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By Robert S. Shoemaker

At this Symposium on Gold which is sponsored by The Metallurgical Society of AIME and the International Precious Metals Institute many distinguished authors will present the latest developments in the metallurgy of gold and in operating practices at mines and in refineries. It seems appropriate then, as the introduction to this volume to recall some of the history of gold and the metallurgical developments which have been accomplished, especially during the past 100 years and some of the people who have contributed so much to the metallurgy of gold. Of all the elements gold has been the most sought after since the earliest times. Perhaps the quotation from Virgil's Aeneid best describes man's desire for gold but Pliny the Elder also put it very well when he wrote in 79 A.D. that "Gold is the first of man's follies, silver the second". This quest for gold has markedly influenced man's history and through the efforts of the early philosophers and alchemists to turn base metals into gold the foundations for modern chemistry were laid. The pages of history literally teem with references to gold. Gold is the first metal mentioned in the Bible and was the source of Croesus wealth as well as the death of King Midas whose touch turned everything into gold. And of course almost everyone has heard of Jason's Argonauts and the golden fleece. They are the subject of one of the many drawings in Agricola's De Re Metallica published in 1556. The Argonauts were probably prospectors seeking the source of the placers in the region near-the Black Sea. The time was about 1200 B.C. and the placer miners recovered gold by trapping the particles in sheep's fleeces placed in sluices. After drying, the fleeces were shaken to recover the gold. Gold is not hydrophilic, or wetted by water and thus the oils in the wool aided in collecting the particles. Here we have perhaps the earliest reference to surface chemistry and the basis for concentration of gold by flotation.

Jan 1, 1984

Sinter mixes of three iron ore types were prepared with a range of water contents in a laboratory investigation. The mean diameter of the granulated mixes and the void fraction of beds of the mixes were determined experimentally. Pressure drop measurements over a range of flow rates were made in a laboratory permeameter with pressure tappings at several depths in the bed. The Ergun equation was applied to the results to determine the shape factor of the granulated mixes. The pressure readings down the bed were used to estimate the local void fraction in the bed using the Ergun equation and the calculated granule shape factors and it was found that there was a decrease in void fraction with depth in the bed. The significance of this and the variation of the shape factor values with the amount of water used for granulation is discussed in relation to the strength of granules of the sinter mixes.

Jan 1, 1984

By P. R. Bremmer

As part of a program to devise alternative technologies for producing alumina from domestic resources, the Bureau of Mines investigated the leaching of calcined kaolinitic clay to form basic aluminum chloride solutions. Bench-scale experiments were conducted for single-stage batch leaching with AICl3 solution and three-stage countercurrent leaching with substoichiometric HCI. Variable conditions of clay calcination and leaching were studied to determine their effects on aluminum extraction and pregnant liquor composition,

Jan 1, 1984

By Richard P. Walters

This Bureau of Mines report reviews and assesses the technology for preparing electrodeposited coatings of the platinum-group metals from molten alkali metal cyanide baths. Methods are described for the preparation and purification of the cyanide electrolyte. Vacuum drying, fusion, and purity of the cyanide salts are discussed. Use of a sodium borosilicate test tube as a sodium-ion-conducting membrane for the addition of the desired platinum-group metal is described. The optimum plating parameters of potential and current density for Pt, Pd, Rh, Ru, and Ir coatings that result in the best deposits are given. A method for producing platinum-rhodium alloy coatings of predetermined composition is also described. The importance of careful substrate surface preparation is illustrated. While problems still remain with respect to coating porosity, careful application of the methods described permits the preparation of adherent, coherent electrodeposited coatings of the platinum-group metals.

Jan 1, 1984

Western Mining Corporation (W.M.C.) operates a nickel refinery at Kwinana, 30 km south of Perth. The refinery commenced pro- duction in May 1970, with a rated capacity of 15 000 tpa of nickel metal. A hydrometallurgical route was chosen as the most expedient way to produce nickel metal at a time when world demand for nickel was outstripping the supply. Later events dictated that an increase in production from the refinery be achieved. To this end, matte produced from Kalgoorlie Nickel Smelter, which was commissioned in 1972, was used in varying proportions as a complement to the concentrate initially utilised as input to the refinery. The effect of matte addition was to increase the capacity to 30 000 tonnes of nickel per annum. This was accompanied by other benefits which were 1. reduction in energy consumption per unit of nickel produced, 2. improved metal extraction, 3. improved precious metal recovery, 4. reduced production of ammonium sulphate by-product. Refinery operating results for the years 1970 to 1983 show how matte feed has improved refinery performance in these areas.

Jan 1, 1984

By He BQ

Static attachment of bubbles to solids is contrasted with dynamic attachment in flotation cells. The times of contact during particle-bubble collisions in dynamic attachment are compared with the induction time determinations and the kinetics of thinning of the liquid films separating solids and bubbles. The thinning is examined mainly in terms of electrostatic and dispersion (van der Waals) contributions to the disjoining pressure existing in the films. The local heterogeneity (on a molecular scale) of charge distribution invariably present at all interfaces (even at conditions of zero zeta potential) calls for some means to minimize possible electrostatic repulsions which arise when the electrical double layer at the air-bubble interface begins to overlap that present at the solid surface, on encounter between particles and bubbles. It is postulated that dipoles of frother molecules, owing to their ability to "flip over" (polarise), replace localized electrostatic repulsion by attraction within fractions of a milli- second, as long as the structure of the frother molecules is sufficiently "bulky" to maintain diffuse films (of mixed collector-frother) at the air/liquid interface of bubbles. The relaxation times of dipoles (signifying their "flipping over" ability) have to be shorter than the collision times between particles and bubbles for particle-bubble attachment to be facilitated under dynamic Conditions.

Jan 1, 1984

By Graham Jones

During 1982 Ash Grove Cement Company contracted with Wagester, Walker, Thornton & Company to convert a Calcimatic rotating hearth kiln at its Portland, Oregon lime plant from gas/oil to coal firing. Increasing costs of natural gas and No. 6 fuel oil made this conversion mandatory if the plant was to remain competitive. Unique features of this project are 1) the distributors of pulverized coal to eighteen small burners around the inner and outer perimeters of the doughnut-shaped kiln, and 2) the attrition-dryer-pulverizer mill. Ash Grove, a century-old lime and cement producer headquartered in Overland Park, Kansas (Kansas City area), looked at various schemes for multiple burner firing before employing Wagester, Walker, Thornton & Company. W.W.T. of Pitts- burgh, Pennsylvania was formed in 1980 by acquiring the Solid Fuels Division of the Pullman Swindell Corporation. This division had been active in developing solid fuel firing for brick tunnel kilns, principally in the Southeast. They continue to supply such systems firing wood waste as well as coal to the brick industry and have also converted two Calcimatic lime kilns for Dixie Lime, Sumterville, Florida, a fluid bed calciner for Texas Gulf in Aurora, North Carolina, and a chrome concentrate kiln for Diamond Chemicals at Castle Hayne, North Carolina. Testing and a proposal have been made for INMETCO, Elwood City, Pennsylvania, on an annular hearth furnace for direct reduction of iron ore to metallic iron.

Jan 1, 1984

By R. J. Sweigard

Productive and beneficial use of reclaimed surface-mined land is a concern of industry, government, and the general public. An investigation was conducted of current mined-land planning practices to aid in the development of a procedure for evaluating postmining land use potentials. This investigation considered both the industry and public planning approach to mined-land planning and was based primarily upon three case studies conducted in various regions of the United States. The site planning process that was developed during the investigation is iterative in nature and has been designed specifically for the mining industry. It centers around preliminary studies and data collection, development of land use alternatives, and the evaluation of alternatives. Use of this process facilitates the evaluation of economic, environ- mental, and social impacts of postmining land use alternatives. In this paper, the process is presented along with a description of its development, application, and significance.

Jan 1, 1984

By Jaime Lomelin

The brines from the sub-surface of the Laguna del Rey dry lake are pumped to Química del Rey, S. A. plant, where they are cooled in adiabatic crystallizers precipitating sodium sulphate decahydrate. This salt is dehydrated in multiple effect evaporators and dried in rotary kilns producing high purity anhydrous sodium sulphate. The spent brines from the sodium sulphate operation are concentrated in solar ponds, precipitating astrakanite and leaving a brine with a higher concentration of magnesium ions. This brine is treated with calcium chloride solution to eliminate the remainder of sulphates, leaving a solution of magnesium chloride ready for the manufacture of refractory grade magnesium oxide or periclase. The magnesium chloride is reacted with dolime to produce magnesium hidroxide which is washed, filtered, and calcined to produce soft burned magnesium oxide, which is briquetted and dead burned to produce the periclase.

Jan 1, 1984

By C. M. Lesher, R. R. Keays

"The komatnte-associated Fe-Ni-Cu sulphide mineralization at Kanihalda, Western Australia, is generally believed to be magmatic in origin, but a number of postmagmatic processes significantly modified the original distribution, structure, texture, mineralogy and chemistry of the ores. Two important types of mobilized magmatic sulphides are interpillow/interbreccia sulphides and hydrothermal vein-type sulphides. Interpillow and interbreccia sulphides occur interstitial to pillowed or volcaniclastic footwall metabasalts beneath or adjacent to the stratiform contact ore horizons. They are mineralogically and compositionally similar to massive ores (and are similarly depleted in PGE relative to the compositions of bulk samples of mined ores), but normally do not contain the distinctive chalco-phile ferrochromites characteristic of contact ores. They are interpreted as magmatic sulphides that have been mobilized from the overlying or adjacent massive sulphide layer during peak tectono-nietamorphism.Hydrothermal sulphide-quartz + albite veins also occur in the footwall metabasalt and contain unannealed deformation fabrics indicative of emplacement during retrograde metamorphism. The high Ni and Pd contents of these sulphides (7-13% Ni, up to 70 ppm Pd) indicate that the metals have been derived from the spatially associated komatiites and/or contact ores, consistent with the Pd depletion previously inferred for massive ores. Very low Ir contents and high Pd/Ir ratios of the vein-type sulphides confirm an aqueous transportation-deposition mechanism; hydrothermal transfer of PGE results in strong decoupling of Pd from Ir.There appears to be a complete continuum of sulphide mobilization at Kambalda ranging from whole-scale phy sical dislocation (fault offset ores) and selective mobilization (stringer sulphides) through nietamorphie replacement (interpillow/interbrec- cia sulphides) to jiydrothermal dissolution and redeposition (vein-type sulphides)."

Jan 1, 1984

By Robert L. Frantz

The various facets of university-company cooperative activities and the opportunities for collaborative research for the mineral industries are presented in this paper. The advantages and disadvantages of various alternative research funding arrangements for the researcher, the university, and the sponsoring corporation are discussed. Examples of university-industry cooperative research programs are briefly outlined. The concept of a cooperative mining research program is presented. The improvement of performance through techno- logical developments and human skills may well be the greatest competitive edge available to the U.S. mining industry. In this regard, the need for new endeavors between industry and universities can hardly be overemphasized.

Jan 1, 1984

By S. P. Singh

In order to simulate the operation of coal extraction machines, a portable workability instrument has been designed. Initially, the tests were performed with the instrument on modeling material, which were followed by in situ tests on coal in underground mines. The peak and mean cutting resistance and work done to cut a unit length of coal were determined for coal as well as modeling material. In addition, rebound strength and dynamic penetration tests were also performed in situ. On the basis of the cutting characteristics of coal, a "Workability Index" has been developed and its role in the judicious selection of coal cutting machines has been discussed. With reference to prior works and the strength characteristics of coal, it was found that the coal plow may not be suitable for the seams under investigation and the shearer seems to be the only choice. It has been observed that peak cutting resistance and the "Workability Index" in the case of coal as well as modeling material depend upon compressive strength. The peak cutting resistance exhibited certain dependence upon the Schmidt rebound hardness and dynamic penetration strength of coal in situ.

Jan 1, 1984

By S. A. Bortz

IIT Research Institute has initiated several multi-sponsored research programs. In this paper the methods for developing four of these programs are discussed. In general, a broad area of investigation must be proposed to interest a spectrum of different industries. The work must not touch upon proprietary data and will probably involve a number of scientific disciplines. Thus, the problem to be solved will attract sponsors who need to know more about the area under study but do not wish, as a single company, to commit the resources required to obtain the necessary know-how for their needs. The paper draws on the background of four IITRI multi-sponsored projects: Size Reduction, a study of grinding of material to reduce their particle size; Melt-Formed Ceramics Research, a method of producing dense, polycrystalline ceramics using glass forming methods; Binders in Ceramic Processing, which addresses the problems associated with the use of organic aids for ceramic processing; and a Study in Air Pollution Technology, a program to review and assess pollution control equipment for current and future applications.

Jan 1, 1984

By David L. Bradfield

This paper covers the development of the Yeelirrie Uranium Project from the discovery of the Yeelirrie deposit in 1970 to the present time, with emphasis on the mining, processing, and environmental requirements of the project. The Yeelirrie Uranium Project is managed by the "Yeelirrie Uranium Joint Venture Partnership", which, when formed, consisted of Yeelirrie Development Company Pty., Ltd., Urangesellschaft, Australia Pty. Ltd. and Esso Exploration and Production Australia Inc. The Yeelirrie Uranium Joint Venture Partnership holds mineral claims over the Yeelirrie uranium ore deposit in Western Australia. This deposit encompasses some 35 million tonnes of ore containing in excess of 50,000 tonnes of uranium as U308. Agreement has been reached with the State of Western Australia to mine and process the ore to produce uranium ore concentrate. The Project scope provides for an open-cut mine, alkaline leach hydrometallurgy plant, power plant, township, airstrip, access roads, community services and utilities. The Yeelirrie Uranium Project described herein has progressed through the stages of exploration, mine evaluation, process testing, project scope definition, environmental approval, Pilot Plant operation, preliminary engineering and the publishing of a definitive Project Feasibility Study. This article summarizes the project development through the above stages.

Jan 1, 1984

By R. E. Hucko

The principal thrust of the U.S. Department of Energy (DOE) Coal Preparation R&D Program is to develop technology to reduce the ash and sulfur contents of United States coals to levels such that the resultant product can be formulated into a high quality solid or slurry fuel that could replace oil or natural gas in both new and retrofit applications. Specifically, the objective is to develop and refine cost-effective physical and chemical beneficiation processes to extract 85-95 percent of the total sulfur and ash. The Coal Preparation program is implemented by the Pittsburgh Energy Technology Center (PETC) and is conducted both in-house and by a cross section of industrial organizations, universities, and national laboratories. Research is subdivided into three areas -coal characterization, beneficiation, and ancillary unit operations. This paper will provide a brief overview of many of the research projects being carried out in these areas in fiscal year 1984.

Jan 1, 1984

By J. M. Kaufman

Recent mining regulations have increased the need for detailed engineering and environmental information pertaining to the hydrogeologic environment in mining areas. The cost of obtaining such hydrogeologic information has also increased. After mineralization of potentially economic grade ore and tonnage has been identified, and after completing preliminary mining feasibility studies (suggesting that development is merited), a second exploration phase can incorporate a simple, cost-effective baseline hydrogeologic data reconnaissance program that is linited but useful. Using exploration drill holes only, this program can provide a direct indication of where ground water is encountered. Also, reasonable estimates can be made on the relative production of water from various water-bearing strata, a composite potentiometric surface map can be prepared, and the general chemistry of the ground water can be characterized.

Jan 1, 1984

By Joseph S. Coffman

To determine the availability of manganese for metallurgical purposes from selected world resources, the Bureau of Mines evaluated the potential production of contained manganese in concentrates based on the demonstrated resources of 23 foreign and 8 domestic mines and deposits in 9 market economy countries. All but 2 of the 23 foreign deposits are operating mines; none of the domestic deposits are in operation. The demonstrated resources of the mines and deposits used in this study represent an in situ ore resource of approximately 2.2 billion tons," containing 780 million tons of manganese with a total recoverable production potential of 514 million tons of contained manganese in concentrates. The analyses of mines and deposits in this study indicate that about 213 million tons of the contained manganese (41 pct) is potentially available at a January 1981 constant dollar long-run total cost of up to $1.50 per long ton unit (22.4 lb, or 10.15 kg contained Mn), approximately 428 million tons (83 pet) is potentially available at a cost of about $1.75 or less, and 491 million tons (95 pet) is available at less than $3.30. The remaining 23 million tons, which is potentially available at much higher costs (about $8 to $35 per unit), represents the U.S. deposits. On an annual basis, with a cost range of up to $1.75 per long ton unit, the availability from currently operating mines would last at least 80 years based on 1980 world production data. Total manganese production costs are estimated to comprise mining-8 pet, beneficiation-3 pet, transportation-26 pet, and smelting-63 pet.

Jan 1, 1984

By Kot F. Unrug

When reading different studies discussing trends in coal mining, it appears that a substantial expansion of output by the year 2000 is predicted, even in the most pessimistic forecasts. Depletion of shallow, easy-to-mine deposits is only a matter of time, and the future average mining depth will increase. The proportion of slope to shaft mines operated during the next decades will change in favor of the shaft mines. Since an increasing amount of shafts in new nine developments seems to be inevitable, it appears appropriate to focus more attention on shaft design criteria. Some valuable papers have recently been published (1) that emphasize geotechnical aspects of shaft design. In the discussion that follows some other aspects of design criteria will be evaluated.

Jan 1, 1984

By Z. J. Hladysz

The Hladysz Rock Tester was developed at the South Dakota School of Mines as a portable rock strength tester. The hand held device is placed against a rock surface and struck by a hammer. The impacted force causes a steel ball in the device nose piece to indent the rock and simultaneously indent a standard steel bar also contained in the nose piece. By comparing the two indented diameters the compressive strength of the rock can be calculated using laboratory determined correlation coefficients.

Jan 1, 1984

By William G. Fischer

This paper attempts to close the gap between extensive rock testing with field measurements and the mine operator's need for safe mine layouts and alternatives. It was found that many of the variables that influence mine geometry and worker safety are relatively unimportant while others are critical. The development of empirical relationships which tie the critical variables to the "safe useful life" of a trona mine layout and observations made in 140 production areas where the variables were researched over a fifteen year period are discussed. The concepts presented may have applicability in mine design for other bedded deposits.

Jan 1, 1984