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By D. J. Murdock

Cominco Ltd. has developed a number of innovative technologies for electrowinning. The paper discusses the application of these technologies to the copper industry. Tankhouse and cell design will be discussed in addition to anode cleaning and cathode handling. Specific examples of the application of this technology to the copper industry are cited.

Jan 1, 1987

By John A. L. Campbell

Are safety concerns justified regarding the potential for a gas explosion due to recirculation when a scrubber is used on a continuous miner? The role of a respirable dust scrubber on a continuous miner section using blowing face ventilation is examined in this paper and the above question answered. Methane control using high efficiency scrubbers coupled with blowing face ventilation is promoted.

Jan 1, 1987

Flexible hoses with rated working pressures up to 40,000 psi are used when high-pressure water jets are employed to cut rock or improve the performance of mining machines. Hose failures at such high pressures can result in serious injuries to workers. The Bureau of Mines used fatigue and burst tests to investigate the failure modes of high-pressure hoses at their rated working and burst pressures. Fatigue failure, at rated working pressures, occurred when the inner liner of the high-pressure hose broke, allowing water to seep through the wire wrapping, although the reinforcement wires did not break. At the burst pressure, all hoses failed catastrophically when the reinforcement wires broke. Low-pressure hoses placed over the high- pressure hoses for safety failed to contain water released by catastrophic failure.

Jan 1, 1987

By D. N. Tallman

The Bureau of Mines has completed 4 yr of deep-bed filtration research comparing the efficiencies of granular magnesium oxide (MgO) and conventional filter sand in single- and dual-medium filters when filtering mineral-processing and mine waters. Bench and field evaluation tests were conducted using water types ranging from synthetic suspensions of asbestos, kaolin, metal hydroxides, and milled sand to process waters from magnetite beneficiation, iron ore flotation, granite cutting, and a steel mill. Even though the turbidity reductions were similiar, MgO filters were found to be advantageous when filtering water pretreated with alum because the volume throughput before breakthrough (turbidity > 1 NTU unit) was much more for the MgO filter than for the sand filter. Reduced head loss owing to the greater porosity of the MgO filter beds is potentially the most beneficial advantage in employing MgO as the filter medium, especially when filtering water pretreated with polymer flocculants. Granular MgO (periclase) is durable and can be backwashed Like sand. It is compatible with anthracite in a dual-medium filter and apparently is not poisoned by dissolved metals in the process water. No single solid-removal mechanism could be identified for the improved filtration observed with granular MgO.

Jan 1, 1987

By Alan G. MacKinnon

The current piling practices in the U. S. have, to a great degree, been influenced by our founding fathers. When our constitution was written by the delegates from the original thirteen colonies, it was a document of compromise. Generally, the individual states retained their sovereign power over those duties that they had historically performed. The concept of States Rights has been tested throughout our history and has been preserved as of today. An example of the extent of this protection is occurring in the State of Ohio where I currently live. Each of the 50 states receives funds for highway construction from the federal government, approximately in proportion to its population. Congress, when it allocates the funds, quite often attaches amendments to the funding bill to exercise their authority. The major amendment prior to the most recent increase in the speed limit to 65 mph from 55 mph was to increase the legal drinking age to 21 from 18 years old. Embodied within the bill was the provision that the Federal government deduct a percentage from the allocation of any state that did not revise its legal drinking age law from 18 to 21. In the State of Ohio, this change in the law was put to a vote of the people and it was defeated. The federal government now is deducting funds

Jan 1, 1987

By T. M. Barczak

This report describes Bureau of Mines research to develop methods to evaluate loading on longwall roof supports to permit better design and more efficient utilization of these structures in compliance with the geological conditions in which they are employed. The resultant vertical and horizontal force acting on the canopy of a shield can be determined, either from a statically determinate solution assuming rigid-body mechanics and elimination of certain unknowns, or from an elastic solu-tion by analysis of the load-displacement relationship of the shield structure. A two-dimensional rigid-body model is presented that determines resultant shield forces by measurement of leg, canopy capsule, and lemniscate link forces. An elastic solution is presented, in the form of an elastic stiffness model with two degrees of freedom, which describes the load-displacement relationship from the stiffness of the shield structure as determined in the Bureau's Mine Roof Simulator (MRS). The ability of both models to determine resultant forces acting on the shield canopy are evaluated from full-scale tests in the MRS. More advanced numerical models are also discussed as part of the Bureau's continuing effort in the evaluation of roof support structures.

Jan 1, 1987

By Frank Hagar, George M. L. Robinson

NTRODUCTION The Resource Conservation and Recovery Act and CERCLA (SUPERFUND), in many instances, has had an adverse economic impact on the hardrock mining industry. Over the last few years, many abandoned and active mining operations have been added to the Environmental Protection Agency (EPA) National Priority List (NPL) . When the property is placed on the NPL the operator or EPA is required to conduct extensive environmental assessments to determine if historical mining practices have degraded the existing environmental. If degradation has or will continue, the responsible party is required to implement appropriate remedial action plans. If a responsible party is not identified, the EPA implements a cleanup program. Experience has demonstrated abandoned and active mining operations are subject to RCRA, and possibly Super- fund, if the mine has not adopted appropriate hazardous waste disposal management procedures. If off-site contamination has occurred, the operator will be required to mitigate the impacts and will be required to adopt additional procedures to minimize future impacts. Since the passage of RCRA and Super- fund, many mining operators are adopting management procedures to monitor and inventory hazardous sub- stances and wastes generated, stored and disposed on site. Many operators are in a difficult position because ore, waste rock, process chemicals or other solid waste, in many instances, can be classified as hazardous waste. If the process or other solid waste is deemed to have the characteristics of a hazardous waste, the operator can inventory and adopt appropriate, in- expensive management procedures. However, if the ore or waste rock has hazardous waste characteristics, in- expensive control technologies are impossible to implement. Since existing statutes and regulations require hazardous waste control, the operator will be required to inventory, characterize and monitor all aspects of the mining operations including but not limited to exploration, mining, ore processing and waste disposal. During this process, geological, geotechnical, geochemical, waste and ore volumes, and process materials must be tracked throughout the mining process. To accomplish this task, the most cost effective method to maintain documented and accurate records, is through the implementation of an integrated database management system. The database management system can be used to model and simulate the entire mining operation and if necessary, used to predict whether the operation is in compliance with existing regulations. The developed database can also be used to operating optimize mining and disposal costs.

Jan 1, 1987

By H. Sevim

An innovative approach in designing the haulage systems for underground coal mines is discussed in this paper. The haulage systems are formed by serially connected components. Therefore an economic and efficient design of the entire system is necessary. The computer model that uses a heuristic algorithm solves this design problem globally in a single run. It is a probabilistic model because it considers the probabilistic aspects of face operations. It is versatile because it can accommodate any type of mining and belt conveyor network configuration. The hoisting section can be used to design drum or friction hoisting systems for single or multiple level operations. These systems can have two skips in balance or a skip and a counterweight in balance. The model also has the option to internally determine the capacity of bunker(s) and shaft-bottom bin. The objective is to minimize the expected cost per ton of coal hauled from the coal faces to the surface. At the end of the paper is an example that illustrated the capabilities of the model.

Jan 1, 1987

By D. A. Larson

The Bureau of Mines conducted basic experiments to study the process of crack propagation with a wedge indenter. The work was conducted under plane stress conditions in a hard, brittle limestone. The purpose of these experiments was to first gain an understanding of the basic crack propagation process under a sharp indenter, and second, to determine how the crack propagation process could be used to improve mechanical fragmentation systems. Three methods of rock fracture with the wedge indenter were investigated in this program. These were the confined indentation tests, the unconfined splitting tests, and the edge chipping tests. The confined indention tests represent worst case conditions for crack growth and formed the lower bound on fracture efficiency. The unconfined splitting tests represented best case conditions and fixed the upper bound of fracture efficiency. The edge chipping tests represented an idealized fragmentation process based exclusively upon the highly efficient fracture propagation process. Edge chipping achieved a specific energy of 25 in lb f/in3 compared to conventional drag cutters, which required a specific energy of at least 2,385 in·lb f/in3? Thus edge chipping is up to 100 times more efficient than conventional drag cutting. Because of these promising results, more work is planned with the fracture propagation process in three dimensions.

Jan 1, 1987

By Young D. R, Webb I. D

The hydro-chlorination of Fe2O3 and Fe304 has been investigated in the range 850-950¦C in order to elucidate the role of iron in the segregation process for nickeliferous laterites. The kinetics of Fe203 chlorination using 20% HC1 - 80% N2 gas mixtures is consistent with a single-stage structure control model, whereas Fe3O 4 exhibits a two-stage reaction mechanism. Oxygen potential measurements using a CSZ probe located above the bed and X-ray powder diffraction results confirm the proposed reaction scheme. When a serpentine nickeliferous laterite (1.03% Ni - 11.7% Fe) was chlorinated at 900¦C with a 20% HCl - 80% N2 gas mixture it was found that the iron oxide in the ore was extracted in a similar manner to the synthetic iron oxides. Also, it was found that the nickel extraction from the ore paralleled that of the iron and the tests indicated that for the major part of the extraction, the solid nickel species were in equilibrium with the gas phase. The recovery of nickel from laterite ores by the segregation process has been investigated by a number of workers and several extensive reviews of the literature associated with this field have been published (Iwasaki, 1972; Canterford, 1975; Wright, 1973).

Jan 1, 1987

By Wright S, Jorgensen F. R A

The reaction between lead sulphate and a number of base metal sulphides (galena, sphal- erite, chalcopyrite and synthetic pyrrhotite was studied as a means of desulphurizing lead sulphate containing fumes and residues to levels acceptable as ISF feed. The reactants were mixed with 50% zinc oxide to act as a "basket" to contain the molten products of the reaction and pressed into small briquettes 20 mm in diam. Factors such as temperature, time and the composition of the atmosphere were investigated. Using the PbS/PbS04 system as an example it was shown that the reaction became rapid above 800¦C and that both sulphur dioxide and oxygen in the atmosphere were detrimental to achieving low sulphur in the product. In an inert atmosphere all the sulphides when roasted for 1 h at 1000¦C gave results corresponding to the elimination of more than 95% of the sulphur in the reactants. Leach plant residues were considered for use as the "basket" material. It was shown that the residual sulphide and sulphate components of the residues underwent similar reactions to those experienced by the pure systems.

Jan 1, 1987

Previous models describing the aggregation of polymer coated particles fail to take into account the fact that there are a limited number of sites onto which a polymer segment can adsorb, called ?active? sites. Thus, the collision efficiency is a factor not only of the fractional surface coverage, but also of the number of active sites. In this study, a physical model of the flocculation system was devised in which the number of these sites could be varied, in order to study the effect on particle aggregation.

Jan 1, 1987

By Yokozawa K, Yamamoto T, Kameoka Y

Japan Construction Method and Machinery Research Institute has been conducting various field surveys of tunnel works and other excavation works, and the cost and efficiency of these two excavation methods have been studied. Based on these data, the costs of blasting excavation and mechanical excavation represented by roadheaders were calculated. The costs were calculated and compared for rocks of various hardness. When the total construction cost is considered, the degree of overbreak becomes one of the most influencial factors, because the overbreak area must be filled up with expensive shotcrete in NATM. So, in the next step, the relation between the excavation costs considering overbreak and the rock hardness was studied using the data on overbreak obtained by the field survey.

Jan 1, 1987

By K. A. Brunk

Newmont's research, operations, history and experience with pre-treatment of preg-robbing carbonaceous ores are described, with emphasis on the chemistry, physics and kinetics of chlorine treatment. Present operations, control strategy and projected changes are also described, including a summary of the adsorption of chlorine into pulps and off-gas scrubbing. Conditions of chlorination have been optimized by the use of Eh-pH diagrams of the gold-chlorine-water system, and have resulted in significant increases in gold recoveries and decreases in chlorine consumptions.

Jan 1, 1987

By T. T. Chen

Kidd Creek continuously-cast copper anodes are characterized by high levels of Se, Pb and Ag; the anode slimes constituents and their morphologies are controlled by both the anode composition and the casting process. Hollow Cu2Se spheroids and tube-like structures, enveloping Cu-Pb-As oxide and/or Cu2O, are present in the as-cast copper. During electrolysis, the selenides are liberated from the copper and accumulate in the slimes layer; the Cu2O and Cu-Pb-As oxide react rapidly with the electrolyte to form soluble species and PbSO4. Silver, which is present mostly as a solid solution in the anode copper, is also liberated during electrolysis and reacts with the Cu2Se to form (Cu,Ag)2Se. The ultimate composition of the selenides in the slimes layer depends mostly on the Ag and Se contents, but various other elements, including Au and Te, are also structurally incorporated. Although the selenides are the major Ag carrier, metallic silver also is present. A thin layer of Cu2O crystals sometimes forms at the copper surface, and may affect anode passivation. Copper sulphate is a common constituent and serves to agglomerate the slimes. Copper sulphate is present on both passivated and non-passivated anodes, but that observed on the passivated metal is present as a thick compact layer. Copper powder is associated with CuSO4.5H2O only on passivated surfaces.

Jan 1, 1987

By B Scheiner, D. A. Stanley

Introduction Treatment of ores to recover metal and mineral values results in waste materials usually in the form of dilute slurries. The US Bureau of Mines (USBM) investigated a technique for dewatering phosphatic clay waste by flocculating with polyethylene oxide (PEO) and dewatering the resulting floes on a static screen and/or trommel screen (Schemer et al., 1985). In the investigation, it was determined that PEO was far superior to polyacrylamide polymers for this type of dewatering. This paper discusses reasons for this superior performance. Comparison of PEO with polyacrylamides Dewatering experiments were conducted by adding PEO solution from a burette to a stirred clay slurry. The dewatering endpoint was characterized by rotation of the floc mass as a unit, a clear supernate, a maximum floc size, and a minimum floc volume. Additional water was removed from the floes by hand squeezing (Schemer et al., 1985). The clays investigated were sodium, potassium, magnesium, calcium, and aluminum exchanged montmorillonite and attapulgite. Nine commercially available (Superfloc) polyacrylamides were compared with PEO at two polymer concentrations. Results are summarized in Table 1. The solids content of the dewatered clays ranged between 24% and 33% and was highest for PEO-treated material. These results and the data in Table 1 indicate that PEO is superior to polyacrylamide in terms of polymer dosage required. Superflocs 16 through 128, like PEO, are nonionic and should give similar results to those for PEO if the flocculation mechanism is the same for both type polymers. Superflocs 204 through 214 are anionic with increasing anionic character from 204 to 214. Generally, the anionic polymers gave the best results for the polyacrylamides tested, but in terms of dosage they were not as good as PEO. Correlation between flocculation and dewaterability of waste slurries The overall mechanism for mechanically induced clay dewatering is not completely known, but certain observations can be made. For instance, when a polymer is adsorbed on a clay such as montmorillonite, the polymer desorbs interlayer water. Polymer adsorption is driven by favorable entropy changes associated with this water desorption. It is also known that the -CH2-CH2- links of the PEO chain are sufficiently hydrophobic to lead to physical adsorption of the polymer (Theng, 1979). For montmorillonite slurries, the sheet-like fundamental particles, called tactoids, consist of a small, variable number of aluminosilicate layers together with interlayer water and exchange ions. The flocculation process consists of adsorption of polymer on the tactoid. Loops and tails of polymer that extend into solution then adsorb on another tactoid, forming a bridge. Mechanical action, induced by hand squeezing or in a trammel, joins the bridged tactoids face-to-face and edge-to-edge to form regions of high density. Similar orientation effects are observed for the needle-like attapulgite crystals (Schemer et al., 1985). Proposed flocculation model Generally, statements concerning flocculation and dewaterability apply to both PEO and the polyacrylamides. However, PEO has additional interaction with the clay material when compared with polyacrylamides. PEO is a polymer with repeating -CH2-CH2-O- groups and interacts with montmorillonite through a water bridge whose strength is greatly influenced by the exchange ion. To obtain insight into this interaction, a series of experiments were conducted in which different ion exchange forms of montmorillonite and attapulgite clays

Jan 1, 1987

By L. A. Haas

The Bureau of Mines, in cooperation with three Minnesota agencies (Department of Natural Resources, Geological Survey, and the Iron Range Resources and Rehabilitation Board), investigated the potential of using glacial lake clay from Minnesota, as well as other areas, as a binder for iron ore pellets. The best clay-characterizing procedures for predicting binder effectiveness were the cation exchange capacity (CEC) using the methylene blue method and the plate water absorption test (PWAT). The best clay binder was found in the Red River Valley. However, compared to a typical western bentonite at the 0.5-pct-addition level, addition of about 2 pct Minnesota clay was required to obtain comparable unfired (green) pellet strengths. Soda ash addition only slightly improved the binding properties of Minnesota clay, but considerable improvement was obtained by the addition of a small quantity of water absorbing organic compounds. For example, with a mixture of 0.5 pct Minnesota clay or paint rock and 0.1 pct pregelatinized starch, the unfired and fired physical pellet properties were about the same as with 0.5 pct of typical western bentonite. The reduction rate at the 40-pct reduction level and the percentage of plus 6.3-mm particles from the reduction disintegration index test were also about the same.

Jan 1, 1987

Mr. Bradford said: - On assuming this chair, which has been oc- cupied by so many gentlemen of conspicuous ability, my first words must be an expression of the gratitude I feel for the honour you have done me in electing me to be your President for this year. When considering the subject matter of this address to you to- night, quite frankly may it be stated that for a long time I was on the horns of a very great dilemma, for while I could discourse on the modern political trend in relation to our industries at great length, it appeared to me that this was not the place for such a discussion.

Jan 1, 1987

By Joachim Klein, Frank Reimann

Nodular-graphite cast iron (GGG) is a material similar to steel, and one which exhibits excellent properties, in particular for components exposed to pressure. GGG cast iron has been used in many cases when sinking mine shafts with conventional tubbing. With linings made of cast iron tubbings (the backfill concrete is not integrated into the calculations, and merely serves as bedding) the properties of the cast iron can be made full use of, provided the tubbing is made to the appropriate cross-section. Calculations have shown that better static values can be arrived at when using cross-sections other than those of tubbings made to conventional German standard. The cross-sectional design of the new types of shaft lining made from GGG is to be developed on these lines irrespective of the cast iron structure being only stressed component or its restistance function being combined with the one of concrete. GGG 50 is used for the first time to make the reinforcing inner liner of a main shaft currently sunk in Germany. The physical properties of nodular-graphite cast iron, strength and deformability, suggest that, in the future, its application will not be restricted to shaft support but also in tunneling. New moulding techniques with better three-dimensional modelling resulted in new tubbing designs as installed e.g. for the Hannover underground at present. Shield-driven tunnels have to withstand earth and water pressure, apart from axial machine loads. In this field time is money as well. Therefore easy handling and quick installation are necessary for successful, use. Last but not least, safety is of first-order importance for work in shaft sinking and tunneling. Cast iron lining systems, accordingly, are adequate systems, in particular for excavations underneath water for transport systems and for goods and passengers.

Jan 1, 1987

By S. J. Stokowski

An extensive drilling and laboratory testing program indicates that diagenetic dolomitization of the Oligocene Sombrerito Fm. limestone, southwestern Dominican Republic, is detrimental to the usefulness and quality of the potential construction aggregate resource. The first part of this program was the collection, photographing, and geologic logging of diamond drill cores to allow lithologic subdivision of the strata into potential quarry layers. The primary lithostratigraphic units are: I (youngest) approximately 10 m of white, dense marine limestone; II, approximately 5 m of white, interbedded dense and chalky marine limestone; III, 2+ m of tan, chalky calcitic dolomite. Unit I has been often altered by lateritic weathering and/or dolomitization; Unit II is often altered by dolomitization. The quarry layers were individually crushed, by core, into coarse aggregate sizes for chemical and physical (specific gravity absorption, MgSO4 soundness, sand equivalent, and LA degradation) analyses. The non-weathered units decrease in coarse-aggregate yield and quality with depth and dolomitization. Dolomitization typically causes about 5% lower yield of coarse aggregate, a sand equivalent of about 20 units below the original value, an increase in absorption of about 3%, an increase in the LA of up to 13%, and a decrease in the average 5-cycle MgSO4 soundness by about 17%.

Jan 1, 1987