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By K. S. Raja, M. Misra, S. K. Mohapatra

"Ordered arrays of TiO2 nanotubular photocatalysts were prepared by a simple anodization process. Band gap states of the TiO2 were altered by controlling the anodization electrolyte composition and thermal annealing conditions that resulted in enhanced photo activity. These nanotubes were used for reducing CO2 to methanol either by photochemical or photo electrochemical routes. Pd nano-particle loaded TiO2 nanotubes were employed for photochemical reduction of CO2 to methanol that showed a conversion rate of 12 x 10-3 mol m- 2h-1. Carbon modified TiO2-xCx type nanotubes were used as photo anode and Ti as cathode for photo electrochemical reduction of CO2. The potential of Ti cathode was maintained at -0.5 V SCE. The formation rate of methanol was determined as 13 x 10-3 mol.m-2h-1.1. IntroductionGlobal warming due to emission of carbon dioxide is a serious environmental concern. The atmospheric concentration of CO2 is about 384 ppm by volume and about 3 x 1012 tonnes by weight. Burning of fossil fuels and deforestation are the leading causes for increase in the anthropogenic CO2. More than 32 x 109 tonnes of CO2 are released per year (based on 2006 data) worldwide from the fossil fuel. Pumping CO2 from the fossil fuel power plants into deep ocean basin is one of the most discussed disposal options. The other potential option is converting this green house gas into valuable fuels.Carbon dioxide feed stock can be converted into fuels of solid, liquid or gas phase by chemical, electrolytic, photocatalytic and photo-electrocatalytic methods. Reduction of CO2 to fuel form of any phase requires energy. The reduction process should be energy efficient so that we do not spend more energy and emit more (indirect) CO2 in the process of converting CO2. From this point of view, conversion processes occurring at room temperature look attractive.Electrolytic conversion of CO2 into various forms such as methane1, ethane2, ethylene3, methanol4,5, ethanol6, n-propanol, formic acid7, and formaldehyde has been widely reported. The standard equilibrium potential (at pH: 0) for reduction of CO2 to methanol is 0.14 VSHE and to methane is 0.2 VSHE which is thermodynamically more favorable than hydrogen reduction. However, the gas phase reduction is kinetically complex requiring effective electrocatalyst. The major issues with electrolytic conversion of CO2 to useful products are:"

Jan 1, 2010

By D. M. C. Valbom

The introduction of new diamond sorting technologies as well as additional manufacturers I vendors, has increased the equipment selection and combinations available for recovery flowsheet design. This paper describes the methodology used and the benefits realized in the design of recovery plants by ensuring a fundamental understanding of the advantages and limitations of the technology embodied in the equipment, a comprehensive knowledge of the ore body characteristics, and the effective matching of this information in combination with operational commercial requirements.

Jan 1, 2010

By Benjamin Cebrian

Rock blasting at quarries represents multiple challenges not easy to see at first sight. Aggregate industries face similar or superior prices for explosives while extracting a material that usually is of less value of metal mining operations. Therefore, learning to optimize a quarry operation can be a perfect training for a position in blasting at larger metal mining operations.

Jan 1, 2010

By G. F. Friel

A series of experiments in the U.S. Bureau of Mines Safety Research Coal Mine at the Pittsburgh Research Center evaluated the effects of crosscuts on the travel time of carbon monoxide (CO) along an entry to improve the accuracy of a mine-fire locator program. Three entries, ten single crosscuts, and three double crosscuts were instrumented with CO sensors. One-percent CO in nitrogen was released and monitored as it traveled the entries. In addition to dispersion of CO at the front of the CO wave, CO was entrained from the entry into the crosscuts. It was determined for an entry and single-crosscut configuration that the measured travel time for a concentration change of 5 ppm was 27% greater than the predicted time based upon entry volume only, but 13% less than the predicted time based upon entry and crosscut volumes. For an entry and double-crosscut configuration, the measured travel time for the same concentration change was 25% greater than the predicted time based upon entry volume only, but 10% less than the predicted time based upon entry and crosscut volumes. An effective dispersion coefficient for CO dispersion along one of the entries was estimated to be 1.5 m2/ s.

Jan 1, 2010

By Joseph P. DuCarme

The U.S. Bureau of Mines explored new methods and technology for extracting coal from the Appalachian Mountain region of the Eastern United States. These methods were aimed at extracting coal from thin seams and focused on the use of "roof-fall-tolerant" (RFT) mining concepts. These methods could be used on existing, abandoned highwalls or in conjunction with new highwall mining. The research was conducted using small-scale and quasi-full-scale physical models to obtain experimental results. Details are provided on (1) the quasi-full-scale model for cross-ridge mining, (2) the quasi-full-scale model for down-ridge mining, (3) the test results of these models, and (4) recommendations for future research. Significant results include demonstration of the RFT concept, a discussion of expected coal produced from these methods, and recommendations for future research.

Jan 1, 2010

By Les Willan, Chris Batten, Matt Sparkes

In late 2008 Xstrata Newlands Coal Mine in Central Queensland and Orica Mining Services engaged in discussion to investigate methodologies to change their current mining practices and overcome the issues in the mining of steeply dipping coal seams, the associated coal loss risk and to assist in improving mining productivity. A strategy was developed and it was determined that through-seam blasting was essential to the success of winning the coal from the Wollombi Pit at Newlands.

Jan 1, 2010

By Rob Thomas

"In Australia, a wide roadway is commonly defined as any roadway that is driven to a width greater than 5.5 m (18 ft). These roadways are typically required to enable the installation of longwall equipment (termed installation roads); however, other applications include the need to house conveyor driveheads and pre-driven recovery roads.As a result of the increasing size of longwall equipment and mine infrastructure, in some mines, roadway widths of between 9 and 12 m (30 and 39 ft) and are being developed.Accepting that these almost always constitute strategically important and often long-term roadways, this paper considers the use of: (i) an empirical roof support design model, which is based on over one hundred case histories, (ii) various roof support design principles, and (iii) commonly accepted strata management techniques.The paper demonstrates that wide roadways can be driven and supported to an acceptable standard providing due consideration is given to the prevailing ground conditions (including the quality of the immediate and upper roof strata, the Depth of Cover and the horizontal stressfield), the final width of the roadway and the required use of the roadway.INTRODUCTIONRoof behaviour and the associated roof support requirements in wide roadways, which are roadways typically driven to a width that is greater than 5.5 m (18 ft), are controlled by a number of key geotechnical and operational factors. The recognition of these factors is an important first step in the design process and it is imperative that each is considered in conjunction with local mine site information.The main points of note in this regard can be summarised as follows:• The greater the final width of the roadway, the greater the resulting surge in roof displacement on widening - note: a) see Figure 1 for a schematic illustration of the roof displacement trends typically measured during the development of the first pass and roadway widening, b) since displacement increases with roadway width, it is always recommended that the roadway width is kept to the minimum required and c) general buckling beam theory indicates that the capacity of any beams present in the roof will reduce in inverse proportion to any increase in roadway width squared (i.e., [final width2 -first pass width2] I final width2)."

Jan 1, 2010

By M. J. Jackson

MIGRATOM is a third-generation PC-based computer program developed by the U.S. Bureau of Mines for geophysical tomography. Like its predecessors, BOMTOM and BOMCRATR, MIGRA TOM was developed to enable users to address a variety of mining-related problems by mathematically reconstructing the distribution of physical properties in a rock mass, using measurements of travel time or amplitude of wave energy propagated through the rock mass. Examples of applications include lithologic characterization, fracture detection, fluid monitoring, stress evaluation, and blast assessment. The resolution and accuracy of tomographic reconstructions generally depend very strongly on the geometry of source and receiver locations. In many practical applications, such as cross-borehole tomography, limited coverage results in nonunique reconstructions. MIGRATOM follows the precedent of BOMTOM and BOMCRATR in allowing the user to constrain the inversion, in order to reduce the nonuniqueness problem. A new approach to application of constraints implemented in MIGRATOM is based on fuzzy logic techniques. Refraction of wave energy is modeled in MIGRATOM using an approach based on Huygens' Principle. Propagation of a continuous wavefront is modeled as a constructive interference phenomenon, which obviates the shadow-zone problem that affects conventional ray-tracing calculations. MIGRATOM has been tested with both synthetic and field data sets.

Jan 1, 2010

By D. K. Dysinger

In this U.S. Bureau of Mines study, neodymium metal of 99.8 pct purity was prepared by electrolysis of Nd203 salts dissolved in a molten fluoride electrolyte. The metal was electrowon in a molten state at current efficiencies of 50 to 60 pct. Oxygen and carbon were the major impurities detected in the product. During operation of the small-scale laboratory cell, a number of technical problems including anode effect, low oxide solubility in the electrolyte, high neodymium metal solubility, reactivity of the metal with the cell materials, and back reaction of the metal with the anode gases were encountered. Approaches to improve cell operation and prospects for commercial adoption of the electrolytic production of neodymium metal are discussed.

Jan 1, 2010

By R. J. Matetic

The objective of this U.S. Bureau of Mines hydrologic-subsidence investigation was to evaluate the effects of longwall mining on the local ground water regime through field monitoring and numerical modeling. Field data were obtained from multiple-position borehole extensometers (MPBX's) that were used to measure subsurface displacements. Survey monuments were installed to measure mining-induced surface deformations. Numerous drawdown and recovery tests were performed to characterize hydrologic properties of the overburden strata. Coreholes were drilled above the study area to determine lithologic and strength characteristics of the overburden strata using the rock samples collected. Electronic recorders were installed on all monitoring wells to continuously monitor ground water levels in coordination with mining of the longwall panels. A combined finite element model of the deformation of overlying strata, and it's influence on ground water flow was used to define the change in local and regional water budgets. The predicted effects of the postmining ground water system determined by the model correlated well with field data collected from the fieldsite. Without an infiltration rate added to the model, a static decrease of 3.0 m (10 ft) in water level would occur due to mining of both longwall panels and if an infiltration rate was inputted in the model, no predicted long-term effects would occur to the ground water system.

Jan 1, 2010

Slope stability is a fundamental part of a successful mining operation. It impacts directly on the safety of personnel and the economics of the mine. The Jwaneng Mine in Botswana is planning a push back of 644m depth in the south east wall. Mining will commence in 2010 and be completed in 2024. This will put the mine in the deep pit category. The mine has invested in extensive geotechnical data gathering and design programs that started as far back as 2003 for the south east wall. The south east wail of Jwaneng Mine is characterized by foliation that dips adversely into the mining faces. The orienta1ion of the foliation is variable due to intense tectonic movements that have also caused the occurrence of faults that are sub-vertical. A considerable amount of information on the characteristics of structural patterns and the rock mass has been collected. This paper presents an overview of the feasibility level geotechnical design that is about to be concluded.

Jan 1, 2010

By G. Ranjan

The designers and the practicing engineers have started using latest and cost effective techniques of ground improvements which utilise the weak and poor sub-soil deposits efficiently for the civil engineering construction. In the present investigation, a new concept of 'skirted granular piles' has been advocated. An effective method of construction of granular piles as an economical alternative to vibroflot, and the skirt has been developed. The construction technique is based on indigeneous know how which effectively utilises the man-power technology avoiding import of costly equipment suiting to the developing countries. Full scale insitu tests have been carried out at four sites, having different soil conditions, on virgin weak sub-soil, and improved ground by casting plain and skirted granular piles. Effectiveness of different types of skirt has been demonstrated through insitu tests. A simple analytical approach has been proposed to predict the ultimate pile capacity. The predicted values of ultimate capacity have been found to demonstrate a good correspondance. Granular pile behaviour in terms of pile depth, diameter, spacing and stress deformation characteristics of the improved ground have been discussed. A significant improvement in ultimate capacity in improved ground has been noted. This is further augmented when granular pile group is skirted.

Jan 1, 2010

By William W. Aljoe

The hydrologic characteristics of two abandoned underground coal mine sites, near Latrobe, PA, and Uniontown, PA, were investigated by the U.S. Bureau of Mines for possible implementation of alkaline injection into the mine pools as a means of abating their acid discharges. The Latrobe site was chosen for a one-time application of alkaline injection to achieve a partial, short-term neutralization of a limited portion of the mine pool. A quantity of alkaline reagent (sodium hydroxide) sufficient for a one-time neutralization of the water in this portion of the pool was added. Although nearly all of the neutralizing reagent had moved away from the injection wells within 6 weeks, no evidence of neutralization was noted at the mine discharge during the study period. This lack of neutralization probably occurred because the injection wells did not intercept a primary flow path through the mine. Criteria for successful application of alkaline injection at this or other sites include (1) positive identification of the primary flow paths through the mine pool and (2) addition of quantities of alkaline reagent sufficient to neutralize the entire volume of the pool along the primary flow path.

Jan 1, 2010

By R. B. Krog

The use of belt air as an intake source at longwall operations has changed greatly over the past decades. The practical considerations for the use of belt air are controlled by a variety of factors, including airflow quantity and velocity, coal methane content, methane desorption rates, coal mining rate, belt length, stopping leakage and the number of gateroad entries. At longwall operations, the advantages and disadvantages of belt air are different than for gateroad development and longwall panel extraction. During gateroad development, the use of belt air to ventilate the working section will reduce the leakage from the intake to the belt compared to the belt air being ventilated outby the working sections because of lower pressure differentials. A greater quantity of airflow will reach the last open crosscut with the belt on intake than outby, given the same amount of pressure and airflow available at the mouth of the section. This paper will investigate the current ventilation practices regarding the use of belt air during gateroad development and longwall panel extraction. Operating considerations regarding air quantities and pressures to deliver the required airflow will be investigated using ventilation network modeling.

Jan 1, 2010

The Namakwa Sands heavy mineral deposit is located along the West Coast of South Africa and the mine is a world class producer of high quality zircon, ilmenite and rutile concentrates from essentially unconsolidated marine and aeolian sands of Cainozoic age. The objective of this study was to characterize rutile with respect to distribution, grain size, textures, colour and mineral chemistry within the Namakwa Sands orebody with the aim to explain its overall poor recovery. A representative suite of heavy mineral concentrates from various sections of the orebody and stages in the recovery circuit has been investigated microscopically and by means of SEM-EDS and LA-ICP-MS. The rutile grain size distribution displays a wide range and is directly related to its variable chemistry and consequently density. In placer deposits such as Namakwa Sands, mineral sorting is a function of hydraulic equivalence, and high density grains are smaller than the lighter grains when deposited under similar conditions. Grain size is also a function of sediment maturity, and the highly mature red aeolians and (RAS) component of the deposit has a coarser grain size than the less mature orange feldspathic marine sands (OFS). The above primary characteristics of rutile are responsible for the loss of the coarse-grained fraction during screening and, given the empirically determined relationship that increased substitution elements reduce conductivity, also during electrostatic separation. Provenance studies using geothermometry have shown that the heavy mineral suite has been sourced mainly by the proximal medium-to high-grade Namaqualand Metamorphic Complex. The positive relationship between substitution elements and temperature of formation explains their high concentration in rutile of this deposit. The heterogeneity of rutile, produced by the combination of a high temperature primary source and the typical marine-aeolian placer genesis is deposit specific and unfortunately not conducive to high recovery levels in the current Namakwa Sands beneficiation circuit.

Jan 1, 2010

By D. L. Yopps

In research conducted by the U.S. Bureau of Mines, platinum-group metal (PGM) flotation concentrate from the Stillwater Complex, MT, was subjected to biooxidation using Thiobacillus ferrooxidans in an effort to break down the sulfide minerals and liberate the associated PGM's for subsequent chemical leaching. Bacterial preleaching oxidized up to 94 pct of the sulfide present, destroyed the PGM-bearing pentlandite [(Ni,Fe)9S8] mineralization, and dissolved most of the nickel in the concentrate. Cyanidation at 80° C proved to be the most attractive chemical leachant, removing 34 pct of the platinum, 76 pct of the palladium, 94 pct of the rhodium, and 97 pct of the gold from the biooxidized concentrate. Research also indicated that increased sulfide oxidation during the preleach phase led to improved PGM recovery in the subsequent chemical leaching phase.

Jan 1, 2010

Bateman Engineering managed the establishment of a second diamond treatment plant at the Letseng Mine in the Mokhotlong District of northern Lesotho, about 100 km from the town of Buthe Buthe. Letseng Diamonds Proprietary Limited, is owned 70 % by Gem Diamonds and 30 % by the Government of the Kingdom of Lesotho. The second plant, which commenced construction in late 2006, doubled Letseng Mines' hard rock processing capacity from 2.6 million t/yr to 5.2 million t/yr, making it the worlds' seventh largest diamond mine by throughput. Bateman Engineering provided the engineering design, procurement and construction management of the new plant.

Jan 1, 2010

By L. M. Nolan

Chemical Mechanical polishing, or CMP, has four components in the polishing interface; namely the polishing pad, the polishing fluid, the abrasives in the fluid, and the surface being polished. Understanding the way that load is transferred between these components is key to understanding and predicting wafer polishing. Numerous models of CMP and the different load sharing arrangements which occur between these four components have been proposed. These include models by Luo and Dornfield (1) and Fu, Chandra and colleagues (2). Other models focus on just one or two loading arrangements, such as `hydroplaning' when all load is transmitted by the liquid in the case of Runnels and Eyman (3). In this work, we consider four possible combinations of load transfer from pad to wafer in CMP. These combinations are listed below in Table 1 and are illustrated schematically in Figure 1. It is important to note the role of scale in this process; the illustrations in Figure 1 are drawn to scale from actual profilometer scans obtained over a length of 5 with particles of 150 nm in diameter. Table 1 - Load Transfer Combinations Load Regime Illustration Wafer - Fluid - Pad Figure la Wafer - Particles/Fluid - Pad Figure lb Wafer - Particles - Pad Figure lc Wafer-Pad Figure ld The interest in load-sharing between the system components is because some configurations are anticipated to achieve higher polishing rates than others. For instance, in hydroplaning, or hydrodynamic lubrication, the lateral force exerted on the polished surface by the particles can be no higher than the fluid shear force developed in the gap between the pad and wafer. This is not expected to generate high rates of material removal from the surface (4). For contact that is largely between the pad and the wafer, such as the regime depicted in Figure ld, the lateral load is transmitted to the wafer by the pad and is hence limited by the pad's low rigidity. This regime is not expected to generate high material removal rates either. The highest levels of material removal are expected from regimes where the mechanical load exerted on the system is transmitted by the particles, in combination with either the fluid or the pad. Under what circumstances does the polishing regime change from one to another? What must occur in order to initiate or terminate contact between the system components? This is an ongoing question in the field of tribology, and has traditionally been viewed in terms of the pressure and velocity applied to the system, the thickness of the fluid film between the two surfaces, and the roughness of those surfaces (4). In this paper, we propose a new mechanism ? that the load on the particles may be sufficient to totally embed them in the polishing pad, at which point they are no longer able to transmit load and polish the wafer surface. This is illustrated schematically in Figure 1(d).

Jan 1, 2010

By Uwe Wyink, Guenther Thiele, Isabel Gollnick, Klaus Thyrock

"The application of a thin spray on liner was implemented in longwall T-junction sections in 2009 for the first time. The development of the material and the application is based on a technical cooperation between RAG Deutsche Steinkohle AG and BASF Corporation. The report gives an overview of the first trials. The underground test occurred in a seam with a height of 1.5 m (5 ft) in a depth of 1,100 m (3,609 ft). The roadway is dual-use entry and the roof strata is composed of shale and sandy clay. In some sections geological faults impact the surrounding strata. The poor conditions induce separating and loosening of roof rock. Several remedial actions have to be implemented for decreasing deformations at the face entrance.The application of thin spray on liner (TSL) provides simplification and cost reduction of supporting work at longwall T-junction. The installation of TSL to avoid roof and coal fall operations for lagging are omitted.INTRODUCTIONFor safe operation of face retreat in dual-use roadways, the processes of securing and stabilizing the face end area are very important in order to minimize deformation and stress. Avoiding roof and coal fall are the main concerns for safe operation. For that reason different methods of reinforcement are tested in underground operation. In this paper the application of TSL is presented.The specifications of TSL are described, followed by the case study results. The underground study is located in one mine of RAG Deutsche Steinkohle. The extraction of the hard coal in this mine is characterized by great depth and high stress. There are poor geological and geotechnical conditions. The roadway used for the underground application was headed with the support system combination type A, which will be described later in the paper. After the first face retreat, deformation of steel arch support and bagging destroyed the roadway, so for the second face retreat remedial actions had to be undertaken. For this a new system of reinforcement, simplifying the supporting work at the longwall T-junction was tested. The reinforcement consisted of different parts that are described in the following report. Furthermore two different versions were applied. One method is the operation with TSL and the other one is the use of concrete for sealing. Both methods are compared in the text."

Jan 1, 2010

By Andrew Lewis, Amarit Nitaramorn, Alexander Garcia, Peter Altounyan

"Indonesia is a major coal producer, the vast majority being sourced from opencast operations. Underground production to date has been constrained by unfavorable ground conditions and limited local experience. However, an underground trial in East Kalimantan has now shown that it is possible to successfully extract coal and mine safely, despite the technical challenges.A trial drift mine has been worked to a current maximum depth of 160 m (525 ft) in a dipping coal seam. The 3 m (10 ft) thick coal seam is overlain by very weak mudstone and sandstones. The mudstone forming the immediate seam roof strata proved a particular challenge given its adverse reaction to water and overall friability.Rock bolts were used as roadway support, the system being carefully selected to optimize effectiveness. An innovative method of partial extraction was trialed, which demonstrated the potential for productive mining despite the ground conditions. Roof falls have occurred within the working area, and roadways demonstrate reasonable stability over time.Throughout the course of the trial, strata behavior monitoring has been an important aspect, and a comprehensive ground control monitoring system is in place. This has enhanced the ability to increase the level of support where required and to react to deteriorating conditions. In addition, monitoring information has allowed a quantitative assessment to be made of the technical feasibility of future full-scale mining.INTRODUCTIONWith current production at over 200 million tons, much of this destined for overseas markets, Indonesia is the second largest exporter of coal (Ritschel and Schiffer, 2007). The majority of the coal is sourced from the Kalimantan coalfields. Mining is predominately opencast, yet in recent years there have been attempts made to introduce underground operations. This move would permit continued access to good quality seams that are beyond the reach of viable opencast mining."

Jan 1, 2010