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By G. Gauvin

Life span of aluminum smelting electrolysis cells can reach up to 3000 days. During this period, cathode blocks go under various physical and chemical changes that could result in an increase of electrical resistivity. The increase may be due to carbon migration from the cast iron to the steel bars, gap evolution between the cathode block and the cast iron, cathode cracking, etc. This paper focuses however only on the collector steel bar electrical resistivity evolution. To reveal the main phenomena responsible for the electrical resistivity increase, chemical analysis, metallographic and electrical resistivity tests were conducted on two steels bars picked from two Hall-Héroult cells after autopsies. Cathode voltage drop and temperature were measured using electrically insulated internal probes and thermocouples on 16 samples from each steel bar. Electrical resistivity can reach up to 1.21µO-m for a steel bar aged 2505 days compare to 0.142µO-m for steel AISI 1008 at room temperature.

Jan 1, 2011

In the late 1980s and into the 1990s, the Mountain Pass Mine in California produced about 40 percent of the world?s rare earth elements. At the height of this production, the facility produced up to 54 L/s (850 gpm) of saltwater that was piped to offshore holding ponds where the water was evaporated. In 1998, following a series of waste water pipeline breaches, separations activities were suspended, reducing the Mountain Pass site to just the openpit mine and mill. The environmental concerns were addressed and the affected areas have since been remediated. However, in the years following the breaches, 97 percent of the world?s production of rare earth elements moved to China. By 2011, Molycorp, and the Mountain Pass Mine, had rebounded from the difficult times and were once again in a position to become a significant player in the rare earth industry.

Jan 1, 2011

This paper details a brief history of the Australian gold industry from the 1980s gold boom to the present day, highlighting an industry characterised by innovation in plant design and junior companies prepared to "have a go", in contrast to the conservatism of many larger mining companies. Design flexibility, the innovation of new processes, the preparedness to exchange "process know how" and technology singularly differentiated the gold industry from other sectors during the 1980s to the present. The introduction of two stage crushing, semi autogenous (SAG) milling, and pebble crushing, mill innovations, carbon in pulp (CIP) and carbon in leach (CIL) and the North Kalgoorlie screen etc were all exciting changes in the industry.

Jan 1, 2011

By Wm. Reisz, Raphael Trousselle

We are now well into our second decade of commercially available electronic initiation systems. Over this time, the technological advances have made electronic systems a very practical option for a wide variety of blasting applications.

Jan 1, 2011

By R. Kamguem

The surface of a mechanical part plays an important role in determining performance in service. The presence of scratches left by the cutting or tearing of the material on the surface of the workpiece supports the concentration of stress and strain. This article presents the experimental study for high speed milling of the aluminum alloy 7075-T6, using cutting tools different by the nose radius and coatings (TiCN, TiAIN, TiCN + A12O3 + TiN). A multi levels factorial design of experiment (DOE) and statistical analysis was used. The roughness parameters investigated are Ra, Ra, Rv, Rc, Rsm, and Rk. The results show that the feed rate, the types of coatings and the geometry of the cutting tools have the most significant impact on the surface roughness profil. Surface finish charts according to feeds and cutting speeds were established for each tool tested.

Jan 1, 2011

By W. Birch, G. D. Rangel-Sharp, L. Bermingham

For many years, the accepted method of Measuring the Velocity of Detonation (VOD) in blast holes has been to use an electric cable of a constant resistance per metre. Thus as the wire is consumed by the explosive in the blast hole, the change in resistance is monitored and when this data is plotted against the time period of the in hole explosion, the VOD can be calculated.

Jan 1, 2011

By Fu-Shen Zhang, Mengjun Chen, Jianxin Zhu

"A novel approach for foam glass preparation, namely vacuum-aided powder sintering technique, was preliminarily investigated in the present communication. The key point of which was to prepare foam glass at a negative pressure. Compared to normal powder sintering process, the new approach could benefit the foaming process by shorting the holding time, reducing the amount of foaming agent and especially decreasing relative density of the product. Optimum conditions were 750 °C, 1000 Pa, 5 min and 1 wt.% foaming agent, respectively.IntroductionFoam glass represents a highly valuable solution for thermal and acoustic insulation, since it possesses a generally higher mechanical, chemical and thermal stability than other foams'1'. The first industrial processing for foam glass production, the direct introduction of gases (""blowing"") into the special molten glass, can be dated back to the end of 1930s'2'. At present, almost all foam glasses is prepared by powder sintering technique instead of blowing,3 since it reduces the temperature by several hundred degrees. Moreover, as fine glass powders or similar powders can be used to substitute corresponding glasses by this technique, considerable attention has been focused on the production of foam glass by considering fully recycled glasses, coal fly ash, or other solid wastes as raw materials,4 especially CRT glasses'3' 5', on the point of environmental protection.In a previous report'6', when discussing the lead removal and recovery from CRT funnel glass by a pyrovacuum process, we found that foam glass could be prepared at a negative pressure. Therefore, in this communication, the similarities and differences between the powder sintering process for foam glass at normal and negative pressure was preliminarily discussed."

Jan 1, 2011

By Russell C. Frith

Risk-based roadway roof support design is now a critical part of the Australian Coal Industry. Safe and efficient mining demands that roof support be tailored to the prevailing geotechnical conditions and coal mining legislation in New South Wales, Queensland, and Tasmania is clear in requiring that formalized roof support design be undertaken. The assumption of dead-load suspension of an otherwise unstable roof has been used in roadway roof support design for many years. However longevity does not necessarily translate into either a best or even reasonable practice in the current industry, particularly when pro-active strata management systems are now routinely used and reinforcing support design methods are available. The paper discusses why the assumption of dead-load suspension is fundamentally incorrect in almost all instances when pro-active or reinforcing roof support is applied and how it can easily result in misleading and potentially under-designed roof support systems under various circumstances. The commonly used design methodology of balancing the installed axial capacity of long tendons with the assumed ?weight? of a future roof fall is summarized, and several fundamental flaws are identified. The critical area of selecting the design Factor of Safety is also discussed in detail. Accepting that under certain circumstances the roof of a roadway will require it to be ?suspended?, suggestions are given for how a robust support system can be developed, designed and applied.

Jan 1, 2011

By K. T. Aye

An investigation into the leaching of chalcocite and covellite in cyanide solutions at concentrations typically encountered daring gold cyanidation has been conducted. The results indicate that, for both minerals, the extent of leaching is greater under anoxic conditions, but is still incomplete even in the presence of free cyanide ions, with undissolved copper solids remaining in equilibrium with solution species. The speciation of the sulfur and cyanide reaction products in solution are interpreted in terms of the fast formation of a copper(I)- cyanide complexes in solution and a sulfur-rich copper(I) polysulfide solid phase, which then reacts more slowly to produce thiocyanate ions.

Jan 1, 2011

By Chao Du, Xiaohui Ning, Hongmin Zhu, Qiuyu Wang, Shuqiang Jiao

"TiCxOl-x solid solutions were synthesized by sintering a mixture of titanium carbide and titanium monoxide at 1600 °C. The corresponding structures and morphologies of the TiCxOl-x solid solutions were characterized by XRD and SEM. A series of tests has been performed on the electrochemical dissolution behavior of TiCxOl-x solid solutions in NaCl-KCl molten salt. The influences of synthesis time and electrokinetic parameters on the anodic dissolution behavior were also investigated. The results showed that TiCxOl-x solid solutions can dissolve as Tin+ into alkali chloride melt. Titanium ion species dissolved from TiCxOl-x solid solutions changes between Ti2+ and Ti3+ depending on the applied potential. The tail gas on the anode was monitored by a mass spectrometer. It was found the synthesis time significantly affects the components of the anodic gas.IntroductionTitanium and titanium alloys have been desired greatly because of their many uses. The critical factor that restricts the range of uses for Ti is its high cost of extraction. The primary titanium metal, sponge titanium, is still produced industrially worldwide by a process invented by Dr. Kroll in the 1940s[1] •Since the early 1970s, the research focus of the titanium industry has been directed towards developing a continuous process to produce high purity titanium at low cost. [2-10] Of the many alternative methods that have previously been investigated, the electrolytic process has been considered a promising method for titanium metallurgy [4-10]. Recently, several electrolysis and related methods such as the PFC-Cambridge process[11-15], calciothermic reduction[16-18], USTB [19,20] and MER[21] process were extensively investigated.The USTB process is a new approach where the pure titanium can be directly obtained by the electrolysis with an anode of titanium oxycarbide in molten salts[19, 20]. The titanium oxycarbide was produced by carbothermal reduction of titanium dioxide under vacuum at a temperature"

Jan 1, 2011

By M. Sukhram

This paper presents a technique to determine the direction of velocity in liquid aluminum (Al) by measuring the temperature distribution within a cylindrical rod while it is inserted into the flow. The heating pattern of the rod is a result of the interaction of the thermal fields of the rod with the liquid Al. This interaction freezes aluminum onto the cylinder in a characteristic pattern and as a result the temperature response within the rod also follows a distinctive heating pattern. Monitoring the temperature within the cylindrical rod as a function of spatial and temporal coordinates, the direction of velocity can be inferred. Experimental research work involving liquid Al was conducted at the University of Toronto using the Revolving Liquid Metal Tank (RLMT). The RLMT is a resistance furnace which can hold up to 50kg of liquid Al. In this RLMT tangential velocities up to 0.35m1s can be generated. Experimental data for different superheat and magnitude of velocity demonstrate that the sensor records different heating patterns under different fluid flow conditions. Using the transient temperature information, the direction of velocity of the molten Al flow field can be detected.

Jan 1, 2011

By Leonardo Massone

The p-y method is one of the most popular methods in pile design and has been calibrated for various boundary conditions using numerical and experimental studies during recent years. Most studies on reinforced concrete (RC) piles have included the impact of flexural nonlinearity, (e.g. nonlinear moment?curvature relations) but not considered associated pile shear deformations when deriving p-y curves from field data. Common p-y curves may be better applicable for piles with flexure dominated failures (e.g. piles with free- head boundary conditions). For piles with fixed head boundaries (i.e. rotation restrained piles) shear deformations could be of significant influence. To study this problem, a coupled shear flexure interaction model for axial-bending-shear behavior coded in OpenSees is applied to a 0.61 m flagpole and a 0.61m fixed head pile specimen to investigate the possible influence of shear deformations to the overall pile responses. The surrounding soil is represented by p-y curves derived from prior large scale testing on piles with similar boundary conditions. Analysis results show that for flagpole piles, shear forces and shear deformations were insignificant. Considerable contributions of pile shear displacements and forces were observed for the fixed head pile, with shear displacements contributing up to 40% of the total pile displacement. Results suggest that nonlinear shear deformations for reinforced concrete piles should be considered for fixed-head or similar conditions, and that currently used p-y curves may underestimate the actual lateral pile displacement and possibly lead to unsafe design for the particular boundary condition.

Jan 1, 2011

By M. Barati

A collaborative research between University of Toronto and Hatch was conducted to understand and optimize the process conditions pertaining to a novel steelmaking technology. In this technology, known as CRISP, direct reduced iron is continuously melted and refined in a stationary electric arc furnace. The major challenge against continuous operation of the electric furnace was identified to be minimizing the corrosion of the refractory in order to achieve uninterrupted operation for a minimum of one year. Theoretical analysis and bench scale experiments together with two pilot runs resulted in defining an operating window for slag chemistry that would minimize chemical attack to the refractory while satisfying the oxidizing conditions required for sufficient decarburization. An analysis of the process in terms of energy consumption and emission of greenhouse gases revealed that it is superior to the current batch DRI-based steelmaking technologies.

Jan 1, 2011

By R. P. van Hille, A. W. van Zyl

The BIOX® culture, aiding liberation of arsenopyrite/pyrite occluded gold, is inhibited by thiocyanate (SCN > 1 mg/L); precluding the recycling of tailings water up-stream of the bioleaching circuit. The activated sludge tailings effluent remediation (ASTERTM) process is a biological process that was developed to facilitate water recovery and treat waste water on-site (to achieve a SCN concentration < 1 mg/L) to be recycled or disposed of. The aim of this study was to investigate the effects of changing temperature and SCN loading on the SCN degradation ability of the mixed microbial population clue to seasonal temperature changes and fluctuations of SCN concentration in the waste water.

Jan 1, 2011

By Steven R. Lowe

Construction of a pump station, consisting of an inlet chamber, wet well and pump chamber, required excavation to a depth of 9.7 m (32 ft) below ground surface and more than 7.6 m (25 ft) below the ground water table in a rural, but rapidly developing part of southern New Jersey. Private houses are located [ ] within a few hundred feet of the pump station that use shallow wells for water supply. The pump station design anticipated support of the entire pump station on shallow foundations bearing directly on the underlying natural soils. However, during construction, uncontrolled ground water flow caused ground loss and damage to the bearing qualities of foundation soils. As a result, remedial repairs were required including support of the pump station on drilled pile foundations and releveling of the pump chamber that had settled. This case study is an example of where a poor understanding of the significance of upward flowing ground water had a major impact on the cost of construction. Anticipated subsurface conditions The pump station layout is shown in Fig. 1 with the locations of two borings made prior to construction superimposed. One of the borings was located within the footprint of the deep wet well excavation. Generally, this is not advisable where a deep excavation is required below the ground water table. This is because there is a history of projects where ground water seepage, or pressure, has broken out into an excavation through an ungrouted borehole and compromised the integrity of foundation soils. Logs of the borings did not indicate that the borings [ ] were grouted upon completion.

Jan 1, 2011

By John Noakes

Marine scientists at the University of Georgia, have in the past few years, designed, developed and refined two geochemical survelliance systems for the exploration of hard mineral resources on the seafloor. The one first developed is an underwater sled which contains a nuclear radiation detector for measuring naturally occurring gamma radiation that is associated either with marine phosphorites containing uranium and its decay daughters or thorium decay products that are indicative of monzanite. The latter can, in most instances, be used as a pathfinder mineral for placer deposits that may contain other heavy minerals of interest such as rutile, ilmenite, chromite, gold, etc. This sled is operational in continental shelf depths. The second system is capable of more definitive measurements in the form of direct elemental analyses of the silt and clay fractions within the surficial sediments. It consists of a towed sled containing a submersible pump which, upon agitating the sediments, transfers the finer fraction up a hose to a shipboard centrifugal cone then to an automated sample processor. The resultant samples are rendered into sediment wafers, suitable for non-destructive XRF analysis. The system is capable of shipboard analysis for specific elements within minutes after sampling, allowing a cursory look upon which an exploration grid can be formulated while on site. A much wider spectrum of up to 40 elements can be evaluated when the wafers are returned to the land based laboratory.

Jan 1, 2011

By M. Nzotta, L. Teng, S. Seetharaman, A. Chychko

The objective of the present work is to optimize the EAF practice towards Mo alloying with maximum retention of the alloying element in molten steel. During Mo additions, there were significant losses to the dust (ca 7 %) and to the slag phase (ca 2 %), which had serious economic and environmental impacts. The present work was aimed at designing a suitable Mo precursor, an alternative to ferromolybdenum, as the Mo source and a process sequence for optimal retention of Mo in the steel. The design of the Mo source should be in such a way that low cost raw materials such as MoO3 concentrate have to be used, stable during the addition so that the vapour phase losses as MoO3 are kept minimum and the dissolution of the precursor in molten steel is easy without loss to the slag phase. After thermodynamic considerations, three precursor materials were chosen, viz. CaMoO4, MgMoO4 and Fe2MoO4. Synthetic mixtures of the component oxides in each case as well as pure MoO3 were investigated by TGA and high temperature XRD in order to find out the temperature range in which the compounds were formed. Experiments were also conducted separately where the evolved gases were analyzed. All the three precursors were formed easily and the loss of MoO3 to the vapour phase was found to be extremely low. Addition of the oxide mixtures to steel melts were conducted in three different scales, viz. 16 g, 500 g and 3 tons (induction furnacle). Initial experiments showed that MgMoO4 was not suitable since the Mo yield in the steel melt was not very high. Fe2MoO4 was found to perform best, the Mo yield reaching 98 %. Further trials were conducted in the 65 ton Electric Arc Furnace (EAF) at Uddeholms AB in Hagfors. Mixtures of mill scale, MoO3 and carbon in suitable proportions were added in a pre-determined addition sequence. It was found that, in the actual practice, the Mo yield reached 99 %, equaling in performance the addition of ferromolybdenum. The process offers an effective use of cheaper raw materials and very high Mo yield avoiding a pre-treatment step like the production of ferromolybdenum. This is both cost effective and environmentally advantageous. The process has been patented and is being currently implemented at Uddeholms AB, Hagfors, Sweden.

Jan 1, 2011

By G. Hamel

The LCL&L process (Low Caustic Leaching & Liming) is a patented hydrometallurgical route developed by Rio Tinto Alcan (RTA) to economically process spent pot lining (SPL) generated by aluminum cells. The three resulting end-products (carbonaceous, fluorinated and caustic liquor) are inert and have valorization possibilities. An industrial size pilot plant located in Saguenay (Quebec) was inaugurated in mid-2008 to demonstrate and optimize the technology. This paper describes characteristics of the LCL&L process and the experience acquired by RTA since the plant&apos;s start-up, including ramp-up capacity and technology challenges that were overcome. Possible end-products valorization methods are also presented. The carbonaceous end-product can be separated into carbon and brick rich fractions and used as either alternative fuel, reducing agents, or as raw material for third party processes. The development of a conversion process for the fluorinated end-product would allow its reuse as a substitute to fluorspar mineral for aluminum fluoride production. Finally concentrated caustic liquor is already valorized at the nearby RTA Vaudreuil alumina refinery.

Jan 1, 2011

By Qingbo Yu, Qin Qin, Junxiang Liu

"Dry-granulation is a new process of molten blast furnace slag treatment and air is used as heat exchange medium. There are some shortages: poor effectiveness of granulation, high air-slag ratio and high energy consumption, which are the obstacles to popularize dry-granulation. Based on rotary cup atomization, the technique of recovering waste heat of molten blast furnace slag through waste heat boiler producing high pressure steam is exploited. The molten blast furnace slag is granulated to uniform small slag granules with high temperature, and slag granules pour into the waste heat boiler. It could produce steam, obtained in first row and second row tubes, when descending velocity of slag granules equaled 1.1mm/s and the Reynolds number equaled 7100. The application of the system for recovering waste heat from high temperature molten blast furnace slag has a significant meaning.IntroductionBlast furnace slag is one kind of solid waste in iron making process, which is discharged at the temperature range from 1723 to 1923K. In China, there was 0.162 billion tons of slag discharged in 2009, and the energy contained in the slag is equivalent to the energy in 9.4 million tons of coal equivalent. The sensible heat of molten slag is a very valuable waste heat source, so it is worthwhile to recover the sensible heat. At present, the molten slag is treated by a water quenching method. But in this process, the sensible heat is not recovered, moreover, an amount of water is consumed and harmful waste gas is discharged into the environment. Due to the considerations of energy conversation and environmental protection, the iron making industry pays close attention to dry-granulation, which is useful to obtain more benefits [1-4]. The sensible heat is recovered and an amount of water is saved by the method of dry-granulation. The amorphous content of slag granules obtained from dry-granulation is over 95% [5, 6], so the slag granules can be used as a perfect raw material for cement [7, 8].In the late 1970s, the Sumitomo Metal Industries, Ltd. and the Ishikawajima-Harima Heavy Industries, Ltd. jointly undertook the research of rotary drum granulation. This method has several disadvantages: the processing capacity and efficiency are low, and it is not adoptive to operate continuously in production [9]. From 1980, Nippon Steel, NKK, Kawasaki Steel, Kobe Steel, Sumitomo Metal Industries and Nisshin Steel were engaged on air granulation, and the experiments were operated for 6 years on the blast furnace in Nippon Steel. In the process of air granulation, there was great power consumption. The complexity of structure and the great floor space of the air granulation device caused high cost of investment. In 1986, Ukraine exploited a new method of heat recovery referring to the technology of Continuous Casting and Rolling [10]."

Jan 1, 2011

By L. E. C. Pignatari

Mine reconciliation is seen, for many, as a test of the quality of model estimates, while in fact it should be seen as a powerful tool for detecting and correcting problems in each step of mining operations, from resource estimation to metal production. Adequate reconciliation practices allow a more efficient control of the mining processes; however, its results can be illusory unless all parties involved have been in compliance with the principles of sampling correctness. This paper presents a new, segmented reconciliation matrix, which is based on the Theory of Sampling (TOS), developed to monitor gold operations and reserve estimation.

Jan 1, 2011