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By T. T. Tomimatsu

This? Bureau of Mines paper discusses the corporate structure dynamics, methods of financing, and financial assessment approaches that should be utilized to evaluate the economic health of the coal industry. It suggests rates of return and other measures of corporate economies necessary to attract capital required to finance emerging coal demand, plus impact of coal sales to total revenues. The study illuminates the activities of 30 selected coal-producing companies, including their subsidiaries or affiliates, that were responsible for approximately 60 percent of the total U.S. production in 1974. The selected firms are not all primary coal producers; many of the larger producer's are classified by the financial institutions as petroleum, metal, and steel producers, public utilities, or chemical industries. The bituminous coal industry is highly competitive as to price, service, and quality of pronuct and is subject to competition from other noncoal energy sources. The top 15 bituminous coal-producing companies mined about 46.6 per-cent of the Nation's total production in 1974, and the balance of approximately 3,885 companies were responsible for the rest of the production. Thus, the U.S. bituminous coal industry is not an oligopoly. Today, about 65 percent of the Nation's total coal production is consumed by electric power utilities and 26 percent by steel, space heating, and other industries; the balance of 9 percent is exported.

Jan 1, 1976

The Particulate Mineralogy Unit has been established at the College Park, Maryland, Metallurgy Research Center. The Particulate Mineralogy Unit will have the responsibility within the Bureau of Mines for the characterization of particulate minerals which have potential for adverse environmental effects. The Unit will provide a focal point for identifying particulates in connection with environmental problems related to the activities of agencies such as OSHA, HEW, EPA, and MESA. The Particulate Mineralogy Unit is seeking to clarify the ambiguities surrounding the mineralogy of and terminology used for asbestiform minerals and other mineral particles. The Unit?s investigations of the morphology, composition, and structure of asbestiform minerals and their nonasbestos analogs have made its members recognized experts in this field. The information which it develops on the characterization of asbestos and other particulate mineral forms such as silica should provide a technically rational basis for decisions by regulatory agencies. Those desiring further information, contact Dr. W. J. Campbell, Program Coordinator, College Park Metallurgy Research Center, College Park, MD 20740, telephone: 301-344-4014. ALUMINUM: For over a month, domestic producers have priced 99.5 percent grade primary aluminum ingot at 48¢ per pound. In the same period, merchants raised ingot quotes by 1.5¢-2.5¢ to a range approaching 44¢-47¢ per pound.

Jan 1, 1976

By J. J. Kim

In a study of buildup in a green-feed reverberatory furnace, it was determined that approximately half of the crucible area has a moderate buildup of 25 in. or less, and that the area extending 45 f t from the burner end of the furnace has only a slight buildup. The false bottom, averaging 6 in. in thickness, was found to cover the entire crucible area. The stratification of Cr2O3, A12O3, and SiO2 occurs throughout the slag layer; this phenomenon is the principal reason for the formation of the false bottom in the green-feed reverberatory furnace. The false bottom is caused primarily by the settling of FeO*(A1,Cr),03 aggregates, which are derived mainly from returned converter slag. The false bottom can be transformed to a solid permanent buildup in the furnace, particularly when the matte is completely withdrawn. From the material balance of Al2O3 and Cr2O3 around the furnace, It is estimated that the average rate of aluminum chromite accumulation is approximately 0.3 ton per day or less.

Jan 1, 1976

By A. J. van der Zeeuw

The use of SME 529 in the extraction of copper from acidic liquors and of copper and nickel from ammoniacal solutions, is illustrated with results of laboratory and bench scale mixer/settler experiments. Special features of SME 529 are its high loading capacity and the ability to keep the complexes dissolved in the organic phase up to quite high concentrations.

Jan 1, 1976

By Vern Miller

The Bureau of Mines developed a detector for controlling sorting devices to separate the copper-bearing fragments from the barren portion of Michigan native copper and western porphyry copper ores. A successful sorter could be used to preconcentrate the ore and eliminate costly hoisting or hauling of waste. An induction balance unit was developed and used in sorting tests on crushed sized -1+1/2-inch (-2.5+1.3-cm) ores from the Kingston (0.9 pct CU) and Centennial (1.6 pct Cu) mines of Upper Michigan. Concentrates of 4.0 pct and 7.5 pct Cu, respectively, were obtained at recoveries of 85 and 80 pct of the copper in the feed. Eighty percent of the sorted ore was rejected as tailing. Sorting larger fragments improved the separation efficiency. Tests on -4+2-inch (-10+5-cm) sized Kingston (1.6 pct Cu) and Centennial (2.1 pct Cu) ore samples yielded concentrates of 4.3 and 4.5 pct Cu, respectively, with corresponding recoveries of 92 and 91 pct. About 60 pct of the sorted ore was discarded as tailing. Porphyry copper sulfide ores also responded to electronic sorting but at a lower separation efficiency. Sorting response was affected by the degree of segregation.

Jan 1, 1976

By J. A. Eisele

The Federal Bureau of Mines is engaged in a continuing program on the recovery of alumina from domestic source materials. Of the six processes being studied, current efforts focus on HCl leach of clays. A key step in the HCI process is the removal of iron from the aluminum chloride leach liquor. This was accomplished .by solvent extracting the iron with a tertiary amine in kerosine to which decanol was added as a phase modifier. In a mixer-settler operation, iron in the raffinate was reduced to <10 ppm in two extraction stages from a feed containing 1.4 gil Fe. Iron was stripped from the organic phase in three stages with dilute HCl.

Jan 1, 1976

By Robert P. Vinson

A sequential sampler, based on the Archimedes screw, has been developed by the Bureau of Mines. Its initial purpose was to collect air samples during tracer gas studies in underground mines. However, the basic concept can be applied to other sampling needs, including sampling of liquids. A prototype was built and successfully tested in the Bureau&apos;s Experimental Mine at Bruceton, Pa. The simple design makes the sampler inherently durable and low in cost.

Jan 1, 1976

Are you afraid of the dark? Of course not, at least not since you were about six years old, anyway. But early man was - afraid of the dark, and he had good reason to be. Since he had no illumination other than fire and moonlight, he was at a disadvantage when it came to mixing it up with some of his fellow creatures. Sabre-toothed tigers, for example, could probably see quite well In the dark, and they were very real enemies. Sabre-toothed tigers haven&apos;t been seen in mining country for some time now; but it&apos;s st111 dark In a mine and, make no mistake about it, there are still enemies in the dark. The enemies are all the things that can injure you if they are not seen. Modern mines can be safe places to work for the trained miner who follows good work practices. But there are mining machines that make sabre- toothed tigers look like pussycats, and if you can&apos;t see well enough they can be ten times more dangerous.

Jan 1, 1976

By John C. Carpenter

Solvent extraction is used to selectively recover copper from iron containing sulphate solutions. As chloride ions, which form series of complexes with transition metals, are now being used for leaching. Little is known of the effects of these ions, on solvent extraction behavior. It has been shown that commercial extractants of the L1X and Kelex series extract copper from chloride media: (1) at a lower pH than from sulphate solutions, (2) to similar loadings, and (3) except for L1X 63, without transferring chloride to the organic phase. A process for selective extraction of copper from chloride solutions should thus be compatible with standard stripping and electrowinning practice. Of several diluents, differing in aromaticity, kerosene gave enhanced extraction only with L1X reagents. A change in operating temperature had little effect on equilibrium metal distribution. All the extractants examined gave adequate separation of copper from iron. L1X 63 was found to extract chloro-complexes of copper and of iron and thus transfer chloride to the organic solution. Consequently this extractant and its mixtures are not preferred for use with chloride leaching systems.

Jan 1, 1976

By Israel Liebman

The Bureau of Mines developed three types of passive water barriers for suppressing slow-moving coal dust explosions. One type is a modification of a conventional tub barrier and depends on the dynamic pressure generated ahead of an explosion to tilt the tub to release its water and suppress the explosion. The other two barriers operate in response to an increase in static pressure developed ahead of the explosion. Tests indicate the first barrier begins to release its water at air speeds as low as 50 ft/sec, and the second and third barriers will operate at a rise in static pressure as little as 0.5 psi. All three barriers were found to be effective in suppressing coal dust explosions propagating at speeds as low as 100 ft/sec. A plan is described for installing a water barrier in a working mine on a trial basis.

Jan 1, 1976

By W. W. Harvey

The work to be described was part of an exploratory research program directed toward identifying potentially useful but little known reactions in extractive metallurgy. In particular, the major copper sulfide minerals, as a group, have long been considered insoluble in nonoxidizing acids (e.g. Forward and Barren, 1J60; Parsons and Ingraham, 1970; Peters et al. 1972). This generalization was considered to include nonoxidizing conditions in warm aqueous MC1 solutions (Ingraham et al. 1972) and, indeed, was consistent with our own chemical and mineralogical experience. On the other hand, under hydrothermal conditions, copper and sulfide species are carried in solution and deposited as sulfides in mineralized veins. The question that poses itself is: what are the mildest conditions of temperature and fluid composition under which commercially important copper sulfide minerals can be solubilized in the absence of an oxidizing agent? A reference to H2S formation during oxygen-sulfuric acid pressure leaching (Warren, 1958) of chalcopyrite, when the oxygen partial pressure was allowed to fall, provided a clue. In the present study, experimentation with chalcopyrite concentrate in dilute hydrochloric acid, under re flux conditions (in Pyrex flasks) and with an inert purge gas, revealed substantial amounts of H2S production and iron solubilization, cite negligible copper solubilization, after 2 ½ -4 days. Under comparable conditions the extent of reaction with dilute sulfuric, acetic and phosphoric acids was markedly less.

Jan 1, 1976

The purpose of this study is to formulate practical guidelines for active underground mining in close proximity to water bodies. This was accomplished through systematic completion of three phases of study: I) Collection and Documentation of Data; II) Application of Existing Guidelines to Case Histories of Previous Inundations; and III) Development of Recommended Guidelines for Underground Coal Mining Near Bodies of Water. Phase I of the study involved a worldwide data collection effort designed to obtain foreign and domestic guidelines for mining near water bodies, and accident records and case histories of accidental mine inundations. Within Phase II, existing guidelines were categorized and classified and then evaluated as to their effectiveness in precluding past inundations had they been in effect at the time of inrush. Advantages and disadvantages of existing guidelines were defined. Drawing on the broad data base established in previous study efforts, Phase III was directed at development of viable guidelines to promote the greatest possible coal extraction while precluding accidental mine inundation. Two levels of guidelines are presented; Level I Guidelines require little or no subsurface exploration on the part of the mine operator, while Level II Guidelines recommend various testing and investigative procedures to permit greatest possible mineral extraction. This report presents findings and conclusions of the study.

Jan 1, 1976

By W. L. Staker

The Bureau of Mines investigated the use of shredded automobile scrap for copper cementation. Air agitation was used to improve the cementation rate and prevent excessive buildup of copper on the iron. The pieces of scrap were too large to be properly evaluated in the laboratory; therefore, a pilot scale test unit was constructed and the process tested at field locations. Pregnant solution was obtained from industrial leaching operations, processed in the test unit and the barren solution and cement copper were returned to the plant process stream. The test results showed that the air-agitated launder containing auto-mobile scrap was an effective means for recovering copper from leach solutions. A continuous l4-day test run was made without a noticeable decrease in cementation efficiency. The most suitable scrap product was obtained from incinerated automobile hulks shredded in a hammer type of shredder. However, it was necessary to remove small pieces such as nuts and bolts because they interfered with the discharge of the copper product.

Jan 1, 1976

By George H. Schnakenberg

This Bureau of Mines publication describes a passive personal sampling device for N02 in air, developed by the New York University Medical Center under Bureau Grant G0133066. The sampler has been successfully demonstrated in the field and in the laboratory. In corroborative laboratory trials the agreement with reference method is excellent. The overall accuracy is approximately ±5 pct of reading to a precision of about ±l pct. All evidence indicates that these samplers should indicate the time-weighted-average N02 concentration to the above accuracy and precision equally well in the field since effects of wind velocity and relative humidity are negligible and the effects of temperature are about 0.1 pct per °F. The duration of exposure and the approximate temperature are the only data that need to be collected in the field. A two-step analysis procedure in field or service laboratory is then used to obtain the total cumulated exposure to N02 in parts per million-hours (ppm times hours), which can be converted to the time-weighted-average concentration of N02 in ppm by dividing cumulated exposure by the duration of the exposure.

Jan 1, 1976

By Richard J. Bielicki

This Bureau of Mines study estimates the number of major pieces of coal- mining equipment that will be required to produce 950 million tons of marketable coal in 1980 and 1.2 billion tons in 1985. The coal tonnages were projected in the intermediate coal supply scenario of Project Independence Blueprint (PIB). The equipment projections were determined by consideration of historical trends and by evaluation of information from equipment manufacturers and mining companies. The ability of the manufacturers to meet the projected equipment demands was also determined. It was concluded that equipment supply offers no presently discernible constraint to mining 1.2 billion tons of coal in 1985. A shortfall in projected production for the intervening years, however, is probable owing to anticipated shortages of draglines.

Jan 1, 1976

When I reached Warren after the "de luxe" South American expedition I had little idea what was in store for me. From the large check Thayer had handed me just before I left New York I was pretty sure the future would be good, and that before long it would involve Anaconda. Evidently, Mr. Thayer had left it to Dr. Ricketts and John Greenway to work out the details The next morning Greenway asked me to come to his office and told me that he and Dr. Ricketts had discussed the question and that Anaconda would make me an offer I could not refuse. They proposed to pay me almost $1000 a month, more than twice my current salary. They had agreed that I should stay with Calumet and Arizona for the rest of the year to help with Bisbee development and anything I could to assist with the New Cornelia plans and construction Of course I could not turn down such a flattering offer, as I had about reached the limit of advancement with a much smaller company in anything save a high executive job, and it would be a long time before I could be ready to change from exploration and geology to operating. Greenway and I agreed that I would stay with him for the remaining eight months of 1916 without any particular title but helping in any way I thought would be most useful. Bisbee and Ajo Study It turned out to be a busy half year, in addition to many good times with my Bisbee friends. The Uplift Club did not meet as regularly as in earlier years, but Mason Ross, Jim Lewis, Bill Gohring, Roy Mitchell, Hubert d&apos;Autremont, Arthur Notman, and I did have many "bull sessions" and poker games. I saw much more of Greenway than before and made many trips with him to Ajo and later to the new

Jan 1, 1976

By James K. Kindig

Hazen Research, Inc., has developed a new process for removing pyritic sulfur and ash from coal. Feed coal is contacted with iron carbonyl vapors, Fe(CO)5, at 190°C which puts a thin skin of magnetic material on the pyrite and ash, but does not affect the coal. Thus, low intensity magnetic separators yield a nonmagnetic coal, low in sulfur and ash, and a magnetic refuse, high in sulfur and ash. Results are given for clean coal produced by this method. A comparison is made between results of the magnetic process and the U. S. Bureau of Mines two-stage flotation process cleaning identical samples of Pittsburgh Coal. Capital and operating costs of the two cleaning methods are discussed.

Jan 1, 1976

By Larry S. Diaz

It is felt that prior to the presentation of the technical portion of this paper, some general information would be of interest. The Sar Cheshmeh Copper Mining Company was founded by the Iranian Government to oversee the design and construction of Iran&apos;s first copper smelter complex, which will be another step in the industrialization of Iran. Since this is the first such plant in Iran, Sar Cheshmeh wisely chose to enlist the technical assistance needed in regard to the facilities requiring engineering and operating know-how from outside of Iran. To obtain the foregoing, SCCM signed a contract with Anaconda-Iran, Inc., which was formed by The Anaconda Company for this project. The general scope of this contract covers the overseeing of engineering and design by Parsons-Jurden as well as physical plant construction. In addition to this, the same services were given to water supply and tailings disposal systems which were not included as part of the Parsons-Jurden contract. Anaconda-Iran is also assisting SCCM in setting up a training program for Iranian personnel for plant operations, administration, etc., which .will go on for some time after the plant startup, under the guidance of Anaconda-Iran expatriates. SCCM?s other responsibilities, in respect to the development of this industrial effort, are the building of a townsite for approximately 2200 families, the expected manning requirements, having all the facilities necessary to provide a pleasant life in a remote area. It has been estimated that the manpower for operations will be 2050.

Jan 1, 1976

By K. J. Liles

This Bureau of Mines paper describes the composition and properties of drilling fluids for use in high-temperature geothermal wells, and summarizes the problems encountered with fluid use at the known major geothermal sites throughout the world. These include the western continental United States, Hawaii, Italy, Iceland, Japan, New Zealand, and Turkey. Water-base drilling fluids of 9- to 10-lb/gal weights are relied on primarily for geothermal well use, although air drilling is sometimes used. Bentonite-lignite-water systems have been used most often, and additives such as polyacrylates, lignosulfonates, and chromates are employed to improve the properties of the basic system.

Jan 1, 1976

By Terry O. Arney

This paper is a description of the digital Data Acquisition and control System that is installed at Cities Service&apos;s Pinto Valley Concentrator. Pinto Valley Concentrator ? The Pinto Valley Concentrator (5, 41 is located approximately seven miles west of the town of Miami, Arizona. The Concentrator is situated south of the open pit mine and was designed to process 40,000 tons of ore per day with an average grade of .45% copper. The comminution process consists of primary, secondary, and tertiary crushing, and single-stage closed-circuit grinding 161. Concentration of the copper sulfides is by means of froth flotation. Concentrates are transferred to the Inspiration Consolidated Copper Company smelter in Miami, Arizona through a slurry pipeline.

Jan 1, 1976