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By D. P. Fenton

The Phelps Dodge El Paso Rod Mill produces approximately 2.4 million pounds per day of copper rod from a casting and rolling operation. The newly formed rod is treated to remove mill scale and oxides using a sulfuric acid and hydrogen peroxide solution which is bled periodically when the copper concentration reaches 30-35 g/L. The bleed solution is heated to 75° C to destroy the residual peroxide. Copper is then recovered in a 270 cell EMEW electrowinning plant. Clean acid is also regenerated in the EMEW plant and is returned to the rod cleaning circuit. The EMEW plant commissioned in January 2006, has two operators and replaces a copper sulfate plant with fourteen operators. The EMEW plant has a capacity of 1700 kg/day of cathode copper at 2.1 kWh/kg copper deposited. The electrowinning plant operates in closed circuit with the rod mill returning up to 2600 kg/day of sulfuric acid resulting in zero discharge. Use of dimensionally stable anodes (DSA®) ensures that the acid quality is maintained in the closed loop operation. The operating conditions, performance and plant experience of the EMEW copper and acid recovery plant are discussed.

Jan 1, 2007

By A. Sinha, N. K. Babar, H. R. Kalihari, A. K. Chakraborty, M. R. Saharan, C. P. N. Pathak

A case study is presented on the optimization of cable bolting patterns in cut-and-fill stopes at the Chikla Mine, MOIL, India. Rock mass characterization, using Bieniawski’s RMR and Barton’s Q, indicated that the stopes lie in the “no supports required” to “spot bolting required” support categories. In contrast, the current practice of cable bolting in a 2.0 m by 2.0 m grid pattern for stope widths less than 12 m displays different results. Numerical modelling results are in line with the rock mass characterization study. It can be affirmed, as well, that no cable is carrying rock loads greater than 5 t. This fact is derived from observational behaviour of the crown pillar of an experimental stope with open stoping operations and hanging cables in the cut-and-fill stopes of the mine. An increase in the cable bolting grid spacing is, hence, recommended for implementation by mine management, based on the study described in subsequent sections. It is also suggested that the mine adopt the open stoping method, provided results of a rock mechanics instrumentation program in an experimental stope with a cable bolting grid of 2.5 m square are favourable.

Jan 1, 2007

By K. Buxmann

Climate change is a subject of growing concern. Based on the International Energy Agency, about 19% of man made greenhouse gas emissions globally are generated by the transport sector. This paper will focus on the environmental aspects of the light-weighting in transport and the resulting savings of fuel and electricity. Aluminium is an option for lightweight applications in transport, with very high benefits not only in the use stage, but also in the stage of vehicle recycling. Life cycle assessment is used to quantify the relative benefits of light-weighting specific components of cars, commercial road vehicles, buses, ships and trains. A vehicle consists of many components, which are produced by different processes and undergo different types of end-of-life operations. This document does not intend to compare a generic aluminium vehicle with a generic "heavy materials" vehicle. It rather tries to use a pragmatic approach based on specific examples of components where aluminium is used and can be used in the design of new vehicles, also taking into account future developments. The case studies in this paper are based on real cases where aluminium was used. For each component, sensitivity analyses are applied to see the impact of specific parameters such as the end-of-life recycling rate and the use stage driving distance. Significant greenhouse gas savings by the use of aluminium are demonstrated for cars and even higher ones for trucks, buses, trains and ships. In addition, the total potential benefits of light-weighting with aluminium are shown on the global level.

Jan 1, 2007

By D. Eastick, S. Hardcastle

"Over the last few years, a multi-faceted feasibility study has been evaluating the introduction of hydrogen fuel cell-powered equipment into underground mines to replaced diesel engine-powered equipment. The analysis has shown that under normal operating conditions fuel cells could at the very least be an environmental and health benefit by eliminating combustion engines and their unwanted by-products. However, they could also generate significant reductions in the amount of ventilation a mine needs to supply when compared to dieselized operations; this would further decrease a mine’s energy consumption, its associated greenhouse gas impact, and also reduce a mine’s significant ventilation-associated costs. Fuel cell-powered equipment also has the advantage of lower noise and heat production compared to its equivalent diesel-powered counterpart.The degree to which fuel cells can generate ventilation benefits in underground mines depends upon a number of operational parameters and mine specific qualifiers such as current ventilation control or management, mine depth, inherent dust conditions, and minimum velocity requirements.However, another major consideration in the introduction of fuel cells in underground mines will be the safety requirements associated with diluting and removing the potentially explosive hydrogen in the event of a gas leak. In outside surface applications, it is possible to use dispersion, buoyancy, time, and lack of ignition sources as mitigating factors in deriving a low risk of an explosion. However, in underground operations, these factors change, and dispersion and buoyancy are limited; time may not be available and, in non-coal mines, ignition sources are not typically controlled. When a hydrogen leak occurs, the availability of sufficient ventilation to dilute and effectively remove the gas will be critical. Consequently, ventilation may be the prime risk controlling factor. In this paper, the authors evaluate the potential benefits of replacing diesel engines with fuel cells in powered production equipment, discuss the mitigating qualifiers that could limit ventilation savings, and evaluate solutions to retain and maintain an additional ventilation capacity in the event of an emergency situation, such as a hydrogen leak from the fuel cell stack or its distribution system."

Jan 1, 2007

By C. Acuña

The case is presented that the key role of frother is control of bubble size in the pulp zone. Compared to water alone, the addition of frother produces a narrower distribution and finer bubble size. An empirical model is presented for bubble size as a function of frother type using a normalized concentration. The model provides a benchmark for assessing operations. There is no agreed upon mechanism of how frothers act to reduce bubble size. Prevention of coalescence is a common explanation and this action is illustrated. The case against the 'coalescence' model alone is presented and a breakup mechanism is introduced based on pilot cell and single bubble studies. Phenomena associated with bubble shape, velocity and surface flows are used to illustrate the force associated with surface tension gradients. Breakup mechanisms resulting from this force are proposed. The concept can be extended to high salt concentrations which also promote small bubbles.

Jan 1, 2007

By A. Luszczkiewicz

This paper presents the beneficial effects of non-oxidative leaching of final and intermediate copper sulfide concentrates with sulfuric acid prior to the final cleaning stage of flotation. This unique process, combining leaching and flotation, appears to be advantageous for difficult-to-treat carbonate-bearing Polish copper ores, such as those processed in copper concentrators at KGHM Polish Copper. It was shown that after the chemical decomposition of about 70 % of the total carbonates naturally present in the flotation feed, a considerable enhancement of subsequent flotation results (both grade and recovery). The resulting products of non-oxidative leaching are solid hydrated calcium sulfate (gypsum), soluble magnesium sulfate and gaseous carbon dioxide. The beneficial effect established by the laboratory leaching tests was subsequently confirmed during a pilot plant operation treating final copper concentrate and a problematic intermediate concentrate at the Lubin concentrator.

Jan 1, 2007

By A. J. Rigby

Computer generated, actual-scale furnace models have been imported into a rendering software application to provide for impressively realistic surface features and lighting. When these models are imported into a 3D engine framework, it is possible to create content-rich virtual environments allowing for complete interactivity and could provide for a powerful tool to conceptualize refractory lining designs. This technology has been applied to illustrate the optimized design concept of an anode-refining vessel, which can be expected to be completely relined in six days and to last for 4-5 years with minimal partial relining. This technology could easily be applied to other smelter furnace, converter and refining vessel designs.

Jan 1, 2007

By Charles W. Axten

Since the mid-1970s, samples of airborne and waterborne fibrous particulates have been collected in the area of the Northshore Taconite Ore Processing Facility by the Minnesota Department of Health (MDH), the Minnesota Pollution Control Agency (PCA), and the University of Minnesota. Indirect sample preparation has consistently been used although other aspects of the sampling methods and sites have varied and analytical procedures were altered over time as more accurate and precise microscopy methods were developed (i.e., phase contrast optical microscopy, transmission electron microscopy, transmission electron microscopy with energy dispersive spectroscopy). In the mid-1970s, levels of airborne fibrous particulate in the Silver Bay area averaged from 0.00030 to 0.03 f/ml. This level was significantly greater than levels of similar particulates in the St. Paul, MN area, although two of the Silver Bay sampling sites, considered individually, did not indicate levels of fibrous particulate markedly different than that seen in St. Paul. More recent sampling data (i.e., 1990?2001) indicate mean concentration of airborne fibrous particulates (amphibole-like fibrous particulates) of 0.0020 f/ml with a range of values from 0.0001 to 0.0140 f/ml. Such levels are not significantly different from those seen in other non-urban environments in the US and Europe. Concentrations of fibrous particulates in water samples were higher in the mid-1970 when iron ore tailings were being deposited in Lake Superior, but since the tailings have been deposited on land waterborne levels of fibrous particulate in the Beaver River have remained relatively constant averaging in the range of 7.5 MFL. This level is only slightly in excess of the current EPA drinking water standard for fibrous particulates. Review and consideration of this data is important in determining the potential health risks associated with airborne and waterborne fibrous particulates in the areas of the Northshore Taconite Ore Processing Facility. © 2007 Elsevier Inc. All rights reserved. Keywords: Taconite; Asbestos; Asbestiform fibers; Fibrous particulates; Cleavage fragments; Phase contrast optical microscopy; Transmission electron microscopy

Jan 1, 2007

The borehole televiewer is a downhole geophysical logging device that produces continuous, oriented, 360¦ images of the drill hole wall. Two types of borehole images are currently being generated at the BHP Billiton Mount Whaleback deposit. The optical televiewer (OTV) tool captures a ærealÆ image of the borehole wall whereas an acoustic televiewer (ATV) generates an image through variations in physical borehole size, scattering the energy from an acoustic beam. Orientation of the resulting ævirtual coreÆ is derived through magnetometers and accelerometers, providing values within one degree for both inclination and azimuth. Downhole structures such as fractures, joints, foliations and bedding planes are selected directly off the borehole image, recorded and displayed in a 3D modelling package along side adjacent drill holes. Measurements are corrected from apparent to true dip and magnetic to true north. Strata-bound magnetic anomalies are identified and corresponding measurements excluded. The importance of borehole imaging increases substantially with its ability to integrate the OTV and/or ATV data with other forms of lithological and structural data. At Mount Whaleback, the borehole televiewer has been implemented to provide information for geotechnical exploration including structural analysis, lithological characterisation and rock-mass conditions. Within the large area in and around Mount Whaleback, drilling may intersect a number of different geological formations with various rock types and conditions. With the application of the borehole televiewer, reverse circulation drilling can provide information traditionally obtained by diamond drilling.

Jan 1, 2007

By S. Gößling-Reisemann

Most copper ores contain valuable co-products such as molybdenum, gold, silver, nickel, etc. Sulphuric acid and steam are valuable by-products, which are generated dur¬ing copper production. The environmental impacts from mining and refining therefore need to be shared between these by-products and co-products, an issue in Life Cycle As¬sessment (LCA) referred to as allocation. There are different, recognised methodologies for doing so: burdens can be allocated based on the market values of these commodities, they can be allocated by mass, volume, molar amount, functionality, or other physical, technical or economic factors. All of these methodologies have their respective merits and restrictions, and the choice is usually case specific. Nevertheless, the choice between alternative methodologies can have dramatic effects on the LCA results. Recycling in LCA has to be handled in a similar way, as it essentially constitutes a special case of co¬production. The existing standards (ISO 14040 ff.) allow different methods for imple¬menting recycling and allocation into metal LCAs (open loop, closed loop, value cor-rected substitution, etc.), which are still a subject of discussion in the scientific community. However, the methodology used can significantly influence the ecological profile of copper and copper products. We will present an overview of the different methodologies available for including recycling and allocation and give an analysis of how the meth¬odological choice affects the final LCA results. This work will be followed up by quantitative case studies.

Jan 1, 2007

By B. Nanthakumar

The impact of stockpile oxidation on chalcopyrite was studied through collectorless and collector-induced flotation conditions. In both cases, the Cu grade-recovery performance of stockpiled ore showed relatively poor concentrate grades with respect to that of a fresh sample. However, the oxidation had a minor effect on chalcopyrite recovery itself. The poor concentrate grades resulted from dilution effect primarily by excessive flotation of pyrrhotite. Size-by-size analyses indicated that for the collectorless flotation, the recoveries in the coarse and fine particle-size regions, were higher for fresh ore than for stockpile sample. A greater impact was seen in the coarse size regions for both types of sample, compared to the collector-induced case. The Cu recoveries showed a remarkable increase in the coarse size range for both samples when a collector was used. However, the case for stockpile sample was a marginally higher compared to the fresh sample. This difference has been offset by an opposite trend that was observed between these two samples in the fine size region. It is concluded that in contrast to the case with nickel-bearing sulphides, stockpiling conditions do not show a significant adverse effect on behaviour of chalcopyrite due to its strong floatability, regardless of oxidation.

Jan 1, 2007

By C. M. Diaz, P. J. Mackey

Since its inception, in 1987, the Copper-Cobre series of conferences has established itself as the prime world forum for discussing advances in copper process metallurgy, in particular copper sulfide smelting, copper recovery by leaching and electrowinning and copper electrorefining. All copper producing countries have actively participated in the pyrometallurgy symposia held in the framework of these conferences. In 1999 and 2003, the close to 100 pyrometallurgy papers that were presented had to be accommodated in two volumes. In the present paper, the authors firstly provide a brief historical sketch of the Copper-Cobre conferences and then focus on providing a retrospective look at the dramatic changes that have taken place in copper smelting in the last few decades, primarily as discussed in the Copper-Cobre and precursor conferences pyrometallurgy proceedings. Topics include: the development of autogenous, increasingly more intensive, environmentally sound and energy efficient smelting processes; significant improvements in Peirce-Smith converting practice and at the same time the commercialization of alternative continuous converting routes; the consequent expansion and modernization of smelters; the increasing compliance with strict government environmental regulations in most copper producing regions of the world; the realignment of the copper smelting industry throughout the world; and trends in copper smelting R&D. A look at the future closes these reflections on the contribution of the Copper-Cobre conferences to the advancement of copper smelting technology.

Jan 1, 2007

By Monique Nykamp

"INTRODUCTIONTerminal 46 is located just south of downtown Seattle, and is one of the Port of Seattle’s busiest container terminals. The Terminal 46 Redevelopment Project was undertaken to replace the existing 15-m-wide (50 ft) cranes along the apron with 30-m-wide (100 ft) cranes, which can unload larger, post- Panamax ships. The project included upgrading the existing waterside crane rail with new piles and constructing a new land-side rail behind the sheetpile bulkhead. The new piles had to be installed adjacent to the existing apron without causing damage, which was a signifi cant geotechnical challenge due to the soft soil conditions at the site. An instrumentation program performed during the test pile program evaluated this challenge and allowed for the development of specifi c production pile installation procedures that had the least possible effect on construction costs and schedule. SITE HISTORYThe site lies along the west side of Elliott Bay, north of the mouth of the Duwamish Waterway. Prior to development, this area was part of the tide fl ats where the Duwamish River drained into Elliott Bay. Prior to 1970, there were several existing timber piers and structures in the area. In the 1970s, the Port of Seattle constructed a 900-m-long (3,000 ft), 30- m-wide (100 ft) apron to support fi ve, 15-m-wide (50 ft) container cranes. The contained backland area was then fi lled with dredged spoils (sand and silt with organics) and the upper 5 to 20 m (16 to 65 ft) backfi lled with sand and gravel.The existing apron was constructed using 0.4 m (16 in) octagonal prestressed concrete piles to support the precast concrete deck and crane rails. The pile-supported bents were spaced at 6.1 m (20 ft), center-to-center, along the longitudinal direction. Pile lengths typically varied from about 20 to 40 m (65 to 130 ft) with 15 to 26 m penetration below mudline (50 to 85 ft penetration). The slope below the apron was constructed at about 1.75 horizontal to 1 vertical to allow for suffi cient water depth for cargo ships. In most areas, a riprap buttress was placed at the toe of the slope. A typical cross section of the apron is shown on Figure 2.Several stability, settlement and pile driving issues arose during the original construction of T-46 (Pita, 1983). Reportedly, movement of the submarine slope occurred during pile driving, resulting in settlement behind the bulkhead. Pile driving reportedly caused settlement of adjacent piles. In addition, some piles were “running” (dropping quickly under one hammer blow) during installation."

Jan 1, 2007

By C. Kelley

For years urethane screen surfaces have been used in a wide range of wet screening applications where openings as fine as 75 microns and coarser have been used. In dry screening operations these same urethane screen surfaces have been relegated to only the coarser separation ranging from 1.0 mm and larger. The purpose of this paper is to expose the reader to new developments in both screen surface and screening equipment technologies, which allow an end user to consider urethane screen surfaces for dry screening operations where separations as fine as 75 microns are required. These technologies allow an end user to realize the inherent advantages of urethane in wear resistance while also realizing the benefits that a high open area urethane screen surface can bring. These benefits include non-blinding characteristics and feed capacities, which rival that of traditional stainless-steel woven wire mesh screen surfaces. The paper will highlight the features of this patented urethane screen surface technology and the screening machines in conjunction with which they are used. There will also be a presentation of several case studies of commercial installations where these technologies are utilized. These case studies are from the mineral sands industry; therefore relevance to the conference is direct and not inferred. Included in the paper will also be constraints, which must be taken into account when considering urethane screen surfaces such as temperature and chemical attack. This paper will expose potential end users to a possibility of using screens to achieve extremely accurate size separations in applications where screens were previously not considered. The paper will explain and demonstrate that prior concerns of screen surface blinding, high screen surface consumption rates and large screen surface area requirements can be eliminated by proper utilization of high open area urethane screen surfaces.

Jan 1, 2007

By J. B. Mitchell

Using digital image correlation the evolution of strain and strain at the onset of localisation resulting in a hot tear has been determined for alloys AA6111 and Al¬0.5wt% Cu during solidification. High resolution images of hot tear formation and growth were captured during a constrained bar test that incorporated a glass window above a central hot spot region. The images were analysed using digital image correlation software to measure the evolution of displacement and strain based on tracking the motion of discrete features on the as-cast surface of the sample. Temperature data was also acquired with a thermocouple cast into the sample in close proximity to the hot tear. The interval starting from the point immediately after solidification shrinkage ends (the metal pulls away from the glass) and finishing when the first sign of a crack or hot tear is visible to the eye was used to determine strain data. The minimum strain at which strain localisation occurs was found to be 0.0069 in AA6111 and 0.0021 for A1-0.5%Cu.

Jan 1, 2007

By M. Tangstad, B. Monsen, H. Midtgaard, R. Ishak, M. Syvertsen, I. Solheim

Charcoal is an interesting reducing agent because it is produced from growing wood which is renewable and does not contribute to global warming, provided that there is a balance between the felling of timber and growth of trees. In the biocarbon project the possibilities for using charcoal is investigated as well as other biological based and renewable reductants for ferroalloy production. The background for the project is that the Norwegian ferroalloy producers wish to contribute to reduction of CO2- emissions. This paper focuses on the use of charcoal instead of coke for the production of manganese alloys, and the consequences of doing so. Results from practical SiMn smelting experiments on a pilot scale have previously been reported, where only 12-14 % Si in the metal was obtained when charcoal was used. Recently we have attained satisfactory 18 %Si also for charcoal, but good results are indeed dependant on good furnace performance. There is no tradition for using charcoal for manganese production in Norway. A change from using mainly coke to the use of some charcoal will demand new routines for furnace operation, raw material and off-gas handling. Hence, characteristic properties of charcoal, which may cause change of furnace operation, have been measured and are compared to coke. The following results are presented: ?Thermal abrasion strength together with CO2- reactivity; important parameters for the performance of the upper part of the furnace. ?Coke-bed resistance; it will increase with the use of charcoal (a review of new results). ?Slag reactivity; a relevant method for testing slag reactivity of industrial reductants is of interest. The suggested method can serve for comparing slag reactivities towards graphite.

Jan 1, 2007

Project-finance risk assessment is mature and approached systematically. Mining industry due diligence remains fragmented with specialists addressing different aspects of the project such as reserves/JORC, environmental impact, commodity market, even financial analysis/ modelling. Each professional has a natural tendency to believe that the risk factors they have examined are the key ones necessary to be reviewed, as if their review will stand in isolation from others in the way a project materialises. By first laying out the project risk categories and risk matrices, this paper examines the due diligence process with a keen eye to the risk assessment and overlap/interaction. Some cross fertilisation of due diligence techniques from other industry sectors is placed into the mining context. Six case studies are then presented with regards to due diligence features in each projectÆs feasibility review or financial information/ offering memorandum. A power case first shows the differences between the due diligence expectations of banks versus bond financings. Then some Australian and Indonesian mining development cases are analysed to see the due diligence learning points. Some of these were project/due diligence failures. The conclusion focuses on the value of a systematic risk assessment for project evaluation, all from the project-finance perspective.

Jan 1, 2007

By B. Law, M. Menabde, B. Baird

Blasor is a new mine planning tool which is being used in the long and medium-term optimization of multi-open-pit operations throughout BHP Billiton’s Base Metals and bulk commodities portfolio. It is not just a scheduler, nor even only a schedule optimizer—although this function lies at the heart of the tool’s functionality—but a pit development plan optimizer, used from ultimate pit design and process plant capacity sizing right through to mining phase design and optimal panel scheduling. The tool uses a mixed-integer-linear-programming optimization engine to determine when material should be excavated and where it should be sent to optimize discounted operating cash flow over the life of operation. The core software design concept of Blasor is to provide a tool which is intuitive and flexible enough so that a competent mine planner can perform a pit development plan optimization without assistance from optimization specialists. To this end, a generalized graphical user interface has been implemented which allows full configuration of the optimization problem, including the definition of all inputs and constraints, specification of the material flow topology, bin and destination class definitions and full specification of the economic model encompassing prices and costs. This paper describes the capability of Blasor and outlines the design concepts underlying its design philosophy.

Jan 1, 2007

By F. Hashiuchi

In 1996, the Saganoseki custom smelter & refinery successfully shifted to a single flash smelting furnace operation and increased the copper production capacity to 450,000mtpy in 1998. As the next step, Saganoseki planned to further increase the productivity, especially in the area of P.S. converters and acid plant. As the results of modifications and operational improvements, the gas washing & cooling sections of the Saganoseki acid plant were consolidated from 3 to 2 lines, and increased the gas treatment capacity. The S02 converters in the acid plant were also modified to increase the acid production. By increasing the matte grade from 65 to 68%, six PS converters have been successfully integrated into four, while maintaining the production capacity and reducing the environmental burden in 2005. This paper discusses recent operational conditions and the results of implementation of technological improvements.

Jan 1, 2007

By J. K. Atherton

If the metals sector is to contribute successfully to sustainable consumption we must adopt principles and practices which address the entire life cycle of the materials we produce. Progress must be founded on a sense of shared responsibility for the resources we utilize and the materials we create - it is this integrated approach which lies at the heart of materials stewardship. Materials stewardship means mining and metals companies producing materials in a responsible manner and then working with others, beyond their site, to ensure that the downstream material flows and applications are managed properly to create maximum societal value. In September 2006 ICMM published 'Maximizing Value: Guidance on implementing materials stewardship in the minerals and metals value chain'. This document takes a practical view presenting structured guidance as well as good practice case studies. In the publication, materials stewardship is described in terms of the range of activities that can be undertaken to ensure that all parties work collectively toward the responsible use of metal and mineral resources. This paper introduces the materials stewardship concept as set out in `Maximizing Value' and describes the business case for implementation as well as the ICMM framework for promoting materials stewardship.

Jan 1, 2007