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By Gerald T. Homce

Accidental contact of overhead electrical power lines by mobile equipment is a leading cause of occupational fatalities in the United States, accounting for 20% of on-the-job electrocutions. Overhead electrical power line proximity warning devices (PWDs) are intended to warn personnel if mobile equipment moves within some preselected minimum distance of an energized overhead electrical power line. Two commercially available PWDs were tested at the National Institute for Occupational Safety and Health?s (NIOSH) Pittsburgh Research Laboratory (PRL). The objective of the tests was to document performance capabilities and limitations for these PWDs by identifying factors that can influence their operation. The two PWDs evaluated in this research are the SIGALARM Model 210 marketed by Allied Safety Systems, LLC, and the ASE Model 2100 from Allied Safety Engineering. Both of these devices operate by measuring the electric field present around energized power lines. The PWDs were installed on a government-owned 22-st (20-mt) rough terrain crane. A purpose-built test site used for this research at PRL allowed operation of the crane near a variety of power line configurations operating at up to 25 kV. Most of the tests involved positioning the crane adjacent to one or more overhead power lines, adjusting sensitivities of the PWDs to alarm when the crane boom was approximately 20 ft (6.1 m) from the power lines, swinging the crane boom toward the lines under a wide variety of test conditions, and finally, for each unique set of test conditions, documenting the deviation from 20 ft (6.1 m) for actual alarm activation. Test results show that several factors can adversely affect PWD performance. PWD alarm accuracy generally deteriorated when operating with a boom position significantly different than that used for the device?s last sensitivity adjustment. Another factor that can affect PWD performance is configuration of the overhead power line(s) involved. Accuracy of alarm activa­tion distances was best for simple single-circuit installations, but degraded for multiple circuits on the same poles. This degradation was slightly greater for installations with different voltage levels and/or a combination of vertical and horizontal conductor arrangements. Performance also degraded for crane operation between two intersecting power line installations, especially for intersecting lines at different voltages. An additional aspect of power line configuration shown to influence PWD accuracy was phase sequence on the power line circuit(s). Specific phase con­ductor arrangements and combinations, particularly in multiple circuit installations, resulted in either improved or degraded accuracy.

Jan 1, 2008

By H. Wallin, I. G. Wallace, J. Akhavan, E. Nilsson

Over the past three years the UK together with Sweden, Norway, Finland, Italy have been taking part in a EU funded Leonardo da Vinci programme. More recently EFEE have participated in the project known as the EU15/10/200715/10/2007Excert project which is aimed at addressing the perceived loss of explosives expertise in several EU nations. This could have implications for explosives safety and industrial competitiveness. The paper outlines the work that has so far been done in phase 1 and describes the work planned for the second phase of the project. The paper will describe work in the UK to develop competencies for all explosives workers in both the civil and defence sectors. These competencies in the form of National Occupational Standards have now been approved in the UK and are accompanied by a range of 24 new National Vocational Qualifications launched in May 2006. The paper will show how the standards define knowledge and skills and how these form the basis for vocational qualifications as well as higher education awards and professional qualifications. This UK initiative is now being considered in other EU countries and the project has now been extended to also include Germany, France, Portugal, Czech Republic, Lithuania and Estonia. To support the occupational standards and qualifications work is also being carried out to improve learning provision in the explosives area. In addition to formal educational and conventional training courses a series of workplace learning initiatives are being pursued as well as internet learning packages. Examples of these initiatives will be given.

Jan 1, 2008

By Michael Wieland

Work-principle computations for explosions underwater or in rock reveal the way the thermodynamic characteristics of surrounding material influence the resulting shock and heave. To reach total thermodynamic equilibrium under such transitory dynamic circumstances, reactions must quickly readjust to changing circumstances, which works for molecular (military) explosives where the fuel and oxidizer type atoms are originally in close proximity. For non-molecular mixtures with their dispersed zones of oxidizer or fuel, in particle or droplet form, there are numerous unproductive collisions, increasing the wait time required to reach chemical equilibrium. Underwater test data for molecular explosives compare rather well with the shock and heave resolved from the work-principal model, while the non-molecular explosives normally used in mining tend to yield a noticeable discrepancy. Years ago, it was recognized that the underwater shock was lower than expected and the heave was higher than expected for ammonium nitrate fuel oil (ANFO), though their resultant sum for the total work was roughly what was expected. When the readjustment of thermodynamic equilibrium warrants quicker chemistry than occurs in underwater or rock shooting, the time-retarded chemistry reduces the shock and raises the heave within the surrounding material without reducing the total work, unless the reaction retardation is quite severe. This technical complication in reality is a nonequilibrium issue that is difficult to resolve with just thermodynamics, though a rational set of transformation factors is formulated herein to represent those circumstances.

Jan 1, 2008

By Kaushik Dey

Bord and pillar is the most predominant method of wining of coal in Indian underground coal mines. Development heading in coal mines often encounters roof stability problem and results in roof overbreak. Research on this reveals that the blast-induced ground vibration may have significant contribution in roof overbreak, especially, when solid blasting is carried out in the bord and pillar method. Solid blasting, in general, is associated with higher charge confinement due to lack of free face and generates higher ground vibration, which in turn results in excess overbreak.

Jan 1, 2008

By A. Ravi Kumar

A trench is a structure to accommodate fluid carrying pipelines for water, gas, petroleum products etc. Trench serves the purpose to haul the fluids in bulk over long distances safely and economically. Use of pipeline for moving oil and gas was essentially a post World War II development, but now it has acquired its own importance.

Jan 1, 2008

By Harsh Kumar Verma

Blasting off-the-solid is the most commonly used method during development of galleries in Bord and Pillar method of underground coal mining. In this method, only P5 explosives are used with permitted delay detonators in accordance with the safety requirements stipulated by the regulatory bodies. Delay detonators made with pyrotechnic delay compositions have inherent scattering in their delay timings. It is desirable to use precise detonators to achieve better fragmentation, less vibration and noise. Overlapping of delay period is undesirable from production as well as safety point of view.

Jan 1, 2008

By Larry Mirabelli, David Lilly

In 1777, the French naturalist, Georges Louis Leclerc, Compte de Buffon developed a statistical technique to estimate the width between two parallel lines by randomly throwing a needle at the two lines and counting the number of times the needle intersected one of the two lines. By knowing the length of the needle, the distance between the parallel lines could be estimated. This analysis was named the “Buffon’s Needle Problem”.

Jan 1, 2008

By Tapan Goswami, Lloyd Hain, Geoff Brent

For many years Ramp 24 at Ensham mine in Queensland, Australia has suffered substantial coal loss and damage due to the fragile nature of the coal and problematic geological conditions, which have proved very challenging. In the past various blasting techniques were applied in attempts to improve coal recovery. One approach was to use a shallow throw (cast) blast followed by a separate post-strip blast underneath. Another method was the introduction of the practice known as “baby decking” with the addition of a large buffer of material in front of the coal. However, despite increasing mining costs, none of these techniques adequately reduced coal edge loss and damage.

Jan 1, 2008

By M. J. Soria-Aguilar, F. R. Carrillo-Pedroza, S. Preciado-Nuñez

"Dust originated from the Iron Blast Furnace (BF) and the Basic Oxygen Furnace (BOF) containing alkalis and zinc are not completely recycled because due affects the process efficiency. These types of dust represents an economical lost as a consequence of values contents of iron and carbon. Several processes in aqueous media have been developed to treat the steelmaking dust. This work presents a laboratory study for reduce zinc and alkali containing in BF and BOF dust, using different acid and alkaline solutions and oxidants as ozone. The results obtained show that the elimination of zinc and alkalis can vary from 5 % to 80 % depending on the treatment conditions (the solution, the oxidant and the temperature). The dust obtained from this treatment can to be recycling to the steelmaking processes to recovery iron and carbon values.IntroductionEach one of the steel making industry processes generate several sub-products and residues containing useful units of iron, carbon and other elements that are or could be recycled to the productive process. Some of those sub products are the dust from the gas cleaning system of the blast furnace and the dust from BOF reductive process; such dusts are sent to the sedimentary lagoons. The dust represent a lost of 2 % of the total iron and coal mineral’s content feed to the process.The typical iron, carbon and zinc content of the blast furnace dust is approximately 40, 24 and 0.3 % and the content of the BOF dust are 50, 15 and 0.9 % weight respectively, with physics - chemical characteristics that became them susceptible to be agglomerated and feed to the blast furnace. But the high content of zinc does not allow recycling it into the process. At the blast furnace the presence of zinc propitiate the formation of film in the furnace wall; these elements are vaporized in the low section of the cube of the furnace and they are dragged by the gases to the top and condensed again at the cube. Part of these condensed materials strongly adheres to the furnace cover harming it and reducing the empty space of that section, causing eventually a severe perturbation of the ascendant gas flux [1]."

Jan 1, 2008

By Carla Lupi, Alessandro Pescetelli

"Spent lead battery recycling still shows few weak points in the achievement of a 100% recycling of different waste matters and by- products arising from the recycling process. Some of said problems are dealing with aqueous streams outgoing the recycling plant, and more particularly, a) the waste waters discarded from the breaking and separation unit, b) purification of the spent electrolyte drained from waste batteries and upgrade to a quality compatible with full re-use by the batteries’ manufacturers, c) purification of the mother liquors discarded in the sodium sulfate crystallization process so to produce a salt of commercial grade. All of the above listed problems have been satisfactorily overcome applying an electrochemical process that, through different process conditions and parameters, is able to remove the harmful impurities that hinder the successful commercialization of such by products, or, at least, that can avoid heavy and expensive treatment plant and operation.IntroductionAlmost 100% of commercial lead and lead alloys produced by secondary lead plants is recycled to the new lead accumulators manufacture. The other by-products and residues produced through the lead recycling process may be classified into two groups:a) matters reusable in the new accumulators production processb) matters produced as a result of various reagents and additives used in the recycling process, to be sold to different market sectorsQuality and saleability of by-products are significant points for the economics of the secondary lead plant operation, because, if said by-products are not saleable, they are just wastes, so offsetting potential revenues, and, at the same time, adding a heavy burden to operating cost, like disposal cost [1]. When looking at a typical, modern lead scrap batteries recovery cycle, it is quite evident that we are still rather far from dealing with a waste-less technology (fig.1).The group a) includes 3 by-products produced through the breaking process: among those matters the polypropylene only usually reaches a standard quality suitable for sale to lead manufacturing sector or to other sectors as well. The other two by-products, electrolyte and separators, do not still reach, through a viable and effective regeneration process, a quality standard sufficient for their re-use in the lead batteries sector ."

Jan 1, 2008

By Andrew J. Ciancia

The construction of the Pennsylvania Station in Manhattan, the Beaux-Arts masterpiece, was completed in 1910. In financial ruin, the Pennsylvania Railroad Company sold the station in the 1960?s and the new Madison Square Garden and the Penn Plaza complex were constructed at the site. The demolition of Pennsylvania Station brought public awareness and outcry to protect historic structures and the Landmarks Preservation Commission (LPC) was subsequently established in 1965. In the 1960?s relatively little engineering data was available on the performance of historic structures during adjacent construction and thus, no published criteria were established by the LPC on allowable movements and vibrations. During the late 1970?s a commercial tower was planned adjacent to the landmark Fraunces Tavern Block (FTB) in lower Manhattan. Through negotiations between the LPC and the developer, Dr. M. I. Esrig and the author were retained to monitor the historic block during foundation construction. The monitoring data and building performance compiled from the project formed the basis of the published 1981 ASCE technical paper by Esrig and Ciancia entitled ?The Avoidance of Damage to Historic Structures Resulting from Adjacent Construction?. Based on the ASCE paper, the NYC Department of Buildings adopted Technical Policy and Procedure Notice #10/88 entitled ?Procedures for the Avoidance of Damage to Historic Structures Resulting from Adjacent Construction When Subject to Controlled Inspection by Section 27-724 and for Any Existing Structure Designated by the Commissioner?, June 1988. This paper describes the author?s recent experience during the installation of deep foundations within, or adjacent to, three Manhattan landmark structures. Discussions are provided on the foundation construction, monitoring programs and performances of the three structures.

Jan 1, 2008

By Cissé Kane, Klaus Hieronymi, Mathias Schluep, Gerry Newson, Susanne Dittke

"E-waste is currently the fastest growing waste stream in South Africa as well as in many other African countries. Informal collectors, dismantlers and recyclers based in Africa play an increasingly larger role in the processing of e-waste under generally unacceptable social and environmental conditions. In direct response to this trend, and as part of Hewlett Packard’s international Extended Producer Responsibility, the project “e-Waste Management in Africa” was started in 2007 in cooperation with the Global Digital Solidarity Fund (DSF) and the Swiss Federal Laboratories for Materials Testing and Research (Empa). This project is investigating the e-Waste situation in various African Countries, including South Africa, while actively supporting the development of practical, socially just and environmentally acceptable local e-waste management solutions. To this end, the project has been funding the development of a pilot project in Cape Town, South Africa since February 2008, supporting the start-up of a low tech/highly labour intensive material dismantling and recovery facility (MRF) for the pre-processing of e-waste. The aim is to test the feasibility of an integrated value adding local e-Waste management system, designed to maximize the potential of refurbishment, repair, re-use, dismantling and recycling of equipment, with environmentally responsible disposal as a last resort only. The project also seeks to incorporate the current informal e-waste processing activities, by transforming them into sustainable and environmentally sound operations. The MRF acts as a nucleus, raising awareness, and providing training and education to previously disadvantaged individuals as a means of creating opportunities for entrepreneurship in the technical maintenance, dismantling and waste-to-art project sectors."

Jan 1, 2008

By G. Gomathi, K. Asokan, K. Subramanian

An electrochemical reactor with anode and cathode chambers separated by a composite perfluoro polymer cation exchange membrane was designed, fabricated and used for the reduction of dissolved carbon dioxide under ambient conditions to formate. The flow reactor enhanced the mass transfer of carbon dioxide compared to the batch reactor. Experiments were conducted using two different perfluoro polymer membranes - Nafion 961. Efficacy of CO2 reduction on various cathode materials (Cd, Pb, Sn and Zn plated stainless steel woven mesh) were determined. Optimum values of flow rate and current density were evaluated for the energy efficient formation of formate in aqueous KHCO3 (pH 7.5-8.5) buffer solutions.

Jan 1, 2008

By Hemraj Dangi, S. Murali, Bhisham Yadav, Mohini Saxena, P. Asokan

"Demonstration studies were carried on the use of fly ash as soil modifier and supplier of micronutrients to improve the agricultural productivity based on the process optimised at lab scale at Advanced Materials & Processes Research Institute, Bhopal. The field trials were conducted in Uttar Pradesh (North India) Orissa (South Eastern India) and Madhya Pradesh (Central India) under different soil and crop conditions. 100-650 tonnes of fly ash per hectare were applied depending upon the soil and fly ash characteristics. Both short and long term studies on impact of fly ash on soil and food quality were conducted. With the fly ash application, the edible yield of tomato, cabbage, potato, wheat, pea, onion, paddy, sunflower, maize etc., were increased from 12 - 46% as compared to the control soil where no fly ash was used. The crop response to various elements mainly heavy metals grown in soil and fly ash applied soil was found comparable to that of control, which are within the permissible limits and meet the food quality standards. The results of impact of fly ash on biotic and abiotic properties of soil, along with the quantity and quality of agricultural produces generated under pilot scale demonstrations in three different parts of India are discussed in this paper. The outcome of this work could act as guiding force for confidence building and to maximise the use of fly ash, generated from thermal power plants worldwide as one of the major mineral waste for agriculture purposes.IntroductionThe advantages of application of fly ash in terms of improvement of soil properties and crop yields have been published by various researchers in India and abroad. Attention is also given about the possible negative and beneficial impact of pond ash in agriculture due to presence of heavy elements, radioactive nuclides and plant nutrients in fly ash. It is evident from the analysis of Indian fly ash that the presence of heavy elements and radionuclides levels are comparable with normal soil. The positive impact that has been reported is with regard to germination, yield and crop growth. The significant impacts are: long term effect of heavy and toxic elements content of fly ash on soil and up take of these elements by plant. Pilot scale demonstration studies have been completed with varying soil crop-combination under different agro-climatic conditions showed considerable improvement in the productivity of cereals, oil seeds and vegetables."

Jan 1, 2008

By Samson Adeosun, Sanmbo Balogun, David Esezobor

"Iron and steel making processes give rise to large amounts of usable and unusable materials, the latter generally being termed wastes. It is sometimes difficult to distinguish between re-usable by-products and wastes which cannot be sold or land-filled. Much depends on circumstances such as the local market for the material. This can itself vary from time to time with by-products which cannot be used or sold becoming wastes and vice versa. This paper defines the concept of “waste-free technology”, discusses its development in the steel industry and highlights the benefits of the technology to the manufacturing sector and the environment. The paper also articulates how the “waste-free” technology could be applied in the proposed Ajaokuta integrated steel plant in Nigeria.IntroductionIn the past, nature was considered an inexhaustible store. Its resources were consequently exploited and waste products therefrom were discarded. Today, attitudes have not changed appreciably even as raw materials cost rise by the year to pose a series of socio-economic problems, which, among others, may include the rational and optimum utilization of resources, environmental protection and reduction of waste formation. Consequently, industrialists now face unexpected regulatory pressure in areas of pollution prevention, waste minimization and hazardous waste disposal.Iron and steel making processes give rise to significant amounts of usable and un-usable materials, the latter generally being termed waste. It is sometimes difficult to distinguish between re-usable by-products and wastes which cannot be sold or land-filled. Much depends on circumstances such as the local market for the material. This can itself vary from time to time with by-products which cannot be used or sold becoming wastes and vice versa. In this paper, the term waste refers to those materials that are either irrationally utilized or, land-filled and part of the byproducts that are not utilized. It includes that part of used materials which is not incorporated into the products manufactured during a process stage and which in contrast to reuseable materials, is considered not suitable for any further use, owing to technical or economic factors. In general, these materials are inorganic and parts of them are either utilized or passed to the other processes; the other part should be disposed of using well-established waste disposal practices to avoid any environmental threat.Thus, creative methods must be developed to modify the manufacturing processes to reduce emissions and process wastes by fully utilizing all resources. One method of eliminating the negative effect of waste formation is the use of purification and cleaning structures (pollution control system, PCS). These are, however, quite expensive."

Jan 1, 2008

By Yoshisada Michiura, Junko Umeda, Katsuyoshi Kondoh

Rice husks or straws, one of the main agricultural wastes in South-east Asia, have a large possibility to be employed as usefully renewable resources to produce energy and high-purity silica (SiO2), because they consist of about 70% organics such as cellulose or hemi-cellulose, and 20% amorphous SiO2. The former is utilized as bio-mass energy; for example, thermal or electric energy, and bio-mass ethanol. High-purity silica can be used as raw materials in the industrial uses. It would be possible to extract silica elements from rice husks and straws by burning them in air because their main contents are organics. In the previous studies, a strong acid leaching treatment on rice husks before burning was carried out by using H2SO4, HCl and HNO3 to prepare high-purity silica materials. This was available to accelerate the hydrolysis of celluloses and hemicelluloses contained in rice husks, and remove the above metallic impurities. A strong acid leaching treatment, however, is significantly hazardous to environment and human life, and causes an increase of the process cost. In this study, the environmentally benign, harmless to human and economically effective process to produce high-purity amorphous SiO2 materials from rice husks has been established without using strong acids. From a viewpoint of the harmless influence on human body, the carboxylic acids were used in the leaching treatment on rice husks. TG-DTA measurement and GCMS analysis indicated that the leaching was effective for the hydrolysis of celluloses and hemicelluloses contained in rice husks at 473K~873K, which produced the same results in using the conventional sulfuric acid. The metallic impurities could be also removed from the husks via a chelate reaction between carboxyl groups (-COOH) and the metal elements. In particular, it was clarified that cadmium (Cd) were completely removed from rice straws by this reaction. Concerning the burning conditions of rice husks after the acid leaching, it was necessary to supply a suitable amount of air to completely combust organics; for example it required air supplement of 50 ml/min. or more. The burning temperature should be less than 1273K to obtain amorphous structured silica. High-purity amorphous silica materials with 99% or more were prepared from rich husks by applying the citric acid leaching treatment and burning process at 1073K in air.

Jan 1, 2008

By J. Borlée, J. P. Birat

"ULCOS is a large European program launched by a consortium of 48 partners led by arcelor and a core group of steel producers, which was started in 2004 with the support of the European Commission (RFCS and 6FP programs) to search for breakthrough process routes that could, in the future, when fully developed, demonstrate the potential of large cuts in CO2 emissions for the production of steel from iron ore.The timescale for commercial implementation is the post-Kyoto period, i.e. 15 to 20 years from today.The present paper presents the progress made in the first 2 years of this 5 year program.Several concepts are being investigated in parallel: re-engineering of the blast furnace to incorporate CCS in the core of the process, smelting reduction with CCS capabilities, massive use of natural with more CO2-lean technologies than today, hydrogen steelmaking and electrolysis of iron ore. Biomass also offers very attractive perspectives, while raising major challenges.None of these new steelmaking routes are ""no regret"", which means that the European Steel Industry has already incorporated extensive energy saving steps in its present process technology and is working as close to thermodynamics limits as is cinematically and economically feasible, and that decreasing GHG emissions further means introducing breakthrough technologies that add significant costs to the operation of the Steel Mills.They will also require much research and development before they can be proven and implemented commercially.IntroductionThe ULCOS program (Ultra Low CO2 Steelmaking) is a large research program of the European Steel Industry and its industrial and research partners launched in September 2004 to investigate steelmaking technologies that have the potential of reducing the CO2 emission of the Industry by a large amount, typically in the order of 50%. It is supported in the European Community by the 6th Framework and the RFCS programs through 3 complementary European projects [1,2].The present paper summarizes the work carried out in the phase 1 of ULCOS and in framing the program of phase 2."

Jan 1, 2008

By Rick Deschamps

A reoccurring problem with support of excavations in urban areas involves the placement of external support components like anchors or nails in right-a-ways, subway and utility setbacks, in areas occupied by adjacent structures, and within the property of non cooperative neighbors. Such a situation occurred for a project in Arlington, Virginia, which ultimately resulted in the preliminary design of a large footing supported cantilever retaining wall that was extremely costly and impractical to build. An innovative design alternate consisting of a series of vertical concrete elements (VCEs) supported by post tensioned tiedowns was proposed to the General Contractor and accepted by the owner. The VCEs were designed to serve as the main structural elements for both the temporary support of excavation system and the permanent wall. The VCE?s were constructed using single bite diaphragm wall panels oriented perpendicular to the excavation face including a rebar cage and tremie concrete. Threaded inserts were placed within the rebar cage to attach the cast in place exterior wall. Overall stability and lateral movement of the VCEs were controlled by high capacity vertical anchors embedded within the VCE. A detailed instrumentation program was installed to monitor the movements of the VCEs with relation to the excavation depth. The paper present the project case history by discussing the design concepts of the VCE, the construction approaches used to install them, the construction challenges encountered, and the performance of the unique system.

Jan 1, 2008

By E. Benguerel, G. Monteith, L. Centomo, S. Pelletier

In early 2007, it became apparent that with changing concentrate feeds, the magnesium (Mg) load projected for CEZinc starting in 2009 and beyond would quadruple and overwhelm the current Mg process bleed capacity. A project was started, following design for six sigma (DFSS) standards, to select both the optimal process and to evaluate its target capacity for the Mg bleed circuit. The economic and process risks of under or over-designing while Mg reduction efforts were underway at the mines also needed to be evaluated. This paper describes the project methodology, the impact on the plant, and some potential optimizations for CEZinc's basic zinc sulphate (BZS) Mg bleed process.

Jan 1, 2008

By S. Shairp

Copper is an impurity as well as a necessary reagent in the processing of zinc sulfide concentrate at Hudson Bay Mining & Smelting Co., Limited's (HBMS) zinc pressure leach plant. Copper is present in the zinc concentrate as chalcopyrite, which consumes reagents necessary for zinc leaching. A small percentage of copper precipitates in the autoclaves, discharge lines, and flash tanks, requiring maintenance of the equipment and disposal of the solids. Copper also precipitates in the neutralization stages and is removed to low levels in a specific copper removal stage of purification. Yet some copper, as copper sulfate, is required, along with potassium antimony tartrate, in the final purification stage to improve cobalt removal from the zinc sulfate solution prior to electrowinning. The behaviour of copper experienced at HBMS's zinc pressure leach plant is discussed.

Jan 1, 2008