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By Yong-Moo Cheong

When the zirconium pressure tube(PT) is in contact with the calandria tube(CT) in the pressurized heavy water reactor(PHWR), the temperature gradient between the inner and outer wall of the PT results in a thermal diffusion of hydrogen(deuterium) and hydride blisters are formed on the outer surface of the PT. Since Zr-2.5Nb pressure tubes have a high risk for the formation of blisters during their operation in a PHWR, there is a strong incentive to develop a method for the non-destructive detection of the blisters grown on the tube surfaces. However, because there is little mismatch in an acoustic impedance between the hydride blisters and zirconium matrix, it is not easy to distinguish the boundary between the blister and the zirconium matrix with the conventional ultrasonic methods. This study has focused on the development of an ultrasonic method to detect the hydride blisters formed on Zr-2.5Nb pressure tubes. Hydride blisters were grown on the outer surface of a Zr-2.5Nb pressure tube using a cold finger attached to steady state thermal diffusion equipment. Ultrasonic velocity ratio method as well as conventional ultrasonic parameters with an immersion technique was developed to detect small hydride blisters on the Zr-2.5Nb pressure tubes.

Jan 1, 2006

By V. C. Pandolfelli, L. Paulino, C. E. Zangiacomi

The continuous improvement in aluminum industry over the last years has increased metal output at lower cost. The potlining plays an important role in this regard due to high cost involved and more recently in its environmental aspects. In order to increase potlife and thus minimize the aluminum cash cost, a systemic approach is needed, through investigating the main cathode failure mechanisms by using a pot autopsy as a powerful tool, and then making the necessary chances to achieve extended potlife. In addition, preheating and pot start-up may also damage the cathode if not performed with an appropriate technique or even if the lining materials are not specified correctly, among other factors. All these aspects will be presented and discussed in this paper. Increased potlife, especially now that the current is reaching values up to 300kA, will allow aluminum plants to match their goals more efficiently at lower costs.

Jan 1, 2006

By J. N. Van der Merwe

The research described in the paper was aimed at providing standardized information of cases of failed and intact coal pillars in the form of databases to researchers. It also offered the opportunity to take stock of the pillar stability situation in coalmining and to review the impact of the application of the safety factor formula for pillar design. It was found that the physical parameters of coalmining have not changed substantially over the last four decades. However, changes in the controllable parameters like pillar width, pillar width-to-height ratio and percentage extraction have all moved toward the more conservative side. Scrutiny of the database indicates that of all the failures recorded, only 23 occurred in panels that were mined after 1969, when one can assume that the safety factor formula was fully applied. If the pre-1969 practices had been continued, at least 144 collapses would have been expected. There has thus been a substantial reduction of pillar collapse cases, justifying the cost paid for the formula, which has shown to be in the region of 600 million tons of coal. It is evident that that are distinct differences in the natures of the failures among different coalfields. This justifies the attempts to derive seam or coal field specific strength formulae and is a topic that should be pursued.

Jan 1, 2006

By Doug Tesarik

Researchers from the National Institute for Occupational Safety and Health1 (NIOSH), together with employees from The Doe Run Company, are monitoring and evaluating the stability of a pillar retreat section at the Fletcher Mine, a lead/zinc, room-and-pillar mine near Bunker, MO. Cemented rockfill is being used to provide roof support as high-grade, remnant ore pillars are mined. Earth pressure cells and deformation meters placed in backfill panel pillars monitor stress change and vertical deformation, respectively, as nearby ore-bearing pillars are extracted. Similarly, biaxial stressmeters and borehole extensometers are used to monitor mining-induced stress change and deformation, respectively, in long-term support pillars. Data from these instruments indicate that when ore-bearing pillars were mined, stress was redistributed from support pillars to a backfill panel pillar. The data also indicate that the backfill and support pillars have remained stable for two years after pillar extraction was completed in the area. This research demonstrates the importance of using reliable instruments to document the geomechanical behavior of pillars and backfill. Gaining a better understanding of roof support and stress redistribution mechanisms is a fundamental part of NIOSH's goal to reduce and/or predict rockfalls, which are still among the leading causes of injuries in metal/nonmetal underground mines.

Jan 1, 2006

By A. Noël, R. Lapierre, M. Provencher

"Modem aluminum smelters are facing significant operating cost pressure. Key methods used by smelters to manage this pressure are automation and production-information systems to optimize processes, manage quality, anticipate problems and reduce operating costs. In 2002, Aluminerie Alouette Inc. began its Phase II Expansion project, and retained the joint venture of SNC-Lavalin and Hatch (SLH) as its engineering, procurement and construction management (EPCM) team. Alouette had the distinction of being one of the most efficient aluminum smelters in the world. Alouette already understood the importance of systems integration in project delivery. For Phase II, key objectives were identified to ensure ""a state of the art"" integrated architecture that would support Alouette's production goals to integrate the existing facilities with the expansion, to form a single efficient facility and meet project schedule and budget targets. Achieving those objectives within the context of a large project often creates major challenges due to the nature of the traditional EPCM delivery model, which relies on several vendors and third-party-systems integrators. In this case, an integrated Alouette-SLH team was made responsible for all aspects of the systems integration, taking over the task from most suppliers. The integrated team was responsible for delivering an automation system and plant-wide-production IT system for the new facilities while accommodating migration for the existing systems. Through the use of rigorous methodology and advanced state of the art technology, the IT and automation strategy led to significant value creation and is recognized today as one of the key factors of the project's success. The primary results were: fast and efficient start-up of facilities, due to quality programming and implementation; a plant able to operate as a single entity; automation and IT systems delivered before time and under budget; standard programming methods implemented throughout the plant; and reduced and simplified maintenance."

Jan 1, 2006

By K. E. Barnes

"The “Jameson Cell” flotation cell was developed at Mount Isa Mines in the late 1980’s to address deficiencies in our flotation column installations. Early base metal installations had a variable record. The test work and trials showed they made an improvement metallurgically when operated correctly, but performance of the early installations was hindered by a range of operational and maintenance issues. The installations needed to be more robust, and we needed a better understanding of how to successfully integrate the cells into the plant flow sheet.During the 1990’s, Jameson Cells had great success in coal fines flotation and organic removal in SXEW applications, and became the standard in these applications in Australia. These installations improved the cell design and materials of construction and the cell flow sheet design, to make it low wear with self-regulating control, producing good performance with little operator input.These improvements have enabled a fresh look at the use of Jameson Cells in base metals. Recent new installations have shown significant benefits in “hybrid” circuits, that combine the best features of both Jameson Cells and conventional flotation cells, achieving better overall circuit performance in a smaller footprint than either technology could do by itself.Case studies of successful base metal applications are discussed, using size-by-size mineralogical performance to explain the improved circuit performance. The new methods of flow sheet test work design are also described."

Jan 1, 2006

Optimizing production scheduling in open pit mines is important for managing cash flows of mining operations. This paper describes a new, probabilistic, mixed integer programming (MIP) formulation which has been developed to minimize the risk of not achieving planned production targets, in terms of metal production and ore tonnage feed for the mill during production, while considering maximization of total discounted economic value. The new MIP model also recognizes that to minimize movement of excavators over long distances and accommodate equipment access, the blocks scheduled for mining within a period cannot be spread too widely. The model is applied to a laterite nickel-cobalt deposit, as an example of multi-element deposits that have complex ore quality constraints. The results show that the proposed model generates feasible schedules. When compared with traditional optimization techniques, the new model is superior in terms of minimizing the risk of not meeting production targets, especially at the early stages of production, and in terms of generating practical scheduling patterns.

Jan 1, 2006

By Ju Shao-hua

Although nowadays gold extraction methods are very abundant, none of them is satisfying, especially, in the field of heap leaching of low grade gold ore. The traditional heap leaching method of cyanide method plays an inglorious role of badly environmental pollution. In this paper, a bran-new and innoxious method of gold extraction system, metal-ammonium-chloride-ammonia (MACA), was proposed, and also analyzed both thermodynamically and practically. Thermodynamically, according to the principles of simultaneous chemical equilibrium and electronic charge neutrality, the thermodynamics of Au-NH4Cl-NH3-H2O system was studied by using the exponential computation method and through MATLAB programming, and the solid figure of its potential - c(NH4Cl) - c(NH4OH) was drawn. The results showed when the concentrate of ammonia is higher than 0.6 mol?L-1, fAu+/Au is only about -0.2 v. Practically, the leaching results of a cuprous gold ore showed that the extraction of gold can reach to 80% in this system. The preliminary results of reduction of the rich solution with copper and zinc powders showed that with deoxygenizing, the reduction effects were relatively good. These new findings and results have established a theoretical and practical base for developing a new process for heap leaching of low grade gold ores in this system. And the new process owns a series of merits such as, non-cyanogens, nontoxic, broader applicability.

Jan 1, 2006

By Shae K. Kim

The aim of this study is to manufacture magnesium alloys with alkaline earth metal oxides (BeO, CaO, MgO or SrO) additions with the objectives of (1) ensuring safety during processing and applications by raising the ignition temperature and reducing oxidation, (2) protecting the environment by reducing or eliminating use of protective gases, (3) maintaining or improving elevated temperature properties with lower amount of Ca or Sr or rare earth metals when compared with conventionally developed high-temperature magnesium alloys, (4) developing cleaner strip casting and continuous casting processes without hot tearing and (5) obtaining all of these objectives without sacrificing mechanical properties or increasing the cost of magnesium alloys.

Jan 1, 2006

By A. -I. Abenhaim, I. Sasu, C. Perron, I. Mantegh, S. Larose

Manufacturing long shafts, such as those used in turbine engines, normally involves with drilling inside them in order to take the excessive mass out. Concentricity between the shaft axis and that of the drilled hole is very crucial as it impacts the mass distribution around the axis of rotation. It is important that the shaft mass be well balanced around the central axis in order to minimise the centrifugal forces on the bearings and supporting structure as well as any unwanted vibrations. The eccentricity problem, mostly in long shafts, comes due to machining limitations. It is difficult in long shafts to maintain the concentricity tolerances while drilling inside the shaft. In this work, we address the problem of correcting this eccentricity problem, i.e., when the axis of the inside hole deviates from the central axis. The presented work is based on a threepoint bending method and investigates its effect on the residual stresses and plasticity regions induced on the shaft. A full finite element model is presented that can used to design the solution parameters (bending load, location, etc.) and predict the effect. Limited experimental results are also presented to validate the finite element modelling.

Jan 1, 2006

By W. G. Pariseau

Introduction Caverns of 50 m in linear dimension at depths below 2300 m with a life of more than 25 years are proposed for the next generation of water-filled neutrino detectors. Little precedent exists for excavations in such an extreme environment, although some guidance is available from mining experience at great depths, for example, in South Africa, in Canada and at the former Homestake Mine in the U.S.A. Unlike mining for ore, there are choices available in the construction of such caverns that may mean the difference between success and failure. These choices should be informed by rock engineering principles. Recently proposed guidelines for orientation of brick-shaped caverns where the long dimension is a small multiple of the short dimension indicate that the most favorable orientation is with the long and short dimensions parallel to major and minor preexcavation principal stresses (Pariseau, 2005). Numerical analyses at reduced strength indicate some yielding at cavern walls should be expected but that an equilibrium state is quite possible and is aided by arching the back into a spherical dome when the cavern is an empty cylinder (Tesarik and others, 2002). The same indications of stability occur with brick-shaped caverns. However, the most dangerous situation occurs during the excavation sequence to final cavern dimensions. There are any number of excavation sequences that lead to the same final cavern shape, so there is an opportunity to partially optimize the sequence with construction guidelines that minimize peak stress concentrations during construction. This contribution discusses three practical excavation sequences that lead to the same brick-shaped cavern in the strong, massive Yates formation at the Homestake Mine where considerable rock mechanics data has accumulated through the years(e.g., Pariseau, 1985, Pariseau and others, 1995) and where actual mining on the 8000 Level indicates a strong possibility of successful investment in the next generation of large, deep neutrino detectors. The main results are: (1) a favorable brick-shape is one with dimensions in the same proportion as the preexcavation principal stresses (compressionpositive), and (2) favorable orientation of the most extreme but temporary shape of excavation is also best for the construction sequence. Analysis results from a mix of Homestake Mine data and possible excavation geometry illustrate the advantages of these guidelines.

Jan 1, 2006

By Maria de Campos

The pre-reduction behaviour of chromite particles in methane-argon and methane-hydrogen gas mixtures was investigated between 1050°C and 1250°C. Loose bed of chromite particles were reacted in a vertical tube furnace under a pre-set gas mixture predetermined time intervals. Metallization results were obtained for the Cr and Fe components by chemically analyzing the reaction products. SEM-EDAX techniques and X-ray diffraction were employed to elucidate the reduction mechanism. It was found that higher reduction kinetics and higher Cr:Fe ratios in the metal phase would be achieved when hydrocarbon gas was used in comparison to classical carbothermic reduction at a given temperature. The reduction rate was generally bulk gas mass transfer controlled to the reaction site for initial stages which then was followed by ionic diffusion rate control. It is proposed that methane did not partake directly in the reduction but cracked, presenting the reaction site with hydrogen gas and atomic carbon, which was able to immediately react at the immediate area of reduction regeneration CO and H2 and thus maintaining a low partial pressure of oxygen at the reaction site.

Jan 1, 2006

For Australian mining projects, sustainable groundwater use is typically defined as a groundwater extraction regime, measured over a specified planning time frame, which allows acceptable levels of stress and protects dependent economic, social and environmental values (DEH, 2004). This principle is compatible with most stakeholdersÆ understanding of our national environmental objectives, yet the application of this policy on a project-specific scale is not always straightforward. Three examples of sustainability issues in the management of groundwater in mining are presented. These examples highlight each of the three dependent values: environmental, economic and social.

Jan 1, 2006

By N Lefebvre, M Jakeman, R Aseervatham

Semi-arid regions suffer from two afflictions; evaporation may exceed precipitation by multiples of two or more and variations in precipitation can be both extreme and difficult to predict. Many Australian mines are situated in semi-arid areas where communities are reliant upon locally sourced water or special purpose infrastructure is built as part of the mine construction. As the question of climate change looms, issues related to future water supply and sustainable water management become increasingly important. Across Australia several mining operations co-exist in a single surface water and/or groundwater catchment area. The management of water on a mine by mine or a community by community basis is illogical and must be reconsidered based on a single water catchment and a whole-of-community basis. Mine water should be considered on a full life cycle basis where the quality is assessed for specific mine site applications. This paper addresses technical challenges that include surface water and groundwater supply in semi-arid regions, operational water in the mining industry, beneficial uses of water, water economics and demand management. In much the same way as emissions trading evolved into a multi-stakeholder forum, mining regions offer scope for innovative thinking in water supply and reuse. In addition, this paper considers a number of initiatives taken by Australian mining companies that are entering a prefeasibility stage and contrasts these initiatives against the established success within a South African mining region. The challenges and potential solutions to this initiative are presented for future consideration.

Jan 1, 2006

By A. Ansari

Standard depressants used in the selective separation of copper and molybdenum sulfides by flotation pose environmental and health hazards. In this investigation, the floatability of chalcopyrite and molybdenite in the presence of six well-characterized lignosulfonates was studied through Hallimond tube flotation and adsorption tests. The results define the physicochemical conditions (lignosulfonate type and dosage, pH, presence of ions) for possible selective separation of molybdenite from chalcopyrite. Dissolved polyvalent cations, especially calcium, appear to serve as "activators" for lignosulfonate adsorption on both minerals. From this point of view, the use of lime as a pH modifier is not always appropriate for optimum selectivity since high dosages of lime to produce high pH tend to indiscriminately depress both sulfides.

Jan 1, 2006

By W. Bullen

A hypothetical economic model has been developed for diamond projects in the Canadian Arctic using data from recent exploration and mining projects. The model reflects economic conditions applicable to the diamond mining industry in the Canadian Arctic at the present time. The economic model captures pre-production expenditures, production data, and post-production costs. Before- and after-tax cash flows are derived from the data along with the relevant economic criteria. From the corporate perspective, the model provides guidance concerning the minimum size and/or in situ value per tonne requirements of targets being sought in order to ensure economic success and predict exploration and development expenditures. From the government perspective, the model provides an indication of income and mining tax revenues that can be expected from a particular diamond project. The model shows, on average, diamond projects in the Canadian Arctic are expensive to explore for and develop, but are economically robust under the present conditions. They generate great economic return for mining companies and significant amounts of tax revenue for governments. The fact that diamonds can be transported directly from the minesite by air makes them particularly attractive targets for mining companies that operate in the Canadian Arctic.

Jan 1, 2006

By J. G. Wiese

Reagents are added to the flotation process of Merensky Reef ores to achieve specific functions that enable the separation of valuable minerals from gangue minerals on the basis of the difference in their surface properties. However, due to the complexity of the process, the various interactions that occur as well as the incomplete liberation of the ore and range of minerals present, it is difficult to quantify the behaviour of each of the reagents. More specifically, changes made to achieve a particular outcome may have secondary effects that can override the desired effect. If all the effects and interactions can be accounted for, it is possible to manipulate reagent suites and obtain better overall metallurgical performance. This paper discusses the effect of the addition of copper sulphate at different operating points of the recovery of the sulphide minerals. Batch flotation tests indicated that the recovery of chalcopyrite was not affected when operating conditions were varied, whereas pentlandite recovery was strongly affected by the point of reagent addition, and pyrrhotite recovery was enhanced by copper sulphate addition, irrespective of the point of addition, with the extent being dependent on the ore source. Floatable gangue was activated by copper sulphate in the presence of the dithiophosphate collector. Froth stability was also affected by copper sulphate addition.

Jan 1, 2006

By K. Östcrdahl

We are developing a cost-saving and environmentally friendly process with low energy consumption to recover the metal content and recycle the acid from spent pickle baths. The metals are precipitated as metal fluorides, which can be turned into metal oxides and hydrofluoric acid by thermal hydrolysis. In the proposed process the solution is concentrated by nanofiltration and the metals are precipitated in a subsequent crystallization step. Different nanofiltration membranes have been evaluated in experimental batch tests. The membrane MPF-34 from Koch Membrane Systems offered both good flux and acceptable metal retention even after long periods of acid storage. The solubility of B-FeF3.3H20 has been measured at varying acid concentrations and at different temperatures. The solubility decreases with increasing hydrofluoric acid and nitric acid concentrations. This suggests that the crystallization process should be operated at high acid concentrations. The crystal growth rate of B-FeF3.3H2O is found to be quite low but increases significantly with temperature. This suggests that the crystallization process should be operated at higher temperatures (40 - 60°C). Within the project a pilot plant has been constructed where the spent pickle bath solution is concentrated by nanofiltration to the desired metal fluoride supersaturation, and B-FeF3.3H2O is crystallized in a 10 L continuous crystallizer.

Jan 1, 2006

By S. Minamiguchi

Grain refinement is effective to enhance strength and ductility of metallic materials. However this advantage has not been utilized fully for magnesium alloys in industry because microstructure control through thermomechanical treatment is difficult owing to their poor deformability. The authors proposed a high-speed heavy-reduction rolling for production of Mg alloy sheets. It was found that the deformability is significantly improved at high speed and that the thickness can be reduced 60% by one-pass operation even at room temperature without fracture at the rolling speed higher than 1000 m/min. In this study, commercial AZ31B sheets were rolled at 2000 m/min between room temperature and 350°C, and quenched immediately after the rolling. The sheets rolled at 200°C show the finest recrystallized microstructure with the mean grain size of 2.2 Rm. They show outstanding mechanical properties with the tensile strength of 293 MPa, and the elongation of 25%. It is concluded that high-speed rolling is very advantageous for grain refinement and improvement in mechanical properties as well as deformability and productivity.

Jan 1, 2006

By H. J. Ni, M. Y. Huang, S. W. Chen

The effects of several fluxes on purification, microstructures and properties of A00 aluminium have been studied. The experimental results and analyses indicate that many cracks and large porosities exist in the surface film above the melt purified by C2Cl6 and that the film is floe and mostly composed of AhO3 and pure aluminum, which carries many carbon particles and AlCh not fully volatilized. And then over 50% of the all-melting residue is pure aluminum, which is one of the major reasons for high melting loss. Moreover, because of a mass of gas bubbles and a state of seethe, there exist many inclusions which size is under l0µm in the microstructure of A00 aluminum purified with C2Cl6 or fluxes containing C2Cl6- With this purifying method, the aluminum crystal grains are extended along the radius that was observed firstly and the average crystal size of A00 aluminum are about 100µm~150µm. In addition, small size inclusions have little affected on tensile strength and micro inclusions under l0µm have little affected on elongation.

Jan 1, 2006