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By R. Amata

"The Gakara Rare Earth deposit in Burundi (East Africa) is unique for its high grade (e.g., 54.3% TREO on average) and low uranium and thorium levels. The majority of the light rare earth (RE) elements in material from Gakara are contained within the familiar RE minerals bastnaesite and monazite. Extensive metallurgical test work was conducted by SGS Minerals Services on mineral samples collected from the Gakara deposit. Various whole ore hydrometallurgical processing routes were examined in a scoping level test program. Preliminary beneficiation testing was also conducted, though it was determined that only marginal upgrading would be achieved with significant RE losses. Thus a hydrometallurgical process on whole ore was developed to minimize the overall process complexity and achieve maximum RE recovery. Results from the test work will be presented, along with the selected base case flowsheet involving agitated atmospheric sulphation of the RE minerals, RE double sulphate precipitation, caustic conversion, redissolution, and carbonate precipitation. Following the base case flowsheet, a purified cerium free mixed RE carbonate with low levels of radioactive elements was produced.INTRODUCTIONRainbow Rare Earths Limited (Rainbow) is a mining company engaged in the exploration and development of the Gakara rare earth deposit in Burundi; Figure 1 shows the project location. The project is located in the Bujumbura Province and 45 km from the Burundi capital of Bujumbura. Notable for its exceedingly high in-situ grade – 54.3% on average total rare earth oxide (TREO), low uranium and thorium levels and familiar rare earth minerals, bastnaesite and monazite – Gakara is the world’s richest rare earth deposit. The project, a previously operating mine from 1948–1978, has a significant mineral inventory base, a long life of mine, well understood mineralogy, and robust economics. Rainbow is focused on bringing Gakara into production in the near term, ramping up to produce 5,000 t/y of a 54%+ TREO concentrate."

Jan 1, 2016

By V. I. Ryaboy, S. A. Kondratyev

"The paper describes influence of desorbed species (DS) of a number of xanthates and higher dialkyldithiophosphates on the collective ability of these reagents. Adsorbed on mineral DS of the reagents in the form of products of non-stoichiometric interaction between xanthates and heavy metal salts can pass to the gas–liquid interface and remove liquid from the layer between mineral particle and water surface. A high-speed video recording displays the process of spreading of DS of xanthates and dialkyldithiophosphates over water at the moment of local rupture of the water layer. Expansion of “dry” spot on the mineral surface after DS of xanthate capture and displace liquid from the layer has been proved with video images. The comparative analysis of collecting ability and dynamic surface activity of dialkyldithiophosphates shows that these characteristics are in good correlation. The forces exerted by spreading film of the reagent’s DS on liquid in the water layer are evaluated, and the water flow rate from the layer is determined. The line of the reduction in thickness of the water layer behind the front of spreading film of DS of dialkyldithiophosphates and xanthates coincides with the line of the increase in their dynamic surface activity. Their force on the liquid volume in the water layer characterizes collecting ability of the DS film of xanthates and dialkyldithiophosphates. It has been supposed that the collecting ability of DS of a reagent is a part of its overall flotation activity, conditioned by surface tension of solution and, thus, defined by the structure of hydrocarbon fragment of the reagent.INTRODUCTIONIt is believed that collecting ability and selectivity of collecting reagents is mainly governed by adsorption of a reagent at the solid–liquid interface. A few studies have shown that activity of collecting reagents at the gas–liquid interface may have deep influence on their collecting capacity and selectivity. Experimental researches have revealed correlation between surface pressure in a carboxylic acid film on liquid’s free surface and floatability of useful components (Kulkarni & Somasundaran, 1975; 1980; Quast, 2006). According to Quast (2006), it is not always that surface pressure of a reagent film influences collecting ability of carboxylic acid. For instance, pH range of adsorption of tetradecanoic acid on hematite does not coincide with pH range of high surface pressure. So, surface properties of this acid contribute little to flotation efficiency.The correlation between reagent film surface pressure and mineral floatability has been reveled for quartz and cationic reagents, too (Bleier, Goddard, & Kulkarni, 1977). Finch & Smith (1973) showed that combination of adsorption of ion–molecular amine complexes on mineral surface and high surface tension of “fresh bubbles” was favorable for flotation performance. The use of bubbles with reduced surface tension resulted in a decrease in quartz floatability."

Jan 1, 2016

By Matthew Grzelak, Gulsah Erinc, David R. Chapman

"The third phase of the Bagram Drainage System project at Bagram Air Force Base in Afghanistan included construction of a shallow, 540-m long, 1.8-m inside diameter drainage tunnel. The tunnel penetrated mostly stiff to hard clayey and silty soils. The contractor’s Value Engineering Change Proposal (VECP) to use pipe-jacking with a microtunnel boring machine (MTBM) instead of the specified two-pass Earth Pressure Balance method was evaluated and supported using hand calculations. Contractor support was provided throughout the project by providing design reviews and instrumentation monitoring during construction. This paper compares the value-engineering proposal to the specified method and describes the construction conditions encountered. INTRODUCTION As part of a larger improvement project at the Bagram Air Force Base in Afghanistan, a shallow, 540-m long, 1.8-m inside diameter drainage tunnel was constructed to provide additional capacity for Coyote Creek to pass below several critical structures, including taxiways and the main runway, for mitigation of recurring flooding (see Figures 1 and 2). Overburden over the tunnel crown ranged from about 3 m to 5.5 m. An existing cast-in-place twin barrel concrete culvert runs approximately parallel to the new tunnel and is within about 8 m at its closest point. The contractor’s Value Engineering Change Proposal (VECP) to the specified two-pass Earth Pressure Balance (EPB) method (steel ribs and lagging or steel liner plate with a carrier pipe later grouted in-place) called for installation of the required drainage pipe by pipe-jacking (one-pass installation) using a slurry microtunnel boring machine (MTBM). The critical nature of the operations at the air base resulted in significant construction coordination challenges and a greater than usual need to avoid excessive settlements. Substantial restrictions were placed on drilling of investigative borings and installing instrumentation near runways and taxiways due to drill mast height. The prime contractor was SERKA TAAHHUT INSAAT A. S. (SERKA), the microtunneling subcontractor was Ludwig Pfeiffer Microtunnel GmbH & Co.KG (Pfeiffer), the jacking pipe designer was Gollwitzer Pipe and Shaft Technology GmbH (Gollwitzer), and the contractor’s tunnel engineer was Lachel & Associates, Inc. (Lachel). Lachel provided contractor support throughout the project including preparation of a VECP/Design Summary (including interpretation of existing and new geotechnical information), design reviews for jacking pipe, estimating settlement of an existing drainage structure above the new tunnel, and instrumentation planning, monitoring, and analysis during construction."

Jan 1, 2016

By S. A. Hosseini, O. Asghari

"The quantification of mineral resources and evaluation of process performance in mining operations at Gole Gohar iron ore deposit requires a precise model of the spatial variability of three variables (Fe, P, and S) which must be determined. According to statistical analysis there are complex multivariate relationships between these variables such as stoichiometric constraints, nonlinearity, and heteroskedasticity. Due to the impact of these complexities in decision-making, they should be reproduced in geostatistical models. First of all, in order to maintain the compositional and stoichiometric constraints, additive log-ratio (alr) transformation has been applied. In the next step cosimulation, using stepwise conditional transformation (SCT) and sequential Gaussian simulation (SGS) has been used to simulate multivariate data. Through statistical and geostatistical validations it is shown that the algorithms were able to reproduce complex relationships between variables, both locally and globally. IntroductionThe key steps in mining projects are the quantification of mineral resources, definition of mining reserves, and production scheduling. They rely on the construction of a block model that is used to represent basically the spatial distribution of ore grades (Montoya et al., 2012). The determination of grades and tonnages affects risk assessment and economic evaluation of mining projects. Evaluation of process performance in mining operations requires geostatistical modelling of many related variables (Barnett and Deutsch, 2012). Iron ore quality is characterized by multiple variables: not only the iron grade but also the contaminants that interfere in the subsequent steel manufacturing processes. Consequently, the spatial variability of multiple variables must be determined. Key variables are frequently correlated, and such correlations must be honoured during estimation and simulation. Data from iron ore deposits constitutes compositional data; furthermore, relationships the between assay data are often heteroskedastic."

Jan 1, 2016

By Dimitrios Litsas, Michael Kavvadas, Panagiotis Sitarenios

"The paper discusses the results of 3D finite element analyses to investigate the effect of face support pressure and soil permeability on face stability conditions in EPB tunnelling. Two main types of face behavior are identified: Undrained conditions ahead of the tunnel face, typically occurring in soils with permeability less than about k=5·10-7m/s, are shown to be favourable for face stability; analyses show that an applied face pressure comparable with the initial hydrostatic pore pressure is sufficient for adequate face stability, even for soils of relatively low strength. Drained or partially conditions, typically occurring in soils with permeability higher than about k=5·10-6m/s, show that face stability is strongly dependent on the horizontal effective stress of the muck in the excavation chamber; the presence of even a small effective stress in the muck is very beneficial for face stability conditions and can be a possible explanation of successful EPB tunnelling through relatively permeable soils. INTRODUCTION Face stability is probably the most important aspect in urban tunnelling. Usually, Earth Pressure Balance (EPB) machines are utilized, to ensure that a reasonable amount of face pressure is exerted on the advancing excavation face, reducing ground loss and preventing potential instability of the face core, thus controlling the amount of disturbance caused by tunnel excavation to surface structures. However, the ideal amount of face pressure depends on several factors (ground and groundwater conditions, tunnel size and depth, muck conditioning, etc.) which are difficult to include in analytical calculations. For many years, conventional empirical or analytical methods (e.g. Anagnostou & Kovari 1996) were the only available tools for quantifying face stability and selecting the required face pressure. In the last few years, however, numerical analyses have gained power over conventional methods, allowing more accurate designs and providing useful information about the anticipated ground deformations due to tunnelling. Numerical analyses have also been used in assessing safety against face instability using face extrusion (horizontal face displacement) calculations (e.g. Prountzopoulos 2012)."

Jan 1, 2016

By Kirsten Corin, Margreth Tadie, Cyril O’Connor, Jenny Wiese, Wonder Chimonyo

"Relating flotation performance to the electrochemical characteristics of a pulp remains a complex issue both in fundamental research and in practice. For example, in the case of thiol collectors different Eh values can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by the control of pH and dissolved oxygen levels in the system. It is also possible to vary the potential by the addition of modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). The objective of the present study was to investigate the effect of the addition of the oxidising agents, NaClO and H2O2, on valuable mineral recoveries and grades in the flotation of sulphides from a PGM bearing Merensky ore. Batch flotation tests were conducted at pH 9.2, the natural pH of the system, in the absence and presence of a xanthate collector and Eh modifiers, viz. NaClO or H2O2. Most importantly in this way it was possible to vary Eh at constant pH and DO levels. The results indicate that in the absence or presence of xanthate the addition of H2O2 reduced both the recovery and grade of copper and nickel. In the absence of xanthate, the addition of NaClO improved the recovery of copper slightly and both the recovery and grade of nickel significantly, but in the presence of xanthate NaClO addition resulted in unchanged copper recovery and grade, but those of nickel were reduced. Based on anecdotal evidence that the addition of trace amounts of a potential modifier could improve flotation performance further tests were conducted the results of which suggest improved flotation performance.INTRODUCTIONIn the Merensky Reef, platinum group minerals (PGM) are commonly associated with base metal sulphides (BMS) and this has an effect on the way in which these minerals can be concentrated by flotation (Vermaak, Venter & Pistorius, 2004; Wiese, Harris & Bradshaw, 2005; Schouwstra, Kinloch & Lee., 2000). A major problem stemming from this association has been reported to be the loss of valuable minerals (PGM) associated with the loss of BMS (Wiese et al., 2005) during flotation. Shackleton (2007) suggested that PGMs behave in a similar manner to sulphides during flotation. Therefore, in order to recover the PGM, base metals are targeted. There is thus a need to investigate ways to improve the flotation performance of the sulphide minerals. The electrochemistry of the flotation of sulphide minerals has been studied for over half a century and there is consensus that sulphide minerals float only under a suitable redox environment (Heyes & Trahar 1979). This implies that reducing and oxidizing conditions during flotation of ores such as Merensky can be manipulated/varied to achieve an optimum flotation response.During flotation, sulphide minerals interact with thiol collectors in an electrochemical reaction to form hydrophobic species at the mineral surface (Finkelstein & Goold 1972; Rand & Woods 1984). The sulphide minerals are semiconductors and their interaction with collectors involves transfer of electrons. As such, a potential difference results which is responsible for driving electrons between reacting species (Fuerstenau, Jameson & Yoon, 2007). The magnitude of the potential difference affects the relative energies of charge carriers (electrons) at the mineral/solution interface hence controlling the direction and rate of charge transfer or rate of reaction (Bard & Faulkner, 2001). In a mixed mineral system the mineral/solution interface potentials account for the mixed potential which is critical to the process of flotation (Chander, 2003; Woods, 2003)."

Jan 1, 2016

By Shinichi Konda, Gary Nishimura

"Thousands of years ago large glaciers carved much of the landscape in Puget Sound, depositing abrasive and granular soils including cobbles and boulders along with layers of clay and sand. Tunneling in this geology – common throughout much of the northern and Midwestern U.S. – is challenging and can be unpredictable. The use of pressurized face tunneling, most commonly with EPBs and slurry type machines, has made excavation in this geology more efficient, but difficulties still remain. Through analysis of recent projects in Seattle, Washington, USA, the authors draw conclusions as to the best TBM designs and operational parameters for this variable, abrasive and often difficult ground. Performance data is analyzed with an eye towards advancements that could further improve TBM tunneling in glacially deposited soils. INTRODUCTION Over the past several ice ages, extensive glaciers reaching across much of North America transported large amounts of soil and rock as they moved across the land. The substantial weight of the ice sheets mixed together a wide range of soil types along with a variety of rocks and boulders of all sizes. Many rock formations were reduced to pebbles or particles containing highly abrasive characteristics. Any boulders able to survive were generally comprised of harder materials which were scattered throughout the soil. This highly variable mixture of abrasive soils and high strength boulders can be found in many areas across the Puget Sound and other regions of the country. Wherever they are encountered, they often create a difficult and unpredictable mining environment for both equipment design and operation. Modern TBMs are optimized early in the design process for specific types of geology, and unexpected conditions can require extensive modifications. In addition, several operational parameters need to be adjusted to balance ground characteristics, and advance rates can be significantly affected in mixed and rapidly changing soil conditions. Both EPB and slurry machines can be used successfully in these conditions, provided their respective operating criteria are met. Ideally, an EPB is operated with a relatively thick muck consistency, which accommodates moderate changes in soil permeability and maintains a reliable pressure differential through the screw conveyor. However, this also causes higher wear on rotating components and requires more energy at the cutterhead. Alternatively, slurry machines typically operate best with a more fluid muck consistency that can be easily pumped through the extensive piping system. This tends to reduce the wear on the cutterhead and the power requirements of the cutterhead drive system, but also makes the machine more sensitive to changing soil conditions. Generally, the slurry piping system is also more capable of controlling high face pressures, although the screw conveyor of an EPB can also be designed to accommodate most high-pressure conditions."

Jan 1, 2016

By Matthew Wilcock, Kenichi Soga, Peter Wright

"This paper discusses how an existing grey cast iron segmental tunnel lining responds to construction of a new SCL tunnel transversely beneath with zero clearance; how the damage assessment for the existing tunnel was conducted for impact of longitudinal movement; how the tunnel is subsequently instrumented to observe both movement and stress manifestation at its longitudinal connections and how the results from the instruments compare with the prediction. An assessment of neutral axis of the tunnel in longitudinal flexure is also explored using interpolated horizontal displacement data from a conventional monitoring system. INTRODUCTION The Royal Mail Tunnel (RMT) (formely Post Office Tunnel or ‘Mailrail’) was constructed using semi-mechanised deep level construction techniques from 1914 and 1917 (Lee 1938). Commencing full commercial operation in 1926, the system was until 2003; conveying parcels the 6.5 miles between seven sorting offices in the center of London, and linking the system with main line rail stations, Paddington and Liverpool Street (The British Postal Museum & Archive 2013). A single tunnel of 2.74m internal diameter facilitated a bi-directional twin narrow-gauge (~611mm gauge) railway road system for electric driverless operation. The tunnel lining is segmental grey cast iron (grade 10) made up of six flanged segments and a smaller flanged key segment; constructed into a ring of width 508mm The external diameter of the tunnel is 2.971m. For further details of the tunnel lining and material properties are outlined by (Devriendt & Alhaddad 2014).London Underground Bond Street Station is a major station of the London Underground system in the very center of London; in its vicinity, the RMT runs west-east perpendicularly above the north south Jubilee Line tunnels. Historic survey record of the Jubilee Line’s (the then Fleet Line) construction in 1974 and its impact on the RMT case is documented in (Crossrail 1993): it is one of only a hand full of case-studies frequently cited when assessing the impact of new construction scenarios of this type; not least including the assessment of the same tunnel, at the same site some 40 years later, and the subject material for this paper: It noted significant vertical displacement of ~90mm to the RMT without noticeable serviceability or operational impediment."

Jan 1, 2016

By Anne Kathrine Kalager

"Stretching from Norway’s capital, Oslo, to the city of Ski, a new railway line is under construction with a 20 km long hard rock tunnel. This is a major project with high demands regarding quality, cost and schedule. In addition, restrictions concerning locations close to sensitive urban infrastructure require execution with the highest level of precision and expertise. The new double track railway line forms an important part of the intercity rail development southwards from the capital and includes the longest railway tunnel to date in the Nordic countries. With its novel methods and solutions, this project offers a model for future railway project developments in the region. This paper provides general pertinent details and facts relating to this current railway project and includes a description of the project with information relating to concept and design of the tunnels, geological conditions, particular challenges, selected tunneling techniques and contracting strategies. THE FOLLO LINE PROJECT The Follo Line is a new 22 km long double track railway line under construction between Oslo Central Station and the city of Ski. The project is divided into four subprojects, as shown in figure 1. The main part of the project consists of a 20 km long hard-rock tunnel, which will be the longest railway tunnel in the Nordic countries to date.The Østfold Line is the existing double-track railway line running between Oslo Central Station and Ski serving 12 local stations. The new Follo Line will offer a direct service, without stops, between Oslo Central Station and Ski and reduce the travel time from 22 minutes to 11 minutes. After completion of the Follo Line, these two railway lines will, in combination, more than double the capacity for train transport in the region south-east of Oslo."

Jan 1, 2016

By Klaus Rabensteiner, Klaus Chmelina

"INTRODUCTION Urban tunneling is often related with special geotechnical risks. Typical causes are difficult (hydro)geological conditions, a very low overburden and the presence of critical and vulnerable (infra)structures in the influence zone of the construction (e.g. existing tunnels, roads and pavements, sewer pipes, gas and power lines, landmarked buildings, historic monuments). To manage these risks appropriately, an early detection and warning of unexpected behavior of the affected geotechnical objects ground and tunnel, as well as existing structures are mandatory. To accomplish this, the design and execution of a dense geotechnical monitoring program is of high importance. In more detail, this means specifying and performing a systematic and continuous acquisition, processing and analysis of monitoring data to support decision making. In recent years the development of new automatic sensors and (wireless) data transfer techniques and the general trend towards an automatic acquisition of monitoring data has led to an enormous increase of data production frequencies and volumes. In order to handle this data explosion efficiently, information systems and geo-databases have been developed and used successfully in many projects. They represent IT tools that support the different tasks of a given geotechnical monitoring program including data acquisition, transfer, check, processing, backup, analysis, distribution, reporting and, last but not least, alarming. Meanwhile, some tools already have developed the capability to connect to other theme-specific databases used in the project and, thus, serve as a central data management system for all kind of digital data produced. This makes possible the implementation of further useful functions and services supporting tunneling tasks such as machine control, tunnel simulation, geological prediction, process optimization, etc. where data from different engineering disciplines must be combined and processed in an integrated way. In the following chapters our aim is to describe how monitoring data management, geotechnical monitoring, alarming and reporting are organized and technically implemented at the metro project Cityringen in Copenhagen (Denmark). We want to highlight the specific role and tasks of the used tunnel information system in the project, and particularly inform on the most relevant challenges."

Jan 1, 2016

By A. Ducastel, S. Connemann, A. Stark, F. Bouillot, C. Fricke-Begemann, LSA, H. Knapp, L. Horckmans

"Refractory materials are essential for all high-temperature applications in industry. Depending on the position in the furnace and specific process requirements, refractories are produced from several raw materials, such as dolomite, magnesite, bauxite, graphite or chromite. Most of these raw materials are not rare but strict quality requirements limit the producers of refractories to only a few deposits in the world. Thus, raw material supply is a critical factor for the production of refractories and accounts for 40-50 % of the total costs of refractories.A possible way to lower dependency on raw material supply is recycling of spent refractories. Main challenge in recycling is the separation of different brick types from each other and the removal of impurities, such as steel or slag. The European FP7 project REFRASORT aims to apply sensor-based sorting for separation of spent refractories. Sensor-based sorting is known from food industry, recycling and mineral processing and has proven its reliability. Nevertheless, some adjustments are necessary compared to applications in mineral processing because of other sensor-types and a higher number of products in one sorting step. This paper presents the results of feasibility tests for sensor-based sorting of refractories with near infrared spectroscopy and laser-induced breakdown spectroscopy (LIBS). Both sensors showed the potential to identify different brick types but the most promising results were obtained using LIBS technology. INTRODUCTIONRefractories are solid, ceramic products, which can sustain temperatures of more than 1500°C, without losing their stability or shape. Bricks of refractories have to withstand corrosion in contact with liquid steel or slag. Various high temperature applications, such as the production of glass, steel, copper or cement, require high quality refractories. The quality requirements of refractory bricks are strict, because small impurities can lower the thermal strength significantly."

Jan 1, 2016

By P. I. Laforest, M. S. Moats

"Antimony in smelted copper anodes has been shown to cause problems in electrorefining including brittleness of starter sheets. In order to improve deposit properties, a study was conducted examining the effect of anode chemistry on cathode ductility and electrolyte chemistry. Two industrial anodes with different molar ratios of As/(Sb+Bi) were used in laboratory electrorefining experiments with commercial electrolyte, and the addition of commercial glue and Avitone. The ductility of 21-hr copper deposits was evaluated by a 180° bend test. X-ray diffraction (XRD) and metallography were performed on unbent specimens to characterize the deposit structure. Increasing the anode As/(Sb+Bi) molar ratio from 0.54 to 3.8 resulted in an increase, on average, from four to eight bends to failure in cathode material produced. Significantly lower concentration of antimony (V) in the electrolyte was detected when operating with the higher molar ratio anode. The presence of (111) and (200) planes was noted in cathode material produced from the higher molar ratio anode suggesting that mixed growth character could be responsible for the observed increase in bend test results. The ductility of the starter sheet materials was improved by a higher anode molar ratio.INTRODUCTIONThe presence of antimony in copper electrorefining electrolyte has been reported to cause problems in cathode production (Hiskey, 2012; Peng, Zheng & Chen, 2012; Wang, Chen, Zhou-Lan & Lian-Sheng, 2006; Wang, Chen, Zhou-Lan, Wang, Xiao & Zhang, 2010; Wang, Chen, Zhou-Lan, Wang, Xiao & Tang, 2011; Wesstrom, 2014). To better understand the impact of antimony, laboratory scale electrorefining experiments were conducted using industrial inputs (anodes, cathodes and electrolyte). The influences of anode chemistry on the valences of antimony and arsenic in the electrolyte were monitored and correlated to physical cathode characteristics, such as a bend test to failure and crystallographic orientation.Commercially, starter sheets are produced by electrorefining impure cast copper anodes onto titanium blanks. The starter sheets are then hung in an electrorefining or electrowinning cell using loops of bent starter sheet material. These loops, in the absence of sufficient ductility, fail resulting in cathodes falling into the electrolysis cells. It is thought that the reduction in ductility can be related to anode composition; in particular, the molar ratio of arsenic to antimony plus bismuth As/(Sb+Bi). It has been stated that maintaining this ratio above 2:1 results in numerous improvements to electrorefining operations (Baltazar, Claessens & Thiriar, 1987; Kamath, Mitra, Radhakrishnan & Shetty, 2003; Krusmark, Young & Faro, 1995; Noguchi, Itoh & Nakamura, 1995; Wenzl, 2008)."

Jan 1, 2016

By K. V. Raj

"The development and advancement of computational fluid dynamics (CFD) has made it possible to better understand pollutant flow and distribution in deep open pit mines. Open pits located at higher latitudes, especially in the Arctic and sub-Arctic, face a unique problem due to atmospheric temperature inversion, which is prevalent during much of the winter. A three-dimensional CFD model of an actual open pit mine in the Arctic was developed to analyze the problem of pollutant growth during inversion, and mitigation of the pollutants through improved ventilation schemes. Due to the availability of mine-specific data, such as contaminant concentrations and coordinates of sampling locations, the actual 2013 pit geometry was used for model validation Concentrations predicted by the selected realizable ?-e turbulent model are compared to measured pollutant concentrations at the open pit. Pollutant concentrations at selected locations showed differences, but remained within the same order of magnitude in most cases. INTRODUCTION Computational fluid dynamics (CFD) has emerged as a useful tool for ventilation modeling in underground mines (Edwards and Hwang 1999, Purushotham and Bandopadhyay 2009, Wala et al. 1998, Xu et al. 2011). Application of CFD in open pit mines has been limited, however, since most open pit mines located at lower latitudes do not encounter considerable ventilation problems. Open pits located at higher latitudes, especially the Arctic and sub-Arctic, face a unique problem due to atmospheric temperature inversion, which is prevalent during winter. A number of Russian researchers have tried to understand the air inversion and resulting pollutant transport problem by modeling air flow phenomena in open pit mines (Baklanov and Burman 1996, Baklanov 1984, Baklanov 1995, Belousov 1985, 1989, 1995). Much of their work, however, was based on numerical models and methods of finite difference. Baklanov (2000) applied a modified ?-e and a ?-l CFD model to air flow phenomena on various terrains. More recently, Choudhury (2011) used the COMSOL CFD package for modeling pollutant transport for an idealized open pit mine. Collingwood et al. (2012a, 2012b) used a two-dimensional model for fluid flow and contaminant transport at an Arctic open pit mine. The authors have also previously presented work on CFD modeling of an actual open pit mine at high latitude (Bandopadhyay et al. 2014, Raj et al. 2015a). However, the CFD work done by the above-cited researchers lacked model validation with field-measured data. Validation of a developed model is important in assessing the quality and accuracy of the predicted results. In general, experiments are done numerous times in controlled environments to assess the validity of collected data. There are two types of assessments used in CFD simulations: (1) verification and (2) validation. Model verification is checking the accuracy of the computer codes during the implementation phase of a real-world problem, within the specific limits of accuracy (Oberkampf and Trucano 2002). Since, the pollution transport model presented in this paper used the commercial ANSYS-FLUENT CFD package, verification is not needed as the program has been tested widely, and verified numerous times."

Jan 1, 2016

By Yun Bai, Ang Chen, Xiangdong Hu, Yanfei Zhu, Gang Li

"It is well known that tunnelling involves a high degree of risk. Conventional risk management only evaluates risks and chooses mitigation measures before the start of a project. However, mitigation measures also introduce risks, which are ignored in the conventional risk control process when choosing different measures. The Multiphase Risk Management Method (MRMM) takes the risk of mitigation measures and dynamic risk control into consideration. This paper introduces this new method and provides a flow chart for better understanding. A case study of the MRMM is given based on Ningbo Metro Line 3, the first quasi rectangle shield tunnel in China. INTRODUCTION Tunnelling itself is generally complex and involves a high degree of uncertainty (Huang, 2006; Thompson and Thompson, 2006). In recent years, several metro tunnel projects in China have been involved in accidents (Wang, 2006; Gong and Zhang, 2012).As a result, Chinese tunnel engineers are paying more and more attention to risk management in tunnel projects (Xiao-lin and Ping et al., 2009; Zhong and Jia et al., 2014), and scholars around the world have put forward many management processes. Existing risk management mainly focuses on a particular stage of a tunneling project. Tunnel engineers or other project parties usually carry out risk assessment and set up schemes or choose mitigation measures before a project begins. The risk from this initial risk assessment may be defined as the initial risk (Bai and Dai et al., 2013). This kind of managing process has been widely used for its simplicity and comprehensibility. However, this static theory cannot properly reveal the dynamic character of the risk during tunnelling. In addition, to reduce the risk from unacceptable level to acceptable level also calls for optimum measures. Therefore, the multiphase risk management method was proposed (Bai and Dai et al., 2013). The purpose of this paper is to introduce and develop the MRMM, and to provide a brief flow chart to illustrate the risk management process based on it. Finally, an example of the first quasi rectangle shield tunnel in China in Ningbo Metro Line 3 is illustrated. It analyzes the initial and secondary risk and sets up a risk control system."

Jan 1, 2016

By A. Otsuki

"This paper discusses the primary collector adsorption onto a sulphide mineral in mixed collector systems to understand its adsorption mechanism. UV-vis measurements were performed to identify the primary collector concentration adsorbed on pyrite, and the adsorption kinetics under different conditions were compared to distinguish their difference between single and mixed collector systems. Small amount of secondary collector addition prior to the primary collector addition significantly improved the adsorption kinetics of primary one. The result was explained by the combination of two previously proposed mechanisms (i.e., different adsorption site mechanism and multi-layer product mechanism). This study showed UV-vis measurement as an effective tool to study mixed collector adsorption behaviour.INTRODUCTIONCollectors are surfactants composed of heteropolar molecules with a non-polar and a polar group (Lotter & Bradshaw, 2010). In a froth flotation process, the function of collector is to improve the hydrophobicity of target minerals and selectively float them with the aid of gas bubbles. Because of the chemical or physical attraction between the polar group and the mineral surfaces sites, collector molecules adsorb on the particle surface with the non-polar group assigned towards the bulk solution (i.e., water), thus the mineral particle surface becomes hydrophobic (Wills & Napier-Munn, 2006).Thiol collectors are major collectors widely used in sulphide mineral flotation. Potassium amyl xanthate (PAX), dithiocarbamate (DTC), dithiophosphate (DTP), mecaptobenzothiazole (MBT) are some common thiol collectors. Previous studies reported that some mixed collectors systems enhanced the flotation performance (e.g., Bradshaw, 1997; Bradshaw et al., 1998; Rao & Forssberg, 1997). Thiol collector mixtures are often used in the flotation of sulphide ores, and discussed with the synergistic benefits (Bradshaw et al., 1998) which include lowering the total collector dosage requirements, improving the sulphide recovery and the rate of flotation as well as the improving the froth characteristics. The current paper mainly considered the mixture between two thiol collectors (PAX and DTC, considered as a weaker and selective collector, and stronger and less selective collector, respectively (Bradshaw, 1997)) to further understand their adsorption mechanism that should assist in improving the flotation performance of refractory gold ore."

Jan 1, 2016

By Tatyana Alexandrova

The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Technological aspects of processing precious metal ores are examined in two respects: enhancing gold recovery from double refractory ores; and using carbonaceous ores on a production scale. The dispersed carbonaceous matter (DCM) present in concentrates causes the adsorption of [Au(CN)2]- complex on their surface during cyanidation process. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The problem of processing refractory (rebellious) gold ores is important for all the countries involved in recovering precious metals from ores. Depending on the degree of graphitization and the organic carbon content in DCM (including kerogens and bitumen), the technology used to recover precious metals varies considerably. The possibility of rare metals recovery, including rhenium, from black-shale rocks, has been examined. Comparative assessment of analytical methods of rare metals detecting has been carried out. It has been proved that neutron activation analysis is a promising technique. It has been shown that colloid-salt fraction (nanofraction) with particle size less than 1000 nm makes up to 3 wt% of black shale samples and is extracted by water under special conditions. The use of water instead of chemically active reagents provides insolubility of the mineral matrix and fully reflects the colloid-salt element of the samples. To sum up, the justification of the choice of technology for processing of carbon-bearing ores is based on examining the type of carbonaceous matter and its adsorption behavior. When the content of carbon of high degree of metamorphism is considerable, it is possible to recover platinum group elements and rare elements from this type of ores. The obtained results predetermine the general guidelines for creating new methods and techniques of processing carbonaceous material for integral development of solid minerals in the mining and oilfield areas of Russia.

Jan 1, 2016

By Guy Reed, Russell Frith, Kent Mctyer

"Coal pillar design has historically been based on assigning a design factor of safety (FoS) or stability factor (SF) to coal pillars according to their estimated strength and the assumed overburden load acting on them. Acceptable FoS VALUES (have been assigned based on past mining experience, and at least one methodology includes the determination of a statistical link between FoS and probability of failure (PoF).The role of the pillar width-to-height (w/h) ratio has long been established as having a material influence on both the strength of a coal pillar and its potential mode of failure. However, there has been significant professional disagreement on using both FoS and w/h ratio as part of a combined pillar system stability criterion, as compared to using FoS in isolation. The argument is that, as w/h ratio is intrinsic to pillar strength, which, in tum, is intrinsic to FoS, it makes no sense to include w/h ratio twice in the stability assessment. At face value, this logic is sound.However, this paper will argue that there is a valid technical reason to bring w/h ratio into system stability criteria (other than its influence on pillar strength), as it is related to the post-failure stiffness of the pillar, as measured in situ, and its interaction with overburden stiffness.When overburden stiffness is bought into pillar system stability considerations, two issues emerge. The first is the width-to-depth (W/H) ratio of the panel, in particular whether it is sub-critical or super-critical from a surface subsidence perspective. As a minimum, this directly relates to the accuracy of the pillar loading assumption of full tributary area loading. The second relates to a reevaluation of pillar FoS based on whether the pillar is in an elastic or non-elastic (i.e., post-yield) state in its as-designed condition, as relevant to maintaining overburden stiffness at the highest possible level.The significance of the model presented is the potential to maximise both reserve recovery and mining efficiencies without any discernible increase in geotechnical risk, particularly in thick seams and higher depth of cover mining situations. At a time when mining economics are, at best, marginal, removing potentially unnecessary design conservatism without negatively affecting safety is of interest to all mine operators and is an important topic for discussion amongst the geotechnical community."

Jan 1, 2016

By Philip Antunes, A. E. (Tony) Reschke

"INTRODUCTION Tunnel Boring Machine (TBM) operations require the injection of material into the annular tail voids as the machine advances ahead of the segmental concrete lining. This annular gap is created because the cutting diameter of the TBM has to be larger than the outer diameter of the concrete segments of the tunnel lining. Fundamentally, the two basic types of annular grout are thick, concrete like mortars and thin, mobile, two-component grouts. While some European countries seem to still favor the concrete like mortars, from a global perspective it is now the two-component type grouts that dominate the industry. Two-component type grouts are comprised of an “A” component grout (typically cement, flyash, bentonite and a retarder/stabilizer) and a “B” component accelerator (sodium silicate or water glass as it is sometimes known). They are thus sometimes referred to as A/B type or bi-component grouts and were pioneered by the Japanese over 30 years ago. They offer a host of operational benefits over thick mortars, such as reduced settlement (Feddema et. al., 2001), effective penetration of the void space, with less energy, and reduced strain on the segmented linings (Robinson et. al., 2007). Two-component grouts are highly mobile and can be pumped many kilometers. The use of a retarder/stabilizer can also extend the shelf life of the “A” component grout for several days while the early strength of the accelerated grout stabilizes the ground and supports the segmental liner almost immediately. The batch plants that prepare the two-component grouts use one of two possible mixing methods for preparing the “A” component grout. The simplest plants use paddle type mixers and numerous tunnels worldwide have been successfully grouted using this technology. However, a superior type of mixer is available, namely the high shear colloidal mixer. Keller Colcrete successfully pioneered the development of the colloidal mixer back in 1937 and for over 75 years colloidal mixers have been internationally recognised as the most efficient method of mixing cement based grouts (Houlsby, 1990). These mixers are used in grout preparation for radioactive waste encapsulation, hydro dam grout curtains, soilcrete jet grouting, soil nailing, and numerous other geotechnical applications. In tunnelling, these mixers are also used for ground treatment, compensation grouting and for the preparation of bentonite lubrication for pipejacking. It has been only within the last decade however that these high-shear colloidal mixers have been adapted for use in the preparation of two-component grouts."

Jan 1, 2016

By Wei Sun, Xiangsong Meng, Xiaodong Li, Weisheng Huang, Yuehua Hu, Chonggao Cao, Haisheng Han, Wensheng Chen, Runqing Liu, Central South University

"The similar flotability of scheelite, fluorite, and calcite resulted in the difficult separation by flotation. This work revealed the effect of water glass on the flotation of scheelite by FTIR and the wettability change of the usual cleavage plane, and proved that water glass inevitably influenced the flotation of tungsten minerals to a large extend in traditional fatty acid flotation process. A new collector, benzohydroxamic acid complexes, was found to be selective for the separation of scheelite and calcium minerals with little water glass. Hence a novel flotation process was developed for the recovery of tungsten minerals in shizhuyuan mine in China. Normal temperature flotation of tungsten minerals was developed to instead of the classical “Petrov's process” for scheelite-calcite-fluorite type ores. Compared with the traditional process, the recovery was improved by 10% and the grade of scheelite concentrate was above 55%. The disappearance or decreasing of water glass contributed to improving the recovery of tungsten and fluorite and the circulation of water and reagents.INTRODUCTIONChina is rich in tungsten resources and the proved reserves accounted for 60% of the world's reserves (Cai Gaipin et al., 2009). However the wolframite has been dried up and the scheelite resource has become the main resource of the tungsten metal. Scheelite deposits were classified to scheelite-silicate type and scheelite-calcite-fluorite type based on the associated gangue minerals. Scheelite was easy to separate from the silicate minerals. Flotation separation of scheelite from calcium minerals creates difficulties because of the existence of the same cation in the minerals and similar physicochemical characteristics such as solubility, hardness, specific gravity, PZC (point of zero charge) etc.(Arnold & Warren, 1974; Yongxin & Changgen, 1983; Ozcan & Bulutcu, 1993a; Deng et al., 2015, 2016;). The conventional collectors used in the flotation of scheelite ores are generally fatty acids or fatty acid derivatives ( Yongxin & Changgen, 1983; Oliveira & Sampaio, 1988; Sivamohan, 1988; Shi et al., 2014; Bo et al., 2015). It is difficult to separate scheelite especially from calcite with these reagents because the adsorption mechanism of these collectors occurs through chemisorption of the oleate ion onto the mineral surface (Atademir et al., 1979; Changgen and Yongxin, 1983; Hiçyìlmaz et al., 1993; Hu et al., 2011). Therefore, it is almost impossible to separate them by fatty acid flotation without using any selective depressant. Although oleoyl sarcosine was used as a selective collector in the flotation of fluorite and siliceous scheelite ores (Ozcan & Bulutcu, 1993b; Ozcan et al., 1994), this selectivity is not adequate for a low-grade calcitic scheelite ore. Unfortunately, the reagents such as organic colloids (dextrine, starch), quebracho, sodium phosphates, sodium silicate solutions containing polyvalent cations (hydrosols), etc. (Yongxin and Changgen, 1983; Schubert et al., 1990; Shi et al., 2014; Bo et al., 2015) used for calcite depression also depress scheelite to a large extent."

Jan 1, 2016

By Vladislava A. Ignatkina, Fillip O. Milovich, Vladimir A. Bocharov

"Complex research of flotation concentrates of monomineral fractions of chalcopyrite, sphalerite, galena, pyrite, pyrrhotite included methods of adsorption of collectors, surface compounds by IR ATR, and surface films of flotoreagents by TEM. They revealed that the proportion of the parts of thionocarbamate (TC) and dithiophosphate had an effect on the adsorption rate of the components of minerals, on the presence of characteristic bands, and, what is an important, visualized surface film of organic flotation reagents on the particles of concentrates by TEM. The predominance of thionocarbamate in a composition selectively increases the adsorption rate constant of the components and recovery of chalcopyrite compared with sphalerite and galena. The highest flotation rate using TC is characteristic for chalcopyrite (0.62 min- 1) in case of individual use, and it's in combination with butyl xanthate (25% butyl xanthate or 3:1) 0.89 min-1 too. We studied the ternary blend - dithiophosphate: thionocarbamates: butyl xanthate. The increase of the proportion of butyl xanthate in combination reduces the contrast of the flotation rate among all sulfides.Practice flotation of refractory sulfide copper-zinc ores of the Urals (content sulfide iron - 75- 95%) confirmed that the use of a combination of selective collectors increases selective recovery of copper sulfide minerals up to 50% at the first fraction that is the conditioned copper concentrate. New selective sulfhydryl collectors resulted in high levels of recovery of copper into a concentrate - more than 90% - against 70-72% (butyl xanthate) from copper-pyrite ore. Low floatability of iron sulfides has been obtained by selective sulfhydryl collectors. Using weak selective sulfhydryl collectors can reduce pH into collective or selective flotation from pH 10-10.5 to pH = 7.2-7.5, which improves the quality of individual concentrates of nonferrous metals and their recovery. The same is true for polymetalic sulfide ore. The volume of gold recovery also increased."

Jan 1, 2016