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By Daniel Stevenson, Richard Guenther

"The preservation of historic buildings is not only essential to the understanding of our national heritage, but it is also environmentally responsible to adapt existing buildings to compatible new uses. With this perspective, the American Enterprise Institute began exploring options to expand the newly acquired Andrew Mellon Building, located at 1785 Massachusetts Ave. NW in Washington, D.C., without causing any harm to the Beaux Arts style limestone façade and its plaster interiors. The building is a National Historical Landmark, but its 72,000 sq ft (6,690 sq m) of usable floor space did not meet the needs of its new owner. The building perimeter is very near the property line, so horizontal expansion was not possible. Adding height to the building was not an option, as this would have altered the historic nature of the building exterior. The only feasible option that could provide the desired floor space was to add a new floor underneath the existing structure. By adding a level beneath the existing building, an additional 28,000 sq ft (2,601 sq m) of floor space could be produced.Berkel & Company Contractors was chosen as the deep foundation/shoring contractor tasked with ensuring that the existing structure was stable and remained undamaged during the excavation and construction of the new lower level. To accomplish this, Berkel provided a shoring system that would act as both excavation support and permanent deep foundation elements for the final structure.Preservation of the existing limestone façade and plaster interiors was critical to the success of the project, as additional foundation settlements could damage these irreplaceable building components. Project specifications, therefore, included very stringent limits for foundation settlements. The maximum allowable total settlement for all existing building walls and columns was ¼ in (6 mm) for the duration of the project."

Jan 1, 2017

By M. A. Gomez, V. Yahorava, J. A. Strauss

"It is accepted widely that pressure oxidation (POX) is the most appropriate technology for processing of arsenic containing refractory gold ores. However, studies on the stability of various iron-arsenic precipitates formed during POX are limited. Since the behaviour of these phases could have significant practical implications for gold processing plants, it is important to study them in isolation. This paper compares two synthetic precipitates, basic ferric arsenate sulphate (BFAS) and basic ferric sulphate (BFS) in terms of their formation, behaviour during hot curing and cyanidation, as well as their environmental stability. BFS and BFAS were synthesised hydrothermally at 205°C and their mineralogy was confirmed using various techniques. During synthesis, the addition of H3AsO4 into an aqueous Fe2(SO4)3-H2SO4 mixture significantly decreased the iron yield to BFAS in comparison to BFS under equimolar initial iron and acid concentrations. The BFAS dissolution kinetics was slightly faster, as compared to BFS, during subsequent hot curing. Cyanidation test work on the washed synthetic precipitates indicated that the lime consumption of BFAS was three times lower in comparison to BFS, while cyanide consumptions were comparable. Fresh BFS and BFAS precipitates, as well as their cyanidation residues, were found to pass the respective environmental tests in terms of arsenic release.INTRODUCTION Pressure oxidation (POX) is generally viewed as the most appropriate technology for the processing of arsenic-containing refractory gold ores due to the stabilisation of arsenic in the leach residue (Dutrizac & Jambor, 2007; Gomez et al., 2008; Harris, 2003; Collins, Berezowsky, & Weir, 1988). Detailed laboratory studies indicated that several Fe(III)-arsenate type compounds may be formed under typical conditions of autoclave treatment of refractory gold ores (Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2010; Gomez, Becze, Cutler, & Demopoulos, 2011). The basic ferric arsenate sulphate (BFAS) phase (Gomez et al., 2008), also known as Type II ferric arsenate (Swash & Monhemius, 1994) or Phase 3 (Dutrizac & Jambor, 2007), is one of the most common arsenic-bearing products (Harris, 2003; Dutrizac & Jambor, 2007). BFAS precipitation is viewed as one of the best routes for arsenic stabilisation and performed equally well to scorodite during environmental stability tests (Harris, 2003; Swash & Monhemius, 1994; Dutrizac & Jambor, 2007; Gomez et al., 2008, 2011)."

Jan 1, 2017

By A. J. Monhemius

"This paper reviews the history of modern iron-control processes in hydrometallurgy. Attention is paid to processes developed in the electrolytic zinc industry for removal of iron from zinc sulfate leach liquors and the problems faced by the industry in the safe disposal of the iron residues produced by these processes. Past lessons learned are projected onto current efforts to develop hydrometallurgical processes for treatment of copper sulfide concentrates. It is argued that any attempt to create a “hydrometallurgical copper smelter” will fail, unless methods are developed that can recover iron in a form that can be directly used by the steel or pigment industries.RÉSUMÉ Cet article passe en revue l’histoire des procédés modernes de contrôle du fer en hydrométallurgie. Il accordera une attention particulière aux procédés développés dans l’industrie du zinc électrolytique pour l’élimination du fer dans les liqueurs lixiviantes de sulfate de zinc anhydre, ainsi qu’aux problèmes rencontrés par l’industrie en termes d’élimination sans danger des résidus ferreux générés par ces procédés. En projetant les leçons tirées du passé sur les efforts actuels, on pourra développer des procédés hydrométallurgiques pour le traitement de concentrés de sulfure de cuivre. Beaucoup prétendent que toute tentative de créer une « fonderie de cuivre hydrométallurgique » échouera à moins de développer des méthodes permettant de récupérer le fer sous une forme pouvant directement être utilisée par les industries sidérurgique ou des pigmentsINTRODUCTIONThis paper resulted from an invitation to the author from the CIM’s Historical Metallurgy Committee to give a presentation on the early developments of iron control in hydrometallurgy. This was to take the form of a plenary lecture at the 4th Symposium on Iron Control in Hydrometallurgy, which formed part of the 28th International Mineral Processing Congress, held in Quebec City in September 2016.I was naturally flattered that the invitation was to give the lecture at an IMPC, the prestigious conference series that has been held since the 1950s. That this particular IMPC was to include the 4th Symposium on Iron Control in Hydrometallurgy, a conference series held only every 10 years, made the invitation even more appealing and appropriate. This was because I had been co-chairman of the First Symposium on Iron Control, together with my erstwhile colleague, John Dutrizac, which was held 30 years ago in Toronto."

Jan 1, 2017

By M. R. Khalesi, Y. Kianinia, A. Seyedhakimi, F. Soltani

"The feed ore to Agh-Darreh gold processing plant (Takab City, Iran) contains 2 ppm Au, 7 ppm Ag, and 120 ppm Hg. After cyanide leaching of the feed at pH 10.4, 80% of the total mercury (in the form of cinnabar and metacinnabar) goes to the tailings dam. In this research, separation of mercury from the tailings by flotation was investigated. The effects of collector type and dosage, pH, and the number of cleaner stages were studied. The results showed that after two stages of cleaning a 40–62% recovery of Hg at a grade of 14.3% Hg is attainable. Recycle water from a test in which 50 g/t amyl xanthate and 30 g/t pine oil was used in the flotation stage showed no adverse effect on the leaching and adsorption of gold onto activated carbon.IntroductionMercury, most commonly found in the nature as the mineral cinnabar (HgS), is a hazardous substance because of its mobility and toxicity (Kyle et al., 2012). Roasting is the wellestablished treatment method for mercury ores, in which the sulphur is burned and volatilized and mercury recovered subsequently by cooling and condensation. However, for low-grade ores, flotation is mainly applied for primary concentration due to its comparatively low costs, low environmental hazards, and flexibility regarding feed variations (Bulatovic, 2007). Particularly, cinnabar can be easily recovered by flotation using pine oil and a collector such as xanthate (Bulatovic, 2007; Crozier, 1991). Floatability of cinnabar is reduced due to surface oxidation when it is exposed to the atmosphere after crushing. This problem can be eliminated by adding copper sulphate and lead nitrate or acetate. The best pH for cinnabar flotation is in the range of 6.5 to 8.5 according to Erspamer and Wells, (1954), who reported that cinnabar and stibnite can be floated with long-chain xanthate collectors and an alcohol frother, with cumulative recoveries of 97.8% and 94.7%, respectively. Lead acetate was used as an activator."

Jan 1, 2017

By O. M. Arafat, J. A. Finch

"The Functional Performance Equation calculated from a plant grinding survey defines two distinct ball mill circuit efficiencies and how they relate to total production rate through the target grind size. The survey data are also used to calculate a complete ball mill size distribution model, represented by the energy specific grinding rates, not just through the target grind size, but through all the size classes. Cyclone separation performance is represented by individual size recoveries to underflow. When these two unit operation performances are entered into the circuit modelling program (Streamline™), along with the circuit feed rate and size distribution, all the circuit survey size distributions and mass flows are perfectly regenerated by the program. The many issues associated with the historical Epstein (breakage-selection) models are eliminated. Once the circuit program is populated, pump and cyclone performance changes can be evaluated using a step-by-step procedure in order to maximize Classification System Efficiency. Mill water use and media sizing opportunities are also diagnosed in order to maximize Mill Grinding Efficiency at the size of interest. An example is provided. This circuit analysis and modelling system, and related training, is provided through a web-based application.IntroductionSince its development (McIvor, 1988), the Functional Performance Equation for ball milling has facilitated new understanding of industrial circuit cause and effect relationships, leading to significant strides in operational performance. Success stories of this refreshing approach to plant circuit performance improvement are now too numerous to list. Finch and McIvor (circa 1986) also discovered that the Functional Performance “Mill Grinding Rate” at the size of interest was the same cumulative grinding rate that is calculated from mill feed and discharge size distributions using a first-order rate equation. By calculating these cumulative grinding rates for all screen sizes, a complete ball mill model is generated (as used by Finch and Ramirez, 1981). Others in industry, Hinde and Kalala (2009), for example, have noted the same. Lacking the complexity needed to maintain their interest, most researchers have ignored this model, broadly opting instead for Epstein’s (1948) characterization of grinding as a chemical reaction, combining “selection rate” and “breakage size distribution” functions. The much simpler ball mill model presented here has previously been incorporated into a proprietary circuit modeling program (McIvor, 2005) and used for plant improvement work (for example, see McIvor and Finch, 2007, and McIvor, 2014). Now, by combining this extremely business-friendly ball mill model with optimization criteria from Functional Performance Analysis, a circuit modeling system (including the needed supplementary steps to assure successful plant implementation of circuit design changes) is at the disposal of every plant metallurgist, grinding equipment/material provider, and circuit designer."

Jan 1, 2017

By Alessandro Bertero, Dylan Pearson, Wesley Schmutzler, Matteo Bertoni

"The SR 83/US 331 highway is located in the Florida panhandle, where it connects the Walton County beaches to the I-10 corridor. The roadway is of vital importance to the economy of the area as well as its safety since it represents the primary hurricane evacuation route from southern Walton County. The Florida Department of Transportation (FDOT) decided to increase the number of traffic lanes from two to four and improve the geotechnical properties of the moderately deep, very loose foundation soils, that had affected the highway rideability for years. The soil mixing was selected as the method to meet the unique deep ground improvement challenges of the project. The design required that Shallow Mixing Method (SMM) be used to build a 10-foot thick platform that transferred axial load to the bottom soil layers through a series of Deep Mixing Method (DMM) columns. Upon completion over 8,300 SMM columns and 1,500 DMM columns had been installed, with no remedial work required. Also, only 1% of the almost 1,500 specimens tested did not meet the specification requirements. This paper will describe the challenges encountered and provide valuable information that may be useful for other future projects, including details not previously published.INTRODUCTIONThe counties of Walton and Okaloosa have been a very popular vacation destination for many ears. The 50-mile long coastline boasts beautiful, sugar-white beaches and waters the color of emeralds. The popularity of the area has been growing even further, over the last few years. A consequence of this phenomenon is a fast-paced increase of the traffic flow on the SR83/US331 highway, especially at the bridge that connects the Walton County beaches across Choctawhatchee Bay (Fig. 1) to the heavily traveled I-10 corridor. The highway plays a very important role for the area also as a commercial link and as the primary hurricane evacuation route from southern Walton County. The increase in traffic has produced higher travel time, when not a complete traffic paralysis, and exacerbated the issue of ground settlement where accelerated wearing of road foundation occurred due to the presence of very loose, moderately deep, soils, that had afflicted the highway for several years. The Florida Department of Transportation (FDOT) decided to put an end to these issues by increasing the number of traffic lanes from two to four and improving the geotechnical properties of the foundation soils. The Design-Build Maximum Price Request for Proposal (RFP) issued for the expansion of the Choctawhatchee Bay Bridge saw the participation of numerous D/B teams which produced various technical solutions. Among them, the FDOT selected the Skanska/Parsons Brinckerhoff (General Contractor) proposal which provided for the use of soil mixing as the ground improvement technology. The design/build team assigned Foundation & Geotechnical Engineering (Designer of Record) the ground improvement design which Treviicos South (Specialty Contractor) would execute."

Jan 1, 2017

By O. A. Ojo, N. Esmaeili

"The effects of brazing and use of composite powder mixture as interlayer material on hot corrosion resistance of brazed IN738 superalloy were studied. Brazing was observed to result in significant reduction in the hot corrosion resistance of the superalloy. However, application of composite powder mixture, which consists of additive superalloy powder, enhanced the hot corrosion resistance of brazed samples. It is also found that although the use of composite powder mixture increased hot corrosion resistance of brazed alloy, if the additive powder completely melts, which is possible during brazing, it can significantly reduce the hot corrosion resistance of the brazed joint. Elemental micro-segregation during solidification of the joint with completely melted powder mixture produces chromium depleted zones and consequently reduces hot corrosion resistance, since a uniform distribution and adequate chromium concentration is necessary to combat hot corrosion. This has not been previously reported in the literature and it is crucial to the use of composite powder mixture for enhancing the properties of brazed superalloys.INTRODUCTION Superalloys have been developed in response to the increasing demand for materials with higher resistance to corrosion and creep and also with higher mechanical strength at higher temperatures (Smith, 1981). Ni-base superalloys are predominantly used in manufacturing hot sections of gas turbine engine components. This is due to their high strength and corrosion resistance in extremely high temperature service environments which is typical for hot sections of gas turbine engines (Miglietti, 2009). The continuous demand for higher efficiency and output has resulted in the use of higher operating temperatures and gas pressure in modern gas turbine engines (Jahnke & Demny, 1983). Consequently, this has caused thermal and mechanical stresses which result in severe degradation and damage of gas turbine engine components due to creep, fatigue and hot corrosion (Zhang, Feng, & He, 2006). The decision to replace or repair damaged parts depends on the overall repair cost and expected life of the repaired components (Jahnke & Demny, 1983). However, in most cases, it is more cost effective to repair damaged parts rather than use a full replacement."

Jan 1, 2017

By Kodi Ranga Swamy, N. Sankar, M. Akhila

"Until recently, liquefaction-related studies concentrated on clean sands believing that only sands are susceptible to liquefaction. However, a few earthquakes like 1976 Tangshan earthquake, the 1989 Loma Prieta earthquake, the 1999 Kocaeli earthquake, the 2010 Chile earthquake, and the 2011 Christchurch earthquake, etc. showed that sand with fines could also liquefy. The research findings on liquefaction of silty soils are limited, and several structures constructed on such soil deposits are damaged during the past earthquakes. Some previous results of research on earthquake events show an increase of liquefaction resistance in silt soils with increase the fines content, but some report the opposite trend. This study presents the results based on undrained triaxial cyclic tests which were carried out on the fine sand with fines (0%, 10%, 20% and 40% fines). The samples were prepared at the required unit weight (Dr = 50%) and saturated by using back pressure and cell pressure increments. Each consolidated sample is subjected to cyclic loading with sinusoidal wave load form at a frequency of 1 Hz. The liquefaction resistance is evaluated in terms of cyclic stress ratio required to cause 100% pore pressure or 20% failure strain occur at 15 numbers of load cycles. Results are presented in forms of pore pressure build up and axial strain propagation plots. As the fines content increased, an increase in liquefaction potential was observed.INTRODUCTIONLiquefaction and related phenomenon have been responsible for tremendous amounts of damage all around the world. In general, the liquefaction may occur in fully saturated sands, silts and low plastic clays. When the saturated soil mass is subjected to seismic or dynamic loads, there is a sudden buildup of pore water within a short duration, and it could not dissipate which leads to reducing the effective shear strength of soil mass. In this state, the soil mass behaves like a liquid and causes large deformations, settlements, flow failures, etc. This phenomenon is called soil liquefaction. As a result, the ability of soil deposit to support the foundations of buildings, bridges, dams, etc. is reduced. Liquefiable soil also exerts a higher pressure on retaining walls.This lateral movement of soil could cause settlement of the retained soil. A sudden build-up of pore water pressure during quake also triggers landslides. Liquefaction damages of structures are commonly observed in low-lying areas near the rivers, lakes, and oceans."

Jan 1, 2017

By Brian M. Fraley

"Portions of the Catholic Total Abstinence Fountain in Fairmount Park in Philadelphia, Pa., were in “imminent danger,” according to a restoration services request for proposals (RFP) issued by the City of Philadelphia in August 2014. Open voids in the subsurface beneath the foundation were causing ongoing settlement of the fountain.The fountain was unveiled in 1876 as an ornamental drinking fountain for the Centennial International Exhibition, which celebrated the signing of the Declaration of Independence. Its creation was commissioned by the Catholic Total Abstinence Union of America, an Irish temperance organization that advocated for total abstinence from alcohol. Ironically, the fountain ran dry decades ago.The now-defunct fountain features a 100 ft (30.5 m) wide granite base with three steps in the shape of a Maltese cross. The centerpiece — enclosed by a 40 ft (12.2 m) diameter basin — is a 15 ft (4.6 m) tall statue of Moses perched atop an iglooshaped marble mound. Four subsidiary statues rise from granite pedestals at the tips of each arm of the cross, including Archbishop John Carroll, Charles Carroll of Carrollton, Father Theobald Mathew and Commodore John Barry.Natural and Man-Made DamageThe City of Philadelphia’s RFP called attention to three “high priority structural areas.” It was noted that Moses, Father Mathew and the steps surrounding the fountain had been documented as public hazards. The long-term effects of water infiltration had set in, eroding mortar joints and causing some stones to jut out. Furthermore, the stone base supporting the 16 ton (14.5 tonne) statue of Moses was in danger of collapsing. The statue of Father Mathew had been struck by lightning in 1910 and was repaired with an iron and metal pin anchor system, which had succumbed to corrosion. The city considered the statue of Father Mathew as the most threatened of the statues. Mike Miluski, P.E., vice president of Compaction Grouting Services (CGS), recalled “the fountain was in pretty bad shape” as he walked onto the site in August 2016 and immediately recognized the challenges ahead."

Jan 1, 2017

By Rouzbeh Vakili, Adel M. Hanna

"The application of piled raft foundations has significantly increased during the last few years. In this system, the raft and the pile group collectively transfer the applied building load to the underlying soil layers. Determination of load sharing between the raft and the piles derives the complexity of piled raft designs due to its multi-parameter nature. These parameters are but not limited to: soil density, pile length, pile spacing, raft geometry, and piles installation technique. This study is to examine experimentally the effect of sand density and pile installation techniques on the load sharing mechanism. Experimentally, tests were conducted on a square rigid raft with a single pile in sand under three different soil densities; 30%, 45%, and 60%. The experimental results are used to determine the pile and the raft shares in non-displacement and displacement piled raft systems. The results of this study reveal that soil density changes the load sharing of displacement piled raft; the pile share increases in higher soil density. However, this is not the case in non-displacement piled raft and load sharing is independent of soil density in working loads.IntroductionThe piled raft foundation is a combination of shallow and deep foundation which transfers the superstructure load to the soil by a complex soilstructure interaction. The interacting mechanism among foundation elements and their surrounding soil is illustrated schematically in Figure 1 and could be classified into two categories: (1) pile-soil-pile and (2) pile-soil-raft. The pile-soil-pile interaction is the same as the free standing pile group and is a function of pile spacing and pile installation method. Pile-soil-raft interaction, which only involves in piled raft foundation design, could be affected by: the length, spacing, and roughness of the pile, the rigidity and dimension of the cap, soil condition, and the pile installation method. Pile-soil-raft interaction could have favourable and unfavourable effects on bearing capacity and settlement, respectively. The pressure between the cap and the soil favourably increases the horizontal stress on the pile shaft and consequently increase the shaft resistance. Whereas, this pressure induces negative skin friction on the piles which increases the settlement. The pile-soil-raft interaction mainly controls the load sharing mechanism of piled raft foundation when pile spacing (S) is more than 3.5dp."

Jan 1, 2017

By G. Goodall, M. Muinonen, R. Pandher, R. Jabbar, S. J. Muinonen

"The implementation of a new and highly efficient converting practice at the Glencore Sudbury Integrated Nickel Operations Smelter has opened the possibility to further capacity increases by using larger ladles. To quantify the impact of increasing ladle sizes from 200 to 300 ft3, XPS constructed a detailed discrete event simulation using the commercial software package Rockwell Arena®. The challenges associated with implementing a model on an intricate and tightly scheduled process, and the solutions needed to derive meaningful results will be presented. The aisle capacity is predicted to increase by approximately 17 %, with a reduction in furnace tapping demand of 8 %. Arena modeling capabilities and the key factors contributing to the overall capacity increase at the Sudbury INO Smelter will be reviewed and presented.INTRODUCTION The Glencore Sudbury Integrated Nickel Operations (INO) comprises two Ni-Cu-PGM mines, Strathcona Mill, and the Sudbury Smelter. The Smelter has operated continuously since 1929 using different processes to produce nickel-copper Bessemer matte. Feeds to the Sudbury INO Smelter are a blend of concentrate from Strathcona Mill, Raglan concentrate produced at the mine-mill complex in Raglan, Quebec, as well as third party concentrate feeds shipped to Sudbury from around the world. In 2016, the Sudbury INO Smelter produced 75,900 tonnes of nickel and 20,000 tonnes of copper in Bessemer matte. The product matte is shipped to Glencore’s Nikkelverk refinery in Kristiansand, Norway where it is refined to produce nickel and copper cathode. A schematic of the Sudbury INO Smelter’s flowsheet is shown in Figure 1."

Jan 1, 2017

By David P. Conover, Jake Bain, Christopher M. Ross

"Highwall mining of thick (up to 100 ft) steeply dipping (20° or more) coal seams provides many challenges, both geotechnically and operationally because seam dips near or in excess of highwall mining machine capabilities are encountered. Maximizing coal recovery while maintaining highwall stability requires innovative techniques with regard to web and barrier pillar layout, depth of penetration, and choice of mining horizon within the seam. Stability of highwall mining slopes, openings, and pillars are typically analyzed using the ARMPS-HWM program, as well as LAMODEL, UDEC, and Slope-W modeling. Highwall stability can be maintained and highwall mining production optimized by applying design criteria in creative ways, including alternating miner penetration depths and initiating mining of thick seams toward the bottom of the seam. Highwall mining of thick, steeply dipping coal requires careful planning and execution, including close cooperation between geotechnical design engineers, the mining company, and the highwall mining contractor. This paper describes the application of creative design techniques to a specific pit arrangement at the Westmoreland Kemmerer Mine, Kemmerer, Wyoming. Highwall mining was accomplished by UGM ADDCAR Systems, LLC, on a contract basis. INTRODUCTION Highwall mining is a technique for attaining additional coal recovery after the economic strip limit is reached in surface mining. It involves remote deployment of a continuous miner in openings beneath the final highwall, with no personnel entry. Many candidate areas for highwall mining have thick and steeply dipping seams. Mining downdip presents challenges related to the maximum pulling capacity of the machine, traction of the cutting head, and material conveying, all of which limit penetration depth. Maximum penetration is greater for flatter slopes and decreases for slopes nearing the threshold of the maximum machine operating angle. Most highwall mining operations are relatively flat with slight undulations within the seam; therefore, the highwall mining pillar design criteria applies fairly equally to the entire mining area. However, in steeply dipping deposits, design criteria based on higher overburden loads at the far end of the penetration are excessively conservative for the shallower portions of the openings near the highwall."

Jan 1, 2017

By Ahmad Ghahreman, Denver Cowan, Yeonuk Choi

"Previous testwork by the authors has indicated that both granular coconut shell based activated carbon and a new microporous carbonaceous bead, Lewatit® AF 5, are highly effective in improving the oxidation kinetics and decreasing the elemental sulphur yield when assisting the atmospheric oxidation of pyrite. While the two carbon catalysts show similar results and improvements to the pyrite oxidation, there are differences between them. For example, the activated carbon assisted oxidation showed faster kinetics than the AF 5 assisted oxidation, while elemental sulphur seemed to remain adhered to the surface of the AF 5 after oxidation when much of the elemental sulphur formed during the activated carbon assisted tests was found in the oxidation residue. The objective of this paper is to investigate the differences between the two catalysts through the use of scanning electron microscopy, photography, Raman spectroscopy, surface chemistry analysis, and Brunauer-Emmett-Teller (BET) surface area analysis. With this investigation the authors should be able to achieve a better understanding of the surface chemistry of the two carbon catalysts (i.e. functional groups, charges, acidity etc.) and help explain the strengths and/or the weaknesses of the catalysts when applied to the atmospheric oxidation of pyrite.INTRODUCTION Previous research conducted by the authors, indicated that both a granular coconut shell based activated carbon (activated carbon) and a microporous carbonaceous bead, Lewatit® AF 5 (AF 5), acting as a catalyst enhanced atmospheric pyrite oxidation in ferric sulphate media by approximately 40% when compared to unassisted oxidation and that elemental sulphur yields were increased from 23% to approximately 69 and 63% when assisted by AF 5 and activated carbon respectively (Cowan, Jahromi, & Ghahreman, 2017). The study indicated that although total pyrite oxidation assisted by the two catalysts was similar, differences were noticed in the impact that the two catalysts had on the outcome of the oxidation. Kinetic curves in the Cowan et al. study indicated that atmospheric oxidation of pyrite seemed to reach completion after 48 hours of oxidation when assisted by activated carbon. A similar trend was noticed in the kinetic curves for oxidation when assisted by AF 5, however the oxidation curve did not reach completion until approximately 96 hours (Cowan et al., 2017). This observation indicated that the kinetics of pyrite oxidation are enhanced by both catalysts, oxidation kinetics are much faster when assisted by activated carbon rather than AF 5."

Jan 1, 2017

By Francisco Sena Leite, Raquel Sobral, Vinicius Gouveia de Miranda, Céu Jesus

"The urgent need for improvements in the control and mitigation of environmental and social conditions associated with the extraction and processing of raw materials is increasingly a demand imposed by legal entities and institutions. Therefore, this present article proposes an improvement of the estimation in the magnitude of the vibrations resulting from rock blasting methodologies in the surrounding areas,incorporating the heterogeneity caused by uncontrollable parameters, such as geological andgeotechnical characteristics. This methodology combines the use of empirical vibration attenuation lawscommonly known and with terrain discretization techniques using Voronoi’s decomposition. For thevalidation assessment of this methodology, the data set collected and compiled is composed by 87 vibration measures collected in 16 sample points in one area of study of which 2/3 of the samples were used to create the model and 1/3 for the validation. Using normality tests for statistical residue analysis,it is possible to infer that this present model has null residual mean, as well as a smaller sum of residualerrors. Comparing the methodology present in this paper with the procedures executed nowadays, areduction of the errors associated with the estimation is obvious, highlighting a better characterization of the behavior of the vibrations associated with rock blasting."

Jan 1, 2017

By Z. Jin, D. DePaoli, P. Zhang

"Phosphorite, or phosphate rock, is the most significant secondary rare-earth resource. It contains high amounts of phosphate-bearing minerals along with low contents of rare earth elements (REEs). In Florida, about 19 Mt of phosphate rock are mined annually and most are used to manufacture fertilizers using a wet process, in which sulfuric acid reacts with phosphates to produce phosphoric acid and phosphogypsum. In the wet process, REEs are also leached out into solution and eventually get lost in the leaching residue and phosphate fertilizer. Recovering REEs from Florida phosphate rock in the wet process will be beneficial to broadening rare-earth availability, improving the quality of phosphoric acid product and protecting the environment.This study focuses on the influences of wet-process operating conditions on REE leaching efficiency. The results indicate that REE leaching efficiency increases with phosphoric acid addition in the initial pulp. At a temperature of 75 °C, a stoichiometric ratio of sulfuric acid (H2 SO4 ) to calcium oxide (CaO) of 1.05 and a weight ratio of liquid to solid of 3.5, REE leaching efficiency reached a relatively high value of 52.82 percent. The trends of REE leaching efficiency were similar to those for phosphoric acid (P2O5 ). Extensive tests on the leaching residue showed that during leaching, about 90 percent of the REEs were released from the phosphate rock but only 52.82 percent ended up in the leaching solution. This phenomenon can be attributed to two factors: (1) the effect of phosphate ions (PO4 3-) in the solution, which caused REE ions to form REE phosphates and be precipitated into the leaching residue, and (2) the influence of large amounts of anions such as sulfate (SO4 2-), dihydrogen phosphate (H2 PO4 -) and hydrogen phosphate (HPO4 2-) anions as well as the polar molecule H3 PO4 , which surrounded the REE cations and formed an ion atmosphere that prevented the PO4 3- from contacting and combining with REE cations. Interaction of these two opposite effects determined the REE distribution between leaching solution and residue."

Jan 1, 2017

By P. J. Le Roux

"Mining companies are under constant pressure to reduce their cost structures to sustain profitability. In mines using an open stoping mining method, dilution often has a significant effect on profitability. At Target mine in South Africa, dilution in some open stopes was found to exceed 10%, falls of ground being a major contributor to the problem. This dilution can reduce the recovered grade from 5.5 to 4.5 g/t, resulting in a potential loss of about R21 million per month based on a gold price of R240 000 per kilogram. In addition to the cost of dilution, the cost of damage to, or loss of, trackless equipment as a direct result of falls of ground in open stopes is significant. Other associated costs include transport, hoisting, secondary blasting, milling, and plant treatment of waste material. Stable open stopes are essential in order to reduce falls of ground. Back-analyses of stope instability at Target mine have indicated that conventional rock mass failure criteria are unsuitable for stope design. An alternative strain-based criterion has been developed, and has proved to be very successful, allowing the stability of open stopes to be calculated reliably. Since its implementation in 2010, dilution and equipment damage have decreased markedly, creating value for the mine. IntroductionMines that make use of an open stoping mining method aim to extract only the ore, leaving the waste behind. Many orebodies have well-defined boundaries between the ore and the waste rock. In such orebodies, the introduction of waste into the ore due to overbreak dilutes the grade. In massive disseminated orebodies, dilution is less problematic. Overblasting, falls of ground, or other causes may result in dilution. A study undertaken in Canada (Pakalnis et al., 1995) found that approximately 51% of all underground metal mines utilized open stoping mining methods and, from surveys conducted at these mines, open stoping operations experienced dilutions of up to 20%, and occasionally more. Dilution of this magnitude has a significant economic impact on any mining venture. Research carried out in Australia by Capes (2009) came to the same conclusion."

Jan 1, 2017

By S. H. Amini, A. Noble

"While many classic mineral processing circuit design approaches rely on deterministic methods, numerous studies have shown that the uncertainty inherent to the various input parameters can significantly influence design decisions. In a separation circuit, many of the technical uncertainties can be mathematically represented as statistical distributions for the unit recovery and feed grade. These uncertainties are then propagated by the circuit design and reflected in the circuit performance indicators, such as product grade and global recovery. An effective design strategy entails identifying which units are most influential in this uncertainty propagation and thus merit further consideration. Unfortunately, few analytical tools provide this information, particularly those that rely solely on deterministic methods. However, one promising approach is through the application of Taguchi’s method, in a fashion similar to statistical tolerancing of manufactured products. Since the technical challenges are fundamentally similar, Taguchi’s method shows promise in evaluating the level of compounded uncertainty by various circuit designs while determining the role of each separation stage on the overall selectivity and variability of separation circuits. This paper demonstrates Taguchi’s method in several two and three unit circuit designs. INTRODUCTION AND METHOD DESCRIPTION Uncertainty in Mineral Processing Circuit Design Analysis and estimation of uncertainty propagation in mineral processing separation circuits is an essential and significant aspect of an optimal circuit design procedure. Most of the current circuit design methodologies have been constructed, implemented, and validated using a deterministic modeling approach. However, numerous studies have shown that the inherent uncertainty induced by uncertain design parameters can be a significant factor in many mineral processing applications (e.g. Kraslawski 1989; Xiao and Vien 2003; Ghaffari et al. 2012). Thus, an effective circuit design methodology must be able to quantify uncertainty in separation circuits with limited input data. This paper describes Taguchi’s method, as an experimental design technique, to approximate uncertainty in mineral processing applications, and then the similarity of results between Taguchi’s method and Monte Carlo Simulation is investigated. Monte Carlo Simulation The term “Monte Carlo Simulation” has been used to refer to a variety of stochastic simulation methods spanning a broad array of business, technical, and scientific domains. Most generally, Monte Carlo Simulation refers to numerical analysis which is based on (pseudo) random sampling from a domain of input parameters with a known statistical distribution. This methodology allows one to determine the distribution of expected results from a standard deterministic process model. Execution of a Monte Carlo simulation begins by identifying the domain of input parameters, statistical distributions for each parameter, and a deterministic process model which describes the anticipated result as a function of the inputs. Next, one discrete random sample is taken for each input parameter, considering the input distributions. The process model is then solved for this mix of input parameters, producing a single simulation result. This procedure is then repeated a “large” number of times, utilizing new randomly sampled input parameters for each simulation iteration. Once the desired number of iterations is reached, the results of each independent simulation are aggregated to produce descriptive statistics such as minimum, maximum, mean, standard deviation, kurtosis, and other distribution parameters. Given enough iterations, the Monte Carlo method fully explores potential synergies between the input parameters. The methodology does not require the process model to be differentiable, continuous, or even analytically defined. While the number of required iterations varies in relation to th"

Jan 1, 2017

By T. Joseph, E. Zheng, M. Curley

"Hydraulic transportation efficiency and production optimization are considerations in the surface extraction of Athabasca oil sand deposits. To reduce the dependence on haul trucks, it is possible to extend the hydraulic transport system to production faces using a mobile at-face slurry system (AFSS). The flexible arrangement of connected pipelines transports slurried minerals from the mining face to the processing plant. An experimentally verified mathematical model indicates the friction loss of oil sand slurry associated with the AFSS. Laboratory-scale testing enables extended analyses for examining pipeline slurry transport in an oil sands environment.RÉSUMÉ L’optimisation de l’efficacité du transport hydraulique et de la production sont des considérations importantes dans le domaine de l’exploitation à ciel ouvert des gisements de sables bitumineux de l’Athabasca. Afin de réduire la dépendance envers les camions de transport, on envisage d’étendre le système de transport hydraulique aux fronts de taille à l’aide d’un système mobile de transport des matériaux sous forme de boue à partir du front de taille (AFSS, de l’anglais at-face slurry system). L’organisation flexible des conduites reliées permet le transport de minéraux à l’état de boue du front d’exploitation jusqu’à l’usine de traitement. Un modèle mathématique vérifié de manière expérimentale indique la perte de charge par frottement des schlamms provenant du traitement des sables bitumineux associée à l’utilisation de l’AFSS. Des essais en laboratoire permettent de mener des analyses approfondies portant sur le transport de boues dans des conduites dans un environnement de sables bitumineux. INTRODUCTIONObjectives and scope of studyThe at-face slurry system (AFSS) concept has become a competitive means for materials handling to optimize haulage system efficiency and cost. The mobile and flexible arrangement of the AFSS introduces a unique set of hydraulic transport problems. This paper will focus on developing the mathematical models governing the friction and head losses within the AFSS concept.Background of the problemLarge-capacity shovels and dump trucks are increasingly used for excavation, loading, and hauling in the operation of surface mining. Production cost and efficiency optimization are demanded during the Athabasca oil sands (Alberta, Canada) mining process to secure North America’s energy supply. Increasing haulage distances, rugged terrain, and a constrained mine environment are conditions that will reduce the effectiveness of the shovel-truck haulage system (Frimpong, Szymanski, & Changirwa, 2003). In such conditions, the tire heat index and weight, distance, and time limits for truck haulage can be exceeded, simultaneously creating extreme tire wear and high maintenance costs. In addition to low production cost and equipment effectiveness, a mining environment also requires efficient waste-material recycling and distribution. Waste materials need to be recycled from the processing plant to a new destination such as a tailings dam, or replaced in mined-out areas such as backfill. The Athabasca oil sands configuration and location characteristics result in a mining environment that would benefit from flexible pipelines for constant production and an efficient waste-material recycling process."

Jan 1, 2017

By G. Granata, C. Tokoro, M. Matsuoka, K. Horiuchi

"Given the high demand of copper and the lack of new high-grade deposits, low grade copper ores containing copper oxides and refractory sulfides need to be processed as well. However, in order to recover copper from refractory copper ores, the leaching performances should be improved. In this study, we investigated the effect of the mechanical activation in the leaching of copper from covellite. The influence of a mechanical treatment by planetary ball milling on leaching rate in sulfuric leaching media was evaluated by using X-ray diffraction (XRD), mineral liberation analysis (MLA) and X-ray absorption fine structure (XAFS). Results showed a significant increase in copper leaching from around 50%up to 100% along with an improvement of the leaching kinetics when using planetary ball milling. XRD spectra showed the disappearance of the covellite peak from (101) face, thus suggesting the amorphization of covellite associated with the use of planetary ball milling. XAFS results showed that the coordination number of Cu changed from 6 to 3, thereby confirming the effectiveness of the mechanochemical effect.INTRODUCTIONDuring the last decades, while the copper grade in copper ores has been decreasing, the concentration of impurities such as arsenic tends to increase, thus requiring for the processing of low grade copper ores. For a suitable processing of copper minerals, hydrometallurgical processes are preferable due to the lower costs, the lower environmental impact and the easier implementation (Watling, 2006). However, for an economical recovery of copper, the leaching performances must be improved.Among the recent advancements in leaching technologies, the mechanochemical activation allows for an improvement of the leaching performances by means of high-intensity grinding(Mohammadabad et al., 2016). In the first place, the improvement is the result of the dramatic decrease of particle size, which results in an increase of the mineral surface area and the consequent enhancement of leaching kinetics. Furthermore, the intense mechanical stress due to the high-intensity grinding could induce the rupture of the crystal structure producing a decrease of crystallinity. Such changes of the mineralogical structure, also known as mechanochemical effect, can lead to more leachable mineral, thereby resulting in a greater dissolution of copper. Last but not least, whereas the mineral surface might undergo passivation during leaching, the high-intensity grinding can continuously refresh the surface of the mineral, thus exposing portions of unleached bulk mineral."

Jan 1, 2017

"Large scale open pit mining and quarrying operations dictate safe and reliable pit wall stability. The current approach of employing the particle velocity-scaled charge distance approach to estimate and minimize damage to residential structures is considered inadequate to protect rock slopes. This study utilizes close-in blasting vibration data as input to an advanced 2D numerical code to study its applicability to serve as a predictive tool in terms of blast-induced rock slope failure. Two tri-axial accelerometer stations, consisting of high-frequency and high-amplitude (20 kHz, 100g) sensors, located within ~100m of the blast, but at two different bench levels, were used to monitor a production blasting in a quarry. The production blast consisted of double-decked explosive loads in 155 mm (6 in) diameter holes, with an inter-deck delay of 42 ms, and each deck consisting of 130 kg (285 lb) of emulsionexplosive. The blasting vibration data obtained at the two bench levels were critically analyzed, and thevibration results served as input to the numerical model consisting of a single rock block with a 45 degree persistent joint plane but with specified strength properties, significantly different from that of the intact rock. The model was able to characterise progressive accumulation of damage in the form of micro-cracks along the joint surface as a function of the vibration load from successive explosive decks. The results showed that such a numerical model can serve as a very good diagnostic and predictive tool, when backed up by careful vibration monitoring and further supported by detailed slope monitoring."

Jan 1, 2017