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By Mehdi Asadi, Heinz Palkowski

"In recent years, the increased demand for advanced high-strength steels (AHSS) mainly had been driven by the need of the automotive industry to reduce weight and to improve safety. Beside good ductility and high strength, those steels have a high bake hardening (BH) effect, giving additional contribution to the strength of structural parts, subjected to the paint baking process. In this paper we concentrate results gained for hot rolled dual phase (DP) steels.For the simulation of changing process conditions within the final hot rolling the specimens were hot deformed using different schedules of temperatures and reductions, selected according to the non-recrystallization temperature (TnRX). It was possible to refine the DP steel structure by control-ling the deformation temperature and the amount of strain below TnRX during the thermo-mechanical controlled processing (TMCP). This structure refinement resulted in an improvement of the strength and BH behaviour. A wide spectrum of mechanical properties could be obtained depending on the different hot deformation schedules. The best strength and BH levels were recorded for the deformation below TnRX at the highest amount of strain.IntroductionDP steels are characterized by a good formability, high strength and a good compromise between strength and ductility [1]. Moreover, the DP steels exhibit a continuous yielding behaviour, low yield point and a high strain-hardening coefficient [2]. Furthermore, the DP steels often show a large potential for bake hardening (BH). BH refers to the increase in yield strength as a result of the paint baking treatment of the shaped auto-body parts. The primary mechanism that causes the additional strengthening is the immobilization of dislocations by the segregation of interstitial atoms, known as classical static strain aging [3]. The increase of strength thus achieved allows a further reduction of sheet thickness and improves the crash safety and the dent resistance. The BH of special steel qualities is technically used in DP, where e.g. the increase in strength is realized in the final heat treatment [4]. Previous own investigations [5-6] stated that the BH effect of DP is much stronger than that one for conventional BH steels."

Jan 1, 2012

By Mari Naess, Jan Erik Olsen, Gabriella Tranell

"Fume, also known as dust, is produced during metal refining. Exposure to fume is damaging to the health of plant operators. A mathematical model has been developed to study the different factors governing the fuming mechanism. It is shown that natural convection is the main driving force of the phenomenon, and that the fuming rate is highly sensitive to the area of the exposed metal surface. A new feature introduced in the modeling concept is the ability to include a gas flux of unconsumed process gas flowing up through the metal surface. This reduces the fuming rate, and should normally not be neglected.IntroductionFormation of fume from the ladle in which metal is refined into its final specifications is an environmental issue of importance for the working environment in the production plant. In layman-term fume is often known as dust. It is formed when metal reacts with oxygen. As an example of a fuming process, we will focus on ladle refining of silicon. Note that many of the principles and conclusions will apply to other metal refining processes. For silicon production, silica fume (S1O2) is produced when silicon metal (Si) reacts with oxygen (O2).Silicon is produced in a submerged arc furnace. The metal is tapped from the furnace into a ladle for refining. The refining is conducted by injecting a mixture of air and pure oxygen at the bottom of the ladle. The oxygen reacts with the metal and the impurities, and the amount of impurities is reduced according to product specification. At the ladle surface, metal also reacts with oxygen present in the air surrounding the ladle. This reaction produces silica fume as illustrated in Figure 1."

Jan 1, 2012

By S. E. Younis

The mining industry is currently looking to better understand, anticipate, and be able to mitigate business and operational risks in order to deliver the rewards of risk taking, and to minimize the frequency and impact of risk on the downside. Assessing risk works from the premise that the identification and management of existing risks can be very challenging, especially when threats are not easy to detect, the likelihood of occurrence is difficult to gauge, and/or the consequences are uncertain. Some approach this as a ?check the box? task, even though fire and safety incidents continue to occur and investigations often find the hazard analyses did not properly identify the cause or consequence. You cannot engineer protective designs and safeguards for causes and consequences that have not been identified appropriately. For the mining industry, risk management is an important tool for making critical decisions and, in some cases, meeting regulatory requirements. Providing high-quality documentation that meets both regulatory and corporate requirements is critical for maintaining safe, uninterrupted mining operations. Risk management is a five-part process: 1. Identify the hazards and their causes, 2. Determine the hazard consequences, 3. Calculate the frequency of occurrence, 4. Quantify the risk associated with the system, process, or procedure, and 5. Provide feasible solutions for the risks

Jan 1, 2012

By J. A. Drozdiak

In this paper we examine, through pilot-scale testing, the possibility of operating a circuit comprised of two stages of HPGR comminution, followed by grinding through a horizontal stirred mill. In order to assess whether the novel circuit design could achieve the reduced energy requirements indicated in the literature, two more-established circuits, a cone crusher / ball mill and an HPGR / ball mill, were examined using a combination of testing and flowsheet simulation. The results showed that, based solely on the specific energy requirements for comminution, the HPGR / stirred mill circuit achieved a reduction of 9.2% and 16.7% over the HPGR / ball mill and cone crusher / ball mill circuits, respectively.

Jan 1, 2012

By Nathália M. Campelo, Alexandre P. Umpierre, Fabricio Machado

"The present work illustrates the reuse of macoporous anion exchange resins (employed for decolorization of solutions of organic substances such as sugar syrup and fruit juice concentrates in the soft-drink and beverages industries), based on crosslinked styrene-divinyl benzene copolymer (Sty-DVB) to the production of polymeric materials. Micro-sized particles of polystyrene and poly(styrene-ethyl acrylate) were obtained by mass-suspension sequential polymerization process. The proposed experimental technique was able to perform proper dispersion of the Sty-DVB in the thermoplastic matrix of polystyrene. The final material showed good thermal stability, showing degradation profile similar to that observed for the pure polystyrene. It was also noticed that polymer particles with spherical morphology can be obtained. In addition, the incorporation of ethyl acrylate monomer into the polystyrene chains minimizes the undesirable effect of fracture in polymeric particles, improving the mechanical and end-use properties of the final polymeric composite.IntroductionIn face of the industrial development, the development of techniques that are safer and less aggressive to the environment has become one of the main challenges in the industrial field. In this scenario, processes more efficient in terms of energy and raw materials can be regarded as an important requirement to minimize the production of waste. The reuse of waste becomes an attractive alternative for most industries engaged with sustainable and economic development.In this context, both the primary and the secondary mechanical recycling are potentially attractive because they allow for reuse of polymeric waste (post-industrial or post-consumer) as a source of raw material in the supply chain by using traditional methods of processing, so that the final materials can exhibit characteristics similar or superior to those observed in the virgins polymeric materials, considered as a starting product in the process of reuse of plastics [1-3]."

Jan 1, 2012

By Mark Weidenbach

OZ Minerals owns and operates the Prominent Hill copper-gold concentrator in South Australia, built in 2008 and commissioned in early 2009. The concentrator operates via semi autogenous grinding in a thirty four foot ThyssenKrupp Polysius mill followed by a twenty four foot Polysius ball mill in closed circuit with hydro cyclones, designed for an ore throughput of eight million tonnes per annum. The main aspects of designing the circuit are discussed along with the issues faced in the early stages of operation. A review of the optimization strategy applied to the milling circuit such as cyclone optimization, advanced process control strategy implementation and reline management to improve availability is then discussed highlighting areas of significant process improvement that have seen the plant exceed nameplate throughputs above nine million tonnes per annum.

Jan 1, 2012

By D. Duffy, V. Papangelakis

"MgCl2 brines present a number of potential advantages for the processing of saprolite ores for nickel production. With a chloride system it is economically requisite to recover hydrochloric acid, which can be performed in a more energy efficient manner by precipitation and subsequent decomposition, as compared with conventional pyrohydrolysis. In addition, concentrated MgCl2 solutions enhance the activity of acid used, allow atmospheric leaching at elevated temperature and inhibit magnesium dissolution, which reduces acid consumption and increases metal selectivity. Leaching and iron control experiments have been conducted in concentrated MgCl2 brines, up to 4.5 m, to determine the most amenable process conditions. INTRODUCTIONChloride metallurgy has received an increasing amount of attention in recent years, especially with respect to the treatment of nickel laterites. Although the limonitic fraction can sometimes be economically treated by High Pressure Acid Leaching (HPAL), acid-consumption problems are encountered with the higher magnesium content of the saprolite fraction. As magnesium does not hydrolyze under HPAL conditions, as iron and aluminum do, any sulphuric acid used to leach magnesium is subsequently neutralized and wasted. In addition, this magnesium must later be disposed of in some fashion, further complicating the process. The most common method used to process saprolite is the Rotary Kiln-Electric Furnace (RKEF). This uses a kiln to dry and preferentially reduce nickel, before sending the calcine to an electric furnace. Although nickel recoveries are high, and the problems of acid consumption are avoided, the capital and energy costs associated with this process are high (de Bakker, 2011).The problems outlined above have led to the investigation of an atmospheric chloride process for the treatment of saprolite ores. The use of a chloride system presents a number of advantages, but also a few limitations. Metal chlorides tend to be very soluble, with a few notable exceptions (silver, mercury and lead), allowing for smaller processing equipment through more concentrated solutions. This solubility also serves to reduce the potential for scale formation. In addition, a hydrochloric acid leach is more aggressive than a comparable sulphuric acid system, and the activity of the hydrogen ion can be augmented by further chloride addition (Peek, 2011). This activity augmentation in concentrated chloride systems, first reported by Jansz, has repeatedly been referenced as a motivating factor behind chloride hydrometallurgy (Jansz, 1983; Harris and Magee, 2003; Harris et al., 2004; Demopoulos et al., 2008; McDonald and Whittington, 2008; Demopoulos, 2011; Peek, 2011; Verhulst and Lakshmanan, 2011). This activity increase allows a similar amount of acid to perform more in a concentrated solution than in a dilute solution, decreasing overall acid requirements. As such, much focus has been placed on leaching in concentrated chloride systems, or brines, using calcium, magnesium or sodium as the cation (McDonald and Whittington, 2008)."

Jan 1, 2012

By W. Y. Kim, K. H. Song, K. Nakata

"The present study was carried out to evaluate the mechanical properties of friction stir welded Inconel 600/SS 400 lap joints. In this process, friction stir welding (FSW) was performed at a tool rotation speed of 200 rpm and welding speed of 100 mm1min, and argon gas was utilized to prevent surface oxidation during the welding. Application of FSW notably decreases the grain size of Inconel 600 alloy from 20 µm in the base material to 8 ~ in the stir zone. However, the grain size of SS 400 in the weld zone was slightly coarsened, when compared to the base material. Also, the hooking in the advancing side and the intermetal1ic compounds (M7C3) in the weld interface between Incone1 600 and SS 400 were well formed. These intermetallic compounds and hooking were effective to increase in mechanical properties such as tensile and peel strengths.IntroductionFriction stir welding (FSW), applicable welding process at solid state, has several advantages in defect suppression such as blow hole, segregation and cracking which mainly occurs in fusion welding [1, 2]. Notable grain refinement in the stir zone due to FSW can expect the outstanding increase in mechanical properties of the welds. In constructing the chemical and power plants, Ni base superal10ys have been used in many parts, moreover, fusion welding as construct method, such as gas tungsten arc welding, electron beam welding and laser welding, has been mainly used [3-5]. However, fusion welding has a limit in an increase in chemical and mechanical properties in the welds. Lately, Ni base superalloys to which FSW applied have been reported with notable enhancement in mechanical properties, which resulted from refined grains in the welds [6-10]. These researches showed the possibility in applying the FSW, directly."

Jan 1, 2012

It is widely accepted that the type of grinding media has an impact on the grinding chemistry and subsequent flotation behaviour of the sulphide minerals being separated. There are countless laboratory investigations demonstrating that inert grinding media produces more oxidizing pulp potentials, reduced levels of grinding media corrosion products, and superior concentrate grades and valuable metal recoveries. However, taking these results to industrial scale has proved difficult. This paper provides details of the protocol developed and used during a high-chrome grinding media plant trial. It describes the test regime employed to measure changes in pulp chemistry as well as concentrate grades and recoveries to produce a statistically meaningful result. The work also highlighted the need for close cooperation between the metallurgists on site and the researchers conducting the trial. To demonstrate the protocol, data gathered during a plant trail in a PGM concentrate will be presented describing the changes in pulp chemistry and metallurgical response observed.

Jan 1, 2012

By Micheal McCarter, Biswadeep Saha, Meenakshisundaram Ramanathan, Chai Ren, Sivaraman Guruswamy

"Three-point bend test was used to study the effect of electrochemically charged hydrogen and magnetic field on the embrittlement behavior of AISI 4340 steel in this work. Acoustic emission signals were collected during the test and analyzed to gain an understanding of the crack growth process. Cathodic hydrogen charging in AISI 4340 steel resulted in drastic reduction of ductility and strength. Hydrogen embrittlement was characterized by a change in fracture surface from dimpled ductile surface to quasi cleavage type fracture. No significant effect was observed in the presence of magnetic field. The acoustic emission signals collected during the test provided an indication of the extent of energy released during the crack growth process.*Support of this work by NSF through the award DMR-0854166 is gratefully acknowledgedIntroductionGrowing interest in hydrogen as a clean fuel and use of steel and other iron based alloys for storage and transport of hydrogen has led to extensive study of the influence of hydrogen on the mechanical properties of these alloys. Hydrogen interaction with materials may result in degradation of mechanical properties. Embrittlement, either ductile or brittle, can be described as a condition which decreases the toughness of the material or increases the ease of crack growth. Hydrogen present even in few parts per million is sufficient to embrittle steels at room temperature [1]. In most cases, hydrogen exposure is through an electrochemical process in aqueous corroding environments. In such cases, they are prone to be exposed simultaneously to electrically induced magnetic fields, which are also believed to affect the hydrogen embrittlement susceptibility of these alloys. So it is also important to study the effect of magnetic field on the hydrogen embrittlement susceptibility. Hydrogen solubility by electrochemical process in aqueous solution is proportional to square root of current density for iron. [2,3]"

Jan 1, 2012

By J. Cui, Z. Meng, W. Zhao

"The decomposition of rare earth concentrates containing bastnasite and monazite by alkali solutions has been investigated. A slurry of the rare earth concentrate and the alkali solutions was calcined at different temperatures. The impacts of calcination temperature on the decomposition of rare earth minerals, the oxidation of cerium, the deportment of fluorine and phosphorous, and the adaptability of the method to the different grades of rare earth concentrate were all studied. A possible technique for comprehensive recovery is proposed in which the chemical elements such as rare earth, fluorine, phosphorus, calcium, iron and thorium could be recycled or recovered. INTRODUCTIONThe liquid alkali decomposition method is an important technique for the decomposition of mixed rare earth concentrates. The technique is relatively clean compared with the sulfuric acid roasting method. However, its operation is intermittent rather than continuous. The two-step solid-liquid reaction and the subsequent water washing make it not very suitable for mass production and application. An important reason for the disadvantage is that an additional process of ""calcium removal by acid leaching"" is needed for the technique. The content of calcium in Baotou rare earth concentrates is usually 6-12%. The requirement of the current technique is that the content of calcium should be reduced to about 0.2% after the calcium removal process. Otherwise, the decomposition and leaching of rare earth will be affected. Therefore, calcium removal by acid leaching is a necessity before the alkali decomposition process is carried out. Research on different alkali decomposition techniques has been conducted with prior calcium removal by acid leaching (Xu, 1995; Yu, 1993; Han, Li, Chang, Liu & Xu, 1985). There have been some investigations of direct decomposition of the bastnasite (Feng, Pan & Li, 1998; Zhao, Zhang, Yang & Liu, 2002)and monazite (Sun, Li, Li, Su, Zhao & Liu, 1998; Zhou, 2005) by alkali-liquid, however, all studies were carried out in solid-liquid reaction system, and continuous calcination studies have not been reported.This paper investigates the process of direct decomposition of Baotou rare earth concentrates by continuous calcination with concentrated alkali. Using the rotary tubular electric furnace, the mixture of rare earth concentrate and concentrated alkali solution were decomposed continuously. Satisfactory decomposition results were achieved. A method for clean processing and comprehensive resource recovery from Baotou rare earth concentrates is proposed."

Jan 1, 2012

By B. T. Stanley

Traditional methods of creating a water tight shaft liner involve the use of segmented or welded steel. When shafts are located in ground that exhibits extremely difficult conditions of high water inflow and hydraulic pressure, composite liners are often combined with ground freezing during construction. The authors were searching for a cost effective and more flexible solution to hydrostatic liners design than the traditional concrete/steel composite design used so far. Searching through new technologies developed for tunneling applications, sprayed on membranes systems seemed very promising but were not developed for the specific circumstances encountered in shaft sinking applications where ground freezing is involved. Even though freezing is a very effective technique, it creates adverse temperature conditions for the application of spray on membranes. In addition, application and hydrating cure times for those membranes products ranged between six to twenty-four hours under ideal conditions (usually temperatures well above freezing point), which eliminated them from consideration in a shaft sinking cycle. While researching different spray on membrane materials, it was discovered that Stirling Lloyd Polychem Ltd. has developed and proven a different membrane material for waterproofing liners in different tunneling applications. The characteristics of the membrane exceeds the pressure parameters encountered in frozen shaft sinking operations, and the chemical cure times were reduced to one hour per layer which worked well into the shaft sinking cycle times. More over their system included a quality control procedure that allowed insuring integrity of the membrane at application time, a very desirable feature for shaft liner construction. However, the frozen rock surface still presented an unknown in the cure time and stability equation. As all membrane products a shotcrete substrate is usually required prior to application. The hypothesis used by the author was to use this shotcrete layer, not only as a substrate, but also as a thermal insulation against the frozen rock and the membrane during both application and curing time. The authors knew from experience that shotcrete could be applied successfully over frozen rock. But the shotcrete temperature curve over time was unknown and no information were found in the available literature. Testing was required to determine whether a suitable mix of shotcrete could be applied to the frozen shaft wall to provide enough heat of hydration for a suitable period of time to create conditions suitable for membrane application and curing.

Jan 1, 2012

By E. Krause, V. G. Papangelakis, S. Garg, R. Mahadevan, E. Edwards

"Bioleaching uses iron and sulfur-oxidizing bacteria to extract base metals from sulfide minerals. As bioleaching involves breaking the iron-sulfur bonds by ferric attack, the biologically mediated rate of iron oxidation is recognized to play a key role in influencing the overall kinetics. In this study, we investigate the catalytic ability of an indigenous AMD culture for oxidizing Fe(II) in solution. This culture was subsequently adapted on pyrrhotite tailings (0.6% Ni) by gradually increasing the solids loading. Results from this study show that such an adaptation reduces the initial lag phase in the biotic oxidation of Fe(II), thereby allowing for a higher Ni extraction when compared to experiments with an un-adapted culture at a similar solids loading. The use of adapted cultures also helps to reduce the residence time for bioleaching of Ni from pyrrhotite tailings. INTRODUCTIONAs the world demand for pure base metals grows; the mining industry is increasingly faced with the burden of processing lower grade ores and mining waste streams in order to recover the occluded metal VALUES ((Watling, 2006). The extractive metallurgy of nickel from sulfide minerals focuses on using a combination of mineral processing, pyrometallurgical (smelting) and hydrometallurgical techniques to extract Ni from its ore bodies.Pyrrhotite (Fe1-xS) is commonly found in association with pentlandite and chalcopyrite in sulfidic Ni ores, such as those found in Sudbury, Ontario, and in Russia, e.g. Norilsk. The vast majority of this pyrrhotite needs to be removed using mineral processing techniques, in order to minimize the Fe and S contents of the concentrates that proceed on to smelting. If all pyrrhotite were left in the concentrate, much more slag and SO2 would be produced, and the smelter throughput would be limited. Beneficiation of Ni sulfide ores leads to the rejection of unwanted constituents as mining wastes, which may still contain extractable amounts of Ni (Edgar Peek et al., 2010)."

Jan 1, 2012

By O. A. Olaseinde

The 2101 lean duplex stainless steel has wide potential application in storage, heat exchangers, and in the oil and gas industries. This work investigates the electrochemical behaviour of 2101 duplex stainless steel with an addition of 0.15 wt% ruthenium, using potentiodynamic techniques in 1M H2SO4 at 25º, 40º, 60º, and 80ºC. The microstructures of samples were characterized using optical metallography and scanning electron microscopy. The results showed that the ruthenium addition moved the corrosion potential of alloy 2101 to a more positive potential. All samples containing ruthenium displayed longer passive regions at 25°C and 80°C compared to those without ruthenium. Alloys without ruthenium had higher critical current density (icrit) values when compared to the alloys with ruthenium. Ruthenium additions decreased the passive current densities and inhibited anodic dissolution. At room temperature the corrosion rate of alloys with ruthenium was lower than these without ruthenium.

Jan 1, 2012

By L. Dufourm

This paper presents a review of plant layout considerations incorporated into recent designs of SAG/Ball mill circuits for two medium sized concentrators. The plant layouts presented and the design concepts discussed, relate to smaller SAG circuits, but can equally apply to larger milling circuits. Included are design concepts and ideas introduced by the various project teams, and the focus is on the primary factors of any layout design which are safety, constructability, operability, and capital cost.

Jan 1, 2012

By Michaela Dina Stanescu, Emilia Visileanu, Eftalea Carpus

"The recovery and reintroduction into the economic circuit of the textile material resources must be considered as component parts of the strategies of harmonizing the relationships between the economic growth, consumption of natural resources and environmental protection of the existing socio-economic system.The waste recovery for ensuring a sustainable development is a major concern of all industrial researches. In the textile domain, the concern in this matter is becoming more evident. An important role in manufacturing textile products it has the notion of eco-design, which has grown considerably over the last twenty years with increasing awareness of environmental and social problems in the industry.Introduction“Humanity must learn from the global financial and economic crisis experience""- is the conclusion of the policy makers who should develop a strategy designed to reinvigorate the economy and make possible an"" intelligent, sustainable and favourable to inclusion” growth, by a better coordination of national and European policies.The new vision for social market economy is based on three priority areas: smart economic growth, the development of an economy based on knowledge and innovation; sustainable economic growth, the promotion of a competitive economy with low carbon emissions and an efficient use of resources, as well as an inclusive economic growth, the promotion of an economy with high degree labour employment, which would generate social cohesion. The recovery and reintroduction into the economic circuit of the textile material resources must be considered as component parts of the strategies of harmonizing the relationships between the economic growth, consumption of natural resources and environmental protection of the existing socio-economic system.The waste recovery for ensuring a sustainable development is a major concern of all industrial researches. In the textile domain, the concern in this matter is becoming more evident. It is obvious that at the origin of pollution there are the technological processes of textile processing with impact on air, water, soil, as well as the storage processes. In all phases of obtaining a product, a series of secondary products and textile wastes with impact on the environment occur. The product used becomes also a factor of environmental pollution, which in most cases fails to assimilate."

Jan 1, 2012

Rock mass classification systems are extensively used in rock engineering design work, and mine design is no exception. Among the systems most widely used for mining-related design work are the NGI 0-system (Barton et al., 1974), the RMR system (Bieniawski, 1976), the MRMR system (Laubscher and Taylor, 1976) and, more recently, the GSI system (Hoek et al., 1998). Classifying the rock mass is widely seen as being the fieldwork required to characterize the rock mass and enable the application of empirical design methods associated with the different classification systems. This paper argues that it is fundamentally important to recognize the distinction between rock mass characterization and rock mass classification. These two processes should, in most cases, be separated from each other. Rock mass characterization should be used to determine the intrinsic properties of the rock mass independently of the application; i.e. independent from the infrastructure to be designed, the size, shape, and orientation of the excavation(s) or pillar(s), etc. Rock mass characterization should also be compatible with most classification systems and empirical design methods to be used. Rock mass characterization is the background fieldwork required to perform rock mass classification and/or engineering design work. Rock mass classification is the subsequent step to the characterization, and an integral part of the design process. Parameters that vary according to the design, such as the relative orientation of geological structures compared to the opening or the mine-induced stresses, should be calculated as part of the rock mass classification and design process, rather than during the rock mass characterization process. The failure to distinguish between rock mass characterization and rock mass classification can lead to major design errors and poor results.

Jan 1, 2012

By Yves Fautrelle, Kader Zaidat, Hervé Combeau, Miha Zaloznik, Mohammed M'Hamdi, Bachir Saadi, Xiaodong Wang, Knut Omdal Tveito

"Numerical simulations of macrosegregation formation during horizontal solidification of a hypoeutectic Sn-Pb alloy in a rectangular cavity is presented and compared to experimental results. The experiment involves a melting phase, a holding stage at constant temperature with/without application of electromagnetic stirring, and finally solidification. We simulate all stages of the experiment and study the segregation of Pb throughout the experiment. A twophase volume averaged model is used for the numerical simulations, accounting for thermosolutal convection and assuming perfect microscopic mixing (lever rule). The influence of the melting phase and the electromagnetic stirring is studied with different cases to illustrate the consequences on the flow pattern and Pb segregation. The numerical simulations are compared to the experimental data and the impact of chemical inhomogeneities prior to solidification on macrosegregation formation is discussed.IntroductionMany extensive investigations have been performed so far on the solidification of metallic alloys. However, the melting process of metallic alloy has not attracted attention in a same manner. Nevertheless, melting of alloy may put forth peculiar effects as described in the present paper. It has been observed from a benchmark experiment [1, 2] that significant stratification might arise during the melting process of Sn-Pb alloy. That effect was put forth thanks to the analysis of the experimental temperature distribution which indicated that the convective fluid flow was almost zero. The effect was enhanced when the lead composition was higher (above 6wt.%). The present paper is aimed at confirming that the melting of an alloy containing a heavier solute may be accompanied with a stratification of the solute which exerts a stabilizing effect on the convective fluid flow. Results obtained from numerical modeling are compared with experimental data obtained from the benchmark facility."

Jan 1, 2012

By Oleksandr Liaskovskiy, Sergey Beringov, Sergiy Yatsuk, Timur Vlasenko, Iryna Buchovska

"Working with solar-grade silicon for solar cells application usually meets some difficulties in comparison to polysilicon produced by Siemens method: higher impurities content leads to lower yield, worse electro-physical parameters and poor performance in solar cells application. However some adjustments in ingot production can show significant improvements in quality of final product: crystalline wafers and cells.Recent investigations have shown that solar-grade silicon is suitable for high effective production process such as mono-like multicrystalline wafer production. Production-scale lots made at Pillar show promising results for solar-grade silicon application: high-quality wafers with significantly big crystalline grains of <100> orientation.IntroductionThe standard technology of producing multicrystalline silicon ingots by directional solidification method in quartz crucibles has a number of disadvantages resulting in limited efficiency of solar cells made of multicrystalline material: crystallites of multicrystalline ingot are relatively small (down to 5 mm size), grain borders of crystallites contain parasitic impurities such as metals, silicon nitride etc., crystallographic orientation of crystallites is random. The listed deficiencies are an integral characteristic of the technology which affects the efficiency of solar cells, such as presence of solar cells with low efficiency even at a high level of average efficiency, problems with shunted cells, silicon nitride inclusions, which adversely affect cell efficiency and are centres for silicon carbide formation, impossibility of application of high effective alkaline texturing etc. Also with regard to the targets set by photovoltaic to reduce the cost per Wp in the nearest future, standard technology of multicrystalline silicon ingots production by directional solidification faces certain challenges some of which are hard to overcome due to rather low efficiency of solar cells made of multicrystalline wafers. Therefore alternative methods of multicrystalline silicon production for photovoltaic application having a number of advantages in comparison to traditional technology are developing rapidly."

Jan 1, 2012

By Lucas Nana Wiredu Damoah, Lifeng Zhang

"Increasing demand for Solar Grade Silicon (SoG-Si) due to rising interest in renewable energy has lead to increased SoG-Si Top – cut scraps generated from the multi-crystalline silicon making process. Due to the high cost of SoG-Si and the potential to use the top-cut scraps as feedstock material, there has been increased effort to develop cost effective and efficient technologies. As a result, several methods to recycle the top-cut scraps are currently been applied, and researched. These include settling under gravitation field, which is a slow process to be industrially applicable. Natural settling of inclusions by gravitational force is a slow process and not attractive to the industry. Recent experiments on Top-cut SoG-Si scrap under high frequency, high voltage, electromagnetic field showed that SiC inclusions settled within a short time to the bottom of the crucible and the characteristic rod-like morphologies of Si3N4 inclusions in SoG-Si were not detected. This study investigates the enhanced settling of SiC inclusions and the behavior of Si3N4 particles under the influence of high frequency, high voltage, electromagnetic field in Top-cut SoG-Si.IntroductionThe photovoltaic industry depends on silicon based PV materials either as single-crystalline silicon, or multi-crystalline Si (MC-Si), or amorphous Si [1] for over 90 % of its market share. [2] MC-Si produced by directional solidification of solar grade silicon melt dominates the silicon PV market. During the directional solidification process, SiC and Si3N4 particles within the melt are pushed by the solidification front to the top of the ingot which is the last to solidify. Therefore the top of the ingot is cut generating what is known as top-cut solar silicon scraps. The Si3N4 particles are mainly from the coating material at the inside surface of the silica crucible and from air absorption during the solidification process. The SiC particles mainly stem from the carbon reduction process of the primary production of silicon [3]. Due to the growth of the PV industry as a result of global demand for clean, reliable, and affordable energy [4], there is the need to develop new methods to compliment exiting ones to recycle SoG-Si waste (e.g. top-cut) for sustainability."

Jan 1, 2012