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By H. H. Li

Reverse flotation is usually used for hematite/silica or bauxite/clay flotation separation in which the silica or clay is floated and rejected. Some properties of these silicate minerals such as particle size and surface characteristics have significant effect on their flotation behaviours. Firstly, the silicate mineral particles (especially clay minerals) generally have fine particle size (< 5 microns) in their natural states or due to overgrinding and they display poor flotation kinetics, consequently having low flotation recovery. Secondly, the wettability difference on different particle basal planes influences the affinity for adsorptions of different types of chemicals such as collectors or macro-molecule. Common polyacrylamide (PAM) flocculants can be used to minimize the exposure of the most hydrophilic planes of clay particles via hydrogen bonding but they can not efficiently enhance the overall particle surface floatability due to the hydrophilic properties of this type of macromolecules. A novel method to improve both flotation kinetics and surface wettability of silicate minerals has been developed and studied. That is to use a temperature-sensitive polymer, poly (N-isopropyl acrylamide) (PNIPAM), as a process aid in the flotation of silicate minerals. Unlike PAM polymers, PNIPAM can induce a hydrophilic/hydrophobic transition on the particle surface when the temperature is changed to be lower or higher than its critical solution temperature (CST). At a lower temperature, the PNIPAM adsorbs on the particle surface via hydrogen bond similar to PAM. It induces strong hydrophobic aggregation when the temperature is increased above the CST. Thus, both floc size and mineral floatability are greatly increased. The flotation results show very good flotation performance and the addition of conventional flotation collector was no more required because the increased particle surface hydrophobicity induced by PNIPAM. Contact angle measurements explained the role of PNIPAM in manipulating particle surface hydrophilic/hydrophobic transition.

Jan 1, 2014

By B. Jin

Removal of fluoride and chloride by alkaline washing from direct lead smelting dust which originated from an Ausmelt furnace is reported. The results show that the fluoride removal efficiency increases with an increase of alkaline concentration, alkaline washing temperature and time. The L/S ratio has little effect on fluoride and chloride removal efficiency. A new flow sheet for removal of fluoride and chloride from the dust was successfully proposed according to the results. Fluoride and chloride removal efficiencies are more than 53.68% and 63.18% respectively using the flow sheet under the optimum parameters of temperature 338 K, L/S ratio 3:1 and alkaline washing time of 1.5 h. The contents of fluoride and chloride in the alkaline washing residues can meet the standard of zinc purity as hydrometallurgical materials for zinc processing.

Jan 1, 2014

Calcium sulfate whiskers are considered to be a prosperous reinforced material in application due to their high mechanical properties. But the hydration occurs easily at moist atmosphere or in aqueous solution. The surface topographies of the calcium sulfate hemihydrate whiskers and the hydrates were analyzed by on-line observation and using XRD. The results indicated the transformation of the crystal type and shape of calcium sulfate hemihydrate whiskers and the reduction of whiskers? aspect ratio. The hydration process of the calcium sulfate hemihydrate whiskers and the effective parameters were further discussed based on FT-IR measurements. The conclusions were obtained that the hydration of calcium sulfate hemihydrate whiskers can be divided into the three phases, namely, initial hemihydration phase, dehydration phase, and coarsening, dissolving and the re-formation of calcium sulfate dehydrate crystal phase. In addition, it was found that in the hydration process of calcium sulfate hemihydrate whiskers the calcium sulfate dihydrate whiskers are formed at first and then converted into the calcium sulfate dihydrate with different crystal shapes, but in the hydration of gypsum hemihydrate the gypsum dihydrate is formed without transition products. The surface active site-calcium ion which has strong trend to react with H2O, the surface ?OH and the inner channels are considered to play important roles in the hydration process of calcium sulfate hemihydrate whiskers.

Jan 1, 2014

By Mike Daniel, Eric Wang

"Several new large copper and gold concentrators have been built and commissioned around the world in the past five to eight years. The success of the ramp-up from these very large concentrators has varied. CITIC SMCC Process Technology was engaged to assist some of these mines by gaining a better understanding of the factors that influence throughput capacity. As such, site-specific throughput forecast models that are influenced by SAG mill performance were developed. The forecast models are easy to interpret and modify and can greatly assist the mine management to make predictions and informed decisions for a range of site improvements. The models investigate the influence of SAG mill performance with respect to ore competency, derived from SMC Test® via the measured DWi model parameter. In some cases the benefits of blasting and from fine tuning milling operations are already incorporated into the "site-specific" forecast models. The methodology follows rigorous plant data analysis that is analogous to a "Mine-to-Mill®" optimisation project. The CITIC-SMCC model validation includes extensive data collection, which includes drill core analysis, ore characterisation and comprehensive comminution circuit operational data to assess the limitations within the comminution circuit within the operating mine. The results and models may be used to define the operating base lines of the processing areas and identify improvement opportunities upstream and downstream of the comminution circuit. The predictive capability of the models use logged production data and has enabled the user to differentiate between alternative circuit configuration options and identify optimum operating conditions. This approach minimises the ongoing requirement for costly plant surveys. The improvement strategy for each site, included the ongoing measurement of grindability, rock strength and via the Bond and SMC Test® respectively. Some commentary as to what other practitioners do with input data and their models is also presented as this highlights some of their shortcomings relative to the CITIC-SMCC methods."

Jan 1, 2014

By K. Rainer Massarsch, Bengt H. Fellenius

"Abstract Vibration limits for buildings with respect to ground vibrations from pile driving published in international standards are reviewed. At first, relevant vibration parameters are defined and the evaluation of vibration records is described. The sensitivity of structures to different vibration parameters (displacement, velocity and acceleration) is discussed. Most vibration standards relate to blasting activities, the dynamic characteristics of which can be significantly different to those from construction activities and in particular, pile driving. Several vibration standards are reviewed. The Swedish vibration standard is described in detail, as it is the only one accounting for several important factors, such as ground conditions, building material, and type of building foundation. Many standards limit the guidance to values based on the dominant vibration frequency and a wide scatter of frequency-dependent vibration limits exists. It is difficult to compare limiting values of ground vibrations proposed in different standards.1. INTRODUCTIONFor poor ground conditions, placing structures on piles is the most common foundation solution, while sheet piles are widely used to support deep excavations. Piles and sheet piles must often be installed in the close vicinity to buildings, structures or installations in the ground, which can be affected by ground movements and vibrations, (Massarsch and Fellenius, 2014). In many areas, environmental concerns with respect to noise and ground vibrations can restrict or even prohibit driving of piles or sheet piles or reduce the efficiency of installation. The design engineer must prescribe – often at an early stage of a project — the permissible levels of ground vibrations in order to minimize the potential risk of building damage. When seeking guidance from the literature, little or practically no applicable information can be found on how to assess permissible levels of ground vibrations."

Jan 1, 2014

By Pengbo Chu, James Finch

Bubbles around 1 mm diameter provide the high interfacial area for capture and transport of hydrophobic particles in flotation. The formation of such fine bubbles is commonly achieved by addition of frothers that appear to simultaneously retard coalescence and promote break-up. High inorganic salt content in process water can substitute for frother. In this work we focus on the action of salt (sodium chloride) on formation of bubbles by break-up. An experimental setup that isolates break-up from coalescence was employed. A pocket of air is exposed to controlled mechanical turbulence to produce single bubbles by the induced deformation of the air and the events imaged. The presence of salt is shown to produce smaller bubbles than in water alone. Comparison with a similar study on frothers is made. The argument is advanced that the presence of frother and salt creates surface tension gradients at the air/water interface which add to the mechanical energy of the deformation and break-up process.

Jan 1, 2014

By M. F. He

The depression of pyrite in marmatite flotation by a new depressant Sodium Glycerine-xanthate (SGX) has been investigated through microflotation, zeta potential, and adsorption measurements in systems open to the atmosphere. The flotation tests of single mineral show that in the presence of SGX, marmatite can be activated by Cu2+ and shows good flotability, while pyrite can?t be activated and therefore shows poor flotability, as a result these two minerals can be separated using butyl xanthate as the collector. The depression mechanism of SGX on sulfide minerals is discussed based on Zeta potential and adsorption isotherm. Zeta potential experiments demonstrate that at the presence of Cu2+, SGX can strongly adsorb on the surface of pyrite, while it can?t adsorb on the surface of marmatite, thus the results are in accordance with those of flotation experiments; the results of adsorption isotherms show that the adsorption density of SGX on pyrite is greater.

Jan 1, 2014

By J. Z. Yuan

The purity of rectorite is only about 70% after preliminary mineral processing, which has limited its application. In this research, different pulp densities, different dispersants, different dispersing methods and purification flow sheets were used to purify rectorite. The results show that it is possible to obtain high pure rectorite clay with the purity above 90% and concentrate yield between 24.9% and 29.4% by the purification process with composite dispersants, stirred mill grinding dispersion and so on. The obtained high pure rectorite can be further used in rectorite nanocomposites.

Jan 1, 2014

By Dilip. Makhija, Asim. K. Mukherjee, Tamal Ghosh, Abhay Patra

In India around 15-20% of Run of Mine (ROM) from any iron ore deposit reports to slime dams as byproduct of iron ore beneficiation process. The proportion of iron ore slime to ROM will increase in future with higher proportion of lean grade ores in ROM. Furthermore, tonnages of iron ore slime will also increase with increasing demand of iron concentrate. Presently, this slime is stored in the dam in the absence of beneficiation technology. A beneficiation flowsheet has been developed at Tata Steel. This process produced concentrate of 2.2% alumina with 40 % yield from slime of 7-9% alumina. The iron content in the reject will be less than 40% thus adhering to the regulatory norm. Pilot scale study show waste from slime beneficiation is a good raw material for making a variety of building materials. Waste from slime beneficiation also has soil amendment properties. Pilot scale studies show productivity of rice increased when the waste of slime beneficiation process is mixed with soil. On commercialization of this zero waste technology slime generated from the iron ore washing plant will be completely used. In this paper the result of the pilot scale studies on slime beneficiation and utilization processes towards soil making and making of building materials are discussed in detail.

Jan 1, 2014

By Stuart Simpson

The biggest environmental challenge in mining is the management of mine tailings. Deep----sea tailings placement (DTSP) is practiced where the environmental impacts are predicted to be less than the impacts of tailings storage facilities on land. However, DSTP is often highly controversial owing to the challenges in assessing the impacts in deep water environments and potential long----term impacts beyond the proposed tailings footprint. It is well recognized that total contaminant concentrations are often poor predictors of the risk posed by contaminants in sediments. Metals within tailings are mostly present in highly mineralised forms that are typically much less bioavailable to organisms when compared to other common anthropogenic metals. Thus while metal concentrations in tailings can often appear alarmingly high, when compared to sediment quality guidelines (SQGs) used for assessing common urban and industrial impacts, the bioavailability is typically low. Although now well----embedded within risk----based sediment quality assessment frameworks, contaminant bioavailability is still often overlooked in the management of contaminated sediments. In this presentation, we assess and demonstrate the low bioavailability and chronic ecotoxicology of mineral----rich tailings to two benthic invertebrates, recognized for their sensitivity to metals: impairment of reproduction of the amphipod, Melita plumulosa, and the harpacticoid copepod, Nitocra spinipes. We demonstrate that the metal exposure from mine tailings is low when total concentrations are considered, and that the dose to the organism and toxic response observed is highly dependent on contaminant bioavailability. We discuss a range of approaches for the effective incorporation of metal bioavailability when applying SQGs or setting site-specific management limits for mine tailings in marine environments. While proposed DSTP operations require a high level of environmental scrutiny and monitoring during operation and post-closure, environmentally sustainable operations may be achieved when the bioavailable forms of metals within tailings remain below suitable management limits.

Jan 1, 2014

By J. P. Gous, M. Tangstad, J. D. Steenkamp

In April of 2013 a 48 MVA submerged arc furnace producing silicomanganese was excavated in South Africa. One of the areas excavated systematically was the furnace taphole. The aim was to obtain a refractory wear profile of the tap-hole area, together with affected hearth and sidewall refractory. Subsequently, thermodynamic modelling was applied to quantify the potential for chemical reaction between refractory and slag and refractory and metal in the tap-hole area.

Jan 1, 2014

By Sevinc Yildirim, Cigdem Oruclus

"Metal-Porous Silicon (PS) based structures dipped in water show the direct hydrogen fuel cell behavior. The effect of the thickness of the cupper (Cu) film on the electrical properties of direct hydrogen fuel cell is studied by fabricating Cu/Porous Silicon/n-Silicon/Indium structures. PS samples were produced electrochemical etching of n-type single crystalline silicon with a resistivity of 1,25 Ocm and (111) orientation. The thin films of Cu with different thickness between 200 and 600 nm were deposited on PS surface by electron-beam technique. Investigation of the effect of Cu layer on the performance of the structure indicates that the performance parameters such as open circuit voltage (Voc) and short circuit current (Isc) strongly depend on the Cu layer thickness. It was observed that the divice with an 350 nm Cu layer exhibits the highest open circuit voltage (0,5 V), short circuit current (0,01 mA) and power density (10 W.m-2).IntroductionHydrogen is the most attractive and ultimate candidate for a future fuel and an energy carrier. Hydrogen is recognized as the environmentally desirable clean fuel of the future since it can be used directly in different types of hydrogen fuel cells [1]. In the past years, the rise in portable electronics requires the development of miniature fuel cells compatible with standard silicon micro fabrication technology. Most silicon micro-fuel cells have used the polyperfluo-rosulfonic acid membranes (Nafion R) as a proton exchange membranes (PEM) that is not really integrated with standard micro fabrication techniques [2-5]. The composite materials such as inorganicorganic hybrid materials (Nafion-silica, Nafion-borosiloxane etc) are next generation of proton conducting membrane [4-8]. But, fuel cells run on pure hydrogen gas, which can be produced with other energy resources. Hydrogen smallest atom and thus the H2 gas can leak easiliy. The application of hydrogen for power sources has been greatly restrained due to the lack of safe and convenient generation and storage methods.A kind of hydrogen fuel cells Metal-PS-Si structures used as an energy water directly. There is no need pure hydrogen. Cu-PS-Si Schottky-type fuel cells with as proton-conducting membrane and the thin-film cupper catalist and water as fuel, which are interesting for fabrication of lowcost miniature fuel cells. Generation of the open-circuit voltage and short-circuit current has been observed by Cu-PS-Si structure dipping in different hydrogen-containing solution."

Jan 1, 2014

By S. S. Yu

In this paper, the producing process of using V2O3 as raw material to obtain vanadium nitride was analyzed through the means of thermodynamic. The analysis shows that conversion follows the principle of reduction step by step in the conversion process of V2O3. The temperature of the reaction system has prominent influence on the nitrogen content of products, and the reaction is very sensitive to temperature. As raising temperature, the fine grain structure of the nitrides is more evident, and the grain size of nitrides increases. At 1703K, the nitrogen content of the products tended to be constant after soaking over 3 hours.

Jan 1, 2014

By Di Liu, Yongjun Peng

"It was identified that clay minerals adversely affect fine coal flotation through slime coatings. In the study, it was interesting to find that an anionic polymer dispersant, lignosulfonate, successfully mitigated the negative effect of clay minerals in coal flotation using fresh water, but in saline water, it exacerbated coal flotation.In order to understand the mechanisms underpinning the different behaviour of lignosulfonate in coal flotation using fresh and saline water, the adsorption isotherm, and dynamic light scattering (DLS) measurements were conducted in this study. While DLS monitored the molecular conformation change (swelling or shrinking) of the polymer in fresh and saline water, adsorption isotherms enabled polymer adsorbed amount on clay and coal mineral surfaces to be determined. It was found that lignosulfonate adsorbed on the coal and clay mineral surfaces providing effective electrostatic repulsions and resulting in a mitigation of clay minerals from coal surfaces in deionised water. In the presence of saline water, however, polymer molecular conformation changed. Polymer molecules were compressed and adsorbed in form of aggregates. The adsorption amount of lignosulfonate on clay minerals increased in saline water. A low dosage of lignosulfonate could not provide sufficient electrosteric repulsion to disperse clay minerals. Moreover, the high adsorption amount of the polymer on coal and clay surfaces led to a more hydrophilic coal surface, and coal flotation was therefore depressed in saline water. This study provides a new insight into understanding the role of anionic polymeric dispersants in mineral flotation using different quality water."

Jan 1, 2014

By Thenepalli Thriveni, Seong-Young Nam, Nam-Il Um

New modern water treatment technologies required for arsenic removal from waste waters contaminated extensively by various background sources from mining, industrial waste, agricultural waste, painting industry and natural geological bed rock system etc. Arsenic is a widely dispersed element in the earth&apos;s crust and exists at an average concentration of approximately 5 mg/kg. Arsenic (As) and heavy metals may be released from the mine wastes to the ground and surface water systems, as well as the geological environment due to their solubility and mobility. This research focuses on the effect of accelerated carbonation process for successful removal of heavy metal arsenic anions from artificial waste water and mining waste waters. This accelerated carbonation process is a simple and novel method with 85 ~ 88% removal efficiency. Carbonation has been studied as a process to further improve immobilization of solidified/stabilized waste and granular waste. After successful removal of arsenic anions from solid mining waste and its potential benefits for producing construction materials. Besides, the industrial and urban management systems are generating bulk solid mining wastes, and most often dumping them in open fields. To prevent the landfilling with mining waste, many efforts are being made for the recycling of different types of mining solid wastes with a view to utilizing them in the production of various construction materials.

Jan 1, 2014

By W. H. Yong

The molybdenum ores currently utilized in China are mostly molybdenum sulfide ores, whereas oxidized molybdenum ores have not been exploited and utilized efficiently. The aim of this article is to study the applied mineralogy of an intergrown iron-molybdenum oxidized ore in order to provide a mineralogical basis for the ore beneficiation research. The ore occurred in a surface oxidized zone seam and contained 23.65% Fe2O3 and 1.58% Mo. Various characterization techniques were employed to study the chemical composition and mineral composition of the ore, the particle size distribution of the minerals in the ore, and the tex-ture and structure of the ore. The results showed that the iron-molybdenum ore occurred in a wet, soft and earthy state. The ore was composed mainly of several oxidized minerals and colloidal min-erals, including wulfenite, barite, limonite and quartz. Wulfenite was one of the major and stable components in the ore and occurred as a separate mineral. Wulfenite, barite and quartz were granu-lar minerals with particle size ranging from fine to coarse but mainly in the fine particle range. Li-monite showed a crust and honeycomb-like colloidal state and composed the framework in the ore for the formation of the other minerals. They filled the pores in the framework and the size of the pores affected the size of the minerals formed in the pores and hence the recovery of wulfenite in ore beneficiation. According to the applied mineralogical properties of the oxidized molybdenum ore, a promising ore beneficiation process was proposed as follow Magnetic separation should be carried out first to separate the magnetic iron minerals and then the molybdenum mineral will be recovered by gravity concentration or a combination process of gravity concentration and flotation, depending on the distribution of the molybdenum mineral in the product of the magnetic separation.

Jan 1, 2014

By K. Soldenhoff, D. Wilkins, E. Ho

In the processing of rare earth ores, a pure, mixed rare earth chloride solution is usually produced and used as the feed to solvent extraction circuits to separate the individual rare earths. Cerium(III) may be separated from the other rare earths by oxidising it to cerium(IV), which precipitates as cerium(IV) hydroxide in chloride liquors. This oxidation step may be inserted either before rare earth separation by solvent extraction or between solvent extraction circuits. Although oxidation of cerium by sodium hypochlorite has been known for many years, detailed conditions for oxidation are not readily available. The effect of hypochlorite addition, temperature, pH and cerium concentration on oxidation of cerium(III) from synthetic solutions was investigated

Jan 1, 2014

By Patricio Berrios, David Barriga, Peter Amelunxen, Gerson Sandoval, Roger Amelunxen

Laboratory test equipment and methods have undergone relatively little change since their introduction in the 1950’s. The Denver sub-A cell is still by far the most commonly used laboratory batch cell, but bottom-driven and instrumented cells are beginning to appear. Test procedures have also changed little over the past 60 years, and most engineers continue to rely on empirical models for predicted plant scale performance from laboratory scale tests. This approach is problematic, because changes in the froth phase characteristics in the lab hamper the reliability and reproducibility of the empirical extrapolation to plant scale. In a previous work, the authors reported on the impact of froth recovery at the laboratory cell, showing that variability in the froth recovery can lead to significant error in the modeled kinetic rate constant unless it is properly accounted for in the scale-up model. In this work, we review the role of hydraulic entrainment in the lab cell, and how variability in particle specific gravity, shape factor, and froth residence time can impact the entrainment recovery.

Jan 1, 2014

By Jiongtian Liu, Guixia Fan, Caom Yijun

A cyclonic-static micro bubble flotation column (FCSMC) is an effective separation device for fine grain treatment. The separation of fine ilmenite by FCSMC was explored in this work. The influence of reagents dosage (regulator, collector and auxiliary collector), pulp density, circulation pressure and aeration quantity on TiO2grade and recovery wasinvestigated.The optimal conditions of a rougher are follows: pulp density 45%, pH 5.0, MOH collector dosage 2800 g/t, diesel oil dosage 700 g/t, circulationpressure 0.19 MPa, aeration quantity 0.8 m3/(m2•min). The optimal conditions of a cleaner are follows: pH 4.0, circulation pressures 0.16 MPa, and aeration quantity 0.5 m3/(m2•min).A pilot plant continuous test with a rougher-cleaner by FCSMC for 72 hours was proceeded under the optimum conditions. Compared with industrial flotation machines, the concentrate grade of FCSMC is 48.11% with an improvement of 1.08 percentagepoints, while the recovery is 82.36% with 13.64 percentagepoints increment. Moreover, the flowsheet is simplified from six parts (a rougher-two scavenger-three cleaner) in flotation machines to two parts (a rougher-cleaner) in FCSMC. Proofs were also provided by the analysis of the by-size grade and recovery of concentrate.Results show the FCSMC is an effective separation device to recover -74 µm size fraction.

Jan 1, 2014

By Ricardo Duque-Soto, Gonzalo Montes-Atenas

The depletion of water resources has posed an enormous challenge to the continuity of many mine sites, particularly those located in arid zones worldwide. In Chile, the use of seawater has been foreseen as one possibility to solve this problem. Nevertheless, the direct use of high ionic strength solutions such as those present in the sea has been found to have some drawbacks. Specifically, rhe extraction of copper from complex ores using high ionic strength solutions such as that of seawater has become one of the most relevant topics in the field of copper hydrometallurgy. This study aims to determine the effect of the degree of salinity on copper extraction kinetics in mixed oxide-sulfide ores. A leach protocol was implemented to study the extraction kinetics, varying the degree of salinity of the medium and the temperature. A thermodynamic model was developed to explain differences in the metal extraction. It was found that the ionic strength impacted positively the copper extraction, probably due to the reduction of the effective concentration in solution due to ionic interactions enhancing the diffusive mass transport of copper ions. This effect is observed to be enhanced when up to an overall salinity values close to 20gpl.

Jan 1, 2014