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By Jing Zhang, Qing Xiao, Xulong Liu, Qiuju Li

"Pickling sludge generated from stainless steel production process contains large quantity of Cr, Ni, and Fe. The disposal of and fill sludge directly not only leads to the heavy metal dissolves in the soil and underwater, but also loss value metals. However, the major mineral phases of value metal are hydroxides and there are lots of calcium fluoride and water in the sludge. So the pickling sludge has to be pretreated before reduction-magnetic separation. The TG analysis, reduction reaction and magnetic separation were all used to study the pickling sludge. The result indicated that up to 900°C the total weight loss of pickling sludge was 22.32%. The mass contents of Fe, Cr and Ni in the tailings (non-magnetic) were 4.27%, 0.067% and 0.041% respectively.IntroductionSince 21st century, the stainless steel production in the world has been continuously increasing because of its excellent performance [1]. However, high stainless steel production means a high pickling sludge production. For example, in a stainless steel plant with waste water quantity of 100m3 /h, the production of pickling sludge will exceed 15 Kt/a. Pickling is essential for generating of a homogeneous and corrosion-resistant surface during stainless steel production subsequent process. Pickling of stainless steels is predominantly carried out with an aggressive solution, sulfuric acid H2S04 or composed of nitric acid HN03 and hydrofluoric acid HF [2]. During the pickling process, the pickling acids are recovered through ion exchange and metal ions such as Fe3+, Cr3+ and Ni2+ get into the acids forming the pickling waste water [3]. Then, the pickling waste water is precipitated with lime, forming pickling hydroxide sludge. It is not feasible to recycle or treat the pickling sludge using conventional methods, because the sludge has high contents of calcium fluoride and water but low contents of iron, chromium and nickel. However, it would also pose a potential environmental problem if deposited outdoors over a long term because it contains heavy metals such as Cr and Ni. At present, solidification/stabilization (S/"

Jan 1, 2014

By Larry M. Southwick

There have recently been executives at major metals companies who have recommended that Greenfield Projects not be pursued. Greenfield includes not only new geographical locations, but also new technologies and new types of feed materials. In the middle part of the 20th Century, two such projects were successfully commercialized to recover nickel from Cuban lateritic ores. One project (at Nicaro) used the Caron ammonia-ammonium carbonate leach and the other (at Moa Bay) a high pressure acid leach. How both of these projects dealt with these Greenfield issues will be reviewed, based on the original reports that described the research and development of the plants. This study will include a review of the critical ore characterization and sorting issues, as well as the extractive metallurgical, product recovery and equipment selection and sizing problems and how they were solved at each stage of project development, from laboratory through one or more pilot scale plants to start up and operation. In one case, a major revision of the plant was made after several years of operation to correct operating, equipment selection and materials of construction problems that hindered economical operation. These descriptions will provide a guide through the complicated and critical issues that in recent times have caused many companies to give up on similar development. Even with the more advanced analytical and computational tools available to today’s mineralogists, engineers and metallurgists, the basic concepts with which these projects successfully addressed their sets of problems are still required. In addition, upper management, now perhaps further removed from hands-on experience than was common then, will see how complicated problems require intense and detailed effort to avoid failure in the field and capital blowouts. Build it and we will make it run, kicking the can down the road and borrowing operating and design concepts incorrectly on technological issues, or nine year olds on a sugar high making financial decisions are not philosophies by which to succeed with Greenfield Projects.

Jan 1, 2014

By Sarah Guzzelli, Enrigue Munaretti, Anneliese Botelho, Jair Koppe

Drill and Blast (D & B) is one of the main operations in the mining production cycle, which aims to fragment rock according to a pre-defined plan for proper loading, haulage and processing specifications. In this sense, data from a Brazilian iron ore mine was analyzed, given emphasis on blasthole length, subdrilling and stemming. The D & B report, including mining data such as number of blastholes, length, and diameter and stemming aspects, was analyzed in order to be able to compare these results with the blast design. The study showed significant differences between the designed blasting pattern and that one obtained by the operation. As a consequence, problems such as inadequate fragmentation, incorrect size distribution and loss of energy, were identified. For example, when stemming has a different length than it should have, noise and flyrock can occur, including inadequate fragmentation and vibration in both situations. Therefore, a comparison between the usual D & B procedures and recommended D & B design based on literature reveals the most important deviations and their consequences. The study intends to identify solutions for simple problems, improving D & B operations and safety practices.

Jan 1, 2014

By Garren Edwards, van der Westhuizen. Andre

"Due to the depletion of easily treated coarser ores, more mineralogically complex ores with smaller valuable mineral grain sizes are treated, the means to liberate these minerals lies in grinding finer (Partyka & Yan, 2007). Grinding to these fine sizes is energy intensive, and using standard ball mills are energy inefficient at these sizes (P80 < 75µm). Therefore, stirred mills are becoming increasingly prevalent in the mineral processing industry. In order to optimize these mills, the effects and mechanisms of the significant variables need to be understood. This paper investigates a laboratory scale vertical stirred mill (Deswik mill) in an ultra fine grinding application of a South African platinum ore. The operating variables that are considered are stirrer speed, media size, media filling, and slurry density. The resulting grinding efficiencies are considered in two ways. Firstly, a statistical model is fitted to identify the effect of the significant variables on grinding efficiency, and secondly, the grinding efficiencies are also considered in terms of a stress energy model to determine whether this can partly explain the grinding mechanism in this mill. A factorial design of experiments was used on three levels for each variable, such that only linear interactions, second order interactions and two variable interactions are included in the statistical model. The results show that tip speed, media size, percent solids and mill filling are all significant to the grind, at differing energy inputs in the grinding process. The interaction effects of these variables are also dependent on the energy inputs. The results also found that the Kwade stress energy model is applicable to this mill and can be very useful to find the most efficient operating conditions for this system. The most energy efficient operating conditions in terms of mill speed and media size were typically somewhat below the standard operating conditions and it is expected that this is most probably done in order to increase the grinding rate, but at the expense of sacrificing some grinding efficiency."

Jan 1, 2014

By Baokuan Li, Qiang Wang, Zhu He

"A mathematical model has been developed to investigate the magnetohydrodynamic (MHD), thermal, and solidified behavior in electroslag remelting process. Based on the finite volume method, a multiphase coupling MHD approach is employed to investigate the droplet formation as well as movement in molten slag under the action of an alternating current. The VOF formulation is adopted for interface tracking. The electrical potential method is adopted for the electric current and magnetic field. The Electromagnetic force and Joule heating are recalculated at each time step and then is implemented in the momentum and energy equations as a source term, respectively. Moreover, solidification of the metal is described by an enthalpy-based formulation, while the mushy zone is treated as a porous medium with porosity equal to the liquid fraction. The model is used to investigate the effect of electrode tip shape on MHD, thermal, and solidified behavior and provide valuable information.IntroductionElectroslag remelting (ESR) process has been used widely to produce high-performance alloys dedicated to critical application, such as hot work tool steels, nickel base alloys, the manufacture of components in aerospace and landbased turbines, etc. Figure 1 shows a schematic diagram of ESR process including a consumable electrode, a molten slag pool, a liquid metal pool, a solidified ingot, and a water-cooled mold. Alternating or direct current flows from the electrode to the water-cooled baseplate through the high resistivity calcium-fluoride-based molten slag which result in Joule heating and Electromagnetic force (EMF). Part of the Joule heating melts the electrode and the droplets travel through the slag and accumulate the liquid metal pool. The electrode is continuously advanced into the slag as it melts to build up an ingot of improved structure and composition by controlled solidification and chemical refinement. The metallurgical properties of the remelted ingot are really related to the solidification structure, which strongly depends on magnetohydrodynamic, thermal, and solidified behavior in the molten slag, liquid metal pool, and mushy zone."

Jan 1, 2014

By F. J. Sotiuo

Variability of the quality of phosphate ore feed to the flotation plant has been of great concern for the industry. This variability sometimes resulted in 10% to 50% decrease of P2O5 recovery, a reduction of P2O5 concentrate grade and/or both due to depression of the system. For this investigation, samples of refractory ore and easy-to-float ore were obtained from the same mining area in Central Florida; and then submitted to bench flotation tests using fatty acids (FA). To understand the cause of difference in flotation behavior of these apparently similar ores (grade, mineralogy, and physical appearance), bulk and surface characterization studies were conducted. Based on the results of characterization studies and bench flotation tests on both refractory and easy-to-float samples, it was possible to determine FA surface coverage. It was found that the surface coverage for the refractory ore was between 6.9% and 9.8%, corresponding to 0% and 80% recovery, respectively; whereas the easy-to-float ore showed surface coverage of 17.2% (89% recovery) to 24.6% (98% recovery). Since size analysis, surface area and pore size measurements showed small differences, it was thought that the surface coverage differences could be caused by the ad-sorption of natural compounds onto the phosphate ore surfaces, depressing the system. SEM, EDS, and Leaching and Solvent Extraction (LSX) studies were performed on the phosphate ores to demonstrate the proposed mechanism. This paper summarized our characterization studies, flotation results, and findings. The study showed that the new identified compounds were responsible for the flotation behaviors of the Florida refractory phosphate ores.

Jan 1, 2014

By K. Saberyan

In this study, solvent extraction of zirconium by using triphenylphosphine oxide as extractant has been investigated. The results showed that extraction of zirconium by triphenylphosphine oxides in nitric acid and hydrochloric acid media were negligible. Extraction of zirconium in acetic acid media with concentration of 0.01~0.2 M has been studied and the results showed that the maximum percent of zirconium extraction was 40% in acid acetic with concentration of 0.01 M. By addition complexing agents such as potassium thiocyanate with the concentration of 0.01~0.2 M zirconium extraction increased up to 86% in 0.2 M potassium thiocyanate. By addition of sodium salicylate with concentration of 0.01 M and in pH=2.5, the maximum extraction of 96% was achieved. The striping of zirconium from organic phase can be carried out by 0.5 M solution of sulfuric acid.

Jan 1, 2014

By Weiran Zuo, Emmy Manlapig, Fengnian Shi

The effect of metalliferous grains on electrical comminution efficiency was investigated by comparative experiments using natural rocks and synthetic samples. The result indicated that the existence of metalliferous grains affects the breakage probability and product size distribution of electrical comminution. On average, metalliferous grains increased the breakage probability of particle in the first pulse discharge by 55% and generated finer product at the coarse end. As a result, particles with metalliferous grains exhibited higher energy efficiency than that without metalliferous grain in electrical comminution. A positive linear relation between product fineness and specific energy in electrical comminution was observed. With the assistance of numerical simulation on the electrical field distribution of ore particle, the role of metalliferous grains in electrical comminution is confirmed and the mechanism of metalliferous grains effect is elucidated. Understanding of the effect of metalliferous grains on electrical comminution is important to evaluate the feasibility of applying electrical comminution to ores with different mineral composition, and to understand the breakage behavior in electrical comminution.

Jan 1, 2014

By Tchingis Lekhatinov, Lev Filippov, Vyacheslav Severov, Alexandre Matinin, Victor Samyguin, Inna Filippova

"Comparison of flotation efficiency of the new multi-zone flotation cell (MZFC) and different conventional cells was carried out at lab and pilot scales on the various samples: high contrast pyrite tailings and old copper containing tailings. MZFC is a cell of intensive flotation, which provides optimal hydrodynamic conditions for all flotation sub processes. Enhancing of particle attachment, creation of conditions for coalescent flotation, selection of spatially separated zones according to optimal hydrodynamic conditions for flotation sub-processes are proposed as main principles to design an MZFC. The bubbles/pulp stratification was pointed out as a limiting step in the existing intensive flotation machines. Two strategies to improve bubbles/pulp stratification in the MZFC were studied: (a) impact of pulp-bubble jet to the surface of a prismatic insert inside of cell, which provides the detachment of low hydrophobic particles from bubbles, and (b) profiling the pulp/bubbles jet from the reactors due to a specific geometry of cell walls. The new continuous MZFC devices were demonstrated similar or higher efficiency in comparison with laboratory batch flotation cells for pyrite flotation. Higher flotation efficiency (82%) with pure pyrite concentrate (51.2% of sulfur) and a recovery level of 92% was obtained in MZFC when the cell with stratification by impact was used. Similar results were obtained with old Cu-containing tailings. Although MZFC had 1.5 times greater yields of concentrate than a batch flotation cell, it provided the increase of chalcopyrite recovery by 29.4% and concentrate grade by 4.8%. An original organization of pulp/bubbles stratification in the separator part of the new intensive flotation machine using variable geometry inserts allowed the best flotation selectivity with a bubble mineral loading coefficient 1.5 fold higher than the laboratory mechanical or pilot cells."

Jan 1, 2014

By Seungwoo Park, Gaurav Soni, Roe-Hoan Yoon, Hyunsun Do, Kaiwu Huang

In a flotation froth (and foam), air bubbles become larger due to coalescence, causing bubble size to increase, bubble surface area to decrease, and hence casing less hydrophobic particles to drop off to the pulp phase below. Thus, bubble coarsening provides an important mechanism by which product grades are increased. On the other hand, excessive bubble coarsening results in low recoveries. In the present work, a model describing the process of bubbles becoming coarser in a foam as they rise to the top by deriving a mathematical relation between the Plateau border area, which controls film drainage rate, and the lamella film thickness, which controls bubble-coalescence rate. The model has been derived by assuming that liquid drainage rate increases due to slip at the air/water interface, and that the critical rupture thickness is determined by the capillary waves created by thermal motion. The model developed in the present work can predict the bubble size ratio between the top and bottom of a foam as functions of aeration rate, foam height, and surface tension (frother dosage). The model predictions are in good agreement with the changes in bubble sizes measured using a high-speed camera.

Jan 1, 2014

By C. B. Wu

This paper presents an analysis of comminution behavior of using cast iron segment (CIS) as fine grinding media with comparison to conventional steel ball. Grinding experiments utilize just one-size medium and mixed size media in laboratory were carried out and its efficiency is expected to be improved. The results show that no matter whether one-size medium or mixed size media employed, grinding efficiency of CIS media can be considerably equal to that of steel ball, on the other hand, grinding product by two kinds of media can conform to Robin-Rammler?s size characteristic curve and distribute in function of . )exp(100nbxy-= Comparing with steel ball, the milling capacity with CIS media could be increased up to about 8.6 percent, overcomminution decreased 3.96 in percentage and qualified size increased 3.98 in percentage in case of grinding fineness retained. At the same time, due to the improvement of grinding product size characteristic and its metal distribution characteristic, the grade and recovery of easy to separation size increased 0.24 in percentage and 6.47 in percentage respectively. Based on these results, the CIS media can be employed as novel fine medium for grinding process substituting for steel ball.

Jan 1, 2014

By X. S. Yuan

With a demand for increasing energy efficiency and a need for improving bitumen recovery, a highly integrated solution for sustainable lease development of Aurora North of Syncrude has been proposed and implementation plans are underway. Flocculation and thickening technology as an important component of the integrated solution provides Syncrude an opportunity of rapid heat recovery from tailings and more flexible tailings closure and reclamation options. Flocculation of fine-particle suspensions by polymers is a non-equilibrium process whose performance is strongly influenced by physical and chemical variables. While polymeric flocculants are frequently used to establish the chemical conditions favorable for flocculation, the actual performance of a flocculation process generally depends more on the physical variables, such as the hydrodynamic conditions in mixing the flocculants and slurry. In order to study the effect of hydrodynamic conditions on flocculation of Syncrude fine tailings, a standardized laboratory test procedure called power flocculation has been developed in comparison with the conventional manual mixing methods. It is shown that the agitation speed and time in conditioning the flocculant solution and the slurry have a profound effect on the flocculation performances measured by initial settling rates, supernatant clarity and sediment density. It was found that the optimum bench test conditions for power flocculation of Aurora fine tailings with a sand-to-fine ratio (SFR) of about 1:1 are conditioning of the flocculant solution and the tailings slurry at 250 rev/min to 300 rev/min in 20 s to 40 s. The test results are inter-preted with a flocculant adsorption/redistribution kinetic model that helps understanding of the effect of hydrodynamic conditions on flocculant adsorption, floc formation and floc growth.

Jan 1, 2014

By B S. Petri, N T. Rouse

Underground limestone mines generally lack air pressure monitoring procedures and instrumentation guidelines. The blasting industry also lacks an applicable source for air overpressure levels that are produced by blasting operations in underground mines. This became apparent during the development of a new underground limestone mine, where overpressure levels from production blasting needed to be estimated. During the development phase of the mine, it was imperative that newly constructed underground structures be capable of withstanding the overpressure produced by blasting. Therefore, a study was conducted to (1) identify and review any published studies for data that may be applicable, (2) identify the appropriate equipment required to record the overpressure levels, (3) determine the proper procedures for setting up the equipment and recording overpressure, and (4) provide an understanding of the nature of the air overpressure in a developing mine.

Jan 1, 2014

By William Conger, Greg Schick

Grinding media consumption is a major cost variable in industrial mineral comminution circuits. Specifically, industrial SAG media consumption results from a combination of surface abrasion wear, media breakage, surface spalling and rejection size from the mill. Three main consumption rates; weight of media consumed per time, per kWh and per weight of ore ground are defined and compared. Recent industrial data has provided an opportunity to relate consumption in terms of weight of media consumed to weight of ore ground (g/tonne) and weight of media consumed per kWh of energy consumed (g/kWh) with SAG specific grinding energy consumed (kWh/tonne). Using relationships developed from this data it is possible to project SAG media consumption in future mineral comminution circuits.

Jan 1, 2014

By Sydney Mantsho, Toni Streczynski, Manuel Gonzalez

"In 2013, the commissioning of the MillStar Stabilisation and FloatStar Stabilisation and Optimisation controllers were completed at the Cerro Bayo Silver (Ag) mine in Patagonia, Chile. The MillStar control system has stabilised the feed to the SAG mill as well as the density at the discharge end of the SAG mill and ball mill. The FloatStar Stabilisation and Optimisation controllers have successfully stabilised and optimised the flotation circuit to ensure consistent product quality within desired specifications.The mill feed is controlled utilising the MillStar Solids Feed controller. Additionally, the solids to liquid ratio into the SAG mill was controlled utilising the Mill Inlet Ratio controller in conjunction with the Solids Feed controller. The discharge end of the milling process is a highly interactive and complex system. The use of a Robust Nonlinear Model Predicative Controller (RNMPC) was ideally suited to control this section of the process. On the Cerro Bayo milling circuit, the RNMPC was used to control the mill discharge sump level and the primary cyclone feed density to produce a more consistent feed to the flotation circuit.Three levels of the FloatStar control system were installed, for flotation stability, concentrate flow stability as well as grade optimisation. The Level Stabiliser was used to stabilise the level control on 6 flotation banks. The Flow Optimiser was commissioned on the Rougher, Scavenger and Cleaner concentrate sumps to stabilise concentrate flow from the flotation cells. The Grade Recovery Optimiser was commissioned on the Roughers section. A number of instrumentation challenges were identified which limited the overall benefit derived from the system. Once these were addressed, the performance was optimised. The overall benefit provided by the system was observed in terms of the improvements in Ag recovery."

Jan 1, 2014

By Xin-liang Gao, Qing Li, Gui-qin Fu, Duo Jin, Miao-yong Zhu

"Optical microscope together with alternative wet-dry cyclic accelerated corrosion tests and XRD, SEM were employed on bridge weathering steel samples with different Mn and Ni contents which were vacuum induction melted and rolled to study their effects on the microstructure and rust layer evolution in er' containing condition. The results show that the microstructure is mainly ferrite and pearlite when Mn and Ni contents are 0.75 %, 0.42 %, respectively. Both the increase of Mn and Ni contents will make pearlite disappear while granular bainite appear, meanwhile the grain size decreases. With the increase of Mn content, the corrosion rate decreases in the initial stage, but the effect becomes little in the later stage. The increase of Ni not only improves the corrosion resistance of steel base at the initial stage but also hinders the tendency of further corrosion. As Mn content increases, a-FeOOH contents in rust layer decreases. With increase of Ni content, the content of a-FeOOH in the rust increases while that ofy-FeOOH decreases.IntroductionWeathering steels had been ~radually applied in manufacture of bridges owing to reducing the corrosion rate remarkably [I- l .Good weldability was needed for high performance bridge weathering steels. Since carbon was thought to be bad for weldability, low carbon content steel was adopted and Mn was added to amend the mechanical strength loss. Some scholars[6, 7l believed that Mn was beneficial for increasing corrosion resistance performance of the steel in marine atmospheric environment. Some scholars [S, 9l thought that Mn had little effect on corrosion resistance in marine atmospheric environment. Presently, the effect of Mn on bridge weathering steel in marine atmospheric environment still remained poorly understood. Ni was considered to be beneficial for increasing corrosion resistance performance in marine atmospheric environment [JO-l4l However, the high cost limited its application range. What would bring to the rust and corrosion by decreasing Ni content needed further research.Most researchers assumed that microstructures only affected the corrosion behavior of bare steel. But the study of Guo et al. P5l showed that the homogenous microstructures were beneficial for the corrosion resistance of steels. The effect of Mn, Ni content change on microstructure and microstructure on corrosion still remained poorly understood. In the present work, the effect of Mn and Ni on the microstructures of steel matrix, as well as the microstructures on the rust and corrosion was investigated."

Jan 1, 2014

By Turgay Gurun

"Digital simulation can be used as an analytical tool to optimize the design of crushing plants without need for large-scale experimental programs.General mathematical description of a crushing operation permits the simulation of a crushing plant flowsheet under various operating conditions. The process model encompasses multistage open- and closed-circuit crushing of hard and soft rock. Crushing balances are analyzed in the light of crusher and screen performance and a comparison of different closed-circuit arrangements is made in terms of process and layout criteria.The simulation model allows comparison of process alternatives to be made in terms of equipment selection and capital and operating cost estimation. It thus provides the pertinent practical information to maximize plant efficiency, and to minimize expenditures in such items as equipment, structures, power consumption, and so on."

Jan 1, 2014

By William Reisz

Managing the blast site at almost any operation can be a daunting task. There are so many details that must be observed, understood, and acted upon. It goes without saying that there are no two locations that have the exact same challenges and concerns. The level and the extent of these challenges can vary widely.

Jan 1, 2014

By Kyle P. Flynn, Frank J. Hrach, James D. Bittner

ST Equipment & Technology, LLC (STET) has developed a processing system based on tribo-electrostatic belt separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to other electrostatic separation processes that are typically limited to particles greater than 75µm in size, the triboelectric belt separator is ideally suited for separation of very fine (<1µm) to moderately coarse (300µm) particles with very high throughput. The high efficiency multi-stage separation through internal charging/recharging and recycle results in far superior separations that can be achieved with a conventional single-stage free-fall tribo-electrostatic separator. The triboelectric belt separator technology has been used to separate a wide range of materials including mixtures of glassy aluminosilicates/carbon, calcite/quartz, talc/magnesite, and barite/quartz. An economic comparison of using the tribo-electrostatic belt separation versus conventional flotation for barite / quartz separation illustrates the advantages of dry processing for minerals.

Jan 1, 2014

By D. Z. Wei

Amine collectors with different structures and length of carbon-chain have been widely used in oxide minerals flotation. In this paper, we synthesized one kind of binary amine, N-dodecylethyl- enediamine, and studied its flotation performance. From the results, we can see N-dodecylethylenediamine which has excellent frothability, is a new type of chelating surfactants. And it also has fine catchability to quartz and hematite. The recoveries of quartz and hematite increase with the augment of N-dodecylethylenediamine concentration. When the dosage of collector reaches 100g/t, the recoveries of quartz and hematite achieve 95.30% and 87.89% respectively. Meanwhile, the influence of pH on the flotation recovery of hematite is studied and test results showed that, as pH increases, the flotation recovery rises until pH=9. And the recovery reaches its maximum in alkalescence. The collector has better flotation capability to quartz than to hematite. And the maximum recovery of quartz is gained in alkaline media, which reaches 97.87%. Finally, the flotation mechanism of N-dodecylethylenediamine is discussed through the measurement of infrared spectroscopy.

Jan 1, 2014