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When selecting a method for monitoring crack growth in pipeline steel, the sensitivity or crack-size resolution plays a dominant role. Even though there are several visual and non-visual methods, the direct current potential drop (DCPD) method is very effective for monitoring crack growth because of its resolution. This method has been used for the past few decades and has gained increasingly wide acceptance in fracture research as one of the most accurate and efficient methods for monitoring the propagation of cracks. Furthermore, most R&D experience has proven that the electrical potential method can be used in most "aggressive" environments. For these reasons, the DCPD method was selected to design a testing machine to monitor corrosion fatigue crack growth. The use of finite-element modelling is shown to facilitate the application of the DCPD method for monitoring crack growth in steels. The 2D model calibration provided a good description of the test data and proved more accurate than the analytic Johnson's formula.

Jan 1, 2005

By Kwang ‘Min’ Kim, Paul T. Behum

The Old Bevier Aerobic Wetland in Macon County, Missouri, was constructed between 1990 and 1991 by the Missouri Department of Natural Resources’ Land Reclamation Program for the purpose of treating acid mine drainage (AMD). The principal source of the AMD is from an underground mine that operated during the 1920's through 1950's, which was partially exposed during surface mining in the 1960’s. Limestone bedding of an AMD collection system provided alkalinity similar to an anoxic limestone drain (ALD). Because the original aerobic wetland failed when a critical dilution water supply became unavailable, the total acidity of the AMD overwhelmed the limited neutralization ability of the aerobic wetland. The aquatic vegetation deteriorated and treatment became ineffective. The Missouri Land Reclamation Program with the assistance of the Office of Surface Mining, Mid-Continent Regional Coordinating Center rehabilitated the Old Bevier Aerobic Wetland in 2001, incorporating newer technologies to improve the performance. The new system, Old Bevier II treatment facility, consists of a 2-stage vertical flow pond (VFP) with associated oxidation cells and aerobic wetlands. This paper discusses the performance of this passive AMD treatment system, updating an earlier report. The new treatment system has operated with nearly continuous net alkaline discharge and a high iron removal rate. Treatment improves during warm months when emergent vegetation is fully established and biologic activity is greater. Reduction in system efficiency is evident during winter months.

Jan 1, 2005

The homologous series of saturated fatty acids investigated in this study generally show a steady gradation of properties with chain length. The solution pKa values were assumed constant at 4.9, however reported pKa values could be lower or higher. Hematite flotation response and surface pressure for aqueous solutions of these fatty acids were measured as a function of pH. For the shorter chain fatty acids, the undissociated acid was shown to be the predominant surface active species with flotation, supplemented by the physical adsorption of acid anions as the chain length increased. The reduced solubility of the longer fatty acid carbon chains made these reagents ineffective as flotation agents. The maximum flotation response of hematite using tetradecanoic acid corresponded with the precipitation edge of the reagent. The results show that the values of surface pressure of the surfactants are not always a good indication of their effectiveness as flotation collectors.

Jan 1, 2005

By S. Kariyawasam, R. McNealy

Pipelines are subject to multiple threats often requiring quantification of pipeline risk and engineering evaluation of in-line inspection and other data to effect discovery of conditions defined by the regulation. Public concern and pressure from regulatory bodies are accelerating the need for pipeline operators to formalize and intensify their approach to integrity management. Most operators need a phased approach to progressively adopt the most relevant and needed assessments. The organized and relevant assessment steps need to be introduced according to data available and maturity of the integrity management program. Each refinement to the quantification offers distinct advantages to the user. In this paper, the progressive integrity assessment solutions using quantitative methods are presented. Methodologies for engineering evaluation of integrity in-line inspection data for immediate and future integrity are summarized. Corrosion is used as an example, but the approach is applicable to any time-dependent defect based hazard. Strategies for pipeline integrity management are discussed.

Jan 1, 2005

By Xianxin Shi

In surface electrical exploration the high resolution earth resistivity method (HRRM) is a very effective method for detecting abandoned drift mines workings. When the abandoned mines are more than 500 ft (150 m) deep, its detection capability reduces greatly and requires more effort to implement. In Yan Quan coal mine, Shanxi province, we tried to adapt this method for underground application. Two survey lines were designed with the spacing of current and potential poles 20 m and 10 m, respectively and measuring points at 2m. The measurement radius of I line and I1 line were 140 m and 60 m, respectively, and the infinitely far pole was 1200~2000 m from the survey line. (Note the I and II lines are located on the north and south ribs of main tunnel, respectively). The survey results showed that abandoned workings were located at 25-70m, Survey Line I and at 80-1 10m, Survey line 11. Based on this finding, the longwall panel gateroads and set up entry were properly located thereby providing safe mining of the No. 15 Coal seam. Key Words: Abandoned coal mine, High resolution earth resistivity, Underground electrical exploration

Jan 1, 2005

Safety and health at work is about people. It is about people who plan for work, organise work and perform work. It is about those who come in contact with the workplace and those who are responsible for the workplace. There are wider ranging safety and health obligations that are imposed on the industry stakeholders that span all phases of the production process. In all cases, those responsible for discharging the obligations must ask the questions: Is what we propose safe?, can it be done safer? and are we sure? What we learn from recent legal cases before the courts is that it is essential that all stakeholders work together in a collaborative way when discharging these obligations. Safety and health at work cannot become an issue that is viewed only through the eyes of a single stakeholder group. The reason for this is quite simple. The interrelatedness of the responsibilities that are imposed on each of the stakeholder groups, means that the performance based legislation simply wont work, where an active model of communication and consultation is not in place.

Jan 1, 2005

By D. Bessinger, J. Nell

The electrical conductivity of rutile was optimised as a function of time, temperature and gas composition. These optimised conditions were used to treat rutile/zircon feed prep concentrate samples from a South African heavy minerals producer, prior to electrostatic separation. Enhanced separation between rutile and zircon was obtained when compared to untreated samples. Samples treated in a hydrogen atmosphere and cooled in nitrogen showed the best separation when passed through a high tension electrostatic separator using conditions of high sample temperature and high relative humidity.

Jan 1, 2005

By J. J. Jonas

The categories of interpass time encountered in hot rolling are characterized. These are shown to fall into three broad categories: short (in rod rolling); intermediate (in strip processing); and long (in plate schedules). The effects of interpass time on recrystallization and carbonitride precipitation are described, and particularly on the interaction between these two mechanisms. The interactions, in turn, determine the final microstructure produced as well as the mechanical properties.

Jan 1, 2005

By D Mcleod, S Brindley, S Green

The design and engineering of flotation circuits is driven by numerous inputs, including (in no particular order) testwork outcomes, site considerations, type of separation required, energy sensitivity of the flotation response, personal experience and preference for flotation machines, maintenance access requirements, operability, level of automation and capital constraints.This paper discusses these and other issues in the Australian context and covers the flotation of copper/gold ores and polymetallic (copper/lead/zinc) ores. The paper discusses aspects of the following: how should testwork be done and what are the important inputs and outcomes? how should testwork results be interpreted and how does this impact on equipment selection? what processes can have a critical impact on flotation circuit performance, eg thickening and regrind? what options are available with the typical æflatÆ Australia site? how do you minimise capital cost and what impact can this have on flotation circuit operation and maintenance? how should circuits be controlled and operated? Particular focus is placed on some practical aspects of process design and engineering and the potential impact that engineering decisions can have on flotation plant operation.

Jan 1, 2005

By Hyunsuk Yoon, Kiho Lee, Juhyng Lee, Younghoon Jung, Junboum Park

"The environmental double pile method is presented as a device to improve the engineering properties and to clean up contamination of low-permeability soil. This method is one of the novel technologies based on the concept of one step process. It can be applied to low permeable contaminated ground for site reuse. It uses piles to improve drainage, contaminant remediation, and bearing capacity of the ground. To evaluate the on-site applicability of this technology, drainage and strength properties of the environmental double pile were assessed by a series of experiments and numerical analysis. Environmental double pile was found to be a feasible alternative method to improve contaminated soft ground.Korea is a peninsula with many coastal industrial zones. These zones are located in regions mostly underlain by soft ground with low permeability and adjacent to industrial areas that can be contaminated. Therefore, a new region-specific remediation method is required to achieve environmentally sustainable development. This research introduces the Environmental Double Pile (hereinafter, refer to as EDP) for the lowpermeability contaminated ground and focused on both contaminant remediation and soft ground improvement. Basically, the EDP is quite similar to sand compaction pile (SCP). The SCP has been studied extensively to improve soft ground (Braja 1999; Hansbo 1994; Madhav and others 1978; Taylor 1948). But unlike SCP, EDP is filled with oyster shells instead of sand and an inner pile is inserted in the center of this oyster shell filled-zone. Therefore, it is a double pile consisting of the oyster shell pile and the inner pile, as depicted in Fig. 1."

Jan 1, 2005

By Tom George

"INTRODUCTIONNo. 1 Queens Rd was an existing 10-storey office building founded on large pad footings. This project involved the construction of a 6-level, 15m (50-ft.) deep basement excavated immediately adjacent to the existing building and also beneath the existing footprint of the Southern end of the building. The total perimeter of the new basement was to be approximately 200m (656 ft.) all with a retained height of 15m (50 ft.). It was also proposed to add a further 5 storeys to the building. Approximately 18 of the existing columns supporting the 10-storey building were to have the applied column load diverted from the existing foundations at ground level onto the new piles or basement raft 15m (50 ft.) below.The geotechnical profile consisted of fill for the top 1.5m predominately comprising of clayey sand with a high gravel content from 1.5m to 9m (5 to 30 ft.), a medium dense to dense clayey sand and then below was a sandy clay extending to 15m (50 ft.) ranging from stiff to very stiff. From 15m on completely to extremely weathered siltstone was encountered. The groundwater was measured at 9.5m (31 ft.) below the natural ground surface.DESIGN BRIEFThe existing building columns were founded on large pad foundations up to 4.4m (14.5 ft.) square, founded on the dense clayey sand. These pads would require temporary support to enable the excavation to proceed beneath them. Upon completion of the excavation under the pads new columns were to be constructed joining into the existing columns to transfer the load onto the new raft slab, 15m (50 ft.) below. The existing 10 floors were to be refurbished. It was planned to undertake all the temporary support and transferring of loads while the structure above was only able to provide a dead load. It was decided that any movement of the building would have minimum impact on a skeleton structure. During the temporary support of the columns, movements due to construction activities had to be monitored to understand any potential stresses in the structure above.The original design required beams to be installed under the pads and supported at either end by temporary piles that were to be founded below the level of the proposed excavation. (Refer to sketch 1). Wagstaff Piling considered that this methodology had difficulties in construction at all stages and did not provide facility for transfer of the load without significant movement of the structure above. Wagstaff Piling revised the design to attach beams to the columns above the pads using shear collars. (Refer to sketch 2). These beams supported on the temporary piles could then be jacked upwards to remove loads off the pads. This would enable removal of the pads with minimal movement of the 10-storey building above. (Refer to photo 1 and back cover photo)."

Jan 1, 2005

This report will differ slightly from the traditional scientific and technical discussions given at this type of conference. It will focus on the personal experiences and choices that I undertook when deciding on my graduate position and location after completing university studies. Throughout the duration of my course I had experience in both fly-in, fly-out operations in the Pilbara and residential operations in the West Australian Goldfields. These experiences, though limited, allowed me to explore the two different methods and their pros and cons, and consequently to make my choice for graduate employment. Throughout the duration of my degree I believed it was important to gain a basic understanding of the two methods, focusing on lifestyle and personal interactions. The decision that a residential site suited my personality and lifestyle then allowed me to refine my job applications to a more specific list of mine sites and companies, resulting in a residential position with BHP Billiton at their Iron Ore operations in the Pilbara, Western Australia.

Jan 1, 2005

By C McInnes

The key to successful flotation plant design, production planning and mine/mill optimisation is a solid understanding of the resource to be processed. As advocated by the authors of this paper, the main components of geometallurgical modelling of an orebody and its associated flotation plant are: an ore sampling program and subsequent laboratory testing of these samples in order to extract process model parameters; geostatistical distribution throughout the resource model of the process parameters; calibration of the plant via benchmarking (for existing operations); and plant simulation using a system of process models and the distributed metallurgical parameters (from step two) as the data set.It is important that the grinding and flotation models are linked. For example, a laboratory test conducted on a drill core sample, intended to represent a portion of the orebody, is conducted at a specific grind (represented by a P80). However, when that ore is actually processed through the plant it may well be (and in many cases most likely will be) at another P80. Additionally, the flotation plant residence time will often be determined solely by the grinding circuit capacity and feed slurry density. In the case of SAG mill û ball mill circuits, the fluctuations in tonnage and grind are known to be high. The modelling approach described in this paper allows for changes in the measured flotation kinetic parameters in order to reflect the expected grind as determined by the comminution process.

Jan 1, 2005

By Y. Feng

Perovskite structured oxide 15% Y-doped BaCeO3 (BCY15) has been evaluated for use as proton conducting electrolyte in SOFC with propane as the fuel and Pt as both electrodes. Under the fuel cell conditions, BCY15 exhibited high proton conductivity and good cell performances. Propylene was detected as product at the anode outlet, and the product distribution suggests that propane dehydrogenation underwent competition with cracking to lighter hydrocarbons. Stability during cell performance tests showed that there was no obvious degradation for BCY15 electrolyte during operation of C3H8-O2 fuel cell.

Jan 1, 2005

By S. A. Jacob

Magnesium sheet is notoriously difficult to form at low temperatures without initiating failure, In the present work cold rolling and annealing conditions are varied to produce samples of AZ3lB sheet with a range of grain sizes. The formability of these samples is investigated using tensile testing and forming limit diagrams (FLD's), The results are discussed in terms of twin types and frequencies.

Jan 1, 2005

By A. Plumtree

The morphology of environmentally assisted cracks in stressed pipeline steel has been investigated. For a dilute and neutral solution (NS4) simulating ground water in contact with the steel, semi-elliptical cracks grow faster on the surface (2c) than in the depth (a), hence, the aspect ratio (a/c) decreases. This is explained using a deterministic concept since corrosion is dominant and the primary constraint is the conservation of charge. By contrast, when mechanistic conditions prevail, significant growth occurs in the depth. When underloads are imposed in the loading history, temporary accelerations in crack growth occur because corrosion rather than mechanical effects become dominant.

Jan 1, 2005

By Vivian M. Troughton, Clifford J. Wren, Tony P. Suckling

"Secant pile walls are used for the construction of deep basement walls and earth retaining structures. Risk associated with secant pile walls is commonly perceived as being the safety of site personnel and the public during piling operations, or safety used in design. It is recognized that both of these are of paramount importance, but additional risks associated with the construction methods must also be considered to complete the risk management profile for any project. For the particular case of secant pile walls, if Clients take a ""back seat"" they may be unaware of the total risk package they are procuring. The authors argue that the piling contractor should be involved at the earliest stage giving input into the overall risk management process. Such early involvement within the professional team will maximise cost benefits to the Client and minimise the delays and cost increases sometimes associated with these works. A consistent methodology for identifying and then managing all the risks associated with secant pile walls is proposed. An example is used to demonstrate how this methodology should be employed. INTRODUCTIONThis paper discusses the value of a complete and integrated risk management process for structures with basements formed using a secant pile wall.The risk associated with any secant pile wall can be consicfered as comprising four components;1. Safety of people on site2. Safety of design or design methodology3. Construction risks4. Commercial risksAny risk management system needs to fully consider and integrate each of these four components to maximise the likelihood of a successful outcome for the basement.This paper concentrates on the construction risks for secant pile walls, as these are not often understood by the Client (in this paper the term ""Client"" also includes the main contractor, principal contractor, Engineer, Planning Supervisor, quantity surveyor and cost consultant)."

Jan 1, 2005

By B. Andreaus

In spite of tremendous efforts in research and development of polymer electrolyte fuel cells (PEFCs), essential properties of the actual catalyst material, supported Pt or Pt-alloy nanoparticles, are not yet well understood. Fundamental understanding of the catalyst structure and the prevailing kinetic mechanisms is, however, of utmost importance for further progress. In the present study, we investigate catalyst activity for CO oxidation from a theoretical point of view. Electrochemical CO oxidation serves as an important test reaction for the study of the fundamental properties of supported Pt nanoparticles. Recent experiments have revealed strong effects of catalyst particle size and supporting material on catalytic activity. It was found, that the activity towards CO oxidation decreases significantly when the particle diameter drops below 2.5 nm. We perform kinetic Monte Carlo simulations of CO oxidation on supported catalyst particles to elucidate this particle-size effect. The simulations are based on the active site concept, highlighting the role of active site formation and finite surface mobility of adsorbed electroactive species for catalyst activity. For comparison with experimental results, potential step experiments were simulated. The Monte Carlo simulations consistently reproduce effects of particle size and electrode potential found experimentally. In comparison with our simulations, analytical mean field models and nucleation and growth models exhibit inferior agreement with experimental data. In summary, our findings support an oxidation mechanism via active site formation. The reason for the slow reaction kinetics on catalyst particles with diameters below 2.5 nm is a rather low CO surface diffusivity. The rates of active site formation, diffusion and CO oxidation via recombination with adsorbed OH can be determined from the simulations.

Jan 1, 2005

By V. Prodanovic, M. Militzer

Production of advanced linepipe steels with strength levels of 685MPa (100ksi) and higher requires excellent control of runout table cooling to produce the desired final fine-grained microstructures, which may include acicular ferrite. Cooling is exerted on the runout table by applying water jets onto the hot surface of the strip and heat is removed from the steel by forced convective boiling. The associated boiling mechanisms are complex and include film, transition and nucleate boiling. A pilot-scale runout table test rig has been built to systematically study boiling heat transfer from a moving steel plate by employing industrial scale headers. Experiments were conducted using test plates moving at speeds between 0.3 m/s and 1.4 m/s. The plates were cooled down from 850°C to temperatures below saturation by a single water jet supplied through an industrial size circular nozzle. Based on these experiments heat fluxes were determined and further used to develop improved runout table cooling models.

Jan 1, 2005

By S K. Ray

Open fire in a mine gallery causes large-scale damage to property and sometimes precious lives. Such fires produce two distinct effects, the throttle effect and the buoyancy effect. These effects disturb the ventilation system of the mine. To understand the complex dynamic phenomenon of open fire and its effect on ventilation systems, a mine fire model gallery has been designed and constructed at Central Mining Research Institute, Dhanbad. Two sets of experiments at air velocities of 1 and 1.5 m/s were conducted in the gallery using coal samples from the Dobrana seam of the Raniganj coalfields. After about an hour of development of fully-fledged fire, heavy backlash, with smoke and fumes, was observed. At the time of backlash occurring the gallery was divided into two zones. In the region of the gallery from the base up to 1.4 m the airflow was normal, in the remaining upper portion the airflow was the reverse. Air quantity reduced substantially, while pressure dropped across the fire zone, the products of combustion (POC) and temperature increased during the period of the throttle effect. It has been revealed from these studies that with an increase in airflow, pressure drops across the fire zone, POC, temperature and reduction in airflow increases. This paper addresses the important design features of the gallery, the instrumentation system, the experimental procedure and assesses the effect of open fires on mine ventilation systems.

Jan 1, 2005