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By P. L. Sibrell

Electrorefining of Ti in nonaqueous solvents has been studied by the U.S. Bureau of mines as a method for recycling impure scrap Ti. Electrochemical behavior of Ti species was investigated using cyclic voltammetry. Research results showed that Ti metal can be dissolved in polar solvents such as dimethylformamide or dimethyl sulfoxide. However, deposition of Ti from these solvents was not successful. Several solvent systems were investigated for electrodeposition of Ti but no deposits were obtained. Reduction of Ti4+ complexes to Ti3+ proved to be straightforward, but reduction to lower oxidation states could not be confirmed. In dimethylformamide solutions, cyclic voltammetry results demonstrated the reduction of Ti to an oxidation state of less than three, but no Ti metal was identified. In dimethyl sulfoxide solutions containing LiCl, it was possible to deposit Li metal. After adding Ti salts to the solution, electrolysis quickly passivated the electrode. Deposition of Ti was also investigated in solutions of dimethoxyethane and propylene carbonate but, again, no reduction of Ti to oxidation states of less than three occurred. Therefore, the prospects for a nonaqueous electrorefining system for Ti metal do not appear promising.

Jan 1, 2010

By D. M. Schubert

As a clean and renewable energy carrier, hydrogen is an important component of most alternative energy portfolios. Hydrogen combines very high energy content by weight with excellent environmental attributes. Since hydrogen reacts with oxygen to produce only water with release of energy, it can be used to power fuel cells, combustion engines, and turbines, without production of greenhouse gases at point of use. However, because of its low volumetric density, storing pure hydrogen is impractical. Thus implementation of hydrogen technologies requires materials that can safely store and release large amounts of hydrogen (1,2). In recent years, the U.S. Department of Energy (DOE) and other governmental agencies around the world sponsored extensive research on hydrogen storage materials, including those based on boron. These efforts have resulted in significant advances in hydrogen storage technologies. Boron materials stand out as leading candidates for hydrogen storage among the many options investigated. Combining excellent hydrogen densities, release rates, and safety characteristics, some boron materials can hold substantially more hydrogen by weight and volume than even pure liquid hydrogen (3-5).

Jan 1, 2010

By Alan D. Hartman

Instabilities in electric steelmaking furnace arcs cause electrical and acoustical noise, reduce operating efficiency, increase refractory erosion, and increase electrode usage. The U.S. Bureau of Mines is investigating methods to stabilize these arcs. To perform experiments to test new hypotheses, Bureau researchers designed and instrumented an advanced, experimental single-phase furnace. This report describes this furnace, which was equipped with high-speed data acquisition capabilities for electrical, temperature, pressure, and flow-rate measurements; automated atmosphere control; ballistic calorimetry; and view ports for high-speed cinematography. Precise environmental control and accurate data acquisition allow the statistical design of experiments and assignment of rigorous confidence limits when potential furnace or procedural modifications are tested.

Jan 1, 2010

By Kanchan Mondal, Anthony (Sam) Spearing, Gopi Bylapudi, Joseph C. Hirschi

"The U.S. coal mining industry uses about 100 million rock anchors per year. ASTM F432 specifies the requirements for rock bolts on mines but does not address corrosion. Corrosion has been found to be an issue in Australian coal mines (Hebblewhite et al., 2003 and Villaescusa et al., 2007), where the problem has been researched and stress corrosion has been found to be a significant cause of rock falls. Corrosion is also a major concern for underground civil construction in the U.S. but has not been considered an issue or adequately researched in coal mines. Underground conditions are conducive to corrosion mainly because of water quality and humid conditions. There is a perception, however, that when bolts are fully grouted, adequate corrosion protection is offered to the steel. Research has shown that this is not necessarily the case, due to the formation of micro-cracks as the resin sets and with subsequent rock movement shearing the resin column. This paper outlines a method to determine the corrosion potential of bolts used in long-term excavations and suggests ways to mitigate such effects based on research conducted in the lab and on three mines.INTRODUCTIONResearch on rock anchor corrosion in mines has not been extensive enough in the past, and the effects of several factors in the mine atmosphere and waters are not clearly understood. One probable reason for this lack of research may be attributed to the time required for gathering meaningful data, which makes the study of corrosion quite challenging.Almost all the rock bolts used in coal mines are made from steel, hence the corrosion of iron needs to be understood. The corrosion of iron is an electrochemical phenomenon with the overall equation"

Jan 1, 2010

By B. B. Broms

Embankment piles are common in the Scandinavian countries (Kjellman, 1940) and in Southeast Asia as support of fills, light structures, bridge abutments and deep excavations (Eide, 1968) as described in the following. Untreated timber piles are often used for light structures and shallow fills when the ground water level is high since they are inexpensive and readily available. When the applied loads are relatively high precast concrete piles and steel piles are preferred. DESIGN CONSIDERATIONS Embankment piles carry the load from a fill or a struc-ture either through skin friction along the sides of the piles (Fig. 1a) or through a precast concrete slab or through pile caps at the top of the piles (Fig. 1b). When the load is carried by skin friction it is often economical to use small diameter timber piles because of the large surface area (Asplund, 1939). For precast concrete or steel piles concrete caps are used to transfer the load to the piles due to the relatively high capacity of the piles since the skin friction resistance alone is not sufficient to transfer the load to the piles.

Jan 1, 2010

By Rob Farnfield, Ben Williams, Bob Woolley

This paper outlines how drilling safety standards are being driven forward in the United Kingdom’s surface mining and quarrying industry with developments in equipment, procedures and competence.

Jan 1, 2010

By Maria I. De Rosa

The U.S. Bureau of Mines performed experiments to determine the hydrogen cyanide (HCN) concentrations and smoke particle characteristics during the combustion of flexible polyurethane foams and other nitrogen-containing materials, for the development of a test parameter. The experiments were conducted in an approximately 2O-L furnace at set furnace temperatures of 250° and 1,000° C for a 14-min duration, with an airflow through the furnace of 10 L/min. The variables studied as a function of time were the gaseous and aerosol HCN concentrations, the smoke particles average diameter (dg) and particle concentration (no), and the product of the smoke particle diameter and concentration (dgno). Carbon monoxide, carbon dioxide, and oxygen concentrations, sample mass weight loss, and furnace temperatures were also studied; analyses of nitrogen and cyanate content of the material were carried out. Results show that dgno correlates directly with the HCN concentrations, which depend on the nitrogen and cyanate contents of the material.

Jan 1, 2010

By G. W. Douglas

The need for dimensionally stable filled polymer composites has spurred the quest for materials that possess a negative coefficient of thermal expansion (CTE). Finding minerals and materials with a negative CTE large enough to counteract the substantial CTE found in polymers proves challenging. Much research has been per-formed over the last decade to uncover various materials that possess this unusual behavior. A list of materials that have demonstrated negative properties are discussed, as well as the experimental use of one such material (ZrW2O8), in a polymer matrix composite. Other negative properties, such as negative Poisson?s ratio and negative stiffness, are also examined. Key words: Negative properties, Coefficient of thermal expansion, Zirconium tungstate

Jan 1, 2010

Paper and paperboard manufacturers need to quantify the carbon footprint and environmental impact of their products to satisfy market, social and government demands. Coated paper products contain minerals, such as kaolin and calcium carbonate, at significant levels; some coated paper grades have mineral contents as high as 45% by weight. Some uncoated paper has no mineral content, but most uncoated paper contains some mineral to improve appearance, process efficiency and cost. Super-calendared paper grades can contain levels of mineral up to 35% by weight. This paper describes how to calculate the carbon footprint of kaolin and calcium carbonate minerals used for white pigments. The carbon footprint of these minerals strongly correlates to the primary energy sources, final product form and energy used to calcine kaolin and lime. Kaolin and calcium carbonate pigments have a favorable impact on the carbon footprint of paper and paperboard products by directly substituting for fiber and by reducing the energy needed for paper making. Key words: Kaolin, Calcium carbonate, Paper production, Carbon footprint, Lifecycle analysis

Jan 1, 2010

By S. Alpay

Underground mining method selection (UMMS) is one of the most important decisions that mining engineers have to make. Choosing a suitable underground mining method to extract a mineral deposit is very important in terms of economics, safety and productivity of mining operations. In real life, UMMS is one of the Multiple Attribute Decision Making (MADM) problems and decision makers have always some difficulties in making the right decision in the multiple criteria environment. Analytic Hierarchy Process (AHP) and Fuzzy MADM (FMADM) are the MADM tools and can be used for the selection of the best underground mining method by considering the problem criteria. UMMSMADM is a computer program which is based on AHP and FMADM and it can analyze the UMMS problems and produce the best underground mining method considering different deposit shapes and ore bodies.

Jan 1, 2010

By J. Larose, E. Irissou

The aerospace business has always been driven by innovation. A significant portion of the overall business technology development strategies is still based today on improved materials and coatings. In this highly regulatory business environment, large amounts of funding are required to increase the maturity level of novel technologies, but the evolution process still remains a delicate endeavor. The technical risks involved during technology development obviously need to be managed and mitigated throughout the development cycle, but other hurdles almost inevitably get encountered, such as budget limitations, transition from lab scale to production scale, loss of focus, intellectual property negotiations and supply chain integrity. This presentation will cover some of the issues raised when a great idea is slowly morphed into an aerospace production part.

Jan 1, 2010

By Naj Aziz, Peter Craig

"Double shearing tests were carried out on the 28 mm (1 in) hollow strand Jennmar TG cable bolt to gain a better understanding of the shearing behavior of the cable. The first test was limited to a 50 mm (2 in) travel on the testing machine and produced a shear load of 900 kN (92 t) at the maximum 50 mm (2 in) displacement. The axial load generated on the cable bolt was 238 kN (24.3 t). In the second test, the machine travel was increased to 75 mm (3 in), and first strand failure of the cable, due to shear loading, occurred at 1,354 kN (138 t) vertical load at a vertical displacement of 59 mm (2.3 in). The cable axial load was in the order of 385 kN (39.3 t). Analysis of the failure mode and loads achieved showed that the cable strands bent and the concrete crushed along the shear plane; the shear loading across the concrete and grouted cable then reached the tensile strength of the steel wires.INTRODUCTIONCable bolts were introduced to the mining industry around 1970, initially to surface mining and underground metalliferous mining and then to coal mining in the early 1980s, mainly for roadway reinforcement as a secondary means of support. Cable bolts have since been used as both primary and secondary supports. As primary support, Fuller et al. (1994) described the application of cable bolts, known as FLEXIBOLT, for strata reinforcement in both Angus Place and Ellalong Collieries, in New South Wales (NSW), Australia. As secondary support, cable bolts have also been used as cable trusses, which act to support the immediate roof in a sling-like manner (Fabjanczyk and Tarrant, 1988; Fuller, et al., 1991; O'Grady and Fuller, 1992), and for reinforcement at higher stratification and beyond the rebar bolt length, mainly for anchoring lower strata layers immediately above the coal seam to the higher, competent bedding formation above. Initially cable bolt anchorage was by cementatious grouting and, since the 1990s, by chemical resin. The dominant type of cable bolts used for secondary support in Australian underground coal mines are 588 kN (60 t) capacity cables which are point anchored, pre-tensioned and post-grouted. Point anchored refers to a cable resin anchor. The cables are tensioned on the resin anchor; then the same cable is grouted by cementatious grout pumped to ·fin the annular gap around the cable from the collar of the hole to the resin anchor. Bulbs are located within the resin anchor section for mixing of the resin chemical components and efficient anchorage. The installation of these typically 8 m long cable bolts involves a lot of manual handling of the cables, lifting of heavy hydraulic tensioners, and exposure to resin grouts. Table 1 shows the specification of various cable bolts currently marketed and installed in Australian underground coal mines."

Jan 1, 2010

When solid pillar is not left to separate different mining levels in underground mine with high dip angle deposit, waste rock in the backfilled stope could be a safety hazard to future mining activities on levels above or below the backfill. Different backfill methods can be used to eliminate this hazard according to the deposit shape and mining method. Building concrete pillar in ore drift of each mining level is one of them. Concrete pillar had been constructed in underground mines based on operational experience. Little design literature and pillar performance data can be found. At Great Basin Gold Hollister Mine, over two thousand feet of concrete pillar had been constructed. The project started with engineering design which combined civil engineering concrete design and the specialties of underground construction. Time Domain Reflectometry technique was installed to monitor the pillar movement and concrete cylinder samples were collected and tested for quality control. Engineering design, underground construction, quality control and concrete pillar monitoring, as well as precious concrete mixing data from years of experience are fully covered in this paper to give a general frame of concrete pillar method.

Jan 1, 2010

By R. J. Kuczynski

The U.S. Bureau of Mines operated a 2,000-g (4.4-lb) batch process development unit for recovering platinum-group metals (PGM) from automobile catalysts. Virgin monolith, used pellet, and used monolith catalyst samples were tested. Leaching twice with 1-pct sodium cyanide (NaCN) solution at 1600 C for 1 h dissolved more than 95 pct of the PGM from virgin catalysts and more than 90 pct from used pellet catalysts. More than 85 pct of the PGM was dissolved from used monolith catalysts when a third autoclave step was added. Solid PGM concentrates containing more than 99.8 pct of the dissolved PGM and analyzing greater than 70 pct PGM were recovered by heating the pregnant leach solutions from virgin catalysts to 2500 C and used catalyst to 2750 C for 1 h. The solution after heating contained less than 0.2 ppm. total cyanide. The virgin residues passed the EPA Extraction Procedure Toxicity Test (EP Tox Test), the EPA Toxicity Characteristic Leaching Procedure (TCLP), and the California Waste Extraction Test (WET) for all elements except Ba. Adding sodium sulfate (Na2S04) to the virgin leach residues reduced the amount of Ba dissolved to an acceptable level. The used leach residues passed the EP Tox Test for all elements but failed the WET and TCLP for Pb.

Jan 1, 2010

By John Tatom, Michelle Crull, Robert Conway

The US Department of Defense Explosives Safety Board is sponsoring the development of a risk-based explosives safety siting program, SAFER. The fragment and debris hazard generated at the potential explosion site (PES) is critical at an exposed site (ES) over a significant range of standoff distances. The Science Panel Impact Debris Evaluation and Review (SPIDER) test program has been planned to develop improved predictions for the hazards inside an ES by fragments and debris. Data will include the mass and velocity required for perforation of the test cross-section and the characteristics of all debris produced inside the ES.

Jan 1, 2010

By C. J. Roos

Ground-engaging tools are used to prevent damage to the main components of earth-moving equipment. These tools consist of everything from shovel teeth to replaceable drill bits to dozer wear plates. The costs of these "consumable" items are increasing with the costs of raw materials. This project developed a tool to be used by Newmont Mining Corp. to predict the consumption of excavator teeth at a particular mine site. This paper presents the results of the Montana Tech research project in which an equation was developed to predict excavator teeth consumption based on production rates and rock properties.

Jan 1, 2010

By G. Wang

With the depletion of easy-to-treat phosphate resources, low quality phosphate ores with high carbonates, particularly dolomite impurities have to be mined to meet the agricultural demand because of the continued growth of world population. The separation of dolomite from phosphate has been recognized as one of the most difficult subjects in mineral processing due to the similarities in their physical and chemical properties. Flotation is considered the most important approach for beneficiating both easy-to-treat and high impurity phosphate resources. There is no doubt that the development of reagents is the key for achieving satisfactory separation performance through flotation process. In order to separate dolomite from phosphate, Arr-Maz Custom Chemicals has made great efforts in developing flotation reagents for removal of carbonates from phosphate ores of different origins worldwide. This paper describes some flotation reagents and processes for the separation of dolomite or/and calcite impurities from phosphate in the ores from different locations.

Jan 1, 2010

By Michael A. Trevits

During the time period from 1990-2007, there were 1601 reportable fires that occurred in the U.S. mining industry (an average of 89 fires per year). The leading causes of U.S. mine fires include flame cutting and welding operations, frictional heating and ignitions, electrical shorts, mobile equipment malfunctions, and spontaneous combustion. The National Institute for Occupational Safety and Health (NIOSH) is conducting a program of research addressing metal/nonmetal and coal mine fire prevention, detection, management and suppression. In the metal/nonmetal area, work was focused on technology transfer and training, and research to reduce the number of mobile equipment fires and their hazards. In the coal arena, research is underway to determine the root cause of cutting and welding-related fires and to evaluate the effects of ventilation schemes relative to the spontaneous combustion risk in longwall mines. Relative to fire management, research is ongoing on remote mine seal installation and remote mine fire suppression technologies. Finally, research is continuing to develop comprehensive and usable smoke management techniques and to develop mine fire growth models, propagation, and suppression. This paper presents a summary of some of the mine fire research and provides an overview of the next phase of the NIOSH mine fire research program.

Jan 1, 2010

From some of the largest tunnel projects in the some of the most vibrant cities, to smaller projects in remote corners of the globe, the Robbins Co. announced two tunneling projects in which its tunnel boring machines will be used. Robbins earth pressure balance (EPB) machines undercut Downtown Zhengzhou. Zhengzhou, a city of 7 million people, is set to become a crossroads for rail commerce in China. The country?s future main routes, traveling between Beijing and Guangzhou (North-South), and between Xuzhou and Lanzhou (East-West), will intersect in the city. The plan includes up to four rail lines in Zhengzhou itself, which will eventually link up to the national lines. Excavation of Zhengzhou Metro?s new Line 1 tunnels began on Sept. 28, 2010, when the first of two 6.3-m (20.7-ft) diameter Robbins earth pressure balance (EPB) machines was launched from a 16-m- (52-ft-) deep shaft.

Jan 1, 2010

By Leith Sharp

I was confronted with a profound dilemma as an undergraduate engineering student at the University of New South Wales in Australia in 1992. I had been taught that our planetary life-support systems were in a state of alarming decline by an institution that operated as if what the faculty was teaching was irrelevant. Lights were left on in empty overcooled classrooms, recycling bins were nonexistent, lawns were maintained using pesticides and herbicides, diesel trucks spewed fumes as they passed on their way to drop off chlorine-bleached virgin paper. This disconnect was very alarming to me. While it was obvious that universities should play a leading role in teaching and researching sustainability issues, I wondered how it could be possible to make widespread institutional changes to meet the demands of environmental sustainability when it was not even being done in the very university sector where these ideas were being promulgated. If universities would not change, then who can and who will, I wondered? To a growing number of people, the idea of teaching sustainability without demonstrating it is highly problematic. It is also widely believed that the ability of the higher education sector to reform its own practices is an important indicator of humankind?s ability to address the global environmental imperative across all sectors of society. These sentiments have helped fuel what is now referred to as the campus sustainability movement, a movement dedicated to transforming our campuses into living laboratories for the demonstration and practice of environmental sustainability.

Jan 1, 2010