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By C. M. Davidson, D. J. Drexler

"Sulphuric acid treated with hydrogen peroxide to destroy organic contaminants could conceivably show increased corrosivity toward carbon steel shipping and storage vessels, caused by the persistence of a peroxide residual. This paper describes work performed to determine the effect of 0-200ppm hydrogen peroxide on the corrosion of carbon steel by 93% and 98% sulphuric acid at room temperature (23ºC) and 50ºC.Steel electrodes were exposed to acid containing several peroxide levels (0. 45, iOO and 200 ppm) for up to two weeks. Specimens were removed at intervals and weight loss, open circuit potential, depth of metal loss and residual peroxide concentration recorded.Hydrogen peroxide decomposes considerably over two weeks in iron-contaminated sulphuric acid. initial peroxide concentrations > l00 ppm suppress corrosion, but the effect is lost when concentration decays below about 60 ppm. Sustained peroxide levels in the range below 60 ppm may increase corrosion rates. These phenomena are interpreted by analogy with anodic passivation."

Jan 1, 1987

By U. S. Sawant

During the last few years, Process Machinery Division, Rexnord, has conducted extensive research on the effects of cone crusher variables such as speed, throw and cavity design on the productivity of the crushers. Simultaneously, Rexnord's engineers have developed advanced design and testing techniques and criteria that assure efficient and reliable crusher designs. The combination of these two has resulted in a design of the 2390 Omnicone (1000 hp) crusher which fits on an existing 7 ft. Symons foundation and yet is capable of producing twice the tonnage compared to our 7 ft. super heavy duty (500 hp) crusher. Both speed and throw can be varied to give a wide application flexibility from making twice the tonnage to the finest product. The 2390 Omnicone also incorporates innovative features such as full balance, cavity clearing, adjusting under load with automation capability, maintenance-free seals, one head for all cavities, ease of maintenance and servicing, etc.

Jan 1, 1987

By R. L. Pariani, R. R. Moskalyk

Justifying refinery material handling equipment jointly involves economics and indirect benefits. The simple evaluation method is applicable when either retrofitting facilities or costing new metal refineries. The text includes points of interest regarding equipment selection as an additional guide. Although the copper industry was used as a basis, it is recognized that similarities in material handling may exist within the parallel electrolytic refining and winning of metals such as copper, nickel, lead, zinc, tin, and cobalt. The analysis of four major automatic systems, typically implemented in many tank houses, includes tabulated data plus a detailed description of additional benefits. General information regarding auxiliary material handling equipment and an overview are included for subject completeness. It is suggested that the quantitative and qualitative aspects presented may contribute to the basis for justification of automated material handling. The labor-oriented economics plus related intangible benefits described herein should provide incentives to modernize or replace manual operations where practical.

Jan 1, 1987

By Robert J. Evans

The monorail bridge conveyor (MBC) is a prototype continuous face haulage system that was surface tested and evaluated by the Bureau of Mines. The MBC consists of a series of cascading belt bridge conveyors suspended from roof-supported monorail track. Tests were conducted to determine MBC haulage capability, maneuverability, power consumption, and reliability using rigid and chain-suspended monorail track installations. Subsequent modifications to improve operation and reliability made during surface testing are described. Mining plans were devised to show potential MBC installations for room-and-pillar, longwall development, and shortwall mining sections. Compatibility tests were conducted with the Bureau's prototype hopper-feeder, to provide additional surge capacity and lump-breaking capability. Results from the surface test program, along with modifications to improve system operation and reliability, indicate that the MBC has the potential to perform success- fully in an in-mine trial.

Jan 1, 1987

By Drew GJ

Smelting is a process in which heat is applied to ores to produce metals. Impurities are removed by segregation in the slag, or converted to gases or sublimates and discharged up the flues. Mate- rials delivered into the smelter have generally been previously concentrated or processed at the mine, and the size of their particles, and also their chem- ical composition, greatly affect the smelting proc- ess. Some impurities are more difficult to remove than others, and are more objectionable in the finished product. The first metal mine in Australia was opened near Glen Osmond in South Australia in 1841, for silver-lead ore. It was followed by the Kapunda Mine for copper in 1844 and by the very signifi- cant Burra Mine, also for copper, in 1845 (Figure 1). A major part of their ores could not be exported profitably for smelting in England and Wales where the large smelters were then located. In addition to treating ores from Cornwall these also smelted ores from recently opened mines in Cuba, Chile, and Mexico. The Welsh smelting process (Figure 2) was developed over a period of years to utilise Welsh coal to treat copper ores particularly from Corn- wall. The first step consisted of a calcination to remove sufficient sulphur from sulphide ores so that subsequent melting operations would produce copper matte, a copper-iron-sulphide which melted at about 1050¦C. Subsequently refined to white metal with the addition of carbonate and oxide ores when these were available, and often through an intermediate step of blue metal, this matte was finally oxidised to pure copper, or as pure as it could be made in those days. The movement of metal towards greater purity was matched by a reverse flow of slag, carrying reducing quantities of copper, so that the slag rejected from the first melting process carried the minimum quantity of copper. Chemical analysis was virtually unknown. Materials were assayed in the laboratory by a small scale smelting process, and the purity of the final refined copper was judged b} the ease with Mhich it could be hammered into thin sheets.

Jan 1, 1987

By Robert B. Parsons

"Starting January 1, 1987 employers, employees, and other taxpayers are confronted with a new set of rules dealing with the taxation of travel and housing benefits relating to isolated posts in Canada, and tax deductions relating thereto. The new rules may not be the simplest in the world, but they are reasonably fair and at least offer a hitherto unknown degree of certainty as to how such allowances are to be treated. IntroductionThe first shoe fell on February 26, 1986 when Finance Minister Michael Wilson' s first budget presented the framework for the future tax treatment of travel and housing benefits (so-called ""northern allowances"") provided to residents in remote regions of Canada. The second shoe fell some ten months later on December 22, 1986 when the Minister of Finance filled in the earlier announced framework with detailed rules. We now have a complete picture of the tax treatment of northern allowances. Here is what the picture looks like with effect from January 1, 1987.According to Revenue Canada, the net housing benefit to employees will be equal to the value of the accommodation provided, less any rent they have paid. In major centres such as Yellowknife and Whitehorse, having a developed rental housing market, the benefit amount will be based on the fair market value of the rental accommodation in that location. In other areas, employers will be required to value the housing benefits and, to assist employers, Revenue Canada has provided the following guidelines: Common shelter- $100 per month including the value of subsidized utilities Apartment! duplex-$270 per month excluding the value of subsidized utilities, or $400 per month including the value of subsidized utilities House-$450 per month excluding the value of subsidized utilities, or $650 per month in- c1uding the value of subsidized utilities.The amounts established as the values of accommodation will be adjusted annually after 1987 based on the housing component of the Consumer Price Index."

Jan 1, 1987

By K. C. Shaver

The Sloan Ranch kimberlite complex is located approximately 130 km north-northwest of Denver in the Precambrian core of the northern Colorado Front Range (Figure 1). A Devonian age for the complex is suggested by the fossil assemblages in limestone xenoliths (Chronic and others, 1969), and by paleomagnetism of the kimberlite (E. E. Larson, personal communication, 1986). The presence of diamond was first reported in rocks from the Sloan diatreme by McCallum and Mabarak (1976). Prior to this time, the distinctive- appearing host rock of the Sloan diamonds had been quarried for use as terrazzo stone; examples may be seen in the floors of the airports in Cheyenne and Laramie, Wyoming. The Minerals Division of The Superior Oil Company obtained a lease on the Sloan property in 1980. During the next four years Superior built and fine-tuned a highly efficient diamond recovery facility, explored and tested the Sloan deposit, and used Sloan as a site for testing numerous exploration techniques for future use in a continuing exploration program in the Colorado-Wyoming kimberlite province. The Sloan property was ultimately determined to be sub- economic, but the lessons learned there have been very helpful in subsequent exploration efforts.

Jan 1, 1987

This paper attempts to put into perspective the implications of the legal disclosure requirements for promoters and consultants when making statements concerning ore resources and reserves. The need to take account of non-technical as well as technical factors is highlighted.

Jan 1, 1987

By W. Z. Choi

In our previous work, a population balance model describing the simultaneous processes of size reduction and mineral liberation has been developed. The experimental verification of this model, however, has been limited to a binary mineral system containing only one composite particle class. When considering multiple classes of composite particles, the estimation of model parameters becomes much more difficult. In the present work, a procedure for estimating model parameters for a multiple composite class model has been developed. Emphasis is placed on the direct experimental determination of these parameters. The physical significance of the breakage rate function and the liberation function in characterizing the liberation process is also discussed.

Jan 1, 1987

The height of permanent slopes at the Panguna mine of Bougainville Copper Limited will vary from 350 to 950 metres. A few degrees difference in slope angle has a large effect on the ore/waste stripping ratio. Optimum slopes can be achieved if longer batter slopes (exceeding 45m height) are excavated using bulldozers to trim parallel to controlling fracture surfaces. Unnecessary slope flattening by incorporating benches can cost millions of dollars in lost ore. Faults and other major weaknesses, which can result in wedge failure or erodible zones have been treated successfully with shotcrete, rockbolts and cable dowels. To minimize support effort and interference with mine production, early identification and treatment of unstable areas is important.

Jan 1, 1987

By Richard D. Miller

The helium resources base of the United States was estimated by the Bureau of Mines to be 1,070 Bcf as of January 1, 1985. These resources are divided into four categories in decreasing degree of assurance of their existence: (1) helium in storage and in proved natural gas reserves, 280 Bcf, (2) helium in probable natural gas resources, estimated at 243 Bcf, (3) helium in possible natural gas resources, estimated to be 287 Bcf, and (4) helium in speculative natural gas resources, which makes up the remaining 260 Bcf. These helium resources are further divided into depleting, non-depleting, and stored classifications. The depleting resources are those associated with natural gasfields that are, or will be, produced for the natural gas they contain. Almost all of the helium in potential (probable, possible, and speculative) natural gas resources is included in this classification. These depleting resources are estimated to contain 900 Bcf of the total helium resource base. Helium resources contained in nondepleting natural gas resources, those in shut-in, abandoned, or otherwise nonproducing natural gasfields, are estimated to total 133 Bcf. There is 37 Bcf of helium in storage in the Federal Government-owned Cliffside Gas Field near Amarillo, TX.

Jan 1, 1987

By C. Babbitt, J. O’Green, N. I. Jayaraman

In many mines, dust-laden air from an entry being driven by a continuous miner will contaminate the intake air to the roof bolter operator and other downwind personnel. Through a US Bureau of Mines (USBM) contract, Foster-Miller Inc. has evaluated several control techniques to reduce the respirable dust exposures of downwind personnel. One fan and tubing technique consisted of bypassing the miner-generated dust directly to the section return. The results of the evaluation of this technique revealed that reductions in dust concentrations of 90% or more can be achieved at downwind roof bolter locations. A second method was to clean the dusty air from the upwind continuous miner by using a dust collector. The cleaned air was then supplied to the bolter through collapsible tubing. An underground evaluation showed reductions of 82% to 96% when the dust collector was operating. A third method was to reduce the quantity of dust contributed by the miner to the return airstream. A water-powered scrubber was installed over the throat area of the continuous miner. More than 1.18 m3/s (2500 cfm) of dusty air moved through five tubes with dust collection efficiency exceeding 75%. Underground evaluation results showed that return dust concentrations were reduced by about 60%. This paper discusses the ventilation and dust control techniques used for personnel downwind of the continuous miner.

Jan 1, 1987

By S. Chander

The formation of surface films on pyrite has been studied through electrochemical techniques of cyclic voltametry and AC impedance measurements. The characteristics of the surface films depend upon the conditions of oxidation and the source of pyrite. At potentials near 0.0 V, some pyrites have large values of polarization resistance showing a certain degree of passivity. Some pyrites show more passivation than the others, however. On oxidation, metastable phases of Fe(OH2) and Fe(OH3) form which transform to more stable 3 phases on aging. The growth of surface films near the corrosion potential of pyrite follows a linear kinetics which is attributed to a chemical (or an electrochemical) reaction as the rate determining step. The surface film is considered to be a hydroxide or an oxide rather than sulfur because the later is expected to be limited to a monolayer in alkaline solutions. This study has also demonstrated that AC impedance measurements can be used to study the growth characteristics of films at mineral/ solution interfaces.

Jan 1, 1987

By Bruce See J

Oxidation of artificial Imperial Smelting Furnace lead bullion was performed during cooling between 1180 and 820°C in order to attempt to produce a tin-rich dross.The addition of sodium carbonate together with stirring increased the tin content of the dross when oxidation was carried out with air or PbO on zinc-free bullion.Zinc in the bullion during oxidation resulted in a decrease in tin concentration of the dross due to zinc oxidation and copper entering the dross.

Jan 1, 1987

By K. A. Brunk

This paper describes Newmont's research, operations, history and experience with pre-treatment of preg robbing carbonaceous ores. The chemistry, physics and kinetics of chlorine treatment are described. Present operations, control strategy and projected changes are discussed. Included is a summary of the adsorption of chlorine into pulps and off-gas scrubbing.

Jan 1, 1987

By R. F. Lynch, F. E. Goodwin, A. F. Skenazi

"The Gal/an alloy has been developed for continuous galvanizing of steel. The choice of the eutectic zinc-aluminum alloy with addition of misch metal gives a coating with specific characteristics as far as structure, analysis, surface chemistry and surface morphology are concerned. The performance of the uncoated Galfan coating is superior when compared to conventional galvanized particularly for corrosion resistance and ductility. For coil coating applications, these two assets are of the utmost importance but in order to benefit from these two advantages, good paint adherence and high resistance to edge creep and blistering have to be obtained. Despite Galfan's unique features compared to other zinc based or aluminum zinc based coatings, existing pretreatments and painting conditions are used with only minor modifications in order to assure good adherence and edge creep resistance. With compatible processing, Galfan can outperform galvanized and Galvalume as a substrate for coil coating as is demonstrated with various test results.IntroductionThe technical and commercial development of Galfan, a 95% zinc-5% aluminum-0.1% lanthanum-cerium hot-dip coating for steel, has been rapid. From its identification as a promising coating in late 1980, it has evolved from a research product to a fully commercial product with over 100 000 metric tons of coated sheet produced to date, and another 90 000 tons, at minimum, scheduled for 1986. The great majority of tonnage produced to date has been coil coated for use in building panel , appliance, and similar applications. Much technical work has been done to determine the suitability of Galfan for these applications and the proper way of processing sheet for best results. The present state of knowledge is discussed in this paper, along with some recent applications which are given asexamples"

Jan 1, 1987

By Y. C. Kim, F. Szidarovsky

The technique of linear kriging as a grade estimation method of mining blocks is reason¬ably established in the mining industry. During the kriging process, negative kriging weights ([]i) are sometimes encountered. Due to negative kriging weights, negative block grades may be obtained in some extreme situations, which makes no practical sense. To guarantee nonnegative weights, an additional constraint is required in the kriging system of equations. Unfortunately, the nonnegative weight constraint results in a set of nonlinear system of equations. In this paper, a derivation of the resulting set of nonlinear equations is presented and a numerical algorithm is developed for the solution of the equations. Because the algorithm developed does not remove negative weights arbitrarily, optimal nonnegative weights are always guaranteed. Results obtained using the developed algorithm were compared with those using the standard linear kriging, in terms of computer, time and the estimation results. Both the computer time and the kriging variance were found to be higher with nonnegative constraint, as expected. However, some systematic pattern was observed in the kriged values (i.e., over-or underestimation) with or without the nonnegative constraint. The study also demonstrated when one should generally expect negative kriging weights in practice, and what practical impact the negative weights can have on the kriging estimates.

Jan 1, 1987

By R. A. Seitz

Although the role of the collector has long been thought to play a predominant role in coal flotation, recent investigations by the authors show that the frother plays an equally important role. These investigations have included extensive testwork in several coal preparation plants and in the laboratory. The factors which were investigated include the absolute level of collector and frother addition, the ratio of frother to collector additions, the type of frother, and the particle size distribution of the feed. Results from this testwork reveal strong interactions between these factors as well as the necessity of considering these factors in order to optimize the reagent regime.

Jan 1, 1987

By Joan Weinberg

The real gross national product (GNP) expanded by 2.3% during the second quarter, down from the anomalous 4.4% growth rate in the previous 3 months. If the expansion continues through October, it will have lasted 5 yr and become the second longest in 40 yr.2 As in the first quarter, improvement in U.S. exports played a role in the continuing--albeit slow--growth. More than 2 yr of declines in the dollar relative to currencies of other industrial countries have contributed to a slight reduction in the trade deficit in real (volume) terms, as real net exports of goods and services rose $1.9 billion (table 1). Exports grew a strong 12.1% while imports, which had fallen the previous two quarters, rose 7.4%. Manufactured goods and petroleum products accounted for most of the second quarter import increase. The American Petroleum Institute estimates that the volume of crude oil and refined products imports in the first half of 1987 surpassed those in the same period last year by 7.5%, reflecting falling domestic production and higher than expected demand. Expenditure on durable goods--those that last at least 3 yr-by both consumers and producers also contributed to the second quarter expansion. Personal consumption of durable goods rose 9.0%, after having fallen the two previous quarters. Motor vehicle purchases accounted for most of the second quarter increase and the first quarter decrease. Sales of automobiles surged in the last quarter of 1986, as consumers rushed to capture the sales tax deduction that was eliminated on January 1. Sales fell in the first quarter of 1987, but have now moved closer to the trend line exhibited in the first three quarters of 1986. Automobiles accounted for half the 0.8% July gain in retail sales, and two-thirds of the 1.4% June gain. Producers durable equipment purchases also rose this quarter, accounting for the increase in nonresidential fixed investment.

Jan 1, 1987

By L. G. Hagenbuch

Several factors need to come together in creating an integrate mining equipment dispatching system. At the hub of these factors ace the central dispatching formulas. This paper details the development of these central dispatching formulas and explores the combining of these formulas with other elements to create an integrated dispatching decision. WHY DISPATCHING? Truck dispatching implies and in reality should equate to mine equipment efficiency. Good truck dispatching will yield good mine equipment efficiency while poor truck dispatching will yield the alternative. Truck dispatching can either be automated through a computerized, process or it can be manual. Every mine with haul trucks has a truck dispatching system whether it is recognized or not. Even a system wherein the hauler operators determine where they are going for their next load is a truck dispatching system.

Jan 1, 1987