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By A. Mcdonald

"An X-Met Analyzer was purchased from Outokumpu in late 1983for use in the Hudson Bay Mining and Smelting smelter. Its first use was in the fuming plant to give zinc assays of each charge of slag tapped from the fuming furnaces. This quickly told the operators exactly when each charge had reached its economic tap-out point, and gave supervision a fool-proof method of identifying good operation. These and other factors led to major improvements in coal utilization in the fumers and to major increases in zinc oxide production. A second unit was later purchased for the reverberatory furnace to give silica and iron assays of the slag, and these were used to make adjustments in the feed composition to maintain the desired SiO2:Fe ratio in the slag. Since purchasing the units for the furnace, the oil consumption and copper content of the slag have dropped significantly. IntroductionSmelters have lagged far behind concentrators in process control by mean s of rapid product analysis. The on-stream X-ray analyzer was developed about seventeen years ago, and soon concentrators around the world were getting assays of the incoming ore, .concentrates and tailings every fifteen minutes, and using these to control reagent additions and other process variables. Almost always, the concentrate grade and recovery improved.In smelters, product streams are solids or molten materials, not the more easily handled slurries, and until seven years ago no inexpensive equipment was available to provide rapid analysis of this type of material. In approximately 1980, several companies developed instruments based on irradiating solid samples with low-intensity gamma rays from radio-isotope sources, and measuring the secondary X-rays emitted from different elements in the sample to provide an analysis of the elements desired.The smelter staff had a close look at what was needed and listed the following points as being critical:1. ability to provide Zn assays of a sample of slag within 15 minutes of taking it, in order to achieve optimum fuming times (zinc fuming , being a batch process, had the greatest potential benefit from rapid slag analysis);2. ability to give Cu and Fe assays on the slag, and on other smelter products, such as matte and converter slag;3. ability to give Si02 assays since the SiO2 content of the slag has a strong effect on fuming rate; and4. ability to stand up to an industrial atmosphere such as exists in the fuming plant."

Jan 1, 1987

By Joseph M. Keane

A number of innovative techniques exist for solving heap leaching problems in special situations. Some of these techniques have been successfully applied and others await an opportunity for application. Discussions in this paper will deal with gold heap leaching under severe thermal conditions, in tropical rainfall circumstances, in the absence of fresh water, and in other situations removed from the ordinary. CLIMATIC CONSIDERATIONS The success or failure of precious metal dissolution operations may be strongly dependent upon proper attention to the influence of climate. A few examples are given in the following paragraphs.

Jan 1, 1987

By Lawson F

Pyrite concentrate and calcine from the Nanjing Lead-Zinc-Silver Mines, China, were leached with aqueous cyanide and thiourea solutions. More than half of the contained gold and silver was able to be extracted from the roaster calcines. The very fine dissemination of precious metal grains, high roasting temperature (850 - 900°C) and residual sulphur are believed responsible for the Iow extractions.A recovery of about 70 per cent for both silver and gold was able to be obtained with cyanide and with thiourea leachants when the pyrite was roasted in the laboratory at temperatures between 600 and 650°C.Thiourea, as an alternative leachant, has received much attention recently and a series of constant potential leaching tests was conducted.When the thiourea to formamidine disulphide mole ratio was about two, the precious metal extraction was greatest. In the Nanjing calcined material, this occurred at a potential of about 210 mV relative to a standard calomel electrode.

Jan 1, 1987

By C. W. Smith

The Bureau of Mines conducted laboratory-scale beneficiation tests on a sample of corundum gneiss from Montana to devise a method for beneficiating corundum for use as a substitute for refractory-grade bauxite. A flotation process utilizing petroleum sulfonate as the collector in an acid circuit was devised. Results showed that two flotation schemes each produced a concentrate exceeding the national stockpile specifications for calcined bauxite. From a feed containing 28 pct corundum concentrates containing up to 92.5 pct alumina (A1203) were produced with a corundum recovery of 78.5 pct.

Jan 1, 1987

The latent conditions clause in various general conditions of contract have traditionally proved to be a source of significant disputes in tunnelling contracts, even when extensive geotechnical investigations have been carried out at the tunnel site and a report of these investigations provided with the tender documents, informing the contractor of the nature and extent of subsurface conditions likely to be met with during execution of the works. This paper discusses the contractual aspects of the new latent conditions clause in the recent Australian Standard AS 2124-1986, General Conditions of Contract, in relation to tunnelling contracts. A comparison of this new clause is made with other latent conditions clauses in general conditions of contract in use in Australia and other commonwealth countries. It is seen that the new latent conditions clause in the recent Australian Standard 2124-1986 has, by providing for a reasonable apportionment of risks, attempted to minimize contractual disputes relating to latent conditions in tunnelling contracts and to provide a satisfactory basis for quick and efficient settlement of such disputes should they arise during execution of these contracts.

Jan 1, 1987

By J. C. Kerkering

The Bureau of Mines used mathematical reliability theory to define, for use in the mining industry, the concepts of risk, safety, reliability, hazard, and mean time between accidents. In this report, the definitions are explained theoretically and illustrated by application to actual underground mine accident data extending over a 9-1/2-year period. The theoretical development proceeds along two parallel analytical paths. For each line of reasoning, the data are presumed to be independent. If they are not, the analysis stops, although there are interesting implications when dependency is demonstrated. The first method uses the elapsed times between accidents as the basic data. These elapsed times are fitted to a negative exponential distribution function using least squares and yielding the function parameter, P1 The P1 is used to form the Poisson distribution function for the data, which is then used to define the safety-related concepts. The second method uses the maximum likelihood estimator to formulate a Poisson distribution function for the data. The function is tested for adequacy by a goodness-of-fit test; if the fit is acceptable, the Poison function is used to define the concepts. Both methods were applied to the data base, yielding nearly identical results.

Jan 1, 1987

By J. A. Farinelli

In the Appalachian region of the United States, approximately 40% of the underground coal reserve base exists in seams 0.7 - 1.1m thick. These seams are, in general, often of premium quality and are frequently accessible through above-drainage drift-type openings. Unfortunately, there are no apparent advantages to mining thin seams, if quality is disregarded. The thin-seam mine is faced with the same legal and economic pressures as any other underground coal mine. But in addition to these common problems, thin-seam operations must also deal with the unique problems associated with mining at such a restrictive height. Small-scale, short-lived operations appear to be the most feasible means of mining these reserves. The purpose of this paper is to evaluate the production and safety potential of various thin-seam mining systems. Recommendations will be made regarding present and future thin-seam operations.

Jan 1, 1987

By R. David Prengaman

During the past several years a new insoluble lead anode has been developed for copper electrowinning. The new anode consists of a rolled lead-calcium-tin alloy sheet attached to a slotted copper bus bar by a soldering process which produces a complete metallurgical bond between bar and sheet. The metallurgical bond greatly reduces the resistance between the bus bar and the lead sheet and the high conductivity does not deteriorate during the life of the anode. The rolled anode thins uniformly and does not suffer preferential grain boundary or internal corrosion commonly seen in cast anodes. The lead-calcium alloy containing a high tin content corrodes slowly because the rolling process produces a uniform, fine grained structure. The wrought product is very strong and ductile; and contains no internal defects, segregation, cracks, or pores which can reduce the life of the anode. Because the anodes corrode uniformly, a high percentage of the anode thickness can be utilized thus extending the life of the wrought anodes. The anode alloy composition which is stable only in wrought form, produces exceptional resistance to passivation during current interruptions. First introduced into liberator cells, the new electrowinning anodes have been specified as the anodes of choice for every new SX-EW tankhouse constructed in the last two years. This paper describes the new anode, its method of construction, service history, and how it differs from present copper electrowinning anodes.

Jan 1, 1987

By J. Lovering, H. Wilhelm, P. Siewert

Introduction The Afton property is located 290 km (180 miles) by air east-northeast from Vancouver and 14 km (8.7 miles) west of Kamloops, a city of 60,000 people, in south central British Columbia, Canada. The mine is adjacent to the Trans-Canada Highway at an elevation of 670 m (2198 ft) above sea level. The ore body is a porphyry copper deposit that has undergone supergene alteration. The major economic minerals in the supergene zone are native copper and chalcocite with chalcopyrite and bornite in the hypergene areas. The grade is 1% with an overall copper distribution - 70% native, 25% chalcocite, and 5% chalcopyrite with bornite and covellite. The ore also contains important but variable amounts of gold and silver. The mill was designed to treat 6350 t/d (7000 stpd). Semiautogenous grinding was selected to minimize capital cost and because of the expected high clay content of the ore, which would have caused problems in a conventional crushing and screening plant. Test work indicated that a recovery of 87% was possible in a circuit incorporating both flotation and gravity separation. Flowsheet Run-of-mine ore is crushed in a 1.06 x 1.65-m (3.5 x 5.4-ft) Allis Chalmers gyratory crusher set at 228.6 mm (9 in.), closed side setting. The surge pocket, below the crusher, is emptied by a Hydrastroke feeder onto number one conveyor, which discharges onto a 180,000-t (198,416-st) coarse ore stockpile. Six Hydrastroke feeders on two conveyors withdraw the crushed material from the bottom of the pile. These two conveyors, in turn, discharge onto the belt feeding the semiautogenous mill. The live storage in the stockpile is approximately 22,000 t (24,250 st), sufficient for three days' mill feed. Primary grinding is accomplished in an 8.5-m (28-ft) diam by 3.7-m (12-ft) long Koppers (Hardinge Cascade) mill (Fig. 1) containing a 10% ball charge and driven by a 4000-kW dc variable speed motor. The mill dis¬charge is pumped by a 10 x 12 G.I.W. pump to a 1.22 x 4.88-m (4 x 16-ft) stationary screen sloped at 20°. Screen oversize returns to the semiautogenous mill (SAM), and the undersize flows by gravity to the ball mill discharge pump box. Secondary grinding is performed in a 5-m (16.4-ft) diam by 8.84-m (29-ft) Koppers overflow ball mill driven by a 3430-kW synchronous motor through an air clutch. The mill is in closed circuit with a Krebs Cyclopac containing 10 635-mm (25-in.) cyclones and the cyclone overflow, at 35% solids and 65% to 70% -200 mesh, is flotation feed. In order to limit the buildup of native copper, circulating in the secondary grinding circuit, a portion of the underflow from the cyclones is processed in a circuit containing screens, cyclones, and shaking tables to produce a finished metallic copper concentrate. Primary mill variable speed drive The overall waste to ore ratio at Afton was 4.5:1. The mining was to be done with only three shovels, which meant that it was highly unlikely that more than one of them would be in ore at any one time. The resulting inability to blend the mill feed made it impossible to prevent wide swings in the grade and grindability. The variable speed do drive motor installed on the semiautogenous mill was selected because of the extreme variability of the Afton ore body. This variability has persisted throughout the lifetime of the mine. There are times, however, when due to ore conditions, the mill is operated at full speed (78% of critical) for extended periods of several shifts duration. There are other times when the mill speed may be changed several times in a 12-hour shift due to changing ore conditions. When ore is processed that contains a fairly large proportion of fine native copper, the primary mill speed and, consequently, the tonnage may be reduced to improve the secondary grind and to maintain an acceptable grind and recovery. High clay ores require less mill speed and more dilute grinding densities. In the latter case, the slower primary mill speed also helps to minimize damage to the mill liners. Approximately 57% of the time the mill operates between 90% and 100% of full speed or between 71% and 78% of critical. The variable speed is also used for inching during mill relines.

Jan 1, 1987

By Mark A. Koestel

Cobalt-sulfide mineralization can he found in potentially economic quantities where permeable, basal Cambrian formations "pinchout" against Precambrian pal eotopographi c highs. These environments are common around the Saint Francois Mountains of southeastern Missouri and they share many similarities with the geologic environments of Zambia and Zaire in South Africa. Exploration for this type of deposit involves test drilling targets identified by trend analysis from past drilling, geophysics, geochemistry and a comprehensisve study of regional geology and isopach maps. Innovative ideas, new exploration concepts and insoluble residue geochemical methods may provide the necessary "edge" needed to complement basic geologic understanding leading to ore discovery.

Jan 1, 1987

By Mikko Ahola

This paper describes recent innovative analyses conducted by the Bureau of Mines to demonstrate the application of the boundary-element method in evaluating the effectiveness of caving chambers or sacrificial entries to relieve the stress conditions initiating cutter roof failure in underground coal mines. The analysis assumes that cutter roof failure results when the shear strength of the roof rock at an entry corner is exceeded by the applied shear stress. The applied shear stress is due to large differences between the horizontal and vertical in situ stresses known to exist in many coal mining districts experiencing cutter roof failure. The results of boundary-element analysis suggest that driving an arched lead entry in advance of adjacent rectangular entries and allowing it to cave significantly reduces the difference between the principal stresses at the corner of the rectangular entry, thereby lowering the maximum shear stress. Slippage of the immediate roof along horizontal bedding planes into the caved entry is shown to further reduce the stress conditions in adjacent entries. Practical applications of this stress control technique to longwall and room-and-pillar mining are discussed.

Jan 1, 1987

By Gerhard Melcher, Hermann Hilbrans, Michael Gamroth

"IntroductionSeveral new smelting processes have been proposed and developed during the last 20 years. This has been true, in particular, for copper smelting technology. The important impulses for the advances in this field have been the recent demands regarding the environmental protection, energy saving and improved utilization of the metals contents of deposits, in particular that of complex raw materials.The methods developed more recently for pursuing these objectives have been outlined in several papers. In some of them the advantages and drawbacks of certain developments have been stressed. These documents are of great importance for assessing the different processes. The following paper tries to explain some details of the cyclone smelting process taking into consideration a few of these well-known presentations. The effectiveness of operation of the cyclone smelting process indicates that this process presents a significant achievement when compared with other conventional methods.The application of the CONTOP smelting cyclone range s beyond the field of copper metallurgy or the smelting of sulphide concentrates with the aid of oxygen. The research work carried out in the pilot plant of KHD Humboldt Wedag AG in Cologne-Porz also includes the recovery of the metal contents of intermediate products and processing of smelter residues which have to be converted in a disposable stat e, free of environmental pollution. This paper explains a few examples in this regard."

Jan 1, 1987

By E. A. Davies, Trevor T. Jones

"Aspects of materials, design and operation of suspension equipment is dealt with, hazard, fatigue and special metallurgical properties of certain steels to resist are described, as is the effect of temperature in service modifying the properties of some steels to resist stress concentration and propagation of cracks.The influence of steady impact and fatigue loading and its results are described. Control of manufacture including nondestructive testing is outlined and acceptance parameters and strength calculations are given. Quality requirements and control in manufacture are outlined. A short description of the overwind detaching hook, together with illustrations of the operation of detachment are presented.MaterialsWinding engine ratings of 8000 h .p. and large capacity shafts 2000 m in depth (4000 m depths have already been reached and it may be necessary to go to 6000 m) and up to ten conveyances are not uncommon today. Loads of 100 or even 200 tons hoisted at low speeds are possible within the near future. Some of these appliances are designed to protect lives and installations in hazardous conditions when, due to human or mechanical fault, a malfunction occurs in the system. In addition, such equipment includes suspension gear of various kinds designed to anchor and apply high mechanical tensions to numerous steel ropes installed in shafts necessary either for the safe passage of conveyances or for balancing purposes when heavy loads are in motion.No unique metallurgical problems are presented in underground mining operations, but they have two special characteristics that influence the metallurgical aspects of the de sign of suspension gear and other equipment concerned in the transport of men and materials. (1) Any uncontrolled release of energy caused by the unexpected failure of a component is more likely to injure personnel and cause costly damage to installations in the narrow confines of an underground mine shaft. (2) Some mechanical equipment in mines, tends to be overloaded in service and suffer plastic distortion."

Jan 1, 1987

By G. Ladouceur

"Northgate Patino Mines produces a copper concentrate assaying 22% Cu. Moisture content of the product averages 12.5% H20 when dewatering with conventional vacuum disk filters. Recent smelter contracts reflect higher energy costs and increased moisutre penalty charges. This situation forced Northgate to investigate possible alternatives such as rotary dryers and pressure filtration. After laboratory testing, it was found that pressure filtration could economically meet the smelter's requirements. Pilot plant testing was then undertaken and confirmed the laboratory test results. Based on these findings, a model I.S.F. 1500 x 28/22 I.R. Lasta filter press was purchased.This paper describes the Copper Rand dewatering flowsheet the operation of the press and the economics of the process.IntroductionNorthgate Patino Inc. operates 2 und erground copper mines and a 3300 ton per day concentrator located in Chibougamau, Quebec, some 425 miles north of Montreal and 300 miles northeast of Noranda, Quebec.Copper concentrate is produced at a rate of 250 tons per day and trucked to a C.N. siding 10 miles from the mill site and then railed to the Noranda Smelter.Until early 1981, moisture content of the concentrate at 12.5070 was acceptable since smelter penalty charges were relatively low ($0.10 per ton per unit over 10070 moisutre). In January 1981, a new contract was signed in which the penalty was raised to $1.10 per ton per unit over 8070 . This and the increasing truck and rail costs justified the change-over from vacuum to pressure filtration . The Lasta I.S .F. 1500 x 28/22 was then purchased and installed, and operation of the plant started in December 1981."

Jan 1, 1987

By A. E. Torma

The efficiency of Thiobacillus ferrooxidans in the desulfurization of a high-sulfur content New Mexico coal was demonstrated. The optimum condition of process variables were found to be pH = 2.3, particle size = 38 µm, pulp density 14.1% (W/V) and temperature 33.9°C. Larger scale experiments carried out with these optimum conditions resulted in coal desulfurizations above 97%, while in sterile controls this was only about 10%.- The rate of desulfurization was described with an exponential expression with respect to the effects of coal particle size. The effect of pulp density on coal desulfurization was quantified by a Monod type equation. The apparent activation and deactivation energies, the frequency factor and temperature coefficient were derived from the effects of temperature to be ?aE - 11720 cal mol-1 and A = 30.44 mol dm-3s-lin the range of 20 - 35°C; ?Ed = 43930 cal mol-1 and A = 9.82 x 10-39 mol dm-3s-1 in the range of 35 - 45°C; and Q10 = 1.94 in the range of 20 - 30°C. The thermodynamic values [(?G+, ?H+ and ?S+)] of the activated complex were calculated. The generalized second order regression equation relating the degree of biodesulfurization of coal to the leach parameters was shown to adequately predict coal desulfurization within the range of process variables studied.

Jan 1, 1987

By Linge H. G

The effect of the presence of ore pulp on the adsorption rate of gold on activated carbon has been studied. A substantial reduction in the rate occurs when the pulp is present. The reduction in rate appears to be caused by two effects: permanent carbon pore blocking by ore particles and temporary shielding of the carbon particle surface, slowing gold access to the carbon due to the physical presence of the fine pulp. There is no significant effect arising from the presence of a pulp viscosity modifier even for conditions when mass transport dictates the loading rate of carbon in clear Solution.

Jan 1, 1987

By Richard F. Lynch, Frank E. Goodwin

"The development of Galfan, a new generation 95% zinc-5% aluminum-mischmetal alloy coating for steel, offers opportunities for greater fabrication flexibility and upgraded corrosion performance in automotive applications. The formability of Galfan is equivalent to that of electrogalvanized steel, based on laboratory tests and automotive component fabrication. Corrosion resistance of Galfan exceeds that of hot dip and electrogalvanized, including performance in automotive industry tests. Automotive production applications for deep drawn and stamped components in France and Germany are based on the ability to meet dual performance requirements for upgraded formability and corrosion resistance. The first U.S. Galfan application was on 1985 model Ford cars and light trucks for transmission oil cooler lines which has now expanded into a number of power steering tubing uses. IntroductionContinuing requirements for improved vehicle performance coupled with the ever present need for reduced cost have spawned the development of a number of new coated steel products. Among this new generation of coated steels is Gaifan™, a 95070 zinc-Solo aluminum-mischmetal hot dip alloy coating. Galfan exhibits particular promise for automotive use based on broad fabrication advantages and upgraded product performance(I ),The unique characteristic of Galfan is the key combination of greatly improved formability with much longer corrosion life. Galfan provides significantly better formability than any other hot dip coating. Testing shows that formability is limited primarily by the steel substrate to which the Galfan coating is applied. Galfan exhibits excellent resistance to flaking and microcracking during commercial forming operations. The result is the elimination of unnoticed damage to the coating which would show up later as premature rusting on the finished product."

Jan 1, 1987

By M. Girgis

The behavior of arsenic III during electrolytic refining of copper in acidic copper ?sulphate electrolytes was studied by different electrochemical methods such as, linear potential sweep, cyclic voltammetry, chronoamperometry and chronopotentiometry. The study showed that arsenic behaves as a depolarizing ion and has a deleterious effect on copper deposit. Three substrates; Pb, Cu and Ag were used during the refining process and the electrode kinetics were found similar for both Cu and Pb electrodes while a little difference was found for the Ag electrode. A microscopic study by scanning electron microscope was undertaken to show the influence of arsenic on deposit's morphology. Surface analyses of the deposit were carried out by some electronspectroscopic techniques such as Auger electron spectroscopy (AES) and X-ray photoelectron spectroscopy (XPS). The results showed that arsenic coexists with copper deposit at potential?~ -0.25 V.

Jan 1, 1987

By Harry W. Campbell

In 1984 and 1985, at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied part of the Meadow Valley Range Wilderness Study Area (NV-050-156) in order to evaluate its identified mineral resources. The study area is located in Clark and Lincoln Counties, NV, about 50 miles northeast of Las Vegas, NV. The Johnston and Fitchett prospect, in the northern part of the study area, has more than 3 million tons of marginal perlite reserves suitable for many commercial uses. A preliminary mining feasibility estimate suggests perlite could be profitably mined from the study area; however, it is unlikely these perlite deposits will be developed in the foreseeable future because of unfavorable market conditions. Zeolite minerals occur in alteration zones adjacent to perlite deposits at the Johnston and Fitchett prospect, but high quality material is closer to potential markets. A metalliferous black shale unit containing 800,000 tons of subeconomic resources may extend into the study area at the Bradshaw vanadium prospect on the northwest boundary. Limestone, stone, sand, and gravel occurrences are wide-spread, but other suitable deposits in the region are more accessible to potential markets. Seven prospects in and near the study area were examined. The entire study area is leased for oil and gas exploration. A group of perlite placer claims covering more than 480 acres was located in the 1940's in the northern part of the study area. A small group of lode claims was located in the mid 1950's in the southwest part of the study area. No mining claims are currently (1985) held inside the study area. No mineral production is known from within the study area.

Jan 1, 1987

Virtually all mineable Appalachian coal seams exist in a multi-seam environment. This makes it inevitable that most seams will eventually experience interaction induced ground control and mining problems. Indeed, it has been estimated that every working face will experience interaction effects from previous or current workings at least once during its lifetime (1), and that these problems are considerably exaggerated when seams are in close proximity -- a distance of less than 110 feet. The continued increase in multi-seam problems has resulted in considerable research activities over many years (2,3,4,1). Theoretical analysis, numerical and physical model studies, statistical and empirical analysis of numerous interaction related field data have been applied to multi-seam mining situations and have identified many useful trends and design criteria (4,5,6,7). To fully utilize research results and transfer multi-seam mining technology to field engineers, a design model -- USEAM was constructed (8). This model, designed for close seam under-mining situations, was computerized to facilitate utilization. In the current research, a new computer program "MSEAM" was developed to produce a model for both under- and overmining close seam situations. It is hoped that both of these software packages will aid field engineers in using important interactive design criteria to gain a better understanding of interaction mechanisms. Through advance planning with these programs, detrimental interaction may be avoided and minimized, and occasionally a design can be selected which will allow interaction effects to be utilized to the benefit of mining operations.

Jan 1, 1987