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By J. Bleeck, G. Mahrt

INTRODUCTION Many excellent papers have been written and presented regarding agricultural lime and the subject has been covered extensively in books concerning soil science, fertilizing, limestone, etc. We felt challenged to construct a paper that wouldn’t merely be a repetition of past presentations. Therefore, we chose to begin with factors having the most impact on plant growth realizing that the audience is likely to be relatively unfamiliar with this subject. So, we decided to dig deep into the roots of soil and plant growth science in order to better understand the significant role of limestone in this important area. The soil with the higher plants growing upon it forms an open and dynamic ecosystem in which there is flux of energy and material (heat, light, water, nutrients, mineral and organic matter, organisms). Plants root in the soil and then take up oxygen for root respiration, yielding energy for nutrient uptake, water for turgescence and transpiration and use in photosynthesis and the mineral nutrients needed for the synthesis of organic matter. Above the ground the plant takes in light energy and heat using them in photosynthesis to assimilate atmospheric CO2. Photosynthesis is the basic life process of creation. However, we will look at the root room where soil, water, air, and heat economy and the supply of nutrients determine soil fertility and the important role lime plays here. Location is the primary point to be considered when discussing agriculture (climate and soil); secondly, the dynamic and mobility of the minerals (plant nutrients) in the soil; and thirdly the conversion of organic substances into humus. And then there is a great deal of water involved in the growing process. In order to produce 1 kg of dry plant substance, 300 to 800 kg of water must be pumped through the plant and is then lost by transpiration. Cereals, vegetables, and sugar beets consume between 400 to 500 kg of water during the growing process and long-growing crops, such as alfalfa and clover, can consume 600 to 800 kg of water per kg of finished product. Without water, a plant cannot grow. (Reference 1)

Jan 1, 2006

By J. P. Weiler

The increasing use of high-pressure die-cast magnesium alloys in the automobile industry requires a better understanding of the mechanical properties, the microstructure, and particularly, the relationship between these two. The goal of this study is to first understand the microstructural features which control the mechanical properties observed from an AM6OB magnesium alloy, and second, to be able to predict the local mechanical properties based on microstructural features encountered in different areas of the die-cast component. The two main tools used in this study are spherical indentation testing, used on local areas of the die-cast magnesium alloy AM6OB to detect changes in microstructure and mechanical properties, and X-ray tomography, used to non-destructively investigate the internal porosity in a sample. The results from these tests are then used to predict the local mechanical properties such as the yield stress, the strain-hardening characteristics, and the fracture properties of the AM6OB component.

Jan 1, 2006

By Huw Williams

It is becoming increasingly common practice to re-use existing foundations for new projects, especially on urban sites where geotechnical conditions are congested. A knowledge of the foundation dimensions and capacity is essential for this to take place, however, as-built records are often non-existent. Non-Destructive evaluation (NDE) is now becoming an important tool in assessing old foundation properties and their potential for re-use. Pile dimensions are also critical in the power industry, when they are supporting transmission towers which need to be upgraded, and may carry additional wind loading. This paper describes the application of various NDE techniques that are available and how they can be used to determine pile length, shape and capacity in difficult site conditions, including foundations under structures.

Jan 1, 2006

By D. G. Lee

Diesel particulate matter (DPM) often contains small amounts of metal as a minor component but this metal may contribute to adverse health effects. Knowledge of the mechanism for particle formation as well as the size preference of the trace metals is critical to understanding the potential for health concerns. To achieve this, the size and the composition of each particle should be optimally measured at the same time. Single particle mass spectrometer (SPMS) would be the best tool for this objective. In this paper, we therefore will introduce new findings about the mechanism and distribution of the trace metals in DPM, derived from a study where an SPMS was used to analyze freshly emitted DPM. KEY WORDS : Single particle mass spectroscopy, Diesel particulate matter, Characterization, Metal contents

Jan 1, 2006

By K. Adham

Iron chloride pyrohydrolysis (ICP) is used as an efficient way to fix iron as an oxide, for sale as a by-product or for safe disposal. Iron chloride is reacted with water at elevated temperatures to yield iron oxide and hydrogen chloride. Both the steel industry and synthetic rutile producers make extensive use of ICP. Two technologies are available for ICP: fluidized bed (FB) and spray roaster (SR). Both technologies are energy intensive. Here, fluid beds and spray roasters are compared with respect to their fuel and electrical energy consumptions. Roaster size and oxide product characteristics are also considered. Process models are prepared, using the METSIM® software, and specific energy consumptions are compared. The results will help the industry decide which technology best suits its goals and at what energy cost.

Jan 1, 2006

By B. Tiryaki

Performance prediction models for partial face mechanical excavators, when developed in laboratory conditions, depend on relating the results of a set of rock property tests and indices to specific cutting energy (SE) for various rock types. There exist some studies in the literature aiming to correlate the geotechnical properties of intact rocks with the SE, especially for massive and widely jointed rock environments. However, those including direct and/or indirect measures of rock fracture parameters such as rock brittleness and fracture toughness, along with the other rock parameters expressing different aspects of rock behavior under drag tools (picks), are rather limited. With this study, it was aimed to investigate the relationships between the indirect measures of rock brittleness and fracture toughness and the SE depending on the results of a new and two previous linear rock cutting programmes. Relationships between the SE, rock strength parameters, and the rock index tests have also been investigated in this study. Sandstone samples taken from the different fields around Ankara, Turkey were used in the new testing programme. Detailed mineralogical analyses, petrographic studies, and rock mechanics and rock cutting tests were performed on these selected sandstone specimens. The assessment of rock cuttability was based on the SE. Three different brittleness indices (B1, B2, andB4) were calculated for sandstones samples, whereas a toughness index (Ti), being developed by Atkinson et al.1, was employed to represent the indirect rock fracture toughness. The relationships between the SE and the large amounts of new data obtained from the mineralogical analyses, petrographic studies, rock mechanics, and linear rock cutting tests were evaluated by using bivariate correlation and curve fitting techniques, variance analysis, and Student?s t-test. Rock cutting and rock property testing data that came from well-known studies of McFeat-Smith and Fowell2andRoxborough and Philips3have also been employed in statistical analyses together with the new data. Laboratory tests and subsequent analyses revealed that there were close correlations between the SE and B4 whereas no statistically significant correlation has been found between the SE and Ti. Uniaxial compressive and Brazilian tensile strengths and Shore scleroscope hardness of sandstones also exhibited strong relationships with the SE. NCB cone indenter test had the greatest influence on the SE among the other engineering properties of rocks, confirming the previous studies in rock cutting and mechanical excavation. Therefore, it was recommended to employ easy-to-use index tests of NCB cone indenter and Shore scleroscope in the estimation of laboratory SE of sandstones ranging from very low to high strengths in the absence of a rock cutting rig to measure it until the easy-to-use universal measures of the rock brittleness and especially the rock fracture toughness, being an intrinsic rock property, are developed.

Jan 1, 2006

By Henrique Ventura Oliveira

Continuous casting is the most important process for solidification of steels. In this process, the fluid flow pattern in the tundish and in the mould have significant effect on the product quality. Problems associated to fluid flow in the tundish include surface turbulence, ?short-circuits?, formation of dead zones and vortexing. During grade changes, mixing in the tundish plays a significant role in determining the length of the intermixed slab. All these flow aspects can be studied by means of mathematical and physical models. In the last years, numerical simulation of fluid flow has become a very popular tool in the analysis of the performance of continuous casting tundishes. In setting-up these numerical simulations, special care should be taken in choosing the appropriate mesh distribution, the interpolation scheme, the adequate location of the inlet boundary and the turbulence model. In the present paper, turbulent fluid flow in different configurations of tundishes was simulated. Different turbulence models were used in the simulations. Residence time distribution (RTD) and mixing curves during grade changes were predicted and compared to results obtained in physical models. The performances of the different turbulence models were evaluated. For the tundishes that have been studied, the performances of the different turbulence models tested in the present work were similar. There is no evidence that any of the models provided sustained improvement when compared to the well-established standard k- model. All turbulence models tested presented limitations in simulating flows under low turbulent Reynolds numbers.

Jan 1, 2006

By Graham Davey

"Low speed stirred milling has been employed for many years in the metalliferous and industrial minerals industries. High speed stirred milling is a relatively new method of grinding in the metalliferous process industries. However it has been it has been in wide spread use in the industrial mineral field for over 30 years for various minerals. Many existing metallurgical operations are looking to maximize economic return from existing deposits, requiring new thinking and technologies. By combining low speed and high-speed milling fine and ultrafine grinding efficiency and operating costs can be improved.The correct selection of different fine grinding technologies is covered, when each mill is applicable and when a combination of the VERTIMILL® Grinding Mill and SMD provides the best economic solution.INTRODUCTIONUltra-fine grinding of minerals has been in wide spread use in the industrial mineral field for over 30 years. Within the last 10 years the metalliferous industry has shown interest in the ability to produce ultrafine particles, as chemical, physio-chemical and physical separation processes have advanced to be able to treat ultrafine metalliferous particles. Also as the primary mineral deposits, around the world are depleted, new more difficult deposits must be mined. Existing operations are also looking to maximize economic return from existing deposits, requiring new thinking and technologies.The traditional approach for gold containing refractory material has been to liberate the locked gold by chemically destroying the pyrite through oxidation. Roasting, pressure oxidation, and bacterial oxidation all employ various degrees of temperature, pressure and catalysis to react the pyrite with oxygen to produce iron oxide and sulfur by-products. However all of these methods are economically impacted due to specific operational added requirements and emissions controls. Pressure and bacterial oxidation have very high capital and operating costs."

Jan 1, 2006

The mining industry has generally been slow to apply ion exchange processes to hydrometallurgical applications even if ion exchange offers an ideal solution for a particular problem. Two notable exceptions are in gold and uranium recovery. The largest application of ion exchange in the metals processing industry has been the use of resin-in-pulp (RIP) for gold recovery as an alternative to activated carbon. Iron is a ubiquitous impurity in hydrometallurgical solutions. In many cases, bulk removal of iron from the process solutions is accomplished by precipitation. However, precipitation for iron control is often accompanied by losses of base metals by co-precipitation. Increasingly, the option of ion exchange for removal of smaller amounts of iron from process solutions has been favoured. A number of applications have been developed and proven at the commercial scale for the removal/control of iron from a range of metal processing solutions. This paper provides an overview of the application of ion exchange for iron removal from a range of metal processing operations, including Cu, Ni and Co solutions. A number of case studies are provided which review operational and resin regeneration strategies and the impact upon the commercial operation of metal processing with improved iron control.

Jan 1, 2006

By N. Tounsi

The use of analytical modeling of continuous chip formation in conjunction with orthogonal cutting experiments was presented in the open literature to identify the coefficients of material constitutive equation within the practical range of stress, strain, strain rate, and temperature encountered in metal cutting. Identification of reliable constitutive data was hampered by a lack of a reliable model for the prediction of the primary shear zone thickness that affects directly the effective strain rate field. An original analytical model to determine the primary shear zone thickness is proposed in this paper. It is based on the mechanics governing the material flow in the primary shear zone. Based on the distribution of the hydrostatic pressure and the forces measured from orthogonal cutting tests, the model that describes the thickness of the primary shear zone is derived. To validate the model, FE simulations of chip formation using DEFORM3D were carried out for different materials and cutting conditions. The results of the analytical model are in reasonable agreement with FEM results.

Jan 1, 2006

By Makarand G. Khare

Though the phenomenon of dragload is known for many decades, there is a lack of clear guidelines to evaluate the amount of dragload. The development of dragload depends on relative movement between pile and surrounding soil which is a complex phenomenon and requires a detailed numerical analysis. Bitumen layer has been used in the past with varying degree of success in reducing the dragload but the reduction appears to depend on number of parameters. No procedure is available in literature to estimate the dragload when a slip layer is applied on pile surface. This paper investigates performance of two commercially available bituminous coats to reduce the negative skin friction on pile. Direct shear test apparatus was used to model the interface friction between soil and coated pile surface. The lower half of direct shear box was replaced with either a concrete block or a mild steel block representing pile surface. Two types of bituminous coats namely Shalikote and bitumen having penetration value of 30-40 were evaluated in this study. Shearing resistance of pile material-coat-soil is found to be influenced by normal stress, coat thickness, and rate of shear. Laboratory results are compared with published field data where coated and uncoated piles have been load tested.

Jan 1, 2006

By P. J. Oakley, W. M. Thomas, S. W. Kallee, D. G. Staines

A Friction stir welding (FSW) is now extensively used in aluminium industries for joining and material processing applications. The (FSW) technology has gained increasing interest and importance since its invention at TWI almost 15 years ago. The basic principle, recent applications and the continuing development of the FSW technology are described. The paper will introduce some of the variants of FSW, such as Dual-rotation, Twin-stir(TM), and the Stir-lock(TM) technique.

Jan 1, 2006

The Mineral Density Separator (MDS) was developed by Mintek to predict mineral separation in a plant, evaluate efficiencies and develop scale-up parameters. This study investigated the influence of particle size on the results of the MDS, the misplacement of material in the MDS and the possibility of replacing heavy liquid float and sink analyses of coal with MDS analyses. Six tests were done with coal of different size ranges. Each MDS layer was subjected to a float-sink analysis whereafter each float fraction was screened to determine the particle size distribution. The results indicated that MDS results represent float-sink analyses when compared to an ash curve. There is some misplacement in the different MDS layers, but this does not seem to influence the results negatively. Keywords Mineral density separator, sink-float analyses, heavy liquid analyses, washability curve

Jan 1, 2006

By Ronald Molnar

"High demand for metals is driving the exploitation of lower grade and more complex orebodies. These projects are often the initiatives of junior mining companies with limited financial resources. In addition, existing operations seek to enhance revenue from their existing metal recovery operations, through the production of value-added by-product metals and chemicals. Typically, hydrometallurgical circuits, often with novel chemistry, are required to exploit these new ores, to produce the multiplicity of products that will make a marginal project economical, or to increase the product range of an existing operation. Often, the mineral processing engineer is given the task of coordinating the development of a back-end hydrometallurgical flowsheet for their mineral processing project. This paper discusses the objectives that companies have when they commission the operation of a hydrometallurgical pilot plant. The paper goes on to enumerate some of the principal differences between mineral processing and hydrometallurgical pilot plants and the effect these have on the design, operability and potential pilot plant outcomes. Important factors include working with chemically reactive solutions and pulps, elevated temperatures operation, changing rheological properties of slurries, the complexity of integrated circuit flowsheets with long hold-up times and multiple recycle streams, and the need in some cases for extreme attention to purity and cleanliness. Examples will be drawn from the extensive experience base of SGS Minerals Services at the Lakefield site, in piloting both mineral processing and hydrometallurgical process flowsheets.INTRODUCTIONWe are currently experiencing a period of strong growth in the demand for metals. This in turn is turning the spotlight on a great many smaller mining companies and mining promotion ventures trying to tap into the rising metal demand. Some of these companies want to develop their properties and recover metals while others want to develop to the point that a major company will take an interest, or in some cases buy them out completely.With the heightened interest in metals, many orebodies that have been known about for years are being reconsidered for exploitation. Often, the reason they have not been developed to date is because of difficult metallurgy and marginal grades leading to marginal economic viability. In both cases the key that unlocks the resources is often the application of a novel metallurgical flowsheet, often a hydrometallurgical flowsheet."

Jan 1, 2006

By Y. Okita

The Goro Nickel Process, developed over a ten-year period, uses a number of novel processing steps and treats two ore types, limonite and saprolite, together. Nickel and cobalt are solubilized using a 270°C pressure acid leach in sulphuric acid, which rejects the bulk of the Fe into the leach residue as hematite particles. The leach liquor, after CCD, is aerated to oxidize any ferrous iron to the ferric form and is neutralized with limestone to precipitate iron as hydroxides together with gypsum from the neutralization of the free acid. Further neutralization with lime, together with steps to remove suspended solids, reduces the iron to trace concentrations. Nickel and cobalt are directly recovered from the low-iron leach solution by primary solvent extraction using Cyanex 301® (SXl) in a high-strength hydrochloric acid solution. Nickel is subsequently separated from cobalt in a secondary solvent extraction circuit using tri-isooctylamine. A granular nickel oxide is made by pyrohydrolysis, and this allows the recycling of hydrochloric acid to SXl. The process is currently being commercialized to produce approximately 60,000 t/y of nickel as nickel oxide granules and approximately 5,400 t/y of cobalt as cobalt carbonate. This paper describes the process development to control the Fe concentration in the SX1 feed solution.

Jan 1, 2006

By J Hudson

Autogenous (AG) and Semi Autogenous (SAG) grinding mills are the conventional selection for large-scale grinding circuits. It is accepted that these forms of comminution are not the most energy efficient available. This efficiency combined with escalating energy prices, steel prices and the requirement to process larger, lower grade deposits has necessitated that better comminution techniques are found to challenge the dominant position of AG/SAG mills in the grinding circuit. Recent advances in high pressure grinding rolls (HPGR), particularly in terms of roll surface protection have meant that, depending on the application, an economic alternative is available to the large diameter AG/SAG mills. Mining companies now recognise the potential benefits of HPGR and so they need proper assessment in the design of new or upgrade of existing grinding processes. Of course, the answer to the question AG/SAG or HPGR is not straightforward and the impact of the grinding process on the whole metallurgical process needs to be evaluated. Clearly this is a complex decision to make and requires substantial metallurgical knowledge, test work, and objective analysis. The perceived downstream processing benefits will differ between different plants depending on the ore type and processing conditions. The optimal design of the comminution circuit requires that a robust methodology is followed to objectively characterise the ore, size the equipment and determine the downstream processing benefits. The paper gives a brief comparison of the capital and operating costs for both grinding systems, and then outlines the appropriate test work that is required to make an informed decision.

Jan 1, 2006

By J-F. Magnan, M-A. Thibault, R. Boulianne, C. Gauthier, J-P. Gagné, G. Dufour

During the production of aluminium in smelters, the anodes used in electrolysis cells have to be replaced frequently. Anode butts are usually placed on anode trays for transportation and cooling, a practice during which Hydrogen Fluoride (HF) is emitted in large quantities. Covers developed in 2000 by Alcoa Deschambault to fit on the anodes trays were implemented, resulting in significant reductions of HF emissions. However, the covers are expensive to maintain and use short-life consumable parts. In January 2004, STAS and Alcoa decided to develop a more efficient design of cover, with lower maintenance costs and no need for consumable materials (like soft cushions). This paper presents a summary of the work performed to develop the new design as well as a summary of the test results.

Jan 1, 2006

By H. A. Kishawy, S. Kannan, M. Balazinski

Metal Matrix Composites (MMCs) are new generation engineering materials that possess superior physical and mechanical properties compared to nonreinforced alloys. However, the presence of abrasive ceramic reinforcements in the ductile matrix causes severe tool wear and premature tool failure. Flank wear was found to be the dominant wear mode while the main wear mechanism was abrasion. Analysis of the cutting tools using scanning electron microscopy has shown that both two body and three body abrasion are operational during machining MMCs. A methodology for predicting the tool flank wear progression during bar turning ofMMCs was presented in an earlier paper [1]. In the proposed model, the wear volume due to two body and three body abrasion mechanisms was formulated. Then, the flank wear rate was quantified by considering the tool geometry in 3D turning. The main objective of this paper is to investigate the contribution of two body and three body abrasion towards the tool wear volume during cutting MMCs.

Jan 1, 2006

By Yong Hack Lee

Electric Arc Furnace (EAF) dust is generated when scraps are treated in the electric arc furnace and usually classified as hazardous industrial waste in most countries. EAF dust usually contains 15 to 25% of zinc and 3% of lead. It is usually treated in rotary kiln (Waelz process) or landfilled after a solidification and stabilization treatment. Numerous methods have been proposed as the EAF dust treatment technology, but few of them are in operation as a commercial scale except the Waelz process. Korea Zinc performed a plant test in which 600 tons of EAF dust was treated using TSL (Top Submerged Lance) technology. The TSL technology is a low cost, proven technology for processing zinc-bearing residues. The EAF dust was first de-chlorinated and fed to the TSL furnace. Finally, clean slag satisfying toxicity criteria was generated and valuable metals such as zinc and lead were recovered as fume oxide. The fume oxide was de-halogenated by sodium carbonate and sent to zinc refinery to recover zinc and lead. The recovery of zinc and lead was 90% and 93%, respectively. Most of the dioxin in the EAF dust was discomposed so dioxin less than the Korean regulation limit was detected in the offgas, which proves that the TSL technology is the best solution to treat EAF dust.

Jan 1, 2006

By D. Borman

The location of underground positions in mines has usually fallen to their survey department's. Their usual tasks include: ? installation of a high-precision peg network like the National Survey grid as beacons ? offset measurements to the sidewalls, and sometimes hangingwall and footwalls, of development tunnels and excavations ? offsetting of stoping panels for the calculation of face ? advance and the square meterage of area removed. Other departments build their observations into the plans produced by the surveyors. If more precision is required, they ask the surveyors to `elevate' their points with a theodolite. Apart from the survey peg network and `elevations' these measurements are usually planer measurements suitable for producing plans, sections and projection sheets. When the only representation medium was a sheet of paper or transparency, this was perfectly suitable. However the development of CAD models of the workings has changed all this. Full 3D representation is not properly catered for in the tool sets in current use, and needless hours are spent converting analogue-type observations into digital form. The basic survey models need to be augmented by the observations of other disciplines that are also required to locate positions underground. These include: ? the need for geologists to plott their mapping and ? borehole logs into 3D space ? the need for samplers to position their sample points accurately because the geostatistical models are biased and inaccurate ? the need for stoping width recorders to position their thickness observations to prevent errant evaluation and bonuses ? the need for rock engineers to place their mappings into 3D to build true geotechnical models to manage geotechnical stresses ? the need for production officials to receive updated face ? positions during the month so that they can manage the ? production and utilize their resources properly. This paper covers a new method of positioning profiling points to a suitable degree of accuracy. I believe the method is sufficiently simple and cheap for all to use. Historical methods Platinum and gold orebodies, especially in South Africa, are generally narrow tabular deposits. This made them suitable for depicting on a 2D medium like paper. The determination of stoping or face widths was not a problem, as the ore is removed in a single stoping process. Such 2D representations could be easily positioned using tape offsetting between survey pegs or points tied in from survey pegs. Problems of dip were handled by using 'Stope Sheets' which chose a best fit projection for the whole area depicted or by using true dip section sheets for inclined tunnels. Rolling reef and potholes were the common areas of difficulty. Most mines now model their orebody and plan the extraction in computer graphics. This means that the representation of the current workings has to change to support this trend. It now becomes a truly 3D problem. Mining officials find it inconvenient to have their actual workings in single-line depictions while their orebody is depicted with top and bottom contacts and the planned tunnels in 3D shapes. Geological models which form the basis for the resource model and planning process are often out of date, as the updating process is slow. The geological mapping has to be plotted onto sections and plans. These are then digitized into graphics by a draughtsman and checked by the geologist. Only then does the interpretation and model update take place. Potential methods to create 3D 'Actuals' Global positioning systems (GPS) Surface mines have been blessed by the advent of GPS technology. These simple-to-operate pieces of equipment and compatible software make it possible for all types of mine employees to locate themselves, and therefore to locate their observations. GPS are often inexpensive and give an acceptable degree of accuracy. Only in deep pits or close to the highwalls are observations hindered. Such technology cannot however, work underground. Ground penetrating radar (GPR) GPR is reported to be very useful for estimating the positions of potholes and faults. However it is still considered as providing an estimate, not a definite measurement. GPR is good for seeing into solid rock, not into open spaces. Inertia reading devices Experiments with inertia reading devices have been conducted on the mines. They were the forerunners of GPS for military guidance systems, and were even used for city navigation in the early 70s. They do however work best with heavy or fast-spinning gyros. Anglogold Ashanti's attempt to use them were discontinued in the mid-90s when the developers asked for an additional few million rand for a device that would weigh more than 12 kg and have a limited operational life.

Jan 1, 2006