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By Roland Kammel

For electrolytic recovery of silver from dilute aqueous solutions improved mass transfer is necessary to achieve favourable current efficiencies and high space-time yields. The many cell designs proposed for this application can be divided into two different groups: cells from which the silver must be redissolved and cells from which the deposit can be reclaimed as a metal. Introduction Electrolytic silver recovery methods have proven advantageous under technical and economic aspects for the treatment of rinse water, still rinses and spent silver solutions in the electroplating and surface finishing industry, of exhausted fixing baths from photographic processing, bleed electrolytes from silver refining processes and leach liquors. Examples of the compositions of typical dilute silver solutions are listed in Table I.

Jan 1, 1984

This Bureau of Mines report is a compilation of information on computer models of mineral commodity markets in the Federal Government, The directory was compiled by the Analytic System Working Group of the Interagency Minerals Information Coordinating Committee to support the formulation of policies related to nonfuel minerals.

Jan 1, 1984

By W. C. Peters

Geologists take the role of mine geologist when they apply their science to the design and operation of a specific minerals project. In doing so, they use the entire spectrum of procedures in economic geology and engineering geology to deal with a specific system of orebodies and associated environment. The objectives are established by stages in the life cycle of a mining operation as it goes from a prospect to a development project and on to a mine. This paper summarizes the elements of a mining geologist's role, with examples highlighted from the preceding papers.

Jan 1, 1984

By N. Kyriazi

A performance study of oxygen self-rescuers from the United States and other countries was undertaken as an assessment of present worldwide technology. The apparatus were tested a an breathing and metabolic simulator in the Life Support laboratories of the Bureau of Mines. Parameters monitored during the testing were inhaled levels of C02 and 02, inhaled gas temperature, and breathing resistance. The metabolic demand placed on the apparatus represented the average demand of the 50th percentile miner performing a 60- min man-test 4, as described in 30 CFR 11H. Results presented include ;apparatus service life and subjective comments as well as averages and peaks of monitored parameters.

Jan 1, 1984

By R. S. C. Rogers

A mathematical model is proposed as a general formulation for the analysis and simulation of once-through crushing machines. Methods are described which can be used to estimate parameters of the proposed model from experimental data, thus minimizing reliance on backcalculation. The applicability of the model is demonstrated in the analysis and simulation of laboratory and full scale double roll crushers, and with evidence given for a laboratory scale cone crusher. An extension of the model for closed circuit crushing is also described.

Jan 1, 1984

By Robert W. Leonardson

The Questa Molybdenite Mine provides a unique opportunity to study the geochemical dispersion of various hydrothermal events, utilizing drill hole analyses. Numerous post-ore factors have altered the primary ore-related geochemical dispersions to the present day configuration, e. g. dikes, faults, hydrothermal convection cells, and weathering. Due to the interaction of an andesitic volcanic pile with the silicic-alkalic generated volatiles, the geochemical haloes of the Goat Hill deposit demonstrate a marked divergence from the classic Climax-type molybdenite ore body. Certainly, however, the similarities to the Climax-type ore body are apparent as potassically-rich fluids have invaded the highly reactive country rock.

Jan 1, 1984

By Philip G. Meikle

The Bureau of Mines Coal Mining Technology program has developed new concepts aimed at improving the efficiency of underground coal product ion. Conceptual designs have resulted in equipment prototypes, some of which are currently undergoing proof-of-concept evaluations at Bureau and cooperator facilities. Several of these systems and concepts are described.

Jan 1, 1984

By W. R. Green, B. W. Barde

"Geological exploration involves the collection and analysis of a wide variety of information. A basic problem in interpretation is to determine the interrelationship s of the different data. A number of statistical methods can be applied to this problem, provided that subsets of data can be selected.We have recently developed a set of interactive computer programs which provide the cap ability to quickly examine a large set of data, and may be used by people with little previous computer experience. There are two main stages in using this system. First is selection of subsets of data , by applying various tests on the values of given items. This includes matching specific entries in descriptive fields, and minimum - maximum tests on numeric fields. The second stage is basic statistical analysis and data display , including histograms, 2-D scalier plots, probability (cumulative frequency) plots, and correlation matrices. All output can be viewed on a computer terminal, and important parameters changed to produce the most effective display for use in interpretation.This system has been applied to a number of different exploration problems. An example was the determination of the nature and extent of mineralization of a gold prospect in the Queen Charlotte Islands, from drill-hole data. With the aid of the computer programs , a mineralized zone was defined, and locations for further exploration identified."

Jan 1, 1984

By L. E. Schultze

The Bureau of Mines has devised techniques to recover lithium from geothermal brines as the chloride. More than 99 pct of the lithium was precipitated from a brine containing 170 mg/L Li by adding a solution of AICl3 and increasing the pH to 7.5 with lime slurry. The Li-Al precipitate was dissolved in HCl and sparged with gaseous HCI to recover the AlCl3; this resulted in a solution containing LiCl and CaCI2. The solution was evaporated at 1000 C to obtain a mixture of the chlorides from which 97 pct of the lithium was recovered and 90 pct of the calcium was rejected by leaching with tetrahydrofuran. The LiCl recovered by evaporation of the tetrahydrofuran was purified by dissolution in water and treatment with oxalic acid. The final LiCl solution contained 89 pct of the lithium originally present in the brine and had a purity of 99.9 pet.

Jan 1, 1984

By Elizabeth A. Johnson

Minor-element behavior and interaction in the copper matte-iron silicate slag system have been studied by the Bureau of Mines. In the present work, the possibility of interactions among the minor elements As, Sb, Bi, Se, and Te was investigated. Equilibrations of matte, slag, and one of each of the five minor elements were performed at 1,250° C under typical matte smelting atmospheres of CO, CO2, and S02 for mattes containing 40, 50, and 60 pct Cu. Results are compared with those of a previous Bureau of Mines study in which all five minor elements were present simultaneously.

Jan 1, 1984

By C. H. Bloomster

This study estimated (1) radon and radon daughter emissions from underground uranium mines; (2) the reduction in radon that would be released to the surface by using control techniques such as bulkheads, sealants, backfilling, and positive pressure ventilation; (3) the cost for radon and radon daughter removal from total exhaust air; and (4) total radon and radon daughter discharge for lower occupational exposure limits. For 13 large underground uranium mines, estimated yearly radon emissions from each mine ranged from 900 to 3,400 Ci. The estimated age of air emitted from the mines ranged from 11 to 37 min. Potential radon removal methods for the total mine exhaust were evaluated. The cost of these methods was prohibitive. Diurnal and seasonal changes may affect radon emission over short periods of time, but do not affect the total emissions over the long run. Radon and radon daughter emissions would be little changed by increased ventilation requirements needed to achieve lower occupational exposure limits. The concentrations in the exhaust would be lower, but the total release would be the same

Jan 1, 1984

By A. E. J. Gallagher

There are many influences which have a bearing on the economics of industrial minerals production. The purpose of this paper is to discuss briefly three factors which have economic significance in the production of these mineral commodities. The three items of discussion include 1) the nature and relative value of the industrial minerals group, 2) project planning, and 3) market analyses. General aspects of these factors are familiar to most of us. However, an attempt will be made to give some current details regarding each. Also, in reality, project planning and market studies are usually so closely associated that they will be discussed jointly, rather than separately. This will be done by way of examples which show how these two activities actually evolved for two industrial minerals projects.

Jan 1, 1984

By Bernard J. Steblay

Millions of mechanical anchor roof bolts are used each year for mine structural support. The benefit of this bolting depends on a number of factors including rock density, bolt length, in situ stresses, time elapsed between mining and installation, rock properties, bolt patterns, and tension (Lang, et al., 1979). Installation tension is a major determinant of support quality. Postinstallation tensions indicate both the usefulness of the individual bolts and the behavior of the reinforced rock structure. The importance of short- and long-term bolt tension measurements is well recognized, and such measurements are required by regulations (Fed. M/NM Nine Safety and Health Reg.). These regulations also take into account the difficulty of practical tension measurements. Only a statistical sample of the bolts installed is required to be measured using current torque wrench technology. Drawbacks to this practice are that the anchorage is disturbed and perhaps weakened, accuracy is limited by friction to about 30% (Lang, et al, 1979, and Barry, et al., 1956), and the procedure is relatively time intensive.

Jan 1, 1984

By Robin G. Burn

An orebody is a mining company's greatest asset; without it there can be no mine. Yet, by the very nature of the industry, orebodies are wasting assets whose progressive depletion must be balanced by continued discovery of new ore to enable both the industry to survive and the raw material demands of society to be satisfied. Although mineral exploration may be viewed as any activity which leads to the creation of investment opportunities in the mineral industry, ultimately new ore can only be generated through discovery. The process leading to discovery may involve a long chain of independent and interdependent events. It will almost always be repetitious and require the examination of many prospects or trials before the goal, a commercially successful discovery, is satisfied. Long term survival of a mining company through regular discovery of new ore, requires a continued commitment of funds and effort to mineral exploration.

Jan 1, 1984

Data recently released indicate substantial improvement in mineral industry performance for 1984. Business plans to increase plant and equipment spending in 1984 by 14.8 percent, according to a recent survey conducted by the Commerce Department's Bureau of Economic Analysis (table 1). In contrast, capital spending by all industries declined 4.8 percent in 1983 and 2.3 percent in 1982. The latest estimate of planned expenditures for 1984 is $2.2 billion higher than the comparable estimate based on the survey conducted in late January and February 1984.1/ [ ] Of particular significance to the U.S. mineral industries are the 15.5-percent increase in capital spending planned by manufacturing in 1984 and the planned 18.6-percent increase in spending by durable goods manufacturing, where the largest increases are planned in the transportation equipment (26.4 percent) and electrical machinery sectors (23.5 percent). Capital expenditures in manufacturing declined in both 1982 and 1983.

Jan 1, 1984

By Ofori-Ansah K

The zeta potential on the surface of activated orit carbon were estimated in lhe presence of selected cations and anions that are normally associated with gold bearing ores in Kalgoorlie area of Western Australia. Additions of such ions to solution of varying pH shifted the isoelectric point of carbon from pH 4.45 to pH 7-8.3, while the anions moved Lhc isoelectric point 10 less than pH 3.2. In the presence of gold cyanide SoluLion additions of spectator ions indicated the isoelecLric poilll to be aL pH less than 3.2; the only exception was for Fe" ion where the isoelecLric point was at pH 5.9. The decrease in zeta potential appeared to be related to the counter-ions present. The decrease may also be related to the adsorption of hydroxyl ion complexes that are likely to be formed when cations are present in the solutions.Gold adsorpLion by activated orit carbon from gold cyanide solution seem to be indicated by the magnitude of zeta potential on the carbon surface. An attempt is made to relate gold adsorption and zeta potential on carbon surface with the pH of the medium.

Jan 1, 1984

By Donald I. Bleiwas

The U.S. Bureau of nines evaluated the potential availability of tungsten from 57 tungsten mines and deposits in 19 market economy countries (1). The 38 properties that were producing at the time this study was performed contain approximately 375,000 tons1 of W03 (tungsten trioxide). The total estimated recoverable resource from all properties studied, both producers and nonproducers, was 1.2 million tons W03 (demonstrated level). Approximately 143,000 tons of W03 is recoverable from producing properties with costs at or below the January 1983 market prices. The study indicates that by 1990 production from currently operating mines in market economy countries will decrease as their demonstrated resources become exhausted. Some of this potential decline may be offset by lower than anticipated levels of market demand, discoveries of additional resources at producing mines, development of other known deposits, and/or discoveries of new deposits. Development of new tungsten resources in market economy countries will likely result in costs higher than exist at currently producing properties. The People's Republic of China has been steadily increasing production and export of tungsten in various form and currently supplies about 25 pct of U.S. imports. China's tungsten mines are large, high-grade operations capable of producing at relatively low cost. These factors, coupled with China's apparent need for foreign exchange, could lead to further expansions of production and exports from China, with a consequent increased dependence by market economy countries on China for tungsten requirements and a threat to the survival of the market economy countries' tungsten industries.

Jan 1, 1984

The history of potential large scale development at Stawell in northwestern Victoria dates back to 1914, when Great Boulder Mines Limited, of Kalgoorlie, Western Australia, took up options on some of the major mines in the Stawell Goldfield. Despite this and other attempts by various groups over the next thirty years, mining activity on the field gradually dwindled to the retreatment of old mill tailings.A static price for gold and indifferent drilling results prevented a major effort towards reopening the field until the late 1970's. A renewed exploration effort led to the discovery of sufficient reserves to justify installation of a carbon-in-leach gold treatment plant.

Jan 1, 1984

By Caroline L. Herzenberg

Recently, neutron-induced gamma spectrometry has been introduced and gained provisional acceptance as a method for continuous automated analysis of coal. Instrumentation based on this technique has been under development for and in testing at coal preparation plants and a coal gasifier. To provide a deeper understanding of, and extended capability in applying this method, theoretical calculations have been performed of the absorption of thermal neutrons by various coal compositions, and the thermal neutron capture prompt gamma emission spectra produced by these compositions have been calculated. Selected results of these computer calculations and the computer generated spectra are presented.

Jan 1, 1984

By Robert F. Chaiken

More than 500 fires are now burning in abandoned coal waste banks and coal deposits in the United States. Once established, such fires can burn for decades, and extinguishing them by conventional methods such as surface sealing to exclude air, excavation to remove fuel, or flushing to cool the fire zone is usually difficult and always expensive. Burnout Control, a technique developed by the Bureau of Mines for the control of abandoned fires, involves the accelerated combustion of coal in place with total management of the heat and fumes produced. A burning waste bank or mine is placed under negative pressure relative to the atmosphere, and heat and combustion products are drawn from the combustion zone through an exhaust ventilation system. Heat produced appears as sensible heat in the exhaust, at temperatures as high as 1,000° C (1,832° F), and can be recovered for the production of steam, hot water, process heat, or electricity. The Bureau's first field demonstration of Burnout Control was at Calamity Hollow in Allegheny County, PA (near Pittsburgh). Calamity Hollow was the site of an underground mine in the 1900's and was surface mined in the 1940's. In the winter of 1961-62, a fire of undetermined origin was discovered in the exposed coal. In 1963, the Bureau constructed a trench barrier around the fire and a surface seal over the affected area. The fire was isolated, but not completely extinguished. In 1979, when the Bureau began work on the Calamity Hollow Mine Fire Project, to demonstrate controlled burnout, the fire was still smoldering on the hot side of the trench barrier. The project, which was begun in December 1979 and ended in July 1982, consisted of the design, construction, operation, and subsequent dismantling of a Burnout Control ventilation system. This report is the fourth in a five-part series that describes the Calamity Hollow Mine Fire Project. The first report, part 1, describes the design and construction of the field installation. Part 2 will present the results of a continuous 4-month burnout operation. (Because part 2 involves the analysis of a substantial body of data, it will not be published until after publication of parts 3, 4, and 5). Part 3 describes the instrumentation used to control and monitor the progress of the burnout operation. This part (part 4) and part 5 both deal with the closeout phase of the field demonstration. The quenching of the fire is described in this report, and part 5 will describe the final excavation and backfilling of the heated zones. The reports in this series document the Calamity Hollow controlled burnout demonstration, which showed that (1) controlled in situ combustion is a feasible method for controlling underground fires in abandoned mines, (2) the resultant thermal exhaust output is sufficient for energy utilization, and (3) water injection with fume exhaustion is a potentially effective method for cooling large underground fire zones. Further trials of both Burnout Control and water injection with fume exhaustion are planned.

Jan 1, 1984