Search Documents

By Bjöm Böhle

Top-down construction (or cut and cover construction) is providing important advantages when comparing with conventional construction techniques for commercial developments with deep basements, underground car parks or near surface infrastructure and traffic tunnels. Main features are substantially reduced restrictions to surface usage, avoidance of intervention with adjacent property, provision of rigid substructures resulting in minimal deforma­tions and settlements and, last but not least, accelerated construction pro­gramme. The present contribution illustrates the construction method in general and elaborates in detail on the special foundation works for a major urban commercial high rise development requiring a six level basement structure.

Jan 1, 2006

By R. L. Derick

On a regular basis, mine personnel should obtain air samples directly from active underground areas as well as remotely from sealed locations. These samples provide mine officials with data relative to the makeup of the various atmospheres. Should conditions underground change, these results can provide a baseline that can assist officials in determining the extent of change. Relating the concentrations of individual gases to time, applying gases to equations, and examining their change over time are tools that have been successfully used to determine if a heating event exists and, if so, the extent of the emergency. These atmospheric status equations have either been developed for the mining industry or adapted from other industries. They serve as tools to assist personnel in determining the condition of underground mine atmospheres. As long as the problem area continues to be ventilated, certain gases, gas ratios, and equations can be used to determine if a fire exists, what type of material could be burning, and what quantity of coal is burning. Once the mine or the involved section has been temporarily sealed, gases, ratios, and gas-derived equations can assist personnel in determining how conditions within the sealed volume are changing over time. To alleviate potential explosions when fresh air is once again introduced into the sealed volume, equations and a diagram have been developed to predict the likelihood of an explosive atmosphere. Similarly, prior to commencing recovery of a mine or section, equations exist that can assist in determining if the fire will rekindle when air is reintroduced. This paper serves as an overview to remind and/or instruct readers about gas-sampling methodologies and gas analyses to assist in determining the status of underground atmospheres.

Jan 1, 2006

By M. Fafard, M. Dupuis, P. Goulet, J. Bédard

Start-up of a Hall-Heroult cell is a delicate task that can affect pot performance and pot life. Modem practices for high amperage cells involve preheating the lining before the molten electrolyte is poured in. Different preheating methods and heat-up schedules are used throughout the industry, and the optimum between a short start-up and damage minimization to the cell is elusive. Direct electrical coke-bed preheating is one of the most common techniques. This practice typically results in a non-uniform surface temperature distribution and can generate detrimental thermal gradients in the cathode blocks. Numerical modeling is an invaluable tool to study this complex problem and can help improve the preheating procedures. The modeling of the mechanical response of the lining is critical to detect risks of cathode block cracking or the development of gaps where liquids could leak into. Taking into account the baking of ramming paste, the quasi-brittle nature of carbon and the contact interfaces between different materials are examples of key elements to consider. A finite element slice model of a cell was built and simulations of different electrical preheating scenarios were performed using the inhouse code FESh++ to demonstrate what can be learned through thermo-chemomechanical modeling. The potential industrial application of the model is discussed.

Jan 1, 2006

By H. Utsunomiya

Most magnesium alloy sheets show low deformability in rolling. Edge cracks and transverse fractures are common difficulties. In addition, rolled sheets show well-developed basal texture <0001>//ND. The texture causes high anisotropy in mechanical properties and low formability in subsequent metal forming. Differential-speed rolling, where the upper and the lower rolls rotate at different speeds, introduces shear deformation through the thickness. Not rolling texture but shear texture evolves in the sheet so that the asymmetric rolling can be a method of texture control. However the primary slip system of the hcp alloy, is basal, the shear texture should be also basal. Differences between the two basal textures, i.e., the rolling texture and the shear texture, have not been understood completely. In this study, conventional (same-speed) rolling and differential-speed rolling have been applied to commercial AZ31B sheets at 623K. Microstructures, textures and mechanical properties of the rolled sheets before/after annealing are compared. It is found that the basal texture is more pronounced by the asymmetric rolling. On the other hand, the asymmetric rolling is effective to decrease the grain size and the planar anisotropy.

Jan 1, 2006

By K. G. Tshilombo

It should be possible to use an oxygen probe to follow iron removal during converting, if local equilibrium is established between iron in the matte and the iron oxides in the fayalitic slag. The oxygen activity is expected to increase strongly as the iron content of the matte decreases (and the iron activity in the matte drops) while the iron oxide activity in the slag remains constant. To test this idea, oxygen activities were measured in synthetic mattes (made up of mixture of Cu2S, FeS and Ni3S2) when in contact with silica saturated SiO2-FeO slags, and silica and (initially) magnetite saturated SiO2-FeO-Fe3O4slags. The measurements were performed on laboratory scale at 1250°C, using an oxygen probe consisting of a stabilized zirconia electrolyte and Fe/FeO reference, and containing the sample in a silica crucible. Electrical contact to the matte was by means of a platinum wire. The measured oxygen activity was sensitive to the iron content of the matte, and insensitive to the composition of the gas atmosphere over the melt. The measured oxygen activity was generally close to that predicted by Fact Sage calculations. This indicates that such oxygen activity measurements could be useful to monitor iron removal during converting of nickel-copper-iron mattes.

Jan 1, 2006

By E Widijanto, A Srikant

PT Freeport Indonesia operates a copper-gold mine located in the remote highlands of Papua, Indonesia, about 3500 km east of Jakarta. Currently, the district produces about 240 000 tonnes per day (tpd) of which about 45 000 tpd come from the DOZ Block Cave and the rest is mined from the Grasberg Open Pit. Over the next ten years, ore production from large block caves in the area is expected to reach about 200 000 tpd, replacing a large part of the production from the Grasberg Pit. Block cave mining alters the hydrological characteristics of the area being mined and when the cave expresses itself at the surface in the form of subsidence, it increases the entrapment area for surface water. Operating a large block cave mine in a region with an average annual rainfall of 5500 mm in steep mountainous terrain and complex geological and hydrological features presents a challenging scenario for dewatering or depressurisation of the area. The high rainfall infiltration and entrapment in stacked mines operating within an essentially single orebody, coupled with the presence of fine-grained and clayey material within the draw points of the block cave, creates mud rushes or wet muck spills, which can endanger the personnel and interrupt production. This paper outlines the problems caused by high water inflow into the DOZ Block Cave and the efforts undertaken to ensure the safety of the miners and continued achievement of desired production rates from underground mining in the district.

Jan 1, 2006

By W. Gan

The interactions between bitumen and quartz sands in aqueous solutions were studied with the objective of recovering residual bitumen from Athabasca oil sands froth treatment tailings. It was observed that the presence of various multivalent metal cation (Fe3-, Fe2+, Mg2+,Ca2+, etc.) increased the mutual coagulation between quartz particles and oil or bitumen droplets within certain pH ranges. While the increased coagulation was detrimental to the recovery of the bitumen since it lowered the degree of bitumen liberation from sands, this effect could be reduced or eliminated by the addition of organic chemicals such as citric acid, oxalic acid and EDTA. Among these organic chemicals, citric acid was found particularly effective even at very low concentration.

Jan 1, 2006

By A. P. Paiva

The solvent extraction properties exhibited by some /V,N&apos;-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By M. J. Latva-Kokko

This paper describes the behaviour of iron and the methods used for iron control in the nickel matte leaching process. OMG Harjavalta Nickel Oy processes approximately 10 000 t/y of iron, which enters the process with the nickel matte raw material. Iron dissolves and precipitates in several different stages of the leaching process. Compounds like ferric hydroxide, parabutlerite, goethite, hematite and jarosite are found. Iron removal is done within the leaching process, and this means that the dissolution of nickel sets the limiting conditions for iron precipitation. A leach residue consisting mainly of the iron precipitates is neutralized and stacked in the waste pond. When iron is precipitated from concentrated nickel sulphate solution, some nickel is lost by co-precipitation. Recent studies have shown that Ni-Fe ratios less than 1%, attributed to co-precipitation, can be obtained with jarosite precipitates, compared to 2-3% ratios typically found with hematite precipitates. Iron can be precipitated as jarosite under the optimal nickel leaching conditions by adding ammonium sulphate to the feed slurry of the autoclave.

Jan 1, 2006

By A. A. Sizikov, V. A. Sizikova

Key parameters to consider for any producer: bring down production cost and lead time; Lean production as a tool to achieve maximum efficiency; How to implement lean principles: discontinuous vs. continuous production (aluminum industry); About RUSAL: global top-three aluminum producer; Lean tools at use at RUSAL&apos;s production facilities; Pull system, Standardization of work, Just in time, Continuous improvement, Customer-Supplier relations, etc.

Jan 1, 2006

By A G. L Pratt, J R. Grant

Mining companies face the ongoing challenge of sustaining and growing production. This paper outlines business investment concepts to grow reliable returns on investment from a portfolio of choices by:improved visualisation, diagnosis and tune up of the investment pipeline (pipeline management); good corporate decision making (governance) to select the right project mix, risks and sequence; and delivery strategies to enhance and reliably execute projects.

Jan 1, 2006

By S. Kashani-Nejad

The formation of oxides during the dehydration of MgC12,6H20, Bischofite, was studied by heating the bischofite over a range of time and temperatures in ambient atmosphere. Using a methanol-leaching technique developed by authors, the oxides that formed were isolated, identified and assayed. Three distinct regions of oxide stability were identified. The oxide produced at dehydration temperatures less than 300 °C was Mg2(OH)3C1,2H2O; at 300 °C, mixtures of MgOHC1 and Mg2(OH)3C1.2H2O were formed and at 400 °C, MgOHC1 was the only oxide produced. The presence of MgO observed in the products of the dehydration of bischofite at temperatures above 400 °C was due to the thermal decomposition of the MgOHC1 that was formed while the sample was heating to over 400 °C.

Jan 1, 2006

By K. Tada

A surface of a magnesium slab (hereinafter, referred to as Mg slab) or magnesium alloy slab (hereinafter, referred to as Mg alloy slab) becomes black with the use of conventional manufacturing methods. The methods also involve a danger that an explosion of the molten magnesium occurs through contact with cooling water. Thus, it has been impossible to produce a slab having a smooth surface. In the present method, a molten magnesium alloy is supplied into a mold, which is sheltered from the surroundings, from a pool in tundish, which is shielded from the surroundings. AZ31B slab formed in the mold is drawn horizontally out to the outside from an outlet of the mold by revolving of the pinch rolls. A cooling water is jetted at an acute angle onto the slab on the outer side of the mold outlet. Further, an inert gas is sprayed at the inner side of the mold outlet in order to seal in a gap between a free surface of the molten magnesium alloy and a sheltered board surrounding an upper surface of the mold. As a result, oxygen and droplets of the cooling water are prevented from running back to the mold side through the gap. AZ31B slab has a smooth surface condition and high quality without a gas porosity, a segregation or the like. Further, the slab has a size of a width of 100 to 120 mm, a thickness of 5 to 20 mm and a span of 10 m or more.

Jan 1, 2006

By Seiji Yokoyama

As a series of fundamental study on the gas evaporation method, a levitation-melted aluminum was evaporated in the gas mixture of argon and ammonia to synthesize ultrafine particles of aluminum nitride. When the ammonia partial pressure were more than 2kPa, the formation ratio of aluminum nitride was about 95%. The particles of aluminum nitride were mainly hexagonal. The mean size of the particles of aluminum nitride was about 57 nm, and it was constant without depending on the temperature of the levitated aluminum and the partial pressure pf ammonia. The aluminum nitride was formed by the reaction between ammonia and condensed liquid aluminum particle whose size was relatively small.

Jan 1, 2006

By Xiyun Yang

Magnetite was prepared by hydrogen reduction method. For a conversion to cobalt-modified magnetite, magnetite particles were suspended into a solution containing Co2+ and Fe2+ to precipitate a cobalt ferrite layer on the surface. pH value influences the particle composition directly, the desirable CoFe2O4 is obtained when pH value is 12. The coercivity increases with the increase of cobalt content, cobalt efficiency reaches a maximum value at cobalt content of 2.71wt%. With cobalt modification, magnetite particles have similar lattice constant and squareness ratio to that without cobalt modification. TEM and XPS analyses indicate that acicular morphology is retained during the coating process, the epitaxial growth layer consists of CoFe2O4and 0.3Co2O3CoFe2O4 at cobalt content of 2.71wt% and 5.03wt%, respectively.

Jan 1, 2006

By David Davison

Metafex®* is an inert material that is more energetic than explosives when activated. Because Metafex is inert until activated (a moment before use), it can profoundly change the logistics of systems and processes that require energetic materials. We have obtained positive test results for a Metafex configuration (called a flat pack) that operates at the practical voltage of ~20 kV. We describe the outcome of the testing and potential uses of the material.

Jan 1, 2006

By B. Daniels, A. Tieu, W. Yan, B. Ren, M. Vijay

"Plasma or thermal sprayed coatings are becoming more widely used in a wide range of industrial applications. The preference to use thermal sprayed coatings is mainly attributed to its superior wear, and corrosion resistant properties akin to hard chrome but without the harmful health implications of chrome in the coating process. Specifically, High Velocity Oxygen Fuel (HVOF) plasma sprayed Tungsten Carbide & Cobalt (WC/Co) coatings are presently being tested on aircraft landing gear. This coating can be efficiently applied and is highly resistant to corrosion and wear. However, HVOF coating&apos;s durability also makes it difficult to be stripped for inspection and overhaul. Current coating removal methods usually involve a multi-step process whereby the coating must undergo diamond wheel grinding, chemical dipping, grit blasting, ultrahigh pressure (UHP) 380 MPa (55 Kpsi) water blasting, and subsequent chemical dipping, depending on the type and thickness of the coating. As explained by Yan, et al [l]"" a unique method has been developed for removing HVOF coatings with the use of only water. The method consists of modulating a stream of water at a pressure of only 69 MPa (10 Kpsi) with ultrasonic waves to generate a forced pulsed waterjet. The resulting cyclic loading of the hard coating due to the impact of the water pulses easily causes it to flake off the substrate. This paper will briefly describe the fundamentals of the forced pulsed waterjet technique with an emphasis on insitu applications of the removal of various plasma and HVOF coatings."

Jan 1, 2006

By H. Lind

The consumption rate of Estonian oil shale increases due to the growing rate of exported oil-shale oil. Estonian oil shale active resources in working mines are predicted until the year of 2025 when the consumption rate stays at the level of 12 tons per year. If the consumption rate stays at that level, new mines should be opened after 20 years, if the rate increases new mines should be opened even earlier. The predicted active resources in Estonian oil shale deposits are calculated for 60 years, based on the parameters of the power station technicoeconomics. As a result, there is a need to open new mines. One of the potential areas for surface mine is the Tammiku-Kose prospect area (Rheinbaun Engineering, 1996).

Jan 1, 2006

By C. Pelley, S. Kelebek, T. Katsabanis, B. Nanthakumar

"As part of a larger investigation on generation of fines from mining activities and their effect on downstream operations, ore samples from Onaping area stockpiles of Falconbridge Ltd were studied. Batch flotation tests were conducted on the stockpile samples and fresh ore samples to explore the effect of stockpiling on grade-recovery performance. Head grade and particle size distribution of the samples from stockpiles were adjusted so that the samples compared are similar to each other. In additional tests, fresh ore samples were blended with stockpile samples at various percentages, representing 27.4, 50.2 and 81.5% of stockpile samples.The samples from stockpiles produced inferior nickel grade-recovery curves compared to fresh ore. The poorer grade-recovery performance was attributable to two factors. First, a significant dilution effect was observed due to the nearly complete flotation of pyrrhotite. Secondly, while pyrrhotite from stockpiled ore became highly floatable, the same stockpiling conditions caused nickel losses that were attributable to non-floatability of some pentlandite.In the case of blending, there was generally insignificant difference in the nickel grade-recovery between fresh and blended samples when the blending cases involved 27.4 and 50.2% stockpile samples. However, an increase in pyrrhotite recovery was observed for both blending cases. At 81.5% blending case, degraded grade-recovery was significant primarily due to the nearly complete flotation of pyrrhotite. There was a small, but noticeable amount of nickel loss for this case. However, for lower ratios of blending this loss was negligible.The increase in pyrrhotite recovery was partly attributed to its activation by Cu and Ni ions. Formation of a significant amount of elemental sulphur was also apparent from analysis of stockpiled samples. It can be concluded that pyrrhotite is mildly oxidized under stockpiling conditions while part of the pentlandite undergoes a more severe oxidation."

Jan 1, 2006

By A. O. Orumwense

Mill circumferential speed, the number of passes of pulp through the grinding chamber, media type, size and filling ratio were investigated in an attempt to determine how to effectively grind copper concentrates in a stirred mill. The stirred mill product fineness was enhanced to some extent by decreasing media size, high media filling, and an increased number of passes of the pulp through the grinding chamber. Shape also plays a major role in grinding media effectiveness, with spherically shaped media producing a finer size. The fineness of the product increases with increasing power consumption but the method of energy transfer is very important in energy utilization. The effect of the mill parameters on copper flotation was evaluated. Copper recovery was influenced by grinding media size, mill speed and the number of pulp passes through the grinding chamber.

Jan 1, 2006