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By Thierry Bernard

For many years now electronic initiation has brought the time parameter to the centre of blast designs forever. Although this parameter existed before the era of electronic detonators, Blasting engineers or blasters could not directly handle it; technology imposed it. Only discrete values were available. Today, the fact that we can choose any detonation time for an explosive charge questions the viability of most of the rules applied for blast design. Thus, the very famous charge per delay method, that enables a level of vibration to be forecast at a given distance (“Chapot’s law”), is no longer necessarily valid when using electronic initiation. Therefore, it must be approached in a totally different manner. The KUZ-RAM formula, that allows fragmentation to be forecast, is also subject to the same distortion. The aim of this article is to show how the calculation laws used for blast design are influenced by the time parameter (sequence) and how we can efficiently make the most of this, in particular for vibrations. Copyright ©

Jan 1, 2005

By T. M. Ahmed

Sherritt International Corporation experienced corrosion failures with the 316L stainless steel tubing in a high-pressure still condenser employed for ammonia recovery. A detailed failure analysis was conducted on the condenser tubing to determine the mode and the root cause of the failure. The analysis included both optical and scanning electron microscopy (SEM) of the inner and outer surfaces of the tube as well as characterization of the corrosion products using energy-dispersive X-ray spectroscopy (EDX). Results revealed that the corrosion attack was confined to the first ?100 mm of the tubing at the inlet where the tube was connected to the top tubesheet. The tube suffered both external stress-corrosion cracking (SCC) and crevice corrosion from the shell side (water side), and wall thinning of the inner surface (the tube side) due to erosion corrosion. It was evident that failure of one of the tubes occurred due to SCC that penetrated the whole wall thickness and resulted in a leak failure. Some prevention measures are proposed to avoid this type of corrosion attack in the future.

Jan 1, 2005

By M. J. Steffens

ESPLIM is a novel separation technique that combines the advantages of solvent extraction and electrostatic dispersion but its application in the extraction of nickel by the direct solvent extraction route and the effect of high electrostatic field on the stability of organics have not been explored. These were investigated in this study and it was found that the technique allows 97% extraction of the nickel in a single stage compared with 3 stages by the conventional solvent extraction. Also, three months of exposure to 5.0 kV under simulated operational conditions had no adverse effect on the stability of organics.

Jan 1, 2005

By P J. Harris, C T. OÆConnor

Collectors are used to impart hydrophobicity on particles thus increasing their chances of reporting to the froth phase. Also, the extent to which naturally hydrophobic gangue particles, such as talcaceous minerals, report to the froth can be reduced by the use of depressants. Thus the use of collectors and depressants will directly influence the extent to which hydrophobic particles report to the froth. However these hydrophobic particles will also have a direct effect on the characteristics of the froth phase, more strongly hydrophobic particles causing a reduction in the stability of the froth with the expected concomitant effects on grade and recovery. This study included microflotation (ie frothless flotation) and batch flotation of various ores using a number of different collectors and depressants and a newly developed froth imaging device (SmartfrothTM). Flotation performance was characterised by mass and water recovery, and recoveries and grades of the valuables. This paper shows how the various reagents influenced the behaviour of the pulp and froth phases. The critical importance of managing the type and dosage of reagents used in flotation with a view to optimising their influence on the froth phase is discussed.

Jan 1, 2005

By P. C. Patnaik

Performance of industrial gas turbine engines in terms of power output, reduced cooling and efficiency have been continuously increasing in parallel with aero gas turbines due to the advances made in the development of new materials, protective thermal barrier coatings (TBCs) and the advanced diagnostics to monitor service induced problems such as hot corrosion, thermal and thermo-mechanical fatigue and other operational issues, Environmental attack (hot corrosion or high temperature oxidation) is a common degradation mode in the hot section of the gas turbine, Hot corrosion occurs when Na or K bearing compounds in the environment or in the fuel combine with other contaminants such as S and Pb or V to form corrosive sulphates or vanadates thus attacking the protective oxide on the turbine airfoil, These problems pose far more threat to new turbine engine materials such as directional solidified, single crystals and ceramic matrix composites (CMCs). The CMCs due to their increased temperature capability, when used in the combustion chamber, are likely to reduce the peak temperatures attained during combustion and therefore provide the benefits of reduced emissions of oxides of C and N, These issues will be reviewed critically and their impact will be assessed on gas turbine lives. With respect to alternate fuels, past experience has shown that utilization of residual oils and coal derived fuels in gas turbines have resulted in complex deposition and corrosion processes, In recent years biomass derived alternate fuels have been used either through a gasification cycle or through direct firing of the biomass derived liquid fuel with a view to reduce Green House Gases (GHGs) and improve the climatic conditions. In both cases, the resulting high temperature corrosion processes (in the presence of alkaloids in the fuel) are also very complex, leading to premature removal of hot section components, Technology solutions mitigating these fundamental problems will be reviewed and solutions presented.

Jan 1, 2005

By R W. Wilson, A R. Branch

For hot mines, the use of mechanical refrigeration machines has become an essential feature of ventilation and cooling systems. Over the last 30 years, considerable effort has been made in developing refrigeration strategies and equipment to provide cooling that is cost-effective, reliable and energy efficient. In addition to these general design requirements it is necessary to take into account project specific factors such as long term mine cooling needs, operating strategy and installation time. This paper examines a number of actual mine cooling installations which illustrate how these features have influenced the design and installations. For many mines, it is known how the cooling requirements will increase as the mine develops, based on the life of mine plan. The design of the cooling installation must cater for both short- and long-term needs. The initial installation (to meet short-term requirements) must form an integral part of the ultimate cooling installation and as additional equipment and refrigeration machines are installed, it is necessary to ensure that the system remains cost-effective, reliable and energy efficient at all stages. For many mines, refrigeration machines are installed on surface and either operated near-continuously, or for the summer months only. Different maintenance strategies and policies with regard to standby equipment are highlighted for three mine installations. In spite of developments in cooling strategy, the cost of providing refrigeration remains expensive and many mines delay the introduction of refrigeration, as long as possible. When it is finally accepted that refrigeration is absolutely necessary, it is frequently necessary to æfast trackÆ the installation. To minimise site erection time and meet installation deadlines, factory pre-assembly and standardised modular equipment are widely used.

Jan 1, 2005

By Jewel A. Gomes

Keywords: Electrocoagulation, arsenic removal, fuel cell, windmill, energy simulation, combined Fe-Al electrode assembly Arsenic contamination of well-water in different countries has caused signs and symptoms of arsenic poisoning. Although several physicochemical treatments are presently used for the removal of arsenic compounds from drinking water, an electrochemical treatment, electrocoagulation, is a promising processing technology and currently is the most efficient (above 99% removal) and environmentally friendly technique, particularly if combined with alternative energy sources. Wind and fuel cell technologies can be considered the most promising developmental clean power sources. We will discuss new insights into the materials processing mechanisms and show the coupling of electrocoagulation with fuel cells and simulated wind energy sources. Different electrocoagulation plate materials were considered, along varied currents from the fuel cell to produce maximum arsenic removal. Coupling these technologies will remove carcinogenic arsenic from water sources, and will exhibit efficient usage of these energy sources by producing pure water for human and agricultural consumption.

Jan 1, 2005

By J. M. Ortiz, J. P. Bertini

"In mineral resource and ore reserve estimation, several sources of information are generally available, such as diamond drillholes, reversed-circulation drillholes, and blastholes, and originate from one or more sampling campaigns and are analyzed by one or more laboratories. In such a situation, the grade measurements may not have the same precision and one should distinguish between hard and imprecise data.This work aims at studying the impact of data imprecision in resource/reserve evaluation through two case studies on simulated deposits: a porphyry copper deposit conditioned to real exploration and production data, and a gold deposit simulated without any conditioning data. Several geostatistical techniques are used to estimate the grades of selective mining units from exploration samples, including kriging, cokriging, lognormal and indicator kriging. Two types of imprecision are examined— measurements with multiplicative errors and measurements defined as intervals. The results are compared to the simulated grades of the selective mining units from a statistical and economic viewpoint.The study concludes that imprecise measurements should never be discarded because they help to improve the estimates, and that simple methods such as kriging are as efficient as more sophisticated ones for resource/reserve assessment. Finally, a few indications on how to diagnose and model the data imprecision are given."

Jan 1, 2005

By M Darby, B Burdett, F Lovell

The results of the process control improvement project aimed at improving the quality of Australian Bulk MineralsÆ (ABM) iron ore pellets produced by four vertical shaft furnaces are very positive. These results are achieved through process stabilisation and optimisation, improvement in process monitoring and taking early corrective actions when operating variables were outside the target ranges. A number of benefits are obtained from this project. These benefits include: More consistent and improved pellet quality. The average cold compression strength (CCS) value of pellets produced during the eight-month trial is 260 kg/pellet, which is 16 kg/pellet higher than that produced during the 12 months prior to the trial (244 kg/pellet). Reduction in the heat input by eight per cent, from 727 MJ/tonne to 668 MJ/tonne. Reduction in bentonite rate by six per cent, from 7.1 kg/tonne to 6.7 kg/tonne. Increase in the furnace throughput rate by four per cent and additional production of 10 000 tonnes per annum through process stabilisation. Better understanding of the process behaviour. This knowledge is valuable not only for setting the target operating conditions but also for developing the ABM expert system to control the process.

Jan 1, 2005

By R Dunne, D Yan

In flotation where a bulk flotation concentrate is produced or a gangue sulfide such as pyrite contaminates a concentrate, residual collector has to be removed from the sulfide surfaces to allow selective separation in a subsequent flotation step. Depending on the sulfide mineral, the main species that needs to be removed when using a xanthate collector is either a metal xanthate or dixanthogen. For the identification of surface species, specific solvents may be used to remove each species û metal xanthates are known to be soluble in acetone whilst dixanthogens are known to be soluble in non-polar solvents such as diethyl ether. Xanthates break down with time, temperature and pH into various decomposition products. The major decomposition product is dixanthogen which can aid flotation but other products such as perxanthate and carbon disulfide can have an adverse effect on flotation. Various analytical techniques can be employed to monitor the formation of decomposition products on the surface of the mineral and in solution. The best of these is ultraviolet spectroscopy as it has diagnostic peaks for decomposition product determination. In this work two approaches were taken to understand the relationship between the flotation of a chalcopyrite and pyrite from an ore containing these two minerals. One approach was to remove the xanthate species with an organic solvent and then use ultraviolet spectroscopy to determine the concentration of dissolved species. The second method involved measuring xanthate decomposition in solution by measuring the residual xanthate concentration using ultraviolet spectroscopy. These experiments confirmed the species adsorb at the surface of the mineral and how these species affect the recovery and grade of the valuable mineral. In both cases pH and temperature were varied and two xanthate collectors (SEX and PAX) were used to study these relationships. These relationships could be applied to industrial flotation systems and allow for more accurate determination of optimal xanthate dosage and hence save on reagent costs.

Jan 1, 2005

By K Hortin

Kidd Creek mine in north western Ontario is developing phase 1 of the deep mine project for mining between 2100 m and 3100 m below surface. Heat problems were experienced during the 2003 summer in working places about 2300 m below surface. At the time the mine had a æcold stopeÆ for cooling the air supplied to the mine below 1500 m from surface. The æcold stopeÆ is where during winter, ice is created in both the open pit and its connecting airways to the mine and used to cool air in summer. The operation and limitations of the existing cold stope were evaluated and led to the requirement for additional mechanical cooling to be available for the summer of 2004. The first stage of a surface refrigeration plant providing 7.5 MWR of cooling was approved, the compressor set was ordered in early January 2004 and the plant commissioned six months later in early July 2004. Based on the current modifications to the mining plan, further plant expansions are required in 2006 and 2009 leading to a total of 19 MWR of mechanical refrigeration and 8.5 MWR equivalent from the extended cold stope. The refrigeration system is described with emphasis on the specific adaptations necessary to suit Canadian conditions. Additional investigations were; using the refrigeration compressors in winter for heating and, extending the performance of either cold stopes or alternative ice storage systems. The winter use of refrigeration involve removing heat from the mine exhaust air to provide a cooling load and to use the hot water in the condensing circuit to heat the intake air and reduce reliance on mine air heating with natural gas. This paper follows on from an earlier one presented at the Seventh International Mine Ventilation Congress where the background and planning of the mine ventilation and cooling requirements were described for extending the mine at depth to 3100 m.

Jan 1, 2005

By D A. Deglon

Solids suspension is important in the design and operation of mechanical flotation cells, and is a necessary precondition to particle collection. Most of the fundamental hydrodynamic research that incorporates some aspect of solids suspension was done by Arbiter, Harris, and co-workers, or Schubert and co-workers. However, a need for research into solids suspension in mechanical flotation cells exists, since very little has been done since the late 1980s; a time that also coincides with the advent of round mechanical flotation cells and the subsequent dramatic increases in maximum flotation cell sizes. In this work, concentration profiles and critical impeller speeds, Njs, were measured in a 0.124 m3, round cell fitted with a 0.150 m, Bateman impeller mechanism. Two solids size fractions (75 - 106 and 150 - 250 ¦m) were tested, in ungassed and gassed conditions (JG = 0, 1 cm/s) and at various impeller speeds (300 - 900 rpm). The effectiveness of solids suspension was quantified in three ways in terms of extent of off-bottom solids suspension, suspension height (extent of solids distribution), and variation within the solids distribution, which together present a complete quantitative picture of solids suspension and distribution within the cell. Consistent trends were found when these effectiveness criteria were considered against relative impeller speed, in terms of percentage of critical impeller speed, N/Njs. Off-bottom solids suspension is complete at or above 100 per cent of Njs, with significant sedimentation occurring as the impeller speed drops below 60 per cent of Njs. Suspension heights consistently reached a level equivalent to 90 per cent of the tank diameter at the critical impeller speed, and dropped off significantly as N/Njs dropped below 60 per cent. The variation in the solids concentrations within the sampled profiles showed consistent trends in two-phase but not under three-phase conditions. The paper concludes that the critical impeller speed, Njs, commonly used in the design and operation of standard stirred tanks, is a very useful solids suspension benchmark for describing all aspects of solids suspension in mechanical flotation cells and should be correlated to system conditions.

Jan 1, 2005

By Y. M. Shneerson, E. E. Zhmarin, E. M. Vigdorchik

One of the Gipronickel Institute activities is research and development of customized leaching technologies. The work is performed in several steps. Leaching kinetics are studied on a lab-scale according to a special procedure. Experimental data are processed using mathematical models of batch and continuous processes. Reliability of kinetic data and preliminary calculations is verified experimentally in laboratory reactors of various capacities. If necessary, certain parameters of the mathematical model are adjusted after pilot plant tests in continuous mode ( 4-reactor train, each with 25 L capacity). The specified kinetic characteristics along with the mathematical model are used for further development of industrial leaching technology.

Jan 1, 2005

This paper investigates the adequacy of current gas monitoring techniques to adequately detect spontaneous combustion in underground coalmines. Despite being in the 21st century spontaneous combustion continues to occur in underground coalmines sometimes being detected only at a very advanced stage. Control of the incident is often then very expensive and time consuming. The adequacy needs to be assessed not only from the point of view of the analysis technique be it tube bundle, gas chromatograph or real time sensor but also the number, location and sampling frequency of the monitoring locations. Recommendations are made to optimise monitoring processes and recognise limitations of current techniques.

Jan 1, 2005

This paper presents a review of heat illness in mining, including reference to several recent investigations by the author. Heat illness is a collective term, covering the conditions of heat stroke, heat exhaustion, heat cramps and miliaria rubra. Heat stroke is life-threatening and is by far the most serious condition. It is rare in mining, if appropriate control measures are instituted. Heat exhaustion is primarily due to hypohydration, following prolonged sweating in hot conditions. Symptoms include fatigue, headaches, dizziness, anorexia, nausea, vomiting, shortness of breath, or brief syncope. Confusion, ataxia, prolonged unconsciousness or convulsions are strongly suggestive of heat stroke. Heat cramps are painful involuntary contractions of skeletal muscle associated with work in hot conditions. The limbs are usually involved and the spasms typically last a few minutes, during which the affected part of the body is incapacitated. Heat cramps tend to occur in heat exhaustion, when hypohydration becomes marked. Miliaria rubra is a skin rash caused by extravasation of sweat into the skin, as a result of obstruction of the sweat glands. It occurs after prolonged and profuse sweating in hot environments. It can take three to four weeks of sedentary duties, in an air-conditioned surface environment, for the condition to resolve. Heat illness would be unlikely in underground mining, if the thermal environment was sufficiently well controlled by ventilation and refrigeration. This is however, often not practicable. Where engineering controls alone cannot provide sufficient control of risk, the residual risk can be assessed using an appropriate heat stress index. While procedural controls may further reduce the residual risk, it is important to remember that these are less reliable than engineering controls and cases of heat illness may still occur. Procedural controls include the application of heat stress limits, education, hydration, self-pacing, early symptom reporting, medical advice, acclimatisation procedures, air conditioned accommodation, support to achieve a healthy body mass index, and an effective emergency response capacity.

Jan 1, 2005

By A. Ghasemi

An alumina-silica coating was deposited on a nickel substrate by sol-gel process, and the structures and composition were evaluated, The sols were made from aluminium and silicon alkoxide, and an acid catalyst including HCl, To produce adherent silica coatings on nickel, various additives such as surfactant, viscose additive and drying control chemical additives were introduced to the system, and appropriate drying and firing cycles were applied after dipping in solution. The hot corrosion and oxidation resistance of the coating at different temperatures were investigated, The structure and uniformity of the coatings were examined by scanning electron microscopy (SEM), The results indicate that a uniform coating of alumina silica can be produced on a nickel substrate by optimizing the composition and process variables of the sol. Coatings can protect substrates from oxidation and hot corrosion at different temperature up to 1000°C, but is not very effective for hot-corrosion resistance at 1000°C.

Jan 1, 2005

By Miguel E. Ruiz, America L. Fernandez, Miguel A. Pandon

"Post-grouted drilled shafts (PGS) are a deep foundation system in which grout is injected at high pressure throughout the tip after the drilled shaft has been installed. Pressure grouting of drilled shaft tips can significantly increase the ultimate capacity and stiffness of drilled shafts. Conventionally constructed drilled shafts usually require higher axial deformation to develop the available side friction and the tip resistance simultaneously. They also tend to have higher tip compressibility and reduced end bearing capacity due to disturbance at the bottom of excavation during drilled shaft construction. PGS foundations have been found to be a cost-effective solution to compensate for this capacity reduction and/or compressibility increase. PGS construction procedure counterbalances tip compressibility and end-bearing capacity reduction. The tip grouting also has a pre-stressing effect over the shaft side friction since the drilled shaft tends to move upwards during the pressure grouting of the tip. After grouting, a bulb tends to form at the pile tip pre-compressing any disturbed material and, in certain cases, increasing the tip area, thus increasing shaft tip capacity.PGS load-settlement predictions using a load transfer approach are presented in this paper and compared with corresponding load test data. The paper also presents the main findings of load transfer analyses that were carried out to investigate the potential different factors that may be contributing to the observed improved performance of PGS over conventional drilled shafts. Results show that the two main factors, that may have a significant contribution on the overall performance of the foundation by increasing its ultimate capacity at any given level of settlement, are the stress-reversal of the skin friction and the formation of a grout bulb at the tip. The grout bulb tip contributes primarily through the increased tip area and to a lesser extent through increased stiffness and strength of the soil in the vicinity of the pile tip."

Jan 1, 2005

By P. D. Katsabanish

Air decking applications are examined using numerical modelling and the AutodynTM code. The mechanism of damage is illustrated and discussed. Air decking is shown to provide advantages over stemming when powder factor is maintained. The current effort does not support reduction of the explosives column in favour of air decking. In a similar fashion, bottom hole air decking increases fracturing in the area of the air deck, compared to when the same volume is occupied by inert materials; however air decking does not appear to reduce the requirement for subdrilling. The apparent discrepancy between the numerical results and some field observations reported in the literature is discussed.

Jan 1, 2005

By Daniel A. Thome, Robert C. Janke

"Installation of permanent soil nails through distressed mechanically stabilized earth retaining walls is a cost effective and aesthetically pleasing solution when using the appropriate equipment and drilling methods for installation. A forensic investigation was performed on an existing mechanically stabilized earth retaining wall to determine the possible causes for the excessive horizontal displacements and visual structural flaws found along a portion of the wall. Reports concluded that the visual shifting was due to a number of factors including improper drainage in the vicinity of the wall and unsuitable compaction of the backfill material. Conceptual designs were proposed to the owner and the installation of permanent soil nails through the existing precast panels was determined to be the most practical solution. A total of ninety-three permanent soil nails were installed to lengths of up to 40 feet (12 m) through sand backfill and silty day fill using a hydraulic rotary percussion drill attached to a tract mounted excavator.IntroductionThe Illinois State Toll Highway Authority awarded Contract RR-03-5144 in the summer of 2004. Construction work for the project consisted of the rehabilitation of two existing concrete culverts and approximately 100 linear feet (31 m) of mechanically stabilized earth (MSE) retaining wall. The retaining wall is located below the southbound lanes of the Tri-State Tollway near the intersection of Federal Highway 41 in Wadsworth, Illinois as shown in Figure 1.Reports were prepared by Applied Technologies in cooperation with Giles Engineering Associates to determine the condition of the MSE wall and recommended conceptual designs to extend the service life of the wall.Nicholson Construction Company (Nicholson) wasselected as the design-build geotechnical subcontractor to install the recommended permanent soil nails through the existing precast concrete panels of the MSE wall. Rehabilitation of the wall involved the installation of ninety-three permanent soil nails through the existing wall, along with soil nail verification tests and proof tests on production nails."

Jan 1, 2005

By R S. Sing, M D. Yadav, G Udaybhanu

This paper presents the results of the first part of a research project to study the effect of various inhibitors to reduce the spontaneous heating susceptibility of some highly susceptible Indian coal seams. In this investigation 11 inhibitors were chosen and applied at three, five and ten per cent of their concentrations in an aqueous solution for four coal samples collected from four different seams. The susceptibility of coal samples, before and after application of these inhibitors, was determined by carrying out crossing point temperature (CPT) analysis. The findings of this study have indicated that it is possible to retard the tendency of spontaneous heating of Indian coals to a considerable extent by the application of six of the inhibitors studied. Further, these inhibitors were tested in 1:1 combination to study their synergistic effect. Finally the economics of the application of these inhibitors has been analysed and four inhibitors are recommended for field use. These results have direct application to control fire and improve productivity and safety in coal mines.

Jan 1, 2005