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By T. M. Barczak

One of the primary goals of Bureau of Mines research is to reduce the cost of coal mining by improving the efficiency of longwall supports. One method of achieving this goal is the optimization of stress distribution within the support structure, resulting in a lower overall weight, more fully stressed shield. However, before stress optimization can be initiated, load conditions must be defined that cause maximum stress in the various support components. A finite-element model of a longwall shield was used to identify these critical load conditions. These load conditions were then evaluated in the Bureau's mine roof simulator (MRS) by instrumentation of a longwall shield and measurement of strains in each of the shield components. The critical (canopy-base contact) load conditions were identified that can cause structural failure at less than rated shield (hydraulic yield) capacity. Comparisons were made between full-contact and partial-contact load conditions. Other parameters investigated included the stiffness of the contact material, changes in shield geometry, rate of load application, and effects of horizontal constraint. Conclusions were drawn regarding the structural integrity of the major shield components and potential for stress optimization.

Jan 1, 1987

In the late 1970's Western Mining Corporation, Exploration Division considered the purchase of a major multi-element spectrometer as an adjunct to our existing atomic absorption spectrophotometers. The analytical work proposed for the unit included barium, uranium and rare earth elements from Olympic Dam, uranium, sulphur, vanadium and strontium on Yeelirrie type deposits, major element and whole rock analysis, multi-element analysis of samples from the laterite, chromium and manganese exploration programmes and tin and arsenic analysis. These were all analyses that were not readily or easily performed by flame atomic absorption or were where we expected that a simultaneous multi-element instrument would be an advantage. Also the turnaround times for the commercial laboratories was considered unacceptably long for some determinations. Other factors, important when considering the spectrometer were the ability to ensure confidentiality of results and the ability to assign our own priorities and not to have to rely on commercial laboratories. The two techniques considered were X-ray Fluorescence Spectrometry and Inductively Coupled Plasma Optical Emission Spectrometry. The decision was made in favour of the ICP unit for several reasons. The ICP fitted in with our existing methodology, ie samples digested for atomic absorption or colorimetric techniques would also be suitable for ICP analysis and vice versa. The technique was suitable for water samples and for major element analyses and for rare earth elements. X-ray fluorescence spectrometers were installed at the Kambalda and Belmont laboratories and would be available to us for routine checking and for elements not suitable for ICP analysis. The final consideration was price. ICP was considerably cheaper than XRF.

Jan 1, 1987

By A. Bilodeau

A new hydrometallurgical process for the production of refined gold and the recovery of palladium and platinum from silver anode slimes has recently been developed and installed at the, CCR Division of Noranda Inc. The process, which facilitates the production of gold of >99.99% purity in the face of increasing palladium receipts comprises; leaching silver anode slimes with hydrochloric acid and hydrogen peroxide at 95°C to solubilize gold, palladium, platinum and base metals while simultaneously rejecting silver as insoluble silver chloride; precipitating gold from the leach solu¬tion with sulphur dioxide gas in two stages to produce a first-stage high purity gold product and a second stage impure gold which is recycled to the leach; washing, melting and casting of the pure gold; precipitation of a palladium-platinum concentrate from the gold-free solution by reduction with sodium formate at pH 4 and 95°C; and neutralization of the palladium precipitation effluent to pH 10 with lime. The results of laboratory and pilot plant studies leading to the adop¬tion of this process are discussed, and data are presented for each of the unit operations. Details of the engineering of the commercial plant are given, and plant start-up experience is described.

Jan 1, 1987

By James P. Ulery, Frank E. Chase

Clay veins found in coal mines have caused numerous injuries and fatalities. These structures plague all phases of mining, including entry development, pillar recovery, and panel extraction. Clay veins also increase production costs and may disrupt or halt mining. These detrimental aspects have prompted the Bureau of Mines to investigate the physical characteristics of and roof instability problems associated with clay veins. This was accomplished by observing and mapping clay veins in surface and underground mines. The occurrence and origins of clay veins were also investigated to determine predictive capabilities. The investigators found that clay veins normally occur in more stable, less rapidly subsiding coal basins. Clay veins result when tensile stresses develop fissures which are later infilled. These fissures can be propagated by compactional processes and/or tectonic stresses active during and subsequent to coalification. The Bureau also found that associated faults, fractures, and slicken-side planes commonly parallel clay veins and disrupt the lateral continuity of the immediate and, sometimes, main roof. When clay veins parallel or subparallel the direction of face advance, the roof is segmented into cantilever beams, causing unstable conditions. Consequently, the strata on either side of the clay veins should be bolted and strapped together to form a beam.

Jan 1, 1987

By J. Eric Nylund

"Intensive mechanization and automation in the LKAB, Kiruna Mine in Sweden have resulted in substantial rise in productivity and decrease in production cost. Capital investment in a modern mine today averages a considerable amount per miner and costs increase with requirements for more efficient methods and equipment. Equipment reliability becomes more and more important. Equipment maintenance requirements are directly proportional to equipment reliability and grade of availability. Weaknesses in the equipment result in unnecessary costs with regard to maintenance which can add up considerably per year, but of more importance are the costs caused by equipment breakdown. These breakdowns disturb or interrupt the production and often cause damage to other parts of the system. This paper discusses the important parameters involved in mine car wheel wear and the design principles of wheels, axle suspension and track.IntroductionTrains operating in an underground mine do not follow the same standard of performance as trains operating on surface railways. The differences in speed, curve radius and environment require different methods of calculation for underground train systems, and when judging the parameters involved one must keep in mind these differences at all times.While surface railway technology was given all possible attention over the last century no one was seriously looking into underground rail haulage in the sense of rail vehicles performance on the track until LKAB in 1975 started to question the methods of calculations used. Even though LKAB by then attained mine car maintenance cost that was 1/6 to 1/10 of other mining companies they were not pleased with the situation. The objective for the ensuing engineering work was to derive the reasons for wear and breakdowns. Once those reasons were established, the design of a completely new generation of mine cars could start. The result of these efforts were beyond all expectations. The maintenance cost on mine cars had been reduced to 1/15 of prior car generation which already had comparatively low cost.The most significant cost savings were made on wheel maintenance, which earlier represented 50% to 55% of car maintenance. Wheel life was increased from an average of 3 to 30 years or more.The LKAB theories around wheel wear are described in the following report."

Jan 1, 1987

By R. J. Mitchell

Results from investigations into impurity distributions over cathodes are presented with implications for various sampling methods, Selection of an optimum treatment procedure for the test sample is outlined. The impact of both these studies on the development of an in-house method for sampling Isa Process cathode is discussed. The economic compromise actually undertaken, satifying wants and needs to sustain confidence in high grade cathode purity is detailed.

Jan 1, 1987

By J. E. Fraley

Full-column anchored resin bolts were first used in underground mines in 1972. These bolts appear to improve support in many roof bolt applications, as indicated by the use of about 30 million resin bolts in 1980. In the mid-1970's, Bureau of Mines in-vestigators began looking for a substitute for resin because of its short supply and rapidly increasing price. The investigators selected accelerated gypsum plaster (CaSO. ·1/2H20), which becomes gypsum (CaSO.· 2H20) when mixed with water. Gypsum makes an effective alternate grout material because it hardens quickly, is readily available, and is inexpensive in comparison with other cementitious materials. The Bureau received a patent (U.s. patent 4,096,944) for a system combining water capsules (wax-encapsulated water) with plaster into cartridges resembling resin cartridges. This report presents the results of tests conducted by the Bureau on the plaster, the water capsules, and their combined use in cartridges. The tests were designed to determine how the gypsum-plaster water capsule bolting system performs and what happens in the hole while the bolt is being inserted through the cartridge. The test results indicate that water capsule plaster cartridges are a workable alternative to resin cartridges under normal or dry conditions.

Jan 1, 1987

By E. M. - Technical Papers Spokes

A.B. Rushton The work and resulting publications of the Committee on Underground Coal Mine Safety and The President's Commission on Coal were appropriate at the time of publication. The statistics cited in the publications appeared to be valid, and the actions proposed by the committee had merit. Although the actions proposed to achieve further improvements in safety may have been worthy of repeating, to associate statistics (Table 1) that are seven to eight years old with company names is bad. Statistics are readily available from the Mine Safety and Health Administration (MSHA) and are usually within three months of being up to date. A review of the most recent Coal Controlling Co. Report will reveal significant changes in the rankings. The more recent statistics should have been cited, or at least compared with those used in the article. Westmoreland Coal Co. is listed as having a 21.1 disabling injury rate for the period (1/78-12/80). The disabling injury rate for the Company for the year ending 1985 was 7.4 for the underground mines and 6.25 for the total facilities. Through March 1986, the dis- abling rate for the underground mines was 2.86. The management and employees of Westmoreland Coal Co. are committed to safety. The improvements achieved over the past five years attest to that commitment. We are justifiably proud of the achievement and dislike being misrepresented as in the April 1986 article Reply by E.M. Spokes I regret that the lapse of time since the original work gives a picture of safety practice that is no longer true today. That Westmoreland has reduced its disabling injury rate by 65% to 7.4 in 1985 is most commendable, and I congratulate you for this accomplishment. It is typical of the progress sought by the National Academy of Science and National Research Council when they funded the original study and published "Toward Safer Underground Coal Mines" in 1982. If a significant number of companies do as well as Westmoreland, the report will have served its purpose. Since the paper was primarily a condensation of the original report, it would not have been appropriate to seek access to later statistics. The purpose in seeking its publication at the time of presentation was to reach those who might have missed the original report. The fact that publication was delayed has not voided that purpose and may have reminded some who were aware of the original that its recommendations still apply to improvement of underground coal mine safety

Jan 1, 1987

By Matti Leiponen

During the last few years Outokumpu Oy has put forth efforts to develop the material handling in the Pori tankhouse. The final objective is full automation including cell loading. The fully automated material handling provides high quality anodes and cathodes as well as equipment and handling systems capable of very accurate cell loading. The new machines and equipment for accurate cell loading and the methods to produce high quality anodes and starting sheets are described in this paper.

Jan 1, 1987

By Wladyslaw John Cieslewicz

Geologically, this region is occupied by Mesozoids, a folded belt of Triassic and Jurassic sediments and volcanics. Gold mineralization is of Upper Jurassic age. Most of the stream placers formed during the Quaternary. Placer gold was first discovered in 1916. Between 1930 and 1957, mining was carried out by the "Dal'stroi," a Russian death- camp organization. At the mines, "Dal 'stroi" exterminated 5-7 million captives taken from Russia's different colonies, each prisoner extracting 1-2 kg of gold before he died. Since 1966 the mines have been worked mechanically. About 10 mining districts are now active, producing altogether 110-135 tons of gold annually.

Jan 1, 1987

Underground mining alters ground condition, producing a disturbance in the ground water regime. The level of disturbance is dependent on the local hydrology, geology, and type of mining. Serious damage is sometimes caused by ground water- when mine roofs collapse, causing subsidence. Subsidence is either unplanned, where pillars are inadequate to provide support; or planned, where total extraction occurs over a large area. The primary objective of this study is to investigate the effects of mine subsidence on the ground water hydrology in the Warrior Coal Basin. Underground openings resulting from coal mining activities have been the most significant cause of subsidence problems in the Warrior Coal Basin, the main source of coal in Alabama. This problem will be even more serious in the future because 19 of Alabama's 24 billion tons of coal reserves are classified as an underground source (Tolson, 1982).

Jan 1, 1987

By G. W. Reimers

Conditions in the underground mine environment can cause self-heating of sulfide ores as a result of exothermic oxidation reactions, which may result in mine fires. This Bureau of Mines report describes thermal analyses of finely ground chalcopyrite, chalcocite, galena, pyrrhotite, marcasite, and arsenopyrite, to characterize their responses under oxidizing conditions. Thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) were used, in the temperature range 1000 to 5000 C. Chalcopyrite showed an initial weight gain, due to formation of sul-fates, a weight loss, caused by ignition of iron sulfide to iron oxide, and a final weight gain, indicating the conversion of copper sulfide to sulfate. Chalcocite did not ignite in the temperature range studied but exhibited a rapid weight gain, because of the rapid conversion of copper sulfide to sulfate. Likewise, galena failed to ignite but underwent a steady weight gain when oxidized in a moist atmosphere, showing conver-sion of lead sulfide to sulfate below the ignition point. Marcasite underwent a rapid weight loss, indicating ignition, at 2000 C. Moisture in the oxidizing atmosphere lowered the ignition point of marcasite and arsenopyrite but not that of pyrrhotite. All the sulfides exhibited exothermic behavior at temperatures below the ignition point.

Jan 1, 1987

Thermodynamics and kinetics? of the removal of Va elements (As,Sb,Bi) from copper were investigated 1n the fire relining by alkaline carbonate fluxes such as Li 2co3 , Na 2CO3 and K2CO3. The distribution coefficients of As, Sb and Bl between alkaline carbonate fluxes and mo) ten copper were ?obtained at 1200°C under the different oxygen potentials. As and Sb were easily removed from copper to fluxes as pentavalent oxide form. On the other hand, Bi was hardly removed except by a Ll2CO3 flux. The removal rates of Va elements from copper were also measured In the temperature range of 1150°C.- 1250°C. The removal rates of As and Sb were much higher than that of Bi. The removal rates of Va elements showed the same order of the distribution coefficients. The removal rate could be expressed by following equation. (1).

Jan 1, 1987

By Paul D. Dupree

Introduction Trapper mine is a dip-line strip coal mine, located about 10 km (6 miles) southwest of Craig, CO. The mine provides the Craig Generating Station, operated by Colorado-Ute, with about 2 Mt (2.3 million st) of coal annually. The Trapper mine is situated on a hillside that climbs in elevation from 2 to 2.5 km (6500 to 7400 ft) at average grade of 15%. The coal seams dip at about 16% down-grade and they outcrop near the top of the hillside. They exceed maximum stripping depth in 1 to 1.7 km (3500 to 5500 ft) of pit length. Stripping in the three existing pits is performed with three Page 752 23 m3 (30 cu yd) walking draglines. Two of the pits are currently being cast blasted. Until the active cut, the Derringer pit was cast blasted only where the lower mined seam exceeded stripping capabilities and the pit was a single seam operation. Now, a 9-m (30-ft) interburden bench has been incorporated into the stripping plan. This bench protects the first seam of coal from shear when the overburden is cast blasted. The cast blasted section of the 1.6 km (53,000 ft) long pit has been increased from the 457 m (1500 ft) casted previ¬ously to 1 km (3500 ft). High speed films show the coal losses due to shear of the blast are minimal. The pit width in Derringer pit is 61 m (200 ft). This is necessary for efficient spoil side stripping of a relatively thin interburden in the two-seam section of the pit. The Enfield pit is entirely cast blasted. The single seam pit is 46 m (150 ft) wide, 1.1 km (3600 ft) long, and varies from 15 and 46 m (50 and 150 ft) in overburden depth. The overburden strata at the mine consists of medium-hard layers of sandstone, shale, and

Jan 1, 1987

By J. K. Whyatt

The Bureau of Mines, under a cooperative agreement with Callahan Mining Corp., measured rock displacement at the 4,7S0-ft level of the 5,100-ft-deep rectangular, timbered Caladay Shaft in northern Idaho. Displacements were measured with multiple-position borehole exten-someters (MPBX) installed 4 ft above the face and timber extensometers (TE) installed with the timber sets. This report presents the displacement data along with preliminary, qualitative observations of rock behavior. The measured displacements showed an instantaneous response to shaft sinking and significant time dependency. The relative magnitudes of displacement measured at the shaft walls were heavily influenced by local geologic structure and distance from the shaft bottom.

Jan 1, 1987

By G. M. Wilemon

The Bureau of Mines conducted preliminary investigations on the use of an acid-alcohol leaching technique for recovering phosphate values from phosphate matrices. H2S04 and methanol were used as the leaching agents. Starting-matrix particle size and acid-apatite ratio were found to significantly affect the efficiency of phosphate leaching. Phosphate extractions of more than 80 pct were obtained when minus 200-mesh ore was used and the acid-apatite ratio was 8:1 or more. The iron and aluminum oxide impurities (R203) present in the crude acid products were monitored, and R203-P205 ratios are reported. Phosphate extractions in excess of 80 pct also were obtained when phosphatic clay wastes were leached. Typically, leach slurries filtered using test leaf filters ex-hibited filtration rates of 100 lb/(h·ft2) or more.

Jan 1, 1987

By J. P. Landriault, F. W. Harrison

"Zinc-iron alloy coatings can be produced by either thermally alloying hot-dipped galvanized steel or by electro deposition. Stelco Inc. produces a thermally alloyed Zn-Fe alloy-coated steel, which is mechanically wiped to remove free zinc.A more extensive use of Zn-Fe alloy-coated steel has been predicted for unexposed autobody and structural part applications, since this material is characterized by good spot weldability and formability, and provides superior corrosion resistance under automotive primers.This investigation has examined the coating composition, corrosion resistance, spot weldability and formability of Stelco's Zn-Fe alloy-coated steel and found its properties to be similar to those of Zn-Fe alloy-coated steel produced by post coating annealing.IntroductionRecently, there has been increased automotive interest in galvanneal, which is characterized by good spot weldability, good paintabilityt and good corrosion resistance when primed. Stelco produces a thermally alloyed zinc-iron coated sheet product similar to galvanneal. However, this product is produced by mechanically wiping the free zinc from the surface of hotdip galvanize to expose the underlying zinc-iron alloy.The surface of Stelco zinc-iron alloy-coated sheet is matte gray and has longitudinal streaks which result from contact with Kevlar wipers during production (Fig. I). This paper describes the coating composition, corrosion resistance, weldability, formability and surface appearance of Stelco zinc iron alloy coatings and, wherever possible, compares these properties to those of galvanneal."

Jan 1, 1987

By K. O. Bennington

The thermodynamic properties of two manganese silicates, pyroxmangite and fowlerite (zincian rhodonite), were experimentally determined by the Bureau of Mines. The standard enthalpies of formation were determined by hydrofluoric acid (HF) solution calorimetry, the low-temperature heat capacities by adiabatic calorimetry, and the high-temperature heat capacities by differential scanning calorimetry over the range 322 to 1,372 K. Data for the standard enthalpy of formation (AH298), the derived standard entropy (S298), and the standard Gibbs energy of formation (AGf 298) are as follows: Pyroxmangite [(Mn0.9554Cao,0446)(Si03)J- AHf298 319.668±0.46 kcal/mol AH298 (from oxides)... -7.215±0.11 kcal/mol 5295 23.785±0.048 cal/(mol'K) AGf298 -301.190±7.96 kcal/mol Fowlerite [(Mno.7o3Zno.0884Ca0.2086)(Sio3)]--AHf298 ?... -329.914±0.419 kcal/mol AH298 (from oxides)... -8.400±0.104 kcal/mol 5598 21.949±0.059 cal/(mol-K) AGf298 -310.716±7.99 kcal/mol These experimentally determined values were combined with data from the literature to calculate the Gibbs energies and equilibrium constants of formation over the temperature range of the measurements. Standard enthalpies, Gibbs energies, and equilibrium constants of formation are given as a function of temperature from both the elements and the constituent oxides.

Jan 1, 1987

By Jesse L. Hoyer

A Bureau of Mines turbomill was evaluated for use in the production of high-purity, ultrafine x-Sic powders suitable for advanced ceramics that could substitute for high-temperature alloys containing critical materials such as chromium, cobalt, and nickel. The effect of milling param-eters, such as type of dispersant, temperature, pH, and gas environment, on the milling of x-SiC was studied. The addition of dispersants improved the grindability of x-SiC. Of the six dispersants studied, the best results were obtained with Mara-sperse N-22. Grinding efficiency was also increased when the x-SiC was milled in a basic slurry and at elevated temperature. Gas environments did not appear to affect grinding of x-SiC. Optimum grinding efficiency was obtained at 50° C in a slurry at pH 9.5 with Marasperse N-22 as the dispersant. Under these conditions, minus 100-plus 200-mesh x-SiC was ground to 80 pct less than 1 um in 4 h.

Jan 1, 1987

By Edward L. McHugh

In 1984, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied an 84,165-acre portion of the 84,935-acre Clover Mountains Wilderness Study Area (NV-050-139) in order to evaluates its identified mineral resources. The area studied is in Lincoln County, NV, about 90 miles north of Las Vegas, NV. No mineral resources were identified in the study area. Volcanic rocks are the most common in the study area, consisting mainly of a thick sequence of ignimbrites in a cauldron complex. Cambrian to Triassic marine sedimentary rocks and Cretaceous to Oligocene clastic rocks are along and partly inside the west and south sides of the study area. No mineral production ha s come from the study area, but gold, silver, copper, and fluorspar have been mined nearby. Eleven mines and prospects in or adjacent to the study area were examined. Workings inside the study area include two shafts, 10 and 60 ft deep, and eleven shallow prospect pits at four sites along the west edge.

Jan 1, 1987