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By A F. D C Varajpo, R C. Weba, C Volkmer-Ribeiro, C A. C Varajpo, N S. Gomes

This study relates to the spongillite deposits from the region of Jopo Pinheiro, in the north-west of the State of Minas Gerais, south-eastern Brazil. The deposits occur in shallow ponds (with a maximum depth of 3.5 m) on a karstic planation surface developed on rocks of the Spo Francisco Neoproterozoic Supergroup. Cenozoic detritic covers are associated with this surface. The field study of spongillite deposits from the Preguita and Avipo deposits revealed sedimentological and pedological similarities between the different deposits. They have a lenticular shape and contain different layers of sedimentary spicules intercalated with layers of quartz sand and clay minerals. Representative samples from the different layers investigated by X-ray diffraction, differential and gravimetric thermal analysis and infrared spectroscopy showed a range from three to 80 per cent of amorphous silica (opal) corresponding mostly to the sponge spicules in the sediments. Optical microscopic investigation determined that the spicules predominantly belong to the sponge Metania spinata. This species is represented by smooth megascleres (alpha type), prickly megascleres (beta type) measuring 240 to 450 mm in length, as well as the spiny microscleres; whereby the smooth megascleres are larger and thinner. The morphological variation of the spicules as well as the presence of more fragmented spicules towards the base of the deposits, portray a variation in texture and in the state of their preservation along the profile, suggesting environmental variations at the time of their formation and deposition.

Jan 1, 2008

By Gjergj Dodbiba, Toyohisa Fujita, Takahiro Kikuchi, I-Chen Wu

"In order to separate molybdenum (Mo) from the high-level radioactive liquid waste (HLLW), Pb-Fe based adsorbents were synthesized. The adsorbents were precipitated by adding sodium hydroxide in mixture of 1 mol/L lead nitrate and 1 mol/L ferric nitrate aqueous solutions. Each precipitate was then filtered, dried and ground to obtain a fine powder, which has been used as an adsorbent. Two main parameters were considered when synthesizing the adsorbents, i.e. the pH value at precipitation of adsorbent precursor and the calcination temperature of Pb-Fe based adsorbent. Moreover, the structures of the synthesized adsorbents were investigated by means of an X-ray diffractometer.The experimental results indicated that the calcination temperature of the Pb-Fe based adsorbent has a great influence on adsorption capacity of the adsorbent for Mo. It was found that when the Pb-Fe based adsorbent was calcinated at 500 oC, the sorbed concentration of Mo was the highest.1. IntroductionThe high-level radioactive liquid waste (HLLW), arising from the reprocessing of nuclear fuel are generally immobilized in an alkali borosilicate glass matrix. Broadly speaking, alkali borosilicate glasses are the matrix of choice for the immobilization of the HLLW, since they permit vitrification of waste stream of variable composition, [1]. Within this frame, the incorporation of molybdenum (Mo) is of particular interest in the vitrification of HLLW. Molybdenum is know to have a low solubility in borosilicate glass compositions and its presence in excess results in the phase separation of a complex yellow molten salt during vitrification, [1]. The formation of so-called “yellow phase” material during the vitrification process is undesirable since it leads to the accelerated corrosion of the inconel crucible liners. Furthermore, the “yellow phase”, which is reported to contain also other fission products, is soluble in aqueous solution providing a potential route for the leaching of radionuclides from the vitrified waste, should it come into contact with water, [1]."

Jan 1, 2008

By V. Dentoni

The paper deals with the assessment of the visual impact generated by surface mining and quarrying. Previous research works proved the applicability of an indirect method based on the elaboration of digital images through which the extent of the visible altered area and the chromatic contrast with the surrounding environment is calculated. The resulting level of visual impact allows an objective comparison among different cases as far as the evaluation procedure is univocally defined. The article illustrates the application of the method to a number of selected quarries located within the Sardinian territory; different issues are discussed such as the choice of the viewpoints from which the pictures are taken, the influence of the distance from the quarry to the selected viewpoints, the light condition and the orientation of the quarry faces. Moreover, the visual impact level obtained from pictures taken at the same time with five digital cameras are compared in order to evaluate the contribution on the overall uncertainty.

Jan 1, 2008

By Dietrich Gross

This paper describes an advanced oxy-fuel combustion technology for re-melting aluminum that significantly reduces energy consumption and emissions. This oxy-fuel combustion technology developed by Jupiter Oxygen is a patented process for combustion of fossil fuels with pure oxygen while excluding air, thereby creating an undiluted high flame temperature and increased efficiency for process heating in industrial furnaces. This unique process has led to improved heat transfer and longer residence time while maintaining the same process temperatures as with air combustion. The energy efficient combustion process allows aluminum companies to operate at a substantially lower cost due to a dramatic fuel savings of up to 70% for natural gas and waste oil (1). The results of more than 10 years of day-to-day experience utilizing the Jupiter Oxygen Corporation oxy-fuel combustion technology licensed to Jupiter Aluminum Corporation in the aluminum re-melting business are discussed.

Jan 1, 2008

By Iam Pou Ng

Combustion aerosols consist mainly of elemental and organic carbon (EC and OC). Since EC strongly absorbs light and thus affects atmospheric visibility and radiation balance, there is great interest in its measurement. To this end, the National Institute for Occupational Safety and Health (NIOSH) published a standard method to determine the mass of EC and OC on filter samples. Another common method of measuring carbon in aerosols is the aethalometer, which uses light extinction to measure "black carbon" or BC, which is considered to approximate EC. A third method sometimes used for estimating carbon in submicron combustion aerosols, is to measure particle size distributions using a scanning mobility particle sizer (SMPS) and calculate mass using the assumptions that the particles are spherical, carbonaceous and of known density. With an eye toward evaluating the use of these methods for measuring carbon in freshly emitted diesel aerosols, the objective of this paper is to compare the results among these methods and to investigate the role of OC when measuring the mass concentration of elemental carbon (or black carbon) in aerosols emitted by a medium-duty Diesel engine. Results indicate that the aethalometer response correlates well with the data from filter samples (R2 = 0.99), with a very slight positive interference at high levels of OC.

Jan 1, 2008

By W. J. Kogelmann

Roadheaders, also called Boom Miners or Boom-type Tunneling Machines have been in North America since 1968, when first introduced by Willy Kogelmann, the founder of Alpine Equipment Corp. (?Alpine?). Roadheaders were invented in Europe in the late 1940s. Machines with in-line, axial cutter heads were developed in the former Soviet Union. The British Dosco DRCL is based on the Russian PK-3 roadheader. Roadheaders with transverse ?ripper? cutter heads were invented in Hungary (1). The Austrian-made Alpine Miners of VOEST-Alpine, purchased by Sandvik AB, are based on a 1965 Hungarian license. Roadheaders are widely used in the mining and tunneling industries because they can excavate drifts, entries and tunnels with cross sections of any shape and size, can handle mixed faces, work on steep grades, and negotiate tight curves and cross-cuts. A roadheader?s only major limitation is the strength and abrasiveness of rock and minerals to be excavated. This paper covers roadheader selection criteria, improvements in reliability, attachments for flexibility (Multi-Tool Miner), and automated support systems for increased cutting time for increased shift production.

Jan 1, 2008

By C. G. Anderson, L. G. Twidwell

"Throughout the world, there are many orebodies or materials which have significant value but also contain arsenic, antimony, and mercury. As regulations on the transport, exposure, disposition and emission of these elements have become more stringent; it has become increasingly more difficult to derive the values from the resources. This paper outlines the fundamentals of alkaline sulfide hydrometallurgy and its successful application to arsenic, antimony and mercury bearing ores, concentrates, by-products, and other materials.Fundamental Alkaline Sulfide HydrometallurgyHydrometallurgical methods can be employed for treatment of gold, arsenic, antimony, tin and mercury containing materials, concentrates and ores as well as complex ones containing any number of metals. The alkaline sulfide system is one of these and is essentially a mixture of sodium sulfide and sodium hydroxide. This is a unique hydrometallurgical system as it is a very selective lixiviant for the distinct leaching of tin, gold, antimony, arsenic and mercury [1-7]. Worldwide, it is employed industrially in the CIS, China and the United States for the production of antimony [8-15].As an example, when the system is applied to an arsenic containing material like orpiment, As2S3, a solution of sodium thioarsenite is formed. This is illustrated as:"

Jan 1, 2008

By Ernest Bohnet

Each mining operation is unique in some aspect ownership; ore body location, size, geometry, grade, mineralogy, hydrology, or geotechnical parameters; or constraints such as environmental regulations. However, all mining operations are alike in one aspect; the prime objective of any mining project is to maximize the return on the investment. This is the golden rule, or in the language of mining, the investor?s law of conservation. A mineral resource, by definition, does not become a minable reserve unless the mineral or minerals can be extracted economically (and legally). The three preceding sections have covered the various types of surface mining options. The choice of the most economic method is dictated primarily by the type of de-posit to be mined, the mining rate, and the physical characteristics of the deposit.

Jan 1, 2008

By F. Habashi

Lead is an ancient metal, has been produced to-date from its ores exclusively by pyrometallurgical route. The process suffers from high operating cost and excessive pollution problems. Extensive research has been going on since the beginning of the twentieth century to find a non-polluting process for its production and a solution for its complex refining scheme. It has been assumed correctly that the hydrometallurgical route should be the most promising. Pilot plants have been constructed and operated for a reasonable periods, but no process has proved to be satisfactory. As a result, a number of smelters and refineries have been shut down. The present review analyses the situation and suggests that the best route to treat lead sulfide concentrates is by leaching with fluoroboric acid, HBF4, containing ferric fluoroborate, Fe(BF4)3, and electrolyzing the solution in a diaphragm cell - - a process recently invented by Italian metallurgists. In this process, any silver present in the concentrate remains in the residue together with elemental sulfur and can be recovered by known methods.

Jan 1, 2008

By Andrew Baxter

The Crystal Bridges Museum of American Art in Bentonville, Arkansas is a beautiful glass and concrete structure cut into a valley that mingles with water ponds spanned by multiple bridges with suspended roofs. Or, at least it will be when completed in 2009. At Crystal Bridges, most of the proposed buildings involve cuts up to 50 ft high to be retained by the building structures. This requires the construction of retaining walls adequately founded to support lateral loads of up to 70 kip/ft. To add to this difficulty, the site is within a karst region with all the variability and irregularities associated with solutioning and erosion of the parent rock in this environment. The irregular rock profile made it virtually impossible to conceive a predictable arrangement of shallow footings and shear keys for the retaining walls. The existence of layers of soft soils within a hard rock formation made a caisson foundation impractical. The authors developed an innovative solution based on micropiles, which proved to be invaluable from a cost and schedule point of view. In areas where rock was shallow, micropiles were used as ?shear pins? to transfer the horizontal loads to the rock. In areas with significant overburden, a system of vertical and battered micropiles was devised to carry vertical and horizontal loads from the retaining walls. This paper presents a detailed description of the design and installation of the micropiles used as shear pins, and includes the results of lateral load tests performed on full-scale models of the grade beams on shear pins. The work performed shows that micropiles in rock can be effectively utilized for support of significant lateral loads provided that an adequate arrangement of suitably sized micropiles is provided, and that micropiles used as shear pins may develop significant tensile stresses when loaded laterally.

Jan 1, 2008

By Lianyang Zhang

For optimal design of rock socketed shafts used to support axial loading, it is important to predict the end bearing capacity. The existing empirical methods for determining the end bearing capacity of rock socketed shafts use the empirical relations between the end bearing capacity, qmax, and the unconfined compressive strength of intact rock, sc. Since rock socketed shafts are supported by the rock mass (both intact rock blocks and discontinuities separating them) not just the intact rock, one should consider not only the intact rock properties but also the influence of discontinuities when determining the end bearing capacity. Although the effect of discontinuities may have been implicitly (partially) included in the empirical relations derived from the results of load tests, it is not clear how big the effect is and how much of it has been included. In this paper, a database consisting of 50 test shafts, 25 of which contain the RQD (rock quality designation) value, is developed. Using the database, the applicability of the existing empirical relations is evaluated and two new empirical relations between the end bearing capacity, qmax, and the unconfined compressive strength of rock mass, scm, are derived. The new empirical relations explicitly consider the effect of discontinuities by using scm which is directly related to RQD. Finally, an example is presented to demonstrate the application of the newly derived relations.

Jan 1, 2008

By John Starkey

"During the period June 2007 to March 2007, John Starkey of Starkey & Associates (Starkey) worked in Russia for High River Gold, supervising the engineering design work that was being done at the IRGIREDMET Research Institute, in Irkutsk Russia. The work entailed moving the Newmont No. 4 mill from Elko, Nevada to Berezitovy, a mine site north and west of the city of Skovorodino, in the Amur Region of Siberia. This was a grass roots project and required construction of all phases of the infrastructure and process facilities that are associated with a 5000 t/d open pit mine and CIP mill.During the course of this engineering design exercise, many aspects of doing business in Russia were encountered, with regard to laws, norms, and business practices. This paper discusses many of these findings. Also by living in Irkutsk, many observations on Russian life and social customs were made and these merit discussion from a general interest point of view.Prior to going to Russia, another engineering and ore testing firm (TOMS) had approached Starkey to find out if Starkey could assist them in upgrading their SAG ore testing procedures to Western standards in order to offer their clients turnkey projects, that included reliable SAG and AG grinding. TOMS was aware that Starkey had invented the SPI test but did not know that the SAGDesign test had by then been fully developed and was being offered commercially as the most accurate way in the world to design new grinding mills. They were also unaware that this new testing method had been patented by Outokumpu (now Outotec) and that this method allowed them access to a design method, through Starkey, that would lead to a manufacturer’s guarantee (by Outotec) of throughput and grind for any new semi-autogenous or autogenous grinding circuit, with or without ball mills.When Starkey started working at IRGIREDMET in June 2005, they also made a request to add a design method for SAG mills that would be considered acceptable to Western clients. From these requests, presentations were made in Russian to both institutes and each decided to join the SAGDesign Consulting Group as satellite members and buy a SAGDesign test mill to use with their Bond Ball Mill Work Index mills, to provide SAGDesign testing services. To complete the service, contracts have been put in place for Starkey to use these results to design new grinding equipment and to train engineers at TOMS and IRGIREDMET how to do this work.Starkey also undertook to train engineers at both labs to go into the field and to take the samples for SAGDesign testing programs. It is here where the SAGDesign testing service upgrades other grinding test programs because the samples to be used for design are professionally chosen, and the results will be much more likely to produce a satisfactory design. Starkey is a mining engineer and is uniquely qualified to do this task. This and the SAGDesign test are the key components that lead Outotec to offer a performance guarantee for mills designed by Starkey."

Jan 1, 2008

By G Giles

One of the main tools used by mining operations to mitigate the risk of rock burst is the installation of a so-called ædynamic resistantÆ support system. Such systems are designed to absorb the impact of shockwaves created by mine-induced seismic events. Dynamic support must be strong and capable of sustaining high loads and, at the same time, they have to be flexible and accommodate large deformation. A dynamic support system is therefore a system capable of absorbing a high quantity of energy. Ground support systems are composed of rock reinforcement (rock bolts or cable bolts) and surface support (mesh or shotcrete). In terms of surface support, fibre-reinforced shotcrete is increasingly seen as the industry preferred solution when difficult ground conditions are experienced, including areas of high seismic hazard. A thick layer of shotcrete is certainly strong but it is by no means flexible. Normal weld-mesh has some flexibility, but it is not very strong. The Australian Centre for Geomechanics (ACG), in collaboration with Onesteel Reinforcing Pty Ltd, is currently working on a new high-energy absorption mesh that combines strength and flexibility. The new mesh can be installed with a jumbo, in a similar way as the widely used sheet of weld-mesh. This paper describes the development of this new mesh system.

Jan 1, 2008

By Alice Arana, David M. Cacoilo, Joel L. Volterra

"To make space for the new South Ferry Station in lower Manhattan, engineers and contractors carved out a new tunnel beneath three operating subway tunnels and tangentially to yet another tunnel. Creating the space required the design and construction of complex temporary excavation support and underpinning systems and the design and installation of real-time monitoring systems. Construction for the new station and tunnel was mainly cut-and cover in a mixed-face area of soil and rock approximately 2,000 linear ft long, 60 ft wide and up to 70 ft deep. Close coordination between the design/build team and the project owner, the Metropolitan Transportation Authority (MTA), was critical.With the construction of this $400 million project, the MTA and New York City Transit (NYCT) are correcting the numerous physical and operational deficiencies of the existing station and improving the lives of millions of commuters. Built in 1905, the original South Ferry Station is on the IRT Broadway–Seventh Avenue Line of the New York City Subway and is the southern terminal of the #1 subway service, which forms a loop to return uptown. The station has a sharply curved single platform on the outside of the outer track of a two track loop. This platform is short and does not allow the rear five cars of a normal 10-car subway train to load or unload. In addition, once the train stops at the station, commuters wait while retractable floor grates bridge the gap created between the platform and the subway car doors, and then they have only one exit from the station. Spray nozzles keep the tracks lubricated to reduce the train wheels’ friction caused by the tight curve. The sharp curvature of the loop and the inability to use half of the subway car doors slow train operation. With the new ADA-accessible station, 10-car trains will be able to open all doors, and additional entrances, escalators and elevators will greatly reduce travel times."

Jan 1, 2008

By Brian Garrod

Increasing use of pressurized-face tunnel boring machines in North America has produced a similar increase in the application of precast concrete tunnel linings. Where a pressurized TBM is needed, immediate ground support and ground water pressure resistance is also required. A segmental lining installed within the TBM tail shield provides the only available means of providing such a sealed lining. This paper addresses new developments in North America in lining applications and design. For the purposes of this paper, a precast concrete tunnel lining is defined as a tunnel lining constructed using precast concrete segments that are assembled into a lining ring. The lining rings are connected adjacent to each other to form a tunnel lining. Each segment has a sealing gasket around it so that when the lining is completed, it provides a fully waterproof lining system. The ring is erected within the tail shield of the TBM and the annular gap around the ring is filled with grout as the machine moves forward. The ring is not expanded and normally provides the finished lining of the tunnel with no requirement for a second pass lining. The TBM has a series of hydraulic rams that push on the leading edge of the segmental lining to provide the sole system of forward propulsion for the machine. The rings are tapered, being longer on one side than the other. This allows the rings to be installed either on a curve or in a straight line depending on the rotational position of the rings.

Jan 1, 2008

By Donald W. Gentry

This section deals with one of the most fascinating aspects of mining the evaluation of mine investment opportunities. Be-fore proceeding further, it is important to clarify the meaning of some fundamental terms used frequently in the text. 6.0.1.1 Mine Valuation vs. Evaluation The words "valuation" and "evaluation" in a mining context are often used interchangeably. However, for the purposes of this section, a distinction is made between the two terms in accordance with commonly accepted practice. The word valuation in a mining project context has the rather narrow meaning of placing a dollar or other currency value on the worth of the project as a whole. In other words, the value of a mining project refers to a measure of the desirability of ownership of that property. As such, the major item of interest is, "what is the mine worth?," or `what is the value of the mine?" The value of a mining project may actually be determined in the marketplace at any specific point in time, or it may be estimated by one of several methods. The topic of mine valuation is discussed in more detail in Chapter 6.1. The word evaluation in a mining project context connotes the broader meaning of determining the numerical values of all

Jan 1, 2008

By Thomas Barczak

Roof support systems are designed for roof control to prevent unplanned falls. It sounds logical and has been the conventional thinking in support design since supports were first installed. In order to determine which support system should be used or which would be the most effective, the degree of control provided by the support system must be known. This question embodies the concept of a ground response curve, which is a measure of support control by assessment of the convergence in the mine entry as a function of the support capacity. In this National Institute for Occupational Safety and Health (NIOSH) study to optimize standing roof support design, ground response curves were developed for longwall tailgate conditions from numerical models of Pittsburgh Coal Seam geology. The models were calibrated against tailgate convergence measurements that were made in two Pittsburgh Coal Seam mines as the depth of cover varied during the panel extraction. Ground response curves were developed for four loading conditions: (1) development, (2) side abutment, (3) front abutment near the longwall face, and (4) full extraction inby the face. In general, the tailgate convergence and required support capacity increase through each of these loading stages. It was concluded that prior to failure of the rock mass, the support system regardless of its capacity has relatively little impact on tailgate convergence. Recognizing that the support cannot prevent much of the (pre-failure) convergence that is occurring is an important part of support design. Supports that exhibit high loading stiffness but cannot sustain that loading through a displacement compatible with the ground response curve will not provide adequate roof control because they can fail prematurely. The required capacity depends on the loading plus yielding characteristics of the support and the amount of rock failure that has occurred. The loading plus yielding character establishes where the support loading intersects the ground response curve. Design criterion for support capacity based on the identifying the onset of strain-soften rock response leading to ?damaged roof? is proposed as a foundation for assessing support design requirements. The capacity without accounting for the loading and yielding character of one support should not be used to assess the capacity requirement of an alternative support design, particularly when the loading and yielding characteristics are significantly different. A sensitivity study was made to evaluate the impact of mining height and overburden depth. As expected, the results show that convergence increases with increase in mining height and increase in overburden depth. Some specific support examples are also analyzed. Although this is a first step and the two-dimensional numerical models have limitations, these initial studies provide valuable insight into the control provided by the roof support system and will ultimately lead to optimizing support design based on specific mine site conditions.

Jan 1, 2008

By James Rowland, Richard Mainiero

When most people think of explosives transport they think of a hazardous operation. We all know that we aren’t allowed to transport explosives through tunnels and are discouraged from traveling through heavily populated areas. Popular opinion suggests that explosives transport is a very risky operation. The authors decided to look into this a little more thoroughly and found just the opposite to be true.

Jan 1, 2008

By Richard Jack De Klerk

The standard industrial method of arsenic removal from acidic aqueous processing effluents involves coprecipitation of arsenic with ferric iron (Fe/As>3) by lime neutralization in continuous circuits. To better understand current industrial practice, continuous circuit coprecipitation experiments were performed to identify industrially relevant process parameters and co-ion solutes that contribute to improved arsenic removal and retention. The coprecipitated solids were subjected to accelerated ageing at 20°, 40° & 70°C and arsenic behavior was monitored and modeled. Staging and the presence of calcium ions were found to have the most significant impact on arsenic retention. In this paper the techniques used and major results obtained are discussed.

Jan 1, 2008

By Craig H. Olson

"A new ship dock at a Philadelphia area refinery will be capable of docking the largest tanker to travel the Delaware River, the Stena V-MAX, which will induce significant lateral loads. The loads at the dock, a system of mooring dolphins and platforms, will be resisted by over 150 pipe piles, including some 20- and 30-in diameter, reinforced, concrete-filled pipe piles and H-piles. Construction included driving the pipe piles to the required ultimate capacity, flushing the pipe pile casing clean of overburden materials, followed by drilling rock sockets into the underlying Wissahickon Formation. The Wissahickon Formation is a complex subsurface that includes variations in depth to bedrock, rock quality, degree of weathering and the presence of very hard quartzite lenses or inclusions. Because of the problematic subsurface, the designers and client requested extensive pile dynamic analysis (PDA) testing by TRC Engineers (TRC).Before beginning, the contractor requested that TRC perform the WEAP (wave equation analysis program) to evaluate the proposed hammer (APE D30-32 open-end diesel) to drive the piles into the proposed bearing strata while maintaining allowable compression stress levels. The WEAP provided a prediction of blow counts and stresses for various ultimate capacities, and showed that for the HP14x89 piles with a required ultimate capacity of 480 kips, a blow count of at least four blows per in at a stroke of 8.0 ft was necessary.New Approachway RampThe PDA testing began at the new dock approachway ramp, parallel to the existing one. The new structure is a 300-ft-long by 21- ft-wide concrete deck supported on seven bents; each has two 24- ft-diameter steel open-ended pipe piles. Every pipe received an HP 14 x 89 x 80-ft pile that was later driven beyond the pipe pile tip to create a composite pile. The pipe piles were later cleaned of overburden materials and finally filled with concrete and rebar. At each bent, a cap was installed on top of each pair of pipe piles, and then a prefabricated concrete deck was added."

Jan 1, 2008