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By David G. Dixon, Maziar Eghbalnia

"Gold and silver nanoparticles (NPs) were deposited on pyrite at ambient temperature from colloidal solutions prepared by reduction of hydrogen tetrachloroaurate or silver nitrate by sodium sulfide or sodium tetrahydridoborate. The nanoparticles were characterized using Ultraviolet-Visible (UV-Vis) spectroscopy and the experimental spectra were fitted using Mie - Gans modeling. The modified pyrite was investigated using Electrochemical Impedance Spectroscopy (EIS). Electrodes were prepared from both natural and modified pyrite samples and were modeled using an equivalent circuit (EC) based on the EIS data. The comparison of the results revealed a decrease in charge transfer resistance for the ferric ferrous redox couple associated with the modified pyrite. From this behavior it is concluded that the electronic transport between the nanoparticles and the electrode surface over distances in nanometer scale is enhanced. Nanoparticles below a certain size act as quantum dots due to electronic confmement. Decreased charged transfer resistance at the nanometer scale may be caused by electron transport through tunneling mechanism via quantum dots.IntroductionIn recent years, considerable attention has been focused on the synthesis and study of Metal nanoparticles due to their potential applications in the fields of physics, chemistry, biology, medicine, material science and their interdisciplinary fields[!]. When material is nano-sized, the physical properties deviate markedly from those of bulk material, however, this effect is highly dependent on the particle size, interparticle distance, and morphology of the nanoparticles [2].An extremely small region of space defmed in a semiconductor material in order of nanometers is called a quantum dot, a term coined by Reed [3]. The three dimensional confinement of quantum dots can change properties of the excitons in comparison to free excitons in a bulk material [4]. Nanoparticles behave electronically as zero-dimensional (restricted in all three dimensions) quantum dots when the de Broglie wavelength of the valence electrons and the particle are in the same size range.As Reed [3] explains electrons confined in a plane have no freedom to move the third dimension. Those confined in a quantum wire are only free to move in one dimension, and those confined in a quantum dot are not free in to move in any dimension. An electron inside a cube of material IO nm on a side is confined to a point."

Jan 1, 2012

By Yuanbo Zhang, Daoyuan Zhang, Youlian Zhou, Guanghui Li, Tao Jiang

"Modified humic acid (MHA) has been developed by Central South University (CSU) and authorized in China. It has been reported that MHA is an effective binder for oxidized pellets prepared from specularite concentrates. In this research, effects of MHA binder on roasting behaviors of the specularite pellets are studied. MHA is an organic binder, containing much carbon, hydrogen, oxygen, etc. During the roasting, MHA can provide some heat because of combustion of hydrocarbon, which is beneficial for the recrystallization of Fe2O3 in the specularite pellets at high temperature. Simultaneously, part of hematite particles within the pellets are firstly reduced to magnetite, then, magnetite is oxidized into secondary hematite, which obviously improves the roasting performance of specularite pellets.IntroductionOxidized pellets have been widely used in steel production as a kind of high quality burden for blast furnace ironmaking [1]. In recent years, production of oxidized pellets is developing very fast. Therefore, the supply of high quality magnetite concentrates, which is the most suitable for pellet production, becomes scarce. It is imperative to pursue new alternative materials for oxidized pellet production [2]. Specularite concentrates have attracted widespread attention due to the advantages of high total Fe grade and low impurity content. However, due to the poor ballability and firing performance, specularite has not yet been widely applied into pellet production [3, 4]."

Jan 1, 2012

By Alberto Oalvez, Lucya Yunus, Pengfii Tan

"Laboratory flotation tests of slow cooled converter slag have showed that 92.5% copper recovery at the copper cut-off grade of 24 - 25 % can be achieved by using a 50:50 ratio of DSP330 and SIBX (sodium isobutyl xanthate) at the natural pH of 7 and with a grinding time of 18.5 minutes. 70ìéç is the P80 achieved at this grinding time. MIBC is the frother and the solid content of the flotation feed was 46%. In the plant trials, two types of collectors at two different feed particle sizes for both the normal and slow cooled slag were operated. The particle size was controlled by the feed rate. The P80 of 75 ìçé at a feed rate between 32 - 36 t/h were tested. The plant trials have demonstrated that the copper recovery in the milling and flotation process of the slow cooled slags was improved by 3%. IntroductionIt is proposed to float the slow cooled converter slag, in the auxiliary circuit of the copper concentrator at Mount Isa, by using the processing conditions identified from several laboratory flotation tests. Among these laboratory tests, one produced a copper recovery of 4 % higher than those achieved from a normal cooled slag with the same slag feed grade and the same copper content (24 - 26 %) in the concentrate. These test conditions were selected for further studies.Laboratory Test Work and Plant TrialsThere has been a lot of work conducted under laboratory and plant conditions [1]. However, the achieved results did not justify their total implementation in the Mount Isa Copper Concentrator. Initially, the lab trials were carried out with slag cooled 100% in air; then it was changed to combined cooling for 12 h with air and 2.5 days with water sprays. The reason for this change was the shortage of space when the slag was cooled 100% in air, as it takes several days to achieve safe temperatures for its removal. The San Manuel Copper Smelter has reported that their slag was left for air cooling in pits for 8 h and then was followed by water cooling for 2-3 days [2]"

Jan 1, 2012

By Lawrence Nordell

A Conjugate Anvil-Hammer Mill (CAHM) has the potential to replace conventional crushers and SAG mills, with their respective conveyors and stockpiles, in a SABC circuit. It may improve comminution circuit efficiency by 100%. CAHM compresses rock in a more efficient way, similar to 19th century stamp mills, which follows the fundamental research of Schönert (1990 & 1996). CAHM efficiency is being proven through the use of ROCKY (2011) Discrete Element Method (DEM). ROCKY features allow it to simulate realistic comminution. CAHM is customizable with many geometries that are rock-property specific. ROCKY?s wear modeling compliments the structural integrity of the design.

Jan 1, 2012

In 2009 Newmont Mining Corporation?s annual global spend on grinding media reached $94M USD, having doubled in the five years since 2004. The major contributing factor to the spend escalation during this period was unit consumable price, with total media consumption also rising as a function of annual ore tonnes milled. In an effort to better understand and manage the growth of this expenditure a significant supply chain management program was implemented. This was complemented by a series of technical initiatives focussed on grinding media specifications, quality management and the prediction of grinding media wear rate as a function of physical ore characteristics. This paper discusses the methodology and outcomes of these activities.

Jan 1, 2012

Experimental determination of the response of an AG/SAG mill treating two components of significantly different impact resistance is challenging for two main reasons: firstly, small scale laboratory tests have yet to be confirmed as valid representations of the full scale milling environment, and secondly pilot plant testing requires 10-20 tonnes of ore per scenario which precludes the use of drill core, rendering the process very expensive. In order to mitigate these difficulties, modelling was considered as a potential way forward. However, as the JKSimMet AG/SAG model currently has no capacity to simulate the interaction of two ore types with differing impact resistance, density and/or feed size distributions, an alternative modelling approach was developed. This approach aims to essentially calibrate the AG/SAG process under a set of given conditions, for which survey data and the ore properties of the main components in the feed blend already exist. This paper describes a new conceptual model, which provides a simplified approach for investigating the multi-component behaviour of two ores of differing hardness/SG in a given AG/SAG milling environment, and which can potentially be used for scale-up from laboratory/pilot testwork and geometallurgical estimation of throughput.

Jan 1, 2012

By V. “Ram” Ramachandran

"In view of the increasing number of environmental regulations that have been promulgated all over the world in the last thirty years, non-ferrous smelters and refineries have had to learn and adapt to treating process bleed waste streams containing heavy metals. The result of such treatment invariably yields a gypsum-saturated solution containing salts such as alkali metal sulfates, chlorides and fluorides. Presence of anions such as sulfates, chlorides and fluorides in the discharge streams – presently not a major problem- are coming under increasing scrutiny and will have to be addressed in the near future. It is envisaged that discharge limits for sulfate ions will be in place in the near future. Treatment of brackish water to produce drinking water also results in brine streams containing alkali salts that have to be addressed for proper disposal. This paper reviews treatment options for such streams containing high levels of total dissolved solids with emphasis on sulfate removal. Areas covered would be: a) chemical treatment for removal of various constituents that make up the total dissolved solids b) processes for sulfate removal processes –thermal and non-thermal-to recover and reuse of treated water and c) brine use and treatment options.INTRODUCTIONThe rising cost of water and meeting the ever-changing stringent environmental discharge regulations make water recycling and reuse essential. The metallurgical industry has used water as a medium for dissolving and/or rejecting metals and chemicals in addition to removing thermal energy. Any excess process effluent is collected and sent to end-of-pipeline treatment and ultimately discharged to surface water for disposal under a permit. The conventional- and probably the cheapest way -of treating metal-bearing process effluent streams is lime neutralization followed by sulfide polishing for elimination of heavy metals to produce a stream that meets NPDES discharge limits. This results in a stream containing dissolved solids.These dissolved solids normally comprises of inorganic salts. The possible constituents are cations calcium, magnesium, sodium and potassium. The anions are sulfate, chloride, fluoride, nitrate, carbonate and bicarbonate. In addition to these constituents, the treated effluent streams contain very small amounts of heavy metals, oxyanions such as arsenites, arsenates, selenites and selenates. Process streams from gold operations contain residual cyanide. Small amounts of ammonium ions are also present in these streams based on the pH of the solution."

Jan 1, 2012

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few ? but very important ? instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By Jyri Talja, Shaolong Chen, Hannu Mansikkaviita

"Drying (water removal) prior to smelting is always economically feasible. Unnecessary heating of vapour can thus be eliminated resulting in savings of5-15 MUSD every year.Thermodynamically removal of one ton of water out of copper concentrate at 100 °C (with 10 % moisture) requires approximately 3150 MJ/tH2o, consisting of heating of the water (377 MJ), heating of the concentrate (509 MJ) and water evaporation (2260 MJ). This is quite independent of the selected drying technology. In reality some more heat is needed as higher temperature is practiced to enhance the drying performance and to reduce the equipment size.Major nominator in drying energy efficiency is amount of gases, which depends greatly on the drying technology. Dryers based on direct heating with fossil fuels have high gas flow rates, and thus they require additional energy of about 1400-1600 MJ/tH2o, compared to indirect modemsteam drying at 250-400 MJ/tH2o.Significant benefits in energy consumption (900-1300 MJ/tH2o) with additional potential for a bonus profit of 2-4 MUSD/y year, together with full elimination of some 40 000 tpy CO2 per mid-size dryer is available by selecting sustainable, energy efficient steam drying.IntroductionRemoval of water from the concentrate is very energy intensive thus having a significant environmental impact. However, drying prior to smelting is always economically feasible and very often viable also from the perspective of process operations. This environmental impact of drying can, however, be decreased or even fully eliminated with proper selection of the drying technology.Energy incorporated in drying consists always of a number of phases like liquid (water), solids (concentrate) and gases (water vapour, purging I dilution air, combustion gases). Each phase is heated to a specific temperature during the drying process.Heating of water, heating of the concentrate and water evaporation consumes more or less the same amount of energy despite of the drying technology (3150 MJ per ton of water). In conventional drying this amount of energy is achieved by combustion of fossil fuels wirg subsequent CO2 emission. Alternatively, chemical energy derived from sulphide smelting can be utilized in a form of steam thus generating zero emission ofCO2, in modem steam drying."

Jan 1, 2012

By Fernando Aracati Botelho, Jose Antonio Silva Souza, Luis Alves Venancio, Emanuel Negrão Macedo

"1 AbstractThe production of alumina from bauxite using the Bayer process generates 0.7 to 2.0 ton of the residue known as red mud and about 800 kg of CO2 per ton of alumina. The direct use of exhaust gases to react and neutralize the bauxite residue may allow a double gain: open a wide range of new applications for bauxite residue reducing its reactivity and sequester from 3 8 to 107 kg of CO2 per ton of alumina. This paper shows a pilot scale reaction of a suspension of bauxite residue-water with flue gas produced from direct burning oil, similar to the exhaust gases of a refinery. Two different types of reactors are used, a spray tower and a packed column. The inlet and exhaust gases are analyzed using electrochemical cells and non-dispersive infrared sensors. The pH of the suspension is monitored during the reaction and after to evaluate the buffer effect. 2 IntroductionThe production of millions of tons per year of alumina around the world generates from 0. 7 to 2.0 ton of the residue known as red mud (RM) per ton of alumina. The vast majority of the red mud is stored in large sealed lakes. Due to the high reactivity this material is considered dangerous and currently there is no operating process capable of reusing all the material produced at any refinery. These lakes after filled of solid material eventually have the surface revegetated [4]. In any case they will remain as an environmental passive and needs monitoring for decades. The search of a industrial process that combines the reduction of the CO2 emission and the reduction the pH of the red mud opening the possibility of large scale and economically viable ways is the main objective of this work.The use of the exhaust gases of the refmeries to neutralize the bauxite residue may allow a double gain: Open a large array of new applications for the residue with the reduction of its reactivity and sequester millions of tones ofCO2 plus other gases like SO2 [7] and NOx. This project studies the reaction of the exhaust gases from a boiler burning diesel with RM in different reactor types and conditions in order to obtain parameters to design equipment capable of process this reaction on a larger scale. With these objective compositions of red mud were processed with flue gas at concentration similar to the exhaust gases of the calcination process and boilers of the refmeries."

Jan 1, 2012

By Honggang Zhong, Tan Yi, Qijie Zhai, Zhao Dan, Xinping Mao, Huigai Li

"The influence of superheat degree on the distribution and volume content of inclusions were studied in 65Mn thin slab produced by compact strip production(CSP) in Zhujiang Steel in China, The results showed that the diameters of inclusions are mainly less than 5µm. Most of the inclusions gathered at the 1/4 thickness direction for the thin slab of 27? superheat degree, compared with the center position for that of 37?. There are more inclusions larger than 50µm in the low superheat samples, which is caused by the short floating time. In addition, the inclusions were observed and analyzed by metallurgical microscope, SEM and EDS in order to ensure their composition, type and further find their source. It was find that the types of these inclusions mainly are Al2O3, SiO2,CaO and their composites, a few of them are TiN and MnS.IntroductionIt is well known that inclusions have a great impact on the strength, plasticity, fracture toughness, cutting performance, fatigue property and corrosion resistance of steels. Especially, with the demand for thinner slab, the cleanness is increasingly becoming more significant as a quality criterion[1]. High manganese and carbon steels not only demonstrate high strength but also proper plasticity. There are many problems unsolved for 65Mn steel as a result of the low solidification rate, bad thermal strength, crack sensitivity and low casting temperature[2,3].The superheat of the molten steel has a great impact on the erosion of refractory lining, molten steel fluidity and non-metallic inclusion behavior[4]. The serious erosion situation of ladle lining, nozzle and casting tundish will give rise to more inclusions at a high superheat. Meantime higher superheat will make second dendrite arm spacing coursing and element segregation which lead to inclusion, bubble formation and shrinkage cavity. On the contrary, it is hard for non-metallic inclusions to float up with a low superheat value. Inclusions of 65Mn steel, which produced in different superheat condition by CSP, were studied for the sake of higher slab properties including statistics and EDS analysis."

Jan 1, 2012

By A. D. S. Gillies

The use of refuge chambers for use in handling underground emergencies is an issue of topical relevance within the US mining industry. Chamber design is of importance to meet some new safety requirements of US federal and some state government mine regulations. A review has been undertaken of a steel mine refuge chamber design to predict what will be internal temperature within the chamber over an extended period with miners present? The design has been examined for the situation when the chamber is sited in still mine air. Spreadsheets have been developed to allow various design assumptions to be tested. The evaluation has been undertaken using thermodynamic heat transfer models with some assumptions specified to produce a model of appropriate simplicity but with adequate degree of accuracy. Under normal still air conditions it can be seen that internal chamber conditions rise quickly to often arduous conditions. There will always be quite a few assumptions necessary in complex heat transfer process evaluations. Some important refuge chamber design parameters are: ? External surface area of the chamber, its wall thickness and construction. ? Metabolic heat generated and number of persons making use of the chamber. ? The temperature of the external mine atmosphere to the chamber over the year and the influence of geothermal gradient on temperature at depth. ? The maximum internal chamber Apparent Temperature considered safe. ? The distance inside the underground mine and adjacent ventilation conditions.

Jan 1, 2012

By J. L. Hoover

The goal of the drill bit consumption study was to develop an equation(s) based on various components that affect bit drill wear and use the equation(s) to estimate the consumption of bits during production drilling. Drill bit data from various geographic locations were compiled and used to develop linear regression equations using the Microsoft Excel Software. Multiple drill bit consumption equations were developed and statistical analysis was used to verify the accuracy of those equations. The equations will allow mining companies to more accurately forecast drill bit consumption when evaluating new mine properties. This capability becomes increasingly beneficial to forecasting as the cost of consumables increases.

Jan 1, 2012

By Damon P. Vandermaat

Coupon testing allows for the rapid understanding of a material?s likely behavior in service conditions, allowing engineers and operators to make informed decisions about the likely service-life of parts when subjected to field conditions. Bend testing has been identified as the best approach for exploring rock bolt susceptibility to stress corrosion cracking (SCC) in underground mining. The bend test specimens used were 2?3 mm thick slivers of steel, cut from the outer edge of a rock bolt. For the specimens, 1350 grade steel was chosen due to its wide use in the industry. The jigs themselves are small assemblies made of stainless steel that are capable of imparting a bending load on the specimens. The jigs were installed at a coal mine located in the Western Coals West of Sydney, Australia, in such a way as to expose the test specimen to water dripping from the mine roof. It is expected that this approach will yield results pointing to the likely SCC mechanisms affecting the service life of rock bolts, as well as demonstrate the jigs? usefulness as an early warning system for SCC. Furthermore, the coupon tests will be correlated against the results of large-scale laboratory tests.

Jan 1, 2012

By Chunyang Guan, Jilai Xue, Jun Zhu, Qiaochu Liu

"Al-Sc Alloys have showed many advanced properties for a wide range of industrial application, which is usually produced using thermal reduction process. This work is aimed to develop an electrochemical process to make Al-Sc alloy using industrial Hall aluminum reduction cells. The experiments have been carried out in a lab cell where NaF/AlF3-Al2O3-LiF as electrolyte, Sc2O3 as raw material, and liquid aluminum as cathode were used at operating temperature of 950 °C. The resulting Al contained 0.2 - 0.5 wt.% Sc that is the common range in its content for advanced applications. However, a small fraction of Sc was found from thermal reduction at Al melts interface. SEM-EDS and ICP-AES analysis showed a uniformed distribution of Sc at varying locations of the Al-Sc alloy sample. In addition, a higher Sc content in Al-Sc alloy can be obtained with introducing ultrasound through the cathode than that without it.IntroductionIn recent years, scandium has been investigated as an alloying element for aluminum alloys. With addition of a small amount of Sc, Al alloys can improve the strength, weld ability, resistance to re-crystallization and corrosion resistance [1-3]. Due to their advanced properties and potential applications, the demand for Al-Sc alloys will increase in the future. However, the difficulties in reduction technologies and the high costs in production process may limit their expansion in application areas.The current major method of producing Al-Sc alloys is to mix Sc into Al by melting Al-Sc master alloy. This alloying process has several technical problems, such as easy segregating and heavy burning loss, etc. The price of Sc metal or starting material is also high, so the mixing process is an expensive alloying method. Molten salt electrolysis is alternative method to prepare RE metal and RE alloys [4, 5]. It also can reduce the segregation of alloying elements. Sc2O3 is an ideal material as raw material with low price and decomposition voltage. Some work has proved that Al-Sc alloys can be obtained by electrolysis Sc2O3 directly in cryolite [6-8], or CaCl2 molten salt [9]."

Jan 1, 2012

By K. Hawboldt, J. E. Halfyard, C. Bottaro, I. A. Harrison

"The removal of elemental sulfur from leach residues derived from massive sulfide concentrates via hydrometallurgical routes has been demonstrated in a laboratory setting by converting water-insoluble sulfur to water-soluble polysulfides. The approach was applied to leach residue from Vale's nickel hydromet demonstration plant in Argentia, Newfoundland, which contained significant amounts of elemental sulfur. This technique offers an alternative treatment protocol for residues with a sulfur component not amenable to standard flotation/hot filtration processes. The practical considerations of a proposed flow sheet will be discussed including the impact of other sulfur species (e.g. thiosulfate and sulfides) and key process variables. INTRODUCTIONPresently, large scale elemental sulfur extraction from hydrometallurgical leach residue is performed by Teck Resources using a process of sulfur flotation followed by hot filtration (Chalkley et al., 1993). As mentioned, the technique proves viable for residues derived from specific concentrations - in this case zinc - whose residues constituency is primarily elemental sulfur itself. However, problems arise when this constituency is altered as happens when, for example, a mine containing one particular concentrate is mixed or replaced with a differing concentrate from a second mine. Such cases can often strain the effectiveness of current sulfur removal processes (D'Odorico, 2004). If hydrometallurgical residue containing elemental sulfur cannot be effectively treatment by flotation, the residue is stored subaqueously as is the case in some 'grass roots' hydrometallurgical plants (those not coupled with smelting operations). Hydrometallurgical processing of concentrates involving pressure leaching is becoming increasingly common throughout the mining world, the genesis of which can be found in research performed by Sherritt in Fort Saskatchewan since the 1950’s (Ozberk et al., 1995).The investigation of elemental sulfur removal by means other than flotation includes the uses of sulfide salts (NH3S or Na2S) effecting the conversion of hydrophobic elemental sulfur to hydrophilic polysulfides. The work of Kunda et al. (1974) and Olper et al. (2007) shows that elemental sulfur can be quantitatively removed from hydrometallurgical leach residue via the formation of a mixture of polysulfides."

Jan 1, 2012

By Adrian Dance

Barrick Gold Corporation?s wholly owned subsidiary, Barrick (Granny Smith) Pty. Ltd. operates the Granny Smith operation in Western Australia and has been operating a SAG/ball mill (SABC) circuit for a number of years processing a blend of secondary crushed, open pit and underground material. With closure of the open pit in 2008, Granny Smith was considering different options to process underground only material at a lower throughput. Using the existing equipment available on site, a number of circuits were evaluated by Metso Process Technology & Innovation (PTI) through modelling and simulation. A single stage SAG mill circuit was selected based on power requirements and operating efficiency. In April 2008, Granny Smith started operating their SAG mill in single stage, processing primary crushed feed and using their existing pebble crusher for scats. Smaller cyclones were used to control the final grind size. PTI surveyed the new single stage circuit in July 2008 under normal and high rock load conditions to show the effect on final grind size. Granny Smith continued to operate this circuit until the end of 2009, when alternate feed sources resulted in a return to the complete SABC circuit at a higher tonnage once again. The variable speed, single stage SAG mill proved itself to be very efficient and flexible option to process the hard underground Wallaby Deeps material. This paper will review circuit performance following the conversion to single stage in comparison with the full SABC circuit.

Jan 1, 2012

By Zhang Libo, Wang Xin, Peng Jin-hui, Ju Shaohua, Guo Sheng-hui, Xu Lei, Huang Meng-yang

"China is lacking high grade titanium ores. This work intends to leach impurities such as Fe, Ca and Mg from a low grade titanium ore, to increase the grade. The original material contained 65% TiO2 , 16.12% Fe, 9.4% CaO + MgO, 4.2% SiO2, 1.25% A12O3, and the particle size is between 0.053-0.045mm. Microwave energy was used to enhance the leaching effect. The results showed that when normal heating was used to leach the mineral, the extraction of impurities Fe, Ca and Mg was very low. However, when microwave energy is introduced, the extraction of Fe, Ca and Mg increased dramatically. The optimized conditions are: relative power 5W/g, the ratio of concentrate to HC1 isl5%, leaching at 160°C for 20 min with a ratio of liquid to solid 12:1 mL/g. The material obtained under these conditions contains 92.73% TiO2, 0.207% Ca + Mg, 0.8% Fe, with 94.6% Ti recovery. The poduct meets with the quality for boiling chlorine.IntroductionThe resources of titanium are very abundant, and are distributed all over the world. There are almost 140 minerals containing TiO2 with a content of more than 1%. However, there are only several minerals which can be used for producing sponge titanium. They are mainly rutile and ilmenite. The grade of nature rutile concentrates is higher than 95% TiO2, and it is a high quality raw material. But the resources of nature rutile are relatively low; after mining for many years, its resources are exhausting gradually. Although ilmenite reserves are great, ilmenite cannot be used as a raw material because of its low content of TiO2, only 45-70%; also it has a high impurity content of Ca, Mg and Fe. In these years, there is a tendency for titanium industry to use high grade concentrate."

Jan 1, 2012

By V. B. Telles, D. C. R. Espinosa, J. A. S. Tenório

"The purpose of this work was to study the reutilization of the steelmaking dust, derived from steel production in the electric arc furnace (EAF), in iron ore sintering process aiming zinc elimination. In each sintering process were collected sintered samples, these materials were analyzed by chemical analysis using atomic absorption spectrophotometry in order to determine the zinc content. Samples of not sintered mixtures were also characterized by chemical analysis aiming to determine the initial amounts of zinc, i.e. in order to check the zinc amounts present in the mixture before the sintering process. The comparation among the zinc contents of samples sintered and not sintered allowed to determine the elimination of zinc during the experiments. Results showed that the zinc elimination in the process is proportional to the ratio reducer/waste. The zinc removal was lower when the reducer/waste ratio was decreased.IntroductionThe electric arc furnace dust (EAFD) is a residue generated in the steelmaking process using electric arc furnace. Aproximately 30% of all steel produced (in the year 2009) was obtained through electric arc furance (EAF). In the United States of America the percentage of this process in the total crude steel production was about 62% in 2009, while in 2000 this percentage was only 47% [1].The iron ore sintering is a process that reuses wastes generated in metallurgical industries. However, the materials used must be physical and chemical characteristics compatible with the blast furnaces.The quantity of zinc, cadmium, chrome and other metals present in the EAFD depends on the quality of the scrap used to feed the EAF and the type of steel that it is been made [2,3]. The reuse of EAFD waste is interesting to steelmaking processes because of its iron content. However the presence of zinc inside a blast furnace is undesirable since the zinc oxide can be deposited on the blast furnace walls and in the drivers of gas output, interrupting the flow. Another part of the zinc oxide can form deposits on the refractory lining of the blast furnace [4,5]."

Jan 1, 2012

The Anglo Platinum Mogalakwena North concentrator was one of the first three hard rock mineral processing applications to utilise a HPGR circuit in preference to a SAG milling circuit. This was driven by the extreme competence of the ore that had given rise to throughput issues on the original South Plant. Despite more than adequate capacity and performance of the individual comminution units, the circuit has struggled to obtain full design capacity. A thorough review of the integrated performance of the circuit revealed a wide range of bottlenecks and underutilised parts of the circuit arising from design issues. Interestingly, the major opportunities lie in materials handling issues and mismatch of loads about the circuit. This paper presents the high-level outcomes and the associated opportunities, and is pertinent to all HPGR circuit designs.

Jan 1, 2012