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By G. A. Kordosky

There are a number of reasons why the solvent extraction of molybdenum deserves attention: 1. The solvent extraction chemistry of molybdenum is interesting and complex, 2. The price of molybdenum is predicted to average about US$ 20.00 / pound in 2010 and, as China, India and other countries develop, the demand for specialty steels will increase putting long term demands on molybdenum supply, 3. Uranium ores often contain significant concentrations of molybdenum[1] and typically yellow cake will have a moly specification which when exceeded brings penalties, and 4. The valuable metal rhenium is a byproduct of molybdenum recovery circuits.

Jan 1, 2010

By Kwang-Yeom Kim, Dong-Gyou Kim, Hyo-Kwan Yoon

This study was intended to simulate the blasting model using notched-hole with numerical approach. Numerical analysis approach was applied to compare and evaluate the blasting model using notched-hole and circular hole. To implement non-linear dynamic blasting model, blasting analysis was carried out with AUTODYN code. Behavior of two models was compared and evaluated using AUTODYN and visual analysis and quantitative evaluation based on pressure and stress to verify the effect to induce the destruction territory to the specific direction when blasting with notched hole was attempted.

Jan 1, 2010

By N. F. Dawson

Recovery of a chromite concentrate from UG2 flotation tailings streams, of a grade suitable for further pyrometallurgical treatment for the production of ferrochrome, has certain specific challenges not only by virtue of the decoupled nature of the primary PGM recovery process and secondary gravity based chromite recovery circuits, but also because of intrinsic variations in the nature of the ore and its mineral composition. Variability in the ore, together with upstream process dynamics, creates a challenging environment in which to achieve optimal recovery of a gravity concentrate with accurate grade control. This paper examines certain inter-relational aspects between the ore gangue and chromite mineral types, the influence of the primary PGM extraction circuit and secondary chromite extraction activity as applied specifically to UG2 ore against a background of actual plant experiences and circuit configurations applied in order achieve a suitable quality of chromite concentrate.

Jan 1, 2010

By A. E. Petersen

To reduce U.S. dependence on imports of titanium, the U.S. Bureau of Mines has investigated the recovery of titanium from perovskite (CaTi03). Domestic perovskite deposits represent a significant, but untapped, titanium resource. An acid sulfation method was developed that will extract about 97 pct of the titanium and the columbium and 70 to 90 pct of the rare-earth byproducts from perovskite concentrates. A flow-sheet for recovering titanium as pigment-grade titanium dioxide (Ti02) is discussed. Test work performed in developing each unit operation is described. The first three unit operations have been demonstrated using laboratory-scale continuous methods of operation: acid sulfation of perovskite concentrates, leaching sulfation residue to dissolve metal values, and precipitation of titanium oxysulfate monohydrate (TiOS04?HP) from the resulting leach flltrate. Batch testing of other unit operations was performed: TiOS04?H20 redissolution and iron reduction, precipitation of Ti02 by hydrolysis, and regenerating recoverable acid with rare-earth byproduct recovery. Cost evaluation results are provided, indicating that processing perovskite concentrates by acid sulfation may be an economically viable means of producing Ti02.

Jan 1, 2010

By Roger Francis

There is increasing use of acid leach extraction methods at elevated temperatures and pressures by the mining industry. In many locations there are limited supplies of fresh water, and waters with higher chloride contents must be used, making conditions more corrosive. The fluids downstream of the main autoclave are hot, acidic, oxidizing and contain chlorides and present a challenge to the mining community to ensure reliable operation. Zeron 100 is a high strength superduplex stainless stee, that offers high corrosion resistance at a cost effective price. The paper presents a combination of laboratory data and service experience, particularly in the aggressive fluids found in downstream processing.

Jan 1, 2010

By D. Tao

Coal is a major source of energy in the U.S. and more than 51% of the electricity used in the country is generated from coal. Coal cleaning prior to combustion is necessary and often accomplished using wet physical processes at coal preparation plants to remove impurities such as ash, sulfur, mercury. However, the resultant clean coal product still contains a significant amount of impurity due to the fact that impurities are not well liberated from coal particles ranging from several millimeters to inches in size at which wet cleaning processes take place. A cleaner coal product can be obtained if a cost-effective dry process is developed to further clean pulverized and thus better liberated fine coal at the power plants prior to its combustion. The benefit of such a process is a significant reduction in the cost of expensive post-combustion chemical cleaning processes such as flue gas scrubbing employed to meet the stringent environmental air quality regulations. In this study, a novel rotary triboelectrostatic separator (RTS) was investigated for its application to dry cleaning of fine coal samples acquired from the power plants in the state of Illinois. The pulverized fine coal contains well liberated ash and pyrite minerals and is an ideal feed to the triboelectrostatic separator for further cleaning without the use of water or any chemical reagents. The proprietary rotary triboelectrostatic separator (RTS) is characterized by an innovative high efficiency rotary charger, charger electrification, laminar air flow, and specially designed electrodes. Compared to existing triboelectrostatic separators, the rotary triboelectrostatic separator offers significant advantages in particle charging efficiency, solids throughput, separation efficiency, applicable particle size range, etc. Testing with several fine coal samples has demonstrated that this technology can significantly reduce ash content with a process efficiency similar to or better than froth flotation. Important process parameters such as charger rotation speed, injection and co-flow rate, feed rate were investigated for their effects on separation performance.

Jan 1, 2010

By T. H. Jeffers

The U.S. Bureau of Mines has developed porous beads containing immobilized biological materials such as sphagnum peat moss for extracting metal contaminants from waste waters. The beads, designated as BIO-FIX beads, have removed toxic metals from over 100 waters in laboratory tests. These waters include acid mine drainage (AMD) water from mining sites, metallurgical and chemical industry waste water, and contaminated ground water. Following the laboratory studies, cooperative field tests were conducted to evaluate the metal adsorption properties of the beads in column and low-maintenance circuits, determine bead stability in varied climatic situations, and demonstrate the beads' potential as a viable waste water treatment technique. Field results indicated that BIO-FIX beads readily adsorbed cadmium, lead, and other toxic metals from dilute waters; effluents frequently met drinking water standards and other discharge criteria. The beads exhibited excellent handling characteristics in both column and low-maintenance circuits, and continued to extract metal ions after repeated loading-elution cycles. Based on laboratory and field data, cost evaluations for using BIO-FIX technology to treat two AMD waters were prepared. Operating costs for BIO-FIX treatment, which ranged from $1.40 to $2.30 per 1,000 gal of water treated, were comparable with chemical precipitation costs.

Jan 1, 2010

By A. L. Martikainen

Booster fans increase air pressure to overcome resistance, the objective being to force adequate amounts of air through distant workings. They are used in areas that are difficult or uneconomic to ventilate with main fans alone. Booster fans are currently permitted in underground coal mines in some countries; the United Kingdom, South Africa, Australia and Canada have been defined as major users. Booster fans are not allowed in the US bituminous and lignite coal mining operations at the present time due to safety concerns. This paper presents the history of booster fan use in coal mines of the United States during the last 90 years. Changes in regulations, as well as advantages and disadvantages of booster fan use, are discussed. Research and petitions for booster fan use are highlighted in order to bring the debate into focus.

Jan 1, 2010

By M. Mathiba

High CO2 fluxes associated with reclaimed coal mine spoils pose an environmental hazard where such sites are used for building. CO2 concentrations in excess of 25% have been reported in homes constructed on or down gradient of such spoils. The objective of this study was to investigate the effect of a mitigation trench used at one mine site on CO2 fluxes across the trench using chamber?based trace gas measurement. LI8100 automated CO2 flux system was used to measure CO2 fluxes from 32 sample points located across a deep mitigation trench on June 8 and 9. The maximum recorded fluxes were 7.29 and 8.18 µmol/m2/s, with averages of 4.15 and 5.50 µmol/m2/s, up and down-dip respectively. These preliminary results show CO2 flux is higher up-hill than down-hill at 95% significant level. This work shows that flux measurement can be used to investigate CO2 migration on reclaimed mine land. Further work is necessary to allow geostatistical modeling of the spatial variability of CO2 fluxes over reclaimed coal mine spoils. Knowledge gained would assist mining practitioners and regulators in reclamation planning for envisaged post-mining land uses.

Jan 1, 2010

By W. A. Wilkinson

Mine planners are under pressure to evaluate the impact of changing economic times and newly acquired data on their mine plans. Incorporating changes such as commodity prices, customer sales, fluctuating cost assumptions and newly acquired geologic data requires quick turnaround for model building and planning to keep mine plans on pace with changes as they occur. Because of the length of time required to perform some of the geologic modeling and mine planning tasks, planning frequency may not be keeping pace with the frequency of change. To meet these challenges, one leading North American mining company successfully increased the frequency rate and accuracy of its mine plans to stay current with incoming data, ensuring its mine plans reflect the latest information, thereby minimizing or eliminating production cost variance.

Jan 1, 2010

By Tatiana Ravani von Ow, Leandro Bomvisinho

"The size of mills driven by ring-gear or by a gearless solution has significantly increased in the last years. This has created additional challenges for the driven equipment. The requirements for the mechanical devices and the power grid have become more demanding. Controlled soft starting and operation, especially in dual pinion mills, as well as the protection of the equipment has gained importance. The selection of the drive solution for the mill therefore becomes more critical. Besides the classical criteria such as performance, efficiency and capital costs other factors come in the evaluation of the system such as flexibility and optimization of operation, reliability and the ageing of the grinding equipment.Variable speed solutions offer significant advantages over conventional fixed speed drives due to their application specific features and process optimization capabilities, even for ball mills where these are not seen yet as a must.The initial capital costs are higher than some of the direct on-line solutions however the benefits for the operation during the lifetime of the mill generated by the use of converter solutions justify the additional higher investment.INTRODUCTIONThe method of powering mills such as AG, SAG and Ball has a long and technically interesting history. It can be said; almost every decade in the last half century had its own trend. The trend was dominated by the market demand, by the process development and requirement of the mechanical and the electrical technology but mostly by the price of the applied technology.All has started about 50 years ago with mill diameters less than 20 feet driven by fix speed synchronous or wound rotor motors with the power of about 2 MW. Around 10 years later, the mill sizes increased, but the necessary torque could not be transmitted by one pinion therefore dual pinion solutions were developed to power the mills. However, realization of the dual pinion solution was only possible when load could be evenly shared between the two pinions."

Jan 1, 2010

By H. W. Kilau

The U.S. Bureau of Mines is evaluating water spray additives for the purpose of improving respirable dust control during coal mining operations, with particular emphasis on the longwall shearer. Recent field tests of surfactant-polymer reagents at two production longwall operations have shown favorable respirable dust reductions compared with water sprays containing no additive. Gravimetric dust samples obtained by a technician downwind of the shearer while following or preceding the machine showed dust reductions in the range of about 40% to 60% for some of the reagent formulations compared with using water alone. Three polymers were tested: two polyethylene oxide compounds of different molecular weight and hydroxypropyl methylcellulose (HPMC). All were effective for dust reduction, and two were cost effective when used in combination with sodium di(2-ethylhexyl) sulfosuccinate surfactant. How-ever, the use of these reagents requires the longwall operator to be more aware of headgate dust control. Experimental evidence indicates that dust captured by reagent-treated sprays at the shearer can be reemitted in the headgate area if stagcloader-crusher sprays and other dust controls are inadequate.

Jan 1, 2010

By H. Ankara

Determining the identicalness levels of the same model trucks working in open pit mine transportation system by means of statistical analysis methods is very significant in terms of availability analysis. In this study, the identicalness levels of two trucks picked randomly from the 170-short-tonne truck fleet working in open pit coal mine over one-year period were examined through a non-parametric test, Mann-Whitney U test for two samples. Time to failures (TTFs) and Time to Repairs (TTRs) of the trucks were analyzed with this test technique and then whether they were identical or not was determined. In order to determine whether the trucks identified to be identical at the end of this test displayed the same mining performances within the same open pit transportation system, the availability analysis of the identical trucks was carried out. As a result of the availability analysis, it was observed that the trucks had availability values that were very close to each other. It was also determined that Mann-Whitney U test could be employed together with availability analysis. Finally, it was observed that Mann-Whitney U test for two samples could yield rapid results in the performance analysis of complex systems like open pit mines.

Jan 1, 2010

When science and the human spirit come together amazing things can happen. This was perhaps never more evident than through the events that unfolded during August and October in a remote desert in northern Chile. On Aug. 5, the main shaft of the San José copper and gold mine near Copiapó in Chile?s Atacama Region collapsed, leaving 33 miners trapped more than 624 m (2,000 ft) beneath the earth?s surface.

Jan 1, 2010

By Dennis Dolinar

"Tailgate entries in U.S. longwalls can be subjected to high loads and deformations. Therefore, tailgate entries are generally supported with varying types and amounts of standing support. However, even with standing support, roof falls and blockages can occur in the tailgate when the support system is not properly designed. Safe and efficient operation of a longwall face requires the selection of the appropriate type and amount of standing support. Because of the importance of maintaining a safe and functional tailgate entry, the National Institute for Occupational Safety and Health (NIOSH) is currently developing a standing support design methodology based on the ground reaction curve. Using the ground reaction curve for design requires that the ground and support interaction be quantified. This can be accomplished by the installation and analysis of data from instrumented field sites. Although necessary, the field results cannot develop the complete ground reaction curve. Numerical models, calibrated to the field results, are used to establish the complete ground reaction curve. In the present study, data was obtained and evaluated to establish points for calibration of the ground reaction curve for two western longwall operations.One test site, Mine A, was located at a depth of 1,550 ft. At this site, the floor consisted of siltstone, while the roof was an interbedded siltstone and sandstone. Because of the depth, a double row of22-in diameter CANs1 were installed to support the tailgate. Both the first and second longwall panels have mined past the instrumented site.The second site in Mine B is at a depth of only 760 ft. The floor at this mine consists of a weak shale/mudstone and the roof consists of thick, top coal overlain by weak shales. At this site, a double row of pumpable cementitious cribs was installed. The second test site has only been subjected to side abutment loading from first panel longwall mining.The measurements indicate that the support at both mines was heavily loaded when subjected to the side abutment loading from first panel mining. At the deeper site, the support began to yield when the face was more than 300 ft outby during second panel mining. In comparison to results from previous test sites in the Pittsburgh Seam and Illinois Basin, the amount of support loading and roof-to-floor convergence was an order of magnitude higher at the western sites. This has resulted in a significant difference in the position and shape of the ground reaction curves."

Jan 1, 2010

By Orhan Gokce Goksu

It has been shown that metallic tungsten powder can be obtained by electrochemical reduction of solid CaWO4 in molten CaCl2-NaCl eutectic mixture at 600oC. In this study, constant and pulse voltage electrolysis experiments were performed to optimize reduction kinetics and obtain information about the mechanism of above process. It was found that pulse voltage applications yield faster reduction rates when average voltage of pulse voltage application was the same as constant voltage application. In addition, analysis of the current vs. time graphs of constant and pulse voltage electrolysis studies showed that reduction occurs at potential differences higher than about 2.2 V between CaWO4 cathode and graphite rod anode.

Jan 1, 2010

By Dale Preece, Joergen Pilz, Zavis Zavodni

An overland conveyor was constructed at a surface coal mine to reduce the truck haul distance and make the operation more efficient. An important element in this system is a truck dump facility to transfer coal from truck to conveyor. Mechanically stabilized earth retaining walls were employed to accommodate the coal processing equipment, including the crusher, in this facility. These retaining walls are close enough to the pits being mined that blasting induced vibrations must be considered in analyses of the wall structural stability.

Jan 1, 2010

By Dale Zacherl, Andreas Buhr, Rainer Kockegey-Lorenz

"The microporous calcium hexaluminate insulating material SLA-92 has been introduced as an alternative to refractory ceramic fiber and other insulating refractory materials. Key properties associated with this product include: high chemical purity, long term high temperature stability up to 1500 °C, low thermal conductivity up to 1500 °C, and high thermal shock resistance. The properties of the new material and various applications in the steel and ceramic industries have been reported in previous papers. The current paper summarizes the industrial application experiences with innovative refractories based on SLA- 92 and discusses potential new applications in various manufacturing as well as energyrelated industries.IntroductionSLA-92 was introduced to the refractories industry in 1998 by van Garsel, et al. [1] as a new insulating raw material for high temperature applications, followed by investigations [2] of long term temperature stability for this new lightweight aggregate up to 1500°C.SLA-92 was developed as an innovative alternative to commonly used refractory ceramic fibers. It has unique properties regarding chemical purity and mineral composition and is a microporous, silica-free calcium hexaluminate (CA6 – mineral name: hibonite)."

Jan 1, 2010

By Gerrit V. R. Goodman

Future coal mining systems will be able to cut from crosscut to crosscut where advances could exceed 100 ft. However, limitations arise when ventilating such mining systems. In deep advance mining, there would be no workers at the face to advance ventilation tubing or curtain manually. Traditional methods also provide no means for maintaining face ventilation after the miner backs away from the face. U.S. Bureau of Mines research is studying means to provide effective ventilation at cut depths beyond the current limit of 4D ft. Several innovative ventilation schemes are currently being considered. One such method is the use of a jet fan to ventilate a deep cut. A jet fan is simply a freestanding fan using little or no ducting to direct the ventilation flow. Jet fan testing in a 90-ft entry revealed that higher exit velocities and greater penetration depth occurred when various configurations were used to confine and direct the air flow. Additional testing also indicated that 2,200 cfm of fresh air was delivered to the face? 90 ft distant when a check curtain was used to limit entrainment around the fan. Without this curtain, this quantity dropped to only 1,000 cfm. This testing indicated that a jet fan was capable of providing ventilation to a distant face area. It also highlighted potential problems, such as recirculation at the fan and reentrainment in the jet flow. Despite these potential problems, jet fans may be adequate for ventilating cuts exceeding 4D ft.

Jan 1, 2010

By B. W. Moore

The U.S. Bureau of Mines investigated the separation of heavy rare-earth elements (REE) in an ion-exchange process. An ion-exchange column consisting of two sections, a loading section and a separation section, provides high levels of REE loading and good REE separation with an expected processing cycle of less than a month, while current ion-exchange technology requires more than 5 months. A different resin is used in each section: sulfonic resin in the loading section and iminodiacetic resin in the separation section. The separation section is further divided into two segments: the first conditioned with NH4 and the second with acid. Erbium is loaded onto both segments of the separation column as a retaining ion. Bands of mixed REB eluting between separated bands of pure REB were recycled directly to the column. Without mixed-band recycle, over 80% of the REE eluted from the column was separated into fractions with 99% purity of each element; with such recycle, the percentage of separated elements can be increased to around 90%.

Jan 1, 2010