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By H. B. Trinh, R. R. Srivastava

"Spent auto-catalyst is a potential secondary resource because of the higher concentration of valuable platinum group metals (PGMs) as compared to the primary ores. Despite the well-developed commercially tenable technologies, further researches are being carried out to extract the PGMs with high efficiency. It is however, critical in this context to reuse not only the PGMs but also other metals contained in the spent auto-catalyst particularly that of the cordierite substrate such as aluminum, magnesium and cerium oxide (CeO2). This is important in view of the fact that no recycling process has ever stressed upon the recovery of cordierite substrate and CeO2 since the main target metals are mostly the PGMs. In this study, a new hydrometallurgical approach has been proposed in order to recover the PGMs as well as cerium oxide and materials from the cordierite substrate by using sodium hydroxide roasting followed by sulfuric acid dissolution. Under the optimal conditions for roasting at above 600°C, and weight ratio of sample to NaOH of 1:1 for 60 min, the cordierite was converted to the soluble phases. Dissolution of the roasting products using H2SO4 solution (1M) at 25°C for 60 min enriched the PGMs and Cerium oxide contents in the residue. Subsequently, PGMs in solution after dissolution can be cemented using Al and Cerium oxide in residue can be recovered by hot digestion using concentrated H2SO4.. INTRODUCTION Auto-catalyst can significantly control the gaseous emission of automobiles, and has been considered as a potential secondary source of Platinum group metals (PGMs) after being decommissioned from the vehicles. The PGMs demand is continuously increasing to comply with the growing vehicle population and the tightening of emission standards all over the world; meanwhile the natural resources of these metals is facing the threat of depletion. Therefore, it is crucial to progressively substitute with an alternate resource to supply PGMs other than that of the primary ores. Nowadays, vehicular transportations worldwide are totally installed with the auto-catalysts. However, they should be replaced after reaching their service life. If there is no recycling of such resources, huge amount of valuable metals will be wasted. The quantity of PGMs that can be recovered from the spent auto-catalyst depends on the size of car, which averages to 1-2 grams for small cars and 12-15 grams for the big truck; this is significantly higher than that of the primary ores containing 2-10 grams PGMs per ton. Consequently, the recovery of PGMs from spent auto-catalyst becomes extremely favorable as compared to the primary resources due to higher concentration of PGMs, with much lower and simpler processing steps, and lesser pollution."

Jan 1, 2018

By Lou Gaozhong, Guo Wenbing, Zhao Gaobo, Wang Shuren

"The height of a fractured zone due to high-intensity mining (HIM) plays a vital role in the safety analysis of coal mining under bodies of water. This paper described the characteristics of HIM. The processes of overburden failure transfer (OFT) are analyzed. The state of destruction transfers from a certain stratum to the upper stratum as face advance distance increases, and the processes of OFT are divided into two stages: transmission development stage and transmission termination stage. Through theoretical analysis, the limited suspension-distance and limited overhanging distance of each stratum are proposed to judge the damage of each layer. Based on this, the OFT criteria of fractured zone development are obtained. The mechanical model of strata suspended integrity and overhanging stability are established. Finally, a new method to predict the height of fractured zone due to HIM is put forward based on the processes of OFT, the limited suspension-distance, and the limited overhanging distance. Further, a HIM panel in the Datong coal mine is taken as an example. Theoretical methods are proposed, and engineering analogy is used to predict the height of the fractured zone, which is compared with in-situ measurements reported in the literature. The results show that the in-situ measurements for the height of the fractured zone are in close agreement with the theoretical calculation result. Therefore, the rationality and reliability of the theoretical method proposed to predict the height of fractured zone is verified.INTRODUCTIONThe height of the fractured zone (HFZ) due to the exploitation of coal is a key parameter for the safety analysis of coal mining under a body of water (Wenbing, Youfeng, and Hou, 2012). Accordingly, it is necessary to predict HFZ under the corresponding mining conditions before coal mining."

Jan 1, 2018

By E. McCarthy

"INTRODUCTION Talc is a hydrous magnesium silicate with the approximate elemental composition 4MgO.3SiO2.H2O. It is one of the layered phyllosilicates (like kaolin and mica) but it differs from these in that it is relatively hydrophobic. This is due to its unique crystalline structure whereby a brucite inner layer is sandwiched between silica layers and the adjacent silica layers have no interlayer bonding other than van der Waals forces. This allows talc to be sheared easily along this basal plane, and the surface is covalent not ionic. Talc occurs both as a relatively pure material (>90% talc content) and in conjunction with many other minerals in proportions all the way from 1% to 90%. At lower concentrations, it is often considered a nuisance mineral when it occurs with base metals like copper, molybdenum or nickel or with precious metals like platinum or palladium. It floats readily with these materials and often is suppressed using guar gum or carboxy methyl cellulose which will absorb along the basal surface and make it hydrophilic. Alternately if the reduced ore is hydrophobic, like MoS2, then a partial oxidation of the sulfide will convert the surface to a hydrophilic oxide and the talc can be floated away in a separate step. Talc in grades from 20 to 90% has been commercially exploited in a wide range of pigment (paint and paper), material (ceramic, construction and cosmetic), reinforcing (polymers and composites) and functional (pitch adsorbent, lubricating agent) applications. Initially these tended to be local or regional markets, but eventually with certain higher purity grades, cosmetic, polymer and ceramic applications became valuable enough to be national and trans ocean markets. TALC FLOATATION PLANTS This drove the need for higher purity grades of talc and initially this need was met primarily by ore sorting. This works well for certain deposits with well crystallized talc lenses, but for ores, such as those from widely available ultramafic deposits, where the liberation size is closer to 100 microns, sorting is not effective. That drove the need for floatation and the first investigations were published by Clemmer and Cooke of the US Bureau of Mines in 19362. The first commercial floatation plant was installed in Johnson, VT by the Eastern Magnesia Talc Co in 1937. The circuit is shown in the schematic (Figure 1). The ore was an ultramafic, serpentine derived talc; mineralogy was about 55% talc, 40% ferroan magnesite and 5% oxides, sulfides and other silicates. The oxides include hematite and chromite, sulfides pyrite and gerstorffite and silicates chlorite, serpentine and mica. After crushing, the ore was dry ball milled and then air classified to remove minus 325 mesh fines. The coarse fraction was further classified to cut at about 100 mesh and the fines from this were the feed to floatation. The -325 mesh (about 15% of the ore) was sold as a paint grade and the plus 100 mesh (about 25% of the ore) was screened to make an asphalt backsurfacing grade."

Jan 1, 2018

By V. Sheikhzadeh, M. Saghaeian, R. Hejazi, A. Abazarpoor

The research aimed to compare the chemical analysis (K, Na, Cl) of Iranian concentrate plants, which are the main source of materials corrosion in the pelletizing plants. Cl alongside alkaline elements (especially K) may cause corrosion and plug in the grate plates and other involved equipment. Therefore, it is tried in the processing plants to remove impurities from the concentrate to prevent potential problems in pelletizing and iron/steel making processes. Part of these impurities are existed in the nature of ores and others are sourced in the processing water. Various samples from the largest Iranian concentrate plants including Chadormalu, Gol-e-Gohar, Jalal-Abad and Sechahun were prepared to investigate the possibility of alkaline problems for each samples. The amount of Cl, K and Na of Chadormalu sample was obviously low and therefore no alkaline problem is expected. The Cl content of Gol-e-Gohar sample was high (980 ppm) while amount of K was less (0.008 Wt. %). Due to low content of K, most of Cl will release as Cl2 or HCl and so problems caused by KCl plugging would not be a problem. The amount of Cl in Sechahun case was nearly same as Jalal-Abad (400-600 ppm), higher than Chadormalu and less than Gol-e-Gohar samples. However, the K content was higher than all samples (0.04 Wt. %). Therefore, the amount of evaporated K would be 2-4 times more than other samples. Since the amount of Cl and K is simultaneously higher than usual iron ores, therefore alkaline problems may be a serious prevention factor for the continuous operation of this plant. In order to solve this problem some counter-measures is suggested and discussed including cleaning system, partial dust enriched with KCl removal and variation in the materials type of involved equipment.

Jan 1, 2018

By Kevin Andrews, Scott Nelson, Terry Hamrick

"In the process of Geologic Hazard Mapping (GHM) for underground coal mining, geologists evaluate the effects of various geologic and geotechnical conditions to assist with optimization of mine productivity and with selection of more favorable areas for future development. The methodology involves correlation of multiple geologic factors (such as overburden depth, proximity to sandstone channels, and areas with weak immediate roof strata) with conditions encountered during mining (roof falls, floor heave, pillar spalling, etc.). Such studies yield maps that identify areas where mining is likely to be difficult and allow mining engineers to foresee favorable and unfavorable mining areas when planning new or expanding mines. To expand the benefits of GHM, work has been done to correlate geologic factors with room-and-pillar mining advance rates. Average mining advance rates are mapped and then correlated to different areas, as characterized by GHM. This process exposes the geological characteristics that have a material impact on mining rates of advance, improving the rates of advance into future mining areas with similar geological conditions. The final result of the work allows mine planners to not only design the mine qualitatively accounting for areas of unfavorable conditions, but also allows the mine planner to more accurately apply rates of advance for mine timing and production sequencing. The use of GHM to predict mining advance rates in unmined areas enhances the benefits of traditional hazard mapping and provides quantitative data that can be incorporated into mine sequencing models.INTRODUCTIONThe role of a geologist in the coal mining industry has evolved significantly over the last 30 to 40 years. Geologic Hazard Mapping (GHM) mapping for coal mines began in the late 1970s and early 1980s (Chase, Newman, and Rusnak, 2006). Since its beginnings, the GHM process has evolved significantly and continues to take on new levels of sophistication. Numerous case studies of GHM application to predict future mining conditions exist in the literature. For example, Artrip, Nelson, and Newman (1993), documents the geotechnical characterization of roof and floor for mining in the Imboden Seam in Virginia where previous mining efforts had been abandoned due to adverse mining conditions. In addition, Keim and Miller (1999) summarize evaluation of geological influences on a longwall mine in West Virginia. In both examples, significant geotechnical and geological information was available, including the opportunity to compare predicted mining conditions against actual conditions as mining progressed."

Jan 1, 2018

By M. Morales, J. Yianatos

"In this work, an alternative approach to evaluate the flotation performance along a flotation rougher row is presented. The collection zone as well as the froth zone performances were separately evaluated. For this purpose, sampling for metallurgical balances along with sampling of top-of-froth (TOF) grades in each cell of a flotation row were employed. The modelling of the rougher circuit consisted of using TOF grades for evaluating the collection zone recovery, because they are a good representation of the bubble loading, which identifies the true flotation process, as shown in previous studies for shallow froths. In addition, the feed characterization, size-by-liberation, allowed the identification of the mineral distribution and its evolution along the circuit. The latter result was obtained by fitting the recovery profiles as well as the TOF grades down the flotation bank. The flotation rates and the maximum recoveries in terms of size-by-liberation (size classes: -45 µm, +45-150 µm, +150 µm, and liberation classes: -20%, +20%-80%, +80%) were then estimated. The results were in good agreement with those reported in literature by other authors and showed the new approach allows flotation kinetics to be characterized in industrial circuits.INTRODUCTIONMineral recovery in industrial flotation circuits is a function of the mineral characteristics, such as particle size distribution and liberation (Trahar, 1981, Jameson, 2012), and operating conditions such as air flowrate, pulp flowrate, solids percent and reagent conditioning (Jameson 1977; Klimpel, 1980; Mehrotra and Kapur, 1974). The cell type and size (self-aerated or forced air) and the circuit arrangement (single cells or banks of cells in series) are also relevant factors. Sampling of circuits (e.g. rougher, cleaner or scavenger) are commonly carried out using standard automatic samplers for metallurgical balance assessment. However, the flotation plants are generally not provided with proper accesses for local streams, which hinders the recovery estimations and the flotation rate characterization."

Jan 1, 2018

By Harold Gibson, Ulrich Schwarz-Schampera, Ralf Freitag, Hendrik Mueller

INTRODUCTION Germany has a long history in marine research in the Indian Ocean. The first German scientific cruise started in 1964, followed by a series of state-sponsored research cruises between 1983 and 1995 leading to the first finding of polymetallic sulfides in the Indian Ocean. The research included regional bathymetric, geological, structural, volcanological, petrological and hydrothermal investigations along the Carlsberg Ridge and the Central Indian Ridge (CIR). Early environmental base line studies covered oceanographic and sedimentology aspects. In 2010, BGR took the initiative for the preparation of a license application for the exploration of polymetallic sulfides with the International Seabed Authority (ISA), and prospecting started in 2011 along the southern Central (CIR) and the northern Southeast Indian Ridge (SEIR) in the southwestern Indian Ocean (cruises INDEX 2011 on board R/V Sonne), INDEX 2012 (R/V Fugro Gauss), INDEX 2013/1-2 (R/V Sonne) and INDEX 2014 (R/V Pelagia). After three years of resource-oriented and environmental base line studies, BGR, in order for the Federal Ministry for Economic Affairs and Energy (BMWi), applied for an exploration license which was approved by and subsequently signed with the ISA in 2015. The license gave permission to start a detailed exclusive resource-oriented exploration program in the license area. The program includes the outline of potential ore deposits and a resource assessment but also extensive and detailed base line studies for the sustainable protection of the marine environment in the license area. The license contract has a fifteen years lifetime and may allow the application for a subsequent mining license. The exploration aims at the identification of inactive polymetallic sulfide deposits, formed below former discharge zones of hot hydrothermal fluids on the ocean floor (“black smoker” systems), by advanced and modern exploration techniques.

Jan 1, 2018

By Tobias Hens, Andrew Frierdich, Joël Brugger

The rapid advancement of green technologies in recent years is closely tied to an ever- increasing demand for raw materials. Innovative forms of zero-emission transportation and sustainable power generation will require a variety of traditional metals such as Ni and Co, but also many non-traditional metals (e.g., REY). Many of these elements are known to be highly enriched in deep-sea ferromanganese (Fe-Mn) nodules and crusts. However, unlocking these metals from their deposits through metal processing is – aside from deposit exploration and production – expected to be a critical component that will affect the overall economics of the marine mining value chain. Hence, research and development of tailored metal processing solutions which can target specific metals of interest in Fe-Mn nodules and crusts, is required. Dynamic mineral recrystallization (DMR) of Fe-Mn oxide phases is a geochemical process that may have notable potential for hydrometallurgical applications. We have recently demonstrated that Ni can effectively be cycled between deep-sea Fe-Mn nodules and crusts and solutions through dynamic mineral recrystallization. DMR occurs in nature as abiotic background process during biogeochemical Mn cycling when dissolved Mn(II) is in direct contact with Mn oxides. Trace metals which are incorporated in the Mn host phases, are cycled between solid phase and solution via coupled dissolution (trace metal release) – reprecipitation (trace metal incorporation) mechanisms.

Jan 1, 2018

By Elizabeth Holley, Meriel Young, Gabriel Walton

"The coal mine roof rating (CMRR) was developed by Chris Mark and Greg Molinda to bridge the gap between geological variation in underground coal mines and engineering design. The CMRR accounts for the compressive strength of the immediate roof, the shear strength and intensity of any discontinuities present, and the moisture sensitivity of the immediate roof. The CMRR has been widely used and validated in Eastern US coal mines, but it has seen limited application in the Western US.This study focuses on roof behavior at a Western coal mine. Mine A shows significant lateral geological variation, along with localized faulting and a laterally extensive sandstone channel network. The CMRR is not used to predict roof instability at the mine.It is, therefore, hypothesized that there are other factors that are correlated with roof instability in underground coal mines that could potentially also be included in the CMRR.This hypothesis was tested by collecting 30 CMRR measurements at Mine A. At each measurement location, a binary record of the roof condition (stable or unstable) was made along with parameters, such as depth of cover, thought to also correlate with roof stability. A statistical analysis of the data was performed to determine the parameters in addition to those included in the CMRR, which can be correlated to roof stability.INTRODUCTION AND BACKGROUNDRoof fall is one of the greatest hazards facing underground coal miners (Barczak et al., 2000). In 2017, 91 lost-time injuries occurred due to roof fall in US underground coal mines. A further 48 roof falls occurred with no lost days (MSHA, 2018).The coal mine roof rating (CMRR) classification was developed by Molinda and Mark (1994) to quantify the geological description of mine roof into a single value that could indicate mine roof stability and be used in engineering design. It is widely used in the Eastern US as an input for the analysis of longwall pillar stability (ALPS) in underground coal mines. It provides an excellent start; however, it is arguably not fully comprehensive, nor is it widely used in the Western US."

Jan 1, 2018

By Italo Onederra, Gary Cavanough, Ewan Sellers

Reactivity of ammonium nitrate based explosives is associated with the presence of iron sulfides in the ground reacting with explosive products and in some instances causing spontaneous reactions which can lead to detonation. The stability of explosive products can also be linked to in-hole density, which influences detonation efficiency, breakage performance and the potential generation of Nitrogen Oxide (NOx) fumes. Reactive ground testing involves detecting a temperature rise of a mixture of a bulk explosive product sample, a ground rock sample and some specific chemical agents. This paper describes improvements in reactive ground testing involving the use of time lapse video analysis and detection of NOX gas emissions from the sample. Reactivity is stored and linked to a using cloud based software to map of the mine showing the exact location of the sample. The location marker can be selected to allow quick access to the sample test results and video. In addition to reactivity, the stability and detonation performance of bulk product can also be influenced by depth. In this paper, a system that simulates product at depth and measures density changes and monitors the structure of bulk samples is described. Results from an explosive product are analyzed and detonation performance is assessed by the measurement of velocity of detonation and detonation pressure.

Jan 1, 2018

By S. Gomez, P. A. Bebswa, A. N. Mwale

"The research aimed at improving the way screen performance analysis is conducted using a model that accounts for most feed and design parameters in its formulation. Thus, the aim was to validate the fine screen model that was developed at the Centre for Minerals Research (CMR) unit at the University of Cape Town. Fine wet screening is increasingly becoming an important application in fine grinding operations. Minera Saucito, a lead-zinc Mexican mine has replaced hydrocyclones with eight stacks of five decker derrick screens to close the ball mill in their concentrator plant. The five decker stacks have improved the overall plant throughput by 20% and have had the ball mill circulating load reduced considerably. As a continuous plant optimization process, a number of surveys were carried out to assess the performance of the 75 µm panel aperture installed screens. The surveys were conducted at seven different feed rates to the entire nest of screens to collect performance data. Using the fine screen model to analyze the results, it is found that as the feed rate increase, the sharpness of separation reduces. The CMR fine screen model was fitted to these results. The model fits the plant data with good accuracy. Simulated results based on this model are also presented.INTRODUCTION The potential of high frequency vibrating screens has long been identified as an alternative to hydrocyclones in grinding applications (Rogers and Brame, 1985). However, high frequency vibrating screens have had two main disadvantages, low capacity and high wear rates (Kelley and Mckeon, 2005; Teknikk, 2009). Current vibrating screen technology overcomes these challenges by multiple deck screen design and use of wear resistant urethane materials for panel construction (Kelley, 2007; Valine and Wennen, 2002). For a example, the Derrick screen’s material of construction is a tensionable urethane that provide high open area ranging between 35 to 45% with considerably reduced blinding (Valine and Wennen, 2002). Thus, there has been an increased uptake by the mining industry in the use of wet fine vibrating screens closing the ball mill as the final classification stage in the comminution circuit (Barkhuysen et al., 2010; Frausto, Ballantyne et al. 2017; Pelevin and Lazebnaya, 2009; Teknikk, 2009). Even though there is a number of models in existence, none of these models adequately predict the performance of high frequency vibrating screens (Karra, 1979; Rogers, 1982; Subasinghe et al., 1990; Trumic and Magdalinovic, 2011). Recently Mwale et al., (2016) developed a model for predicting the performance of high frequency vibrating screens using the partition curve properties. The input parameters of the model include screen open area (??) in m2, tonnage feed rate (????) (tph) and the weight fraction of solids (??) in the feed for a given panel aperture size. The model was developed based on data collected from a single deck industrial size derrick screen, in a pilot setup. The work presented in this paper is an attempt to test this model using data collected from Minera Saucito concentrator, an industrial plant whose comminution circuit is shown in Figure."

Jan 1, 2018

By Feiya Xu, Syd S. Peng

"As a highly efficient and new surveying and mapping technique, 3D laser scanning technology has been gradually applied to surface subsidence monitoring in mining areas. 3D laser scanning technology was used to monitor the mining subsidence in a coal mining area in this paper. Based on the 3D laser scanning data obtained in March, May, and December 2016 in the studying mining area, the surface subsidence basin and points deformation were acquired. The 3D laser scanning data were compared with that of the conventional surface movement surveying method. The results show that the 3D laser scanning technology could obtain the data of the subsidence basin more efficiently and reflect the true shape of surface subsidence caused by mining. The maximum surface subsidence obtained by 3D laser scanning technology was 3.60m, while the conventional surface movement surveying was 3.56m; the relative observation error between 3D laser scanner and the conventional surface movement surveying was less than 10%. Therefore, it is feasible to apply 3D laser scanning technology to monitor surface subsidence in coal mines.INTRODUCTIONWith the over-exploitation of coal resources, the problem of surface subsidence has become the focus of attention (Peng, 2011; Guo Wenbing, 2012). Setting up observation stations for surface movement was the traditional method to study the characteristic of surface subsidence and its parameters. At present, hundreds of observation stations have been set up in longwall mining, and a large number of measured data have been obtained (Ministry, 2017). However, due to the length of time surveying requires, great workload in the field, the high cost of observation, and difficult protection for monitoring points, conventional observation stations for surface movement have not met the research on surface subsidence. Therefore, as a new surveying and mapping technique, 3D laser scanning technology has been gradually used for surface subsidence monitoring in mining areas (Ma Liguang, 2005). Li Qiu, Qin Yongzhi, and Li Hong (2006) first proposed 3D laser scanning technology in the application of monitoring surface subsidence in 2006. It was showed that the 3D laser scanning technology had obvious advantages in efficiency and accuracy of data acquisition than other methods of deformation monitoring technology of surface subsidence (such as total station, precision level technique, GPS, etc.). Subsequently, Zhang Shu, Wu Kan, and Wang Xiang (2008) and Chen Ranli and Wu Kan (2012) analyzed the feasibility and precision of 3D laser scanning in subsidence monitoring, concluding that the 3D laser scanning can be used to obtain the subsidence basin and the monitoring precision can reach millimeter. Hu Dahe, Wu Kan, and Chen Ranli (2013) introduced the data processing method of 3D laser scanning for surface subsidence in detail. On the basis of a case study, the subsidence basin in subsidence area was obtained, which reflected the shape of mining subsidence basin intuitively and comprehensively. Wang Qisheng, Wu Kan, and Zheng Ruyu (2010) carried out the research on prediction parameters of mining subsidence by using 3D laser scanning data and got the parameters of major influence angle and the offset distance of inflection point. Meng Wanli, Cai Lailiang, and Yang Wangshan. (2017) made a profile analysis for the 3D view of the surface subsidence using 3D laser scanning data and put forward a “Geomagic” method of surface subsidence prediction."

Jan 1, 2018

By B. Gorain

"INTRODUCTION The last few decades have seen some remarkable advancement in information technology, but recently various digital technologies have resulted in several synergies to deliver innovation in diverse applications. The mining industry has been relatively slow in adopting these technologies compared to the other industries, but this scenario is changing fast. Keywords: Digital Transformation, Operational Intelligence, Gold Recovery, Mine to Mill integration, Planning and Execution strategy, Theory of Constraints. Challenges Mining companies globally are going through a series of challenges such as declining ore grades with complex metallurgy, increasing depth of ore bodies, high capital and operating costs, lower productivity, shortage of technical resources, significant pressure from stake-holders to deliver, along with growing environmental and corporate social responsibility issues. Improvement in profitability would need significant improvements in operational performance. Consequently, over the last few years, there has been a major focus amongst some mining companies to imbibe Operational Excellence. This has been only possible because of the replacement of a silos based approach by an integrated view of the organization. Such an integrated view is now possible via the evolving digital technologies. Even so, such a transformation calls for a change in culture, which, for most organization is not trivial. Attempts in the past to integrate functions such as through Mine-to-Mill initiatives in the mining industry have demonstrated significant benefits to many operations (McKee, 2013). Still, sustaining these benefits has clearly been a challenge due to manpower turn over and lack of proper systems and structures that integrate information between business functions within an operation and between operations and the corporate.Opportunities The advent of digital technology has opened-up opportunities to integrate inter-departmental information for a unified understanding of, and across, an entire organization. The advances in instrumentation, equipment control systems, supervisory control systems (SCADA/Historian) and industrial networks have helped in the direction of enterprise wide integration. The availability of real time information across an enterprise has given rise to numerous possibilities to improve organization performance. As suggested by Seshan & Gorain (2016), some of the potential opportunities are as follows:"

Jan 1, 2018

By Roberto Galéry, Braz J. C. Filho, Marcelo M. Stopa, Douglas B. Mazzinghy, Priscila M. Esteves

"The purpose of the research is to monitor ball mill filling by means of signals usually measured in its electrical drive. The method is based on the mill torque estimated from rotor speed and induction motor stator voltage and currents. New signal processing is presented in both time and frequency domain for measurements in a dry laboratory ball mill. Statistical analysis is applied to time series resulting in good correlation to mill filling. Fast Fourier Transform (FFT) and power spectral density (PSD) also resulted in an accurate filling indicator. The proposed method does not need any sensor to be installed directly on the mill and requires only sensors usually available for motor control purposes. The experimental results showed that the method have potential to be used to construct an automatic system for monitoring operational variables in ball mills. The aim of this monitoring is to improve energy efficiency, reliability and productivity.INTRODUCTION Recently, a great number of papers have pointed the importance of ball mill filling monitoring and also of grinding control (Lu, et al., 2014) (Ramasamy, et al., 2005) (Tsamatsoulis, 2014) (Zhou, et al., 2009). Additionally, great amount of control techniques have also been presented with several complexity degrees (Tsamatsoulis, 2014). According to Eremenko (2015) the lack of effective and accurate methods for fill level measurement is the main reason that makes mill optimal control so complicated. It happens because nonlinearity, long time delay and time varying features of the ball mill turns difficult to develop a truly efficient method for monitoring filling. At the same time, fill level has a determining role in charge motion and consequently on particle breakage. For low levels of filling many energy is expended in impacts with very low breakage efficiency. Those impacts can also damage mill liner. In contrast, high levels of filling causes damping effects that reduces breakage and can also affect energy consumption. Based on this it is conclusive that fill level measurement of ball mills is an important issue for grinding efficiency. This fill level information can be used for operators to control ball mills and also for engineers to run simulations and improve confidence levels of circuit designs (Shi, 2016)."

Jan 1, 2018

By Hong Zhong, Shuai Wang, Zhanfang Cao, Ting Dai

"Manganese is widely used in industries such as the steel industry and is now an essential element in modern industry. Technologies for the efficient and clean utilization of manganese resources must be developed and employed to ensure the sustainable growth of the manganese industry. Our research focuses on the use of beneficiation technologies to improve the grade of ores or the replacement of low-grade manganese carbonate ores with high-grade manganese oxide ores, and thus, to reduce reagent and energy consumption and the yield of electrolytic manganese residues from metallurgical processes; the study of leachate purification technologies; the study of electrochemical behaviors during electrolysis and energy-saving electrolysis methods; the development of chromium-free passivators as alternatives to the highly toxic potassium dichromate passivator; the non-hazardous treatment and resource utilization of electrolytic manganese residues and other manganese by-products; and the development of new manganese products. INTRODUCTION Manganese is widely used in the steel industry, nonferrous metallurgy, the chemical industry, electronics, batteries, agriculture, etc. Globally, more than 90% of manganese is consumed by the steel industry, and thus, it is said that ""No steel industry without manganese""(Banerjee et al. 2017, Zhang et al. 2017). Current manganese resources mainly include manganese ores, marine manganese nodules and waste catalysts. The total global output of manganese ore from land deposits is 18 million tons (metal volume), and the reserves, most of which is in the form of manganese oxide ores, are estimated to be 620 million tons (metal volume). More than 400 manganese ore deposits with a total reserve of 1.22 billion tons have been discovered in China. These deposits are predominantly manganese carbonate ores. Marine manganese nodules exist on the surface of the deep seabed at depths of 2000-6000 m. These nodules, which are also called polymetallic nodules, manganese balls, manganese aggregates and manganese tumors, are mainly composed of iron and manganese oxides. The total reserves of these resources add up to more than 3 trillion tons. Furthermore, the manganese in manganese-containing catalysts can be recycled after they become inactive."

Jan 1, 2018

By I. A. Podkamennyi, O. E. Kovalchuk, G. P. Dvoychenkova

"Using the methods of electron microscopy and IR spectroscopy, mineral components in the run-of-mine kimberlites and on the surface of diamonds were identified. The mechanism and sequence of mineral formation on the surface of diamond crystals were established. Systematization and classification thereof were undertaken for the first time ever.INTRODUCTION The high content of diamonds sized -5 mm in the kimberlite ores of Western Yakutia determines their processing depth in the size class 0.5 mm and finer [1, 2]. These diamonds are recovered by grease and froth separation based on the natural hydrophobic properties of the crystals. When refractory altered kimberlite ores are fed into the industrial process, the performance of grease and froth separation of the diamond ore greatly deteriorates. [4, 10, 15, 17]. Altered kimberlites are known to contain up to 90% of secondary minerals. This reduces by up to 40% the recovery of diamonds by grease and froth separation. [6].Diamond crystals from the grease and froth separation tailings were investigated. On the surface of the examined diamonds, hydrophilic mineral formations were identified, responsible for reduced recovery by physicochemical separation methods [3, 12, 18]. The aim of this study was to identify and describe the relationship between the composition of kimberlite ores and mineral formations on the surface of diamond crystals in order to systematize, classify, and then develop methods of removal in grease and froth separation processes. MATERIALS Following materials were examined in this study: - kimberlites of various material composition, - resulting slimes, - diamond crystals from kimberlite ore processing products."

Jan 1, 2018

By V. F. Bannikov, A. P. Kozlov

"The purpose of this study was to develop a theoretical and technology framework for designing new combined technologies for processing tailings containing non-ferrous and noble metals using dry separation. The main goals of the study were: identifying the distribution patterns of valuable components in various fractions in dry separation processes; examining the patterns identified for different types of non-ferrous and noble metal tailings; developing a theoretical and technology foundation for the development of innovative technologies for the efficient processing of tailings with minimal process water consumption. To examine the possibility of efficient recovery of valuable components from refractory tailings using dry separation, an experimental laboratory unit was designed and built, composed of novel or modified lab equipment: plasma unit for increasing the magnetic susceptibility of Fe - containing minerals; magnetic separator supporting isodynamic and polygradient fields; pneumatic separator for the dry separation of finely dispersed mineral mixtures; dielectric separator using the resonant frequency of the electric field. The laboratory unit supports various modifications and combinations of the lab equipment. The experimental studies led to the development of a unified process scheme for lab tests of mature and non-ferrous smelter tailings using dry separation methods.INTRODUCTION The huge amount of waste from mining and processing of mineral resources Russia inherited from the extensive use of mineral resources in the Soviet Union and amount of waste continue to grow. Often the content of valuable non - ferrous, rare and noble metals in waste exceeds the balance contents in natural ores of the developed deposits. The availability of a rich scientific reserve for the creation highly effective innovative technologies for waste processing determines the necessity of the acceleration in the resolution of problems of the complex assessment, capitalization and involvement in the processing of technogenic resources in Russia (Chanturiya and Kozlov, 2014.)."

Jan 1, 2018

By M. Holuszko, I. Mikhalev

"Previous studies described by Galvin et al. (2017) have shown that for Australian bituminous coal fines, both in batch and in continuous process, the new improved oil agglomeration procedure based on the use of high-internal-phase (HIP) emulsions, as compared to the conventional “pure oil” agglomeration process, enables a significant reduction in the amount of oil while reaching a high yield of clean coal (approximately 90% of agglomerates greater than 355 µm in size) in a significantly shorter time. The HIP emulsion used in these experiments comprised up to 95% vol. aqueous solution of sodium chloride (3% wt. concentration) and for the rest, a mixture of kerosene (oil) and sorbitan monooleate (SMO emulsifier) in a 1:1 ratio as a binder. This study evaluates the applicability of the new HIP-oil agglomeration process to treat Canadian bituminous ultra-fine coal and Russian sub-bituminous coal fines and compares results from agglomeration to the flotation response of both coals. Oil agglomeration is known to be sensitive to surface properties of coal. Since surface properties of coals depend not only on the rank of coal but also on their origin (depositional environment) and mineralogical composition, both the applicability of this new improved agglomeration process to the non-Australian coals and its efficiency became the motivation for this study. To evaluate the applicability of the new process to both Canadian bituminous and Russian sub-bituminous coals, a series of bench-scale tests were carried out under conditions similar to those described by van Netten et al. (2016) for the Australian coals. Based on the results obtained in this research, new boundary conditions for the application of the HIP emulsion-based oil agglomeration process have been outlined and conclusions on the viability of the new process to treat ultra-fine coal from Western Canada and Russian sub-bituminous coal fines have been reached.INTRODUCTION In most cases, to meet the market requirements, the mined coal has to be processed to reduce the ash content by the removal of mineral matter and thus to increase the quality of the coal products (van Netten et al., 2016). Generally, flotation is used for processing fines from high rank coals; however, there are high losses of very fine coal due to the inefficiency of this process. Furthermore, difficulty in dewatering the fine coal results in excessive moisture levels causing coal handleability issues, which increases costs in the coal-cleaning industry (Capes & Darcovich, 1984). Much of the development that has occurred in fine coal cleaning has taken place with higher-value coal, often metallurgical (Klima et al., 2012). If the fine coal is deemed to be too difficult or expensive to process, it may be discarded as waste (van Netten et al, 2014). Such disposal not only creates an environmental liability but may also result in the loss of a valuable, high quality product that is better liberated than the coarser fractions of coal."

Jan 1, 2018

By M. C. Harris

"In the flotation process the contact angle is an important indicator of the hydrophobicity of a mineral particle. There is considerable literature showing that the contact angle increases when the chain length of the alkyl group associated with the collector molecule used to render the valuable mineral particle hydrophobic increases. The extent to which an alkyl group interacts with surrounding water molecules is quantified thermodynamically by the excess Gibbs energy. In the present paper it is shown that there exists generally a strong linear relationship between the excess Gibbs energy of the alkyl group associated with the collector and the contact angle. The structure-activity of such alkyl groups is in turn related to the total surface area, molecular volume, the molar volume, molecular weight of the functional groups in the molecule and interaction energies. It is proposed that the demonstrated relationship is indicative of the role which the alkyl group component of the collector, which is attached to the mineral particle, plays in increasing the extent to which water molecules at the surface of the mineral are rejected from the surface thus increasing the contact angle. The relationship between excess Gibbs energy and surface tension is further explored with a view to relating the observations quantitatively to the parameters in the Young equation.INTRODUCTIONThe issue of wettability of materials is of great importance to many industrial applications. Wettability studies usually involve the measurement of contact angles which indicate the degree of wetting when a solid and liquid interact. As is well known the contact angle (O) is the angle between planes tangent to the surfaces of the solid and the liquid at the wetting perimeter which is the zone where the air, water and solid phase merge. When the air bubble attaches to the solid surface there is an increase in the air/solid interface area and a decrease in the solid/water interface area. For attachment to occur the cosine of the contact angle should be less than 1 and this will be promoted if the interfacial surface tension between the air and the solid (? SV) is low. Classically the relationship between these parameters has been expressed through the Young equation (1) for a perfectly flat surface:"

Jan 1, 2018

By P. Knüpfer, B. Babel, M. Rudolph, F. Perez Maldonado, U. A. Peuker, L. Ditscherlein

"In heterocoagulation processes for the separation of mineral particles, the most famous being froth flotation, the main characteristic of separation is a differing wettability of the constituents to be separated. This most crucial property in the economically important process of flotation is often only and incompletely, quantitatively described in terms of contact angles against water. A water contact angle larger than 90° is referred to as hydrophobic and hydrophilic vice versa. Looking at Young’s equation shows that it is actually the surface energy of the solid in interaction with the surrounding phases and their surface energies (or surface tensions for liquids) which describes whether there will be hydrophobic/hydrophilic hydration interactions leading to attraction or repulsion. This, we have previously published for various more or less hydrophobic minerals in correlation to their flotation response, i.e. flotability (c.f. Rudolph & Hartmann, Coll.Surf.A 513, 380-388). In the same paper we also discussed the heterogeneity of wettabilities as assessed with the novel method of inverse gas chromatography. Furthermore we have also reported on hydrophobic force distributions as assessed with atomic force microscopy which are as well due to wettability heterogeneities (c.f. Fritzsche et al., Coll.Surf.A 459, 166-171).In this paper we present wettability distributions of different substrates and particles with various surface roughnesses/shapes and degrees of hydrophobization as assessed with iGC, AFM and dynamic sessile drop analyses. We are putting the results in context in unifying models and present methodologies helpful to make use of the fundamental information and their impact on the actual industrial separation process in fundamental process models. Besides froth flotation we also emphasize the impact on selective hydrophobic flocculation process."

Jan 1, 2018