcement of a highwall located adjacent to a $10,000,000 shopping center, destabilized by active subsidence, was conducted after an extensive geotechnical investigation. The highwall was excavated in a hillside where a coal seam had been retreat mined and augered. Engineering geological mapping, determination of the properties and behavior of the intact rock, fractured rock, and urethane grout material, and soil were required to characterize the highwall and conduct a stability analysis. Remedial measures included re-excavating portions of the highwall to reduce the slope angle, and pressure grouting of the immediate roof.

Jan 1, 1988

By R. G. Robins

The dissolution of metallic copper powder in aqueous solutions of cupric sulfate with ethylene under low pressure was investigated. The reaction stoichiometry obtained was:

Jan 1, 1988