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By D. E. Cameron

"INTRODUCTION Grade control requirements for base and precious metal projects are an important input to both conceptual and feasibility mine plans. It’s the author’s experience that grade control input is insufficient at these critical stages. The few exceptions are a stimulus for this paper. A significant portion of CRC’s practice has involved assisting operations to solve grade control issues which were finally recognized as contributing to negative production variances. Even in operations perceived to be successful, deficiencies in grade control are often masked by measures taken by an operation to compensate a deficiency in one area with outperformance in another. The advantages in having a realistic and adequate grade control plan developed at an early project stage by a geologist(s) with considerable operations experience are manifold. It’s important for the geologist to prepare clear inputs into the mine plan backed by detailed supporting information in usable, flexible formats. When the decision is made to advance a project, the exploration team passes its model to a mine planner. The team doesn’t usually provide a detailed grade control plan with the block model, thus the planner tends to treat grade control as an activity to be rolled into a broader operating category. The consequences of highly compartmentalized mine planning can be severe in the long run. Once a plan is tabled, and especially once production begins, it is very difficult to improve grade control outside the fixed parameters of the operation. Major fixes tend to be costly in terms of time and dollars. Implementing needed changes to the grade control practices and culture in an established mine can present almost insurmountable difficulties. Hypothetical examples of grade control planning are presented to illustrate the author’s points. The diagrams are conceptual and schematic; any resemblance to actual deposits is coincidental. BEYOND 50¢/TON In more than a few cases, grade control cost is buried in a subcategory of mining cost with little more consideration than a plugged number. It is possible to do a word search in 43-101 Technical Reports on advanced projects and without finding reference to “ore control” or “grade control”. The idea is to reach the orebody by the shortest and least expensive means, achieving production and investor payback at the earliest possible occasion. This entails a low stripping ratio pit or a decline ramp with sills on ore to prepare the first stopes. The processes to achieve the target production, one of which is grade control, will fit into this framework. After all, there is a block model and the planner can see the grade and tons in each block. The exploration geologist whose responsibility was to bring a large percentage of the deposit into mineral resource owns the model and has released it to planning. Now comes the planning stage. Mine geologists haven’t been hired yet and they will be phased in with production. What could go wrong? Larger companies may have the geologists with operating depth who will be inserted into the mine planning discussions, but it’s not a given. Junior companies must often delegate the conceptual and detailed planning tasks to consultant groups. Is a senior-level grade control review part of the scope of work for the mine planning? If a good grade control plan is in place before the mine geology team is staffed, a key element of success is assured."

Jan 1, 2018

By Yuliy Rubinstein

"The paper presents a analysis of the history and the trends of development of flotation apparatus. The laws of their evolution are stated and the place and role of column flotation are indicated. It is demonstrate development and different design of column apparatus. The major parameters of column cell such as diameter and height are discussed. Options are proposed on optimization of hydrodynamic characteristics of columns with large-capacity cells. High efficiency of columns with cell height of 4-6 m is shown on examples of coal preparation. A new generation of multi sectional column cells has been developed. In the cells are zones with different aerohydrodynamic parameters: combined in the machine are co-and counter- counter flows of phases. The transition from single-chamber column to multi-sectional apparatus makes it possible to create favourable hydrodynamic and aeration regimes in each section of the column dependent on the pattern of material distribution by floatability. Efficiency of application different designs column apparatus uses shown on the example of enrichment of various non-ferrous metals ores and coal. The principles of mathematical simulation of the flotation process are developed. A scaling-up procedure for column cells was based on flotation macro- and micro- dynamics simulation.INTRODUCTIONColumn flotation is considered to be one of the most significant achievement in the field of mineral processing in the end of last century. We cannot but agree with this statement but would like to understand what underlies this success. History of the flotation column can not be considered in isolation from the development of flotation apparatus on the whole. It can be argued that the first attempt to switch from oil flotation to the use of bubbles during flotation was performed Bessel brothers in 1877 (Berlin patent 42 class 22, July 2) and in 1886 (Berlin patent 39,369 May 12). According to these patents, the crushed ore was mixed with oils , hydrocarbons and water. Then the pulp received in this way was heated up to boiling . Air bubbles and steam formed during boiling facilitate the flotation of ore particles coated with oil (first patent) or bubbles been generated by the reaction of lime with acid (second patent). The evolution in the design of the flotation apparatus incorporates the following key stages. Further development is connected with the Francis Elmore’s idea to use gas bubbles received at water electrolysis (UK, 13578; 1904). This method was not introduced then, but much later, in our time and on the essentially new technical basis it found a use for sewage treatment (electroflotation). Gas bubbling under vacuum patented also by Elmore (UK, 17816; 1904) obtained a practical use. It should be noted that the method did not lose its importance till now. The design of the camera has been surely optimized (Glembotskii etal, 1963). A year later A. Macquisten (UK, 26712) developed pressure (compression) flotation. Thus, the H.Sulman, H.Picard, D. Bell’s (US, 853120, May 29, 1905) basic patent and the adjoining T. Goover’s patent 1910 (US, 953746) formed the basis of the first and most important element of modern flotation: flotation with air bubbles sucked in from the environment. In 1914, J.Callow received a patent for on an apparatus where air was sparged through the porous false bottom of the cell ( US, 1104755). Woolen fabric folded four times was fixed on a perforated metal frame to be used for air sparging (Gaudin, 1932). The following year Durrel created the prototype of the injection (ejector) apparatus. The jet aerator made it possible to significantly reduce the size of the bubbles, in comparison with the filter cloth. An apparatus with slurry pre-aeration in an airlift prior to feeding into separation cell was developed Wagner in 1917 (US, 1235083). And finally, the first column apparatus with a counter-current of slurry and air was developed by M. Towne and S. Flynn in 1919(US, 1,295,817). ("

Jan 1, 2018

By A. Singh, M. Ntlhane, V. Ross, M. Dlame

"Fine valuable particles are often lost to flotation tailings streams due to inefficient collection by air bubbles as well as passivation of surfaces by oxidation and slimes. The application of high-shear hydrodynamic cavitation devices (HCDs) to overcome this problem has already proven to be a considerable success in the industry. This paper details the results of further investigations that were undertaken at Mintek to better understand the mechanisms involved when preconditioning feed slurries in an HCD. By promoting inter-particle attrition and conditions of high shear within the reactor, cleaning of particle surfaces is enhanced as well as the formation of superfine (nano) bubbles which are believed to aid their agglomeration and subsequent collection by normal sized bubbles. In order to broaden the envelope of understanding with regard to application of the technology, rather than tailings material as investigated earlier, a Platinum Group Mineral (PGM) UG2 ore from the Bushveld Complex in South Africa was used in this study. The results of a series of batch flotation tests in a 10L Denver cell are presented, being conducted after the feed has been subjected to different methods of preconditioning. It was demonstrated that the preconditioning significantly improved the flotation kinetics of the PGMs, the optimum being obtained after around 20 passes through the reactor. This was accompanied by a much enhanced recovery-mass pull relationship and a significant improvement in the grade-recovery response. Significantly, the selectivity between the PGM and the deleterious chromite (expressed as Cr2O3) gangue more than doubled under these conditions. Modelling of the PGM data by means of the modified Kelsall model indicated that both the fast and slow floating rate constants were improved.INTRODUCTIONIt is well known that the flotation recovery of fine and ultrafine particles, typically less than 10 micron in size, is a challenge (Yoon et al., 1989; Miettenin et al., 2010). Although these particles are typically well liberated, due to their very low mass and inertia, the collision efficiency with air bubbles is low as a result of the inability of particles to penetrate the liquid streamlines around bubbles. Hence the probability of contact is often regarded as the ratedetermining step in flotation of ultrafine particles. Introducing more power into conventional flotation machines is likely to solve only part of the problem, as conventional mechanisms are effective only to a point in terms of shear and micro-turbulence. Further challenges are posed by the treatment of low-grade or oxidised tailings dump material, where valuables are passivated due to prolonged exposure to the atmosphere or slimes. Over the years, various mitigating strategies have been investigated, including the use of dissolved air flotation (Martinez-Gomez et al., 2013; Calgaroto et al., 2015), shear flocculation (Subrahmanyam and Forssberg, 1990), seed or carrier flotation (Tabosa and Rubio, 2010), sonication to clean particle surfaces (Aldrich and Feng, 1999; Newell et al., 2006), high intensity conditioning (Bulatovic and Salter, 1989; Chen et al., 1999; Tabosa and Rubio, 2010), and various electrochemical approaches such as changing Eh in order to promote formation of dixanthogen, dissolution of oxidation products by lowering the pH, activation by sulphidisation (Newell et al., 2006; Becker et al., 2014), and the use of alternative collectors."

Jan 1, 2018

By Julie Shang, Tim Evans, Michael McDonald, Yu Guo, Bingfeng Xue

Effective chemical grouting represents a technical and economic solution to many challenges related to soil stabilization and blocking the flow of water. Chemical grouts are facing increasing demands in durability, environmental impact and value. To better meet these challenges, a novel and cost effective process was developed to produce a sodium silicate that increases the ratio (i.e. silica to alkali) beyond what has been used in traditional silicate-based grouts. The move to a lower sodium form of silicate was anticipated to have two desirable performance enhancements; a reduction in leachable sodium and improvement in the durability of the silicate grout. An in-depth study was performed at the University of Western Ontario Geotechnical Research Centre to quantify improvement in durability as well as other performance properties such as compressive strength. The study began by first modelling the gelation time and reaction kinetics of the high ratio sodium silicate over a range of silicate concentrations using two different setting agents as well as with/without a hardener. As expected, reducing the level of sodium produced a much more water resistant grout. These same formulations also showed a four order magnitude reduction in permeability. Somewhat surprising, test results showed the higher ratio silicate having much higher compressive strength. At the time of this abstract, the high ratio silicate was moving to the trial stage for geotechnical applications while the petroleum industry was further along with several successful field trials for water blocking as well as cement remediation. This paper will review the chemistry, testing and features of this next generation form of sodium silicate. Introduction Sodium silicate based grouts have been used for decades for soil stabilization and water control. Over the years, several silicate-based systems have been tailored for specific application conditions to maximize performance and reduce cost. Past research has also focused on the selection of setting agents and hardeners for silicate grouts. A constant in the development effort has been the grade of sodium silicate. The vast majority of chemical grouts have been formulated using a ~3.2 ratio sodium silicate. As a very brief overview on the meaning of “ratio” and why it is so important to performance properties. The ratio describes the proportion of sand to alkali or SiO2:Na2O used to make different grades of sodium silicate. Comparing a 2.2 ratio to a 3.2 ratio, it is easier to polymerize and set the 3.2 ratio. Upon setting and forming a silica gel, the system has higher compressive strength values and improved durability with a reduced level of syneresis (i.e. shrinkage). This leads to the question if 3.2 is better than 2.2 why not go to 4.2 or higher?

Jan 1, 2018

By D. Endara, E. De la Torre, S. Echeverria

"The study was conducted with the sulfide mineral from the province of Zamora Chinchipe. It was characterized physical, chemical and mineralogical, obtaining between its main results a copper concentration of head ore of 0,58 %. The mineral was homogenized and taken to direct closed circuit: rollers mill - vibratory sieve (mesh # 16). Flotation was carried out in two stages: the collective and selective where in each one were performed 6 water recirculation as suggested by the technique used to relate information of a batch flotation to a continuous circuit called cyclic flotation tests (LCT). In the collective flotation (bulk) 2 Kg of mineral were grinded with 10 Kg of balls for 30 minutes and 62.5% of solids, the pulp was taken to the flotation process with solids percentages of 33.3% and pH 7, it was conditioned with 45 g / t of KAX 1%, 50 g/t of Aerofloat 208 and 20 g /t of Pine oil. The concentrate and tailings bulk obtained were filtered separately for the recovery of water and it was recirculated to the next grinding of 2kg mineral. In the selective flotation 1Kg of bulk concentrate was carried to regrind for 40 min, 62.5% percent of solids, 10 g of lime and 5 g of tannin FLOATAN T5, the pulp was taken to the roughing-collection-refining flotation circuit controlling the pH between 10.5 and 11 where conditioning (60 g/t of Aerofloat 208 and 30 g/t of Pine oil) and adding lime to the circuit and FLOATAN according to the procedure. The four fractions obtained from the circuit were filtered; the water was recirculated to the regrind process of the bulk concentrate. In the collective flotation process tends to stability in the fourth recirculating water to obtain a copper content of 4.5% and a recovery of 87%, recirculated water represents 69.8% of all water used in the 6 recycles. In the selective flotation circuit the fifth recirculating of water is the optimal where obtaining a copper content of 13% and a recovery of 72%, recirculated water in the selective flotation circuit represents 95% of the total water used in the 6 recycles."

Jan 1, 2018

By K. Matsuura, M. Ohno, T. Tokunaga

"Recently, weight saving of automobiles has been strongly required to solve the global environmental problems. Mg alloys are one of the promising candidates as a new material for automobile components. However, the application of the Mg alloys is limited due to their poor corrosion resistance. In the authors’ preliminary study, an Al/Mg/Al clad sheet was fabricated by hot extrusion and subsequent hot forging. The clad sheet exhibited a high corrosion resistance and excellent super plasticity. More specifically, the elongation of the clad sheet was as high as 550%.Importantly, despite that the elongation of Al itself was only 40%without cladding with Mg, the ductility of Al was greatly improved in the form of the clad sheet. In the present study, in order to clarify the mechanism of the superplastic deformation of the Al part in the clad sheet, the microstructure evolution of the Al during the tensile de formation is investigated. The tensile tests were conducted at a temperature of 573 K and at a strain rateof1.0×10-3s-1. The Al exhibited fiber-type texture at the beginning of the tensile deformation, and brass-type texture after the elongation of 50%.INTRODUCTIONMg alloys have been gaining attention because of their excellent properties e.g. light weight, good recyclability and high electromagnetic shielding. However, their practical applications have been limited due to their poor corrosion resistance. In the authors’ previous study, in order to solve this problem, Al coating on Mg alloy by hot extrusion has been proposed, and the Al-coated Mg alloy plate was fabricated(Tokunaga, Matsuura, &Ohno,2012). The plate was hot-rolled and an Al/Mg/Al clad sheet was fabricated. No cracks or debondings were observed at the Al/Mg interface. The sheet exhibited a high corrosion resistance in a comparable level as pure Al. Also, the sheet exhibited a large and uniform elongation of 550%in a tensile test at a temperature of 573 K and at a strain rate of 1.0×10-3s-1without any breakings or debondings of the Al part(Tokunaga, Matsuura, &Ohno,2014).Mg alloys have been known to exhibit a superplastic characteristic when the grain size is small. However, it is known that the pure Al does not generally exhibit the super plasticity. As mentioned above, the Al-coated Mg alloy sheet exhibited 550% of elongation in the authors’ previous study (Tokunagaet al., 2014). However, the pure Al itself showed only 40% of elongation, while the Mg alloy itself exhibited 800% of elongation. Thus, it has been demonstrated that the pure Al was super plastically elongated when it was bonded with the Mg alloy. Generally, deformation mechanism of the super plasticity of the Mg alloy is known as a grain boundary sliding. On the other hand, the mechanism of the superplastic elongation of the pure Al is still unclear. The purpose of the present study is investigation of the deformation behavior of the Al part in the Al/Mg/Al clad sheet during tensile de formation."

Jan 1, 2018

By A. Singh

"Flotation of fine (< 10 µm) minerals is a challenge exacerbated by the emerging practice of fine grinding flotation feed to better liberate targeted minerals; however, the ability of conventional flotation cells to float liberated fines remains questionable. The Gold Ore solution using Mach reactors was tested at Mintek, South Africa, and showed an ~180% increase in the Kelsall kfast factor, a projected recovery improvement of 4% for the Mach-reactor case, and final concentrate grade twice that of conventional flotation. Theory, pilot plant results, and key aspects of plant design, supplemented by operational plant observations after commissioning, are discussed.RÉSUMÉ Le procédé de flottation de minerais fins (< 10 µm) pose de grandes difficultés, lesquelles sont aggravées par la pratique émergente de l’alimentation du circuit de flottation avec des mailles de broyage très fines pour mieux libérer les minéraux ciblés ; la capacité des cellules de flottation classiques à flotter les fines de minerais libérées reste cependant discutable. La solution proposée par la société Gold Ore, qui utilise des réacteurs Mach, a été testée à Mintek, en Afrique du Sud ; elle affichait une augmentation d’environ 180 % du facteur kfast développé par M. Kelsall dans son modèle de flottation, une amélioration prévue de la récupération de 4 % dans le cas du réacteur Mach, et une teneur finale des concentrés deux fois plus importante que celle obtenue avec la flottation classique. Sont débattus dans cet article la théorie, les résultats générés par l’usine pilote ainsi que les principaux aspects de la conception de l’usine complétés par des observations relatives à l’usine en activité après sa mise en service."

Jan 1, 2018

By V. M. Bystritsky, M. G. Sapozhnikov, G. M. Nikitin, A. B. Sadovsky, Yu. N. Rogov

"At present kimberlite ore is processed in crushers or grinding rolls with subsequent grinding in wet mills down to a size of 0.2 mm. The basic disadvantage of the standard diamond processing technology is that crushing kimberlite ore can damage the most valuable large diamonds of few carats. Tagged neutron method offers a possible solution to this problem. It allows detecting diamond inside kimberlite ore without its disruption. The results of the tests of the neutron separator prototype carried out at the Lomonosov processing factory of PJSC Severalmaz are discussed. The possibility to detect the diamond in the rock whose size is 10 times larger than the size of the diamond is demonstrated.INTRODUCTION At present standard diamond processing technology implies disintegration of kimberlite ore in crushers or grinding rolls down to a size of 0.2 mm. It inevitably leads to high probability that large and most valuable diamonds could be damaged. The fraction of diamonds which lost integrity in the process of ore enrichment could be as large as 35-65% [1]. Tagged neutron method (TNM) [2] offers a possible solution to this problem. It allows detecting diamond inside kimberlite ore without its disruption. The main idea of the TNM is irradiation of an object by fast 14.1 MeV neutrons from binary nuclear reaction d + 3H ?4He + n (1) and detecting (tagging) the 4He (a-particle) that accompanies neutron. That gives possibility to determine direction of the neutron momentum. Those tagged neutrons irradiate kimberlite ore under investigation and produce gamma rays via inelastic scattering reactions with nuclei"

Jan 1, 2018

By Eduardo Lozano, Vilem Petr

This paper provides an overview of a new method for avalanche control using a high explosive charge placed at the avalanche runout zone: the case charge technique. This new avalanche control technique is well-suited to mountain roads presenting several advantages over the existing methods: minimum deployment time, low cost, reduced probability of misfires, and decreased operation time in the avalanche danger zone. The research work presented in this paper was conducted via large scale laboratory experiments where the detonation velocity and the blast physical properties were measured. During the charge design, several parameters were controlled: charge mass, diameter, geometry, density, and external confinement. In addition, the effective range of case charges was increased by the use of the Mach reflection for certain topographical situations. Finally, field test results collected by the Colorado Department of Transportation (CDOT) during the 2017 winter season are presented. The CDOT avalanche control crews have adopted the new case charge as the preferred technique in numerous avalanche locations along the Rocky Mountains roads.

Jan 1, 2018

By Eugene Mirsky, Eloy Ramos, May ElKhattab, John Wise, Terrence Carroll, Jose Torres

In 2017, Nicholson Construction Company completed a $72.1 million design-build contract for Miami Dade Water and Sewer Department to replace an existing 54-inch diameter pre-stressed concrete force main that runs from the Virginia Key Central District Wastewater Treatment Plant, under the Biscayne Bay at Norris Cut, to Fisher Island. In order to install the new sewer pipe below the bottom of Biscayne Bay, a tunnel boring machine (TBM) was launched from a 42ft diameter and 89ft deep shaft on Virginia Key and a precast segmentally lined tunnel was constructed towards a 28ft diameter and 72ft deep retrieval shaft on Fisher Island. Both shafts were constructed through sand and highly permeable limestone, primarily the Fort Thompson Formation which is part of one of the most permeable aquifers in the United States and two different techniques were used to ensure a water-tight shaft at each end of the tunnel drive. The launch shaft structure was built using the secant pile technique, wet excavation and a tremie plug. For the tunnel break-in a soil freeze block was installed after the ground was treated with low mobility grout. The retrieval shaft was built using the Deep Soil Mixing (DSM) technique and excavated in the dry. Precedence of any other structure built this deep through hard layers (UCS over 3,000 psi) using this technique was not found. This case study addresses the challenges of constructing watertight underground structures in highly porous ground for launching and retrieving a TBM. Design challenges from complex asymmetric loading, selection and comparison of the construction techniques, the installation and excavation of both shafts, and their performance are also discussed herein.

Jan 1, 2018

By T. Bauerle, G. Poplin, Z. Dugdale

"The issue of mine worker fatigue is as complex as it is understudied. Generally, worker fatigue lies somewhere on a continuum between psychology and physiology, which makes the measurement and management of it difficult with no easy solutions for operators or workers. Answers to even basic questions remain elusive—such as what is fatigue, how is it measured, and how can organizational resources reduce fatigue—and answers seem to present no single, clear path to action for the health and safety of the worker. This manuscript supplements the growing body of interest in the problems of fatigue in the mining industry by reviewing some of what is known about worker fatigue in general and in the mining industry in particular. The material covered here includes basic topics of the hows and whys of worker fatigue; an overview of fatigue models, findings, and evidence-based solutions with a focus on mining; and potential future directions aimed at mitigating miner fatigue. INTRODUCTION “It is recommended that the whole fatigue test problem be stated in a form the nature of which may be indicated by the following suggestions: that the term fatigue be absolutely banished from precise scientific discussion, and consequently that attempts to obtain a fatigue test be abandoned [emphasis added].” – Bernard Muscio, Pioneer Australian Philosopher and Industrial Psychologist, in a 1921 Report to the Cambridge Industrial Fatigue Research Board Fatigue presents several challenges for the mining industry. Depending on the specific occupation, daily work, or operational setup on any given mine site, mining jobs can have a fair amount of labor-intensive tasks mixed with monotonous and repetative duties. Combined with the long working hours and shift-work schedules of mining work, the prevalence of fatigue in mine workers may seem rather unsurprising. On the one hand, mining is certainly not alone in facing the challenge of addressing worker fatigue. Indeed, many of the characteristics above mirror the similarities of fatigue in other industries, such as health care, aviation, and security. To the extent that fatigue in mining acts like fatigue in any other industry, then any fatigue management applications, trainings, or interventions in existence can be borrowed from other industries and applied to mining in a “cookie-cutter” approach. On the other hand, some have argued that mining in particular is especially susceptible to increases in the prevalence of fatigue beyond the characteristics listed above due to the multifaceted combination of factors in mining environments associated with fatigue: dim lighting; limited visual acuity; hot temperatures; loud noise; highly repetitive, sustained, and monotonous tasks; shiftwork; long work hours; early morning awakenings; and generally poor sleep habits (Canadian Centre for Occupational Health and Safety, 2012; Legault, 2011). Legault (2011) in particular argues that it is the combination of these factors simultaneously that can make mineworkers particularly susceptible to sleep deprivation and fatigue in comparison to other industries where these factors are often not present alltogether. If fatigue looks and acts different in mining, as others have argued, more research is needed to determine if, how, and why worker fatigue might need to be managed differently in mining."

Jan 1, 2018

By V. Panayotov, M. Panayotova

"Wastewater from ores processing is often polluted by molybdate and sulfate (SO42-) ions. Sorption is one of suitable methods for removing those pollutants when presenting in low concentrations. This work reports results on adsorption of sulfate and molybdate ions on metal modified (with barium - Ba and lead - Pb) and organic reagent modified (with Hexadecyl-trimethyl-ammonium bromide - HDTMA) clinoptilolite. Zeolite’s modification with Pb, Ba and HDTMA increases its uptake capacity with respect to Mo(VI) at pH 3, with the uptake capacity decreasing in the order CL-Pb > CL-HDTMA > CL-Ba. Lead-modified clinoptilolite shows high uptake with respect to Mo(VI) in acidic, neutral and slightly alkaline conditions. The presence of SO42- in concentrations twice higher than the amount of Mo(VI) do not interfere with the Mo(VI) removal by CL-Pb. Zeolite’s modification with Ba and Pb renders it able to immobilize SO42- from water in the pH range 3-9. Kinetics of the uptake process is best described by the pseudo-first order kinetic equation. Increasing the initial concentrations of Mo(VI) and SO42- increases the removed amount of pollutants. INTRODUCTION Wastewater from copper-molybdenum ores processing is often polluted by molybdate and sulfate ions. Molybdenum (Mo) migrates easily in water and consequently the Mo polluted areas could extend for hundreds and thousands of meters (Ryzhenko, 2010). Molybdate anion is the only Mo(VI) species in natural water, i.e. at pH > 6.0. Its median freshwater hazardous concentration affecting 5% of the species (HC 5.50%) is 38.2 mg Mo/L (De-Schamphelaere et al., 2010). The marine water chronic toxicity (HC 5.50%) is assessed at 5.74 mg Mo/L (Heijerick et al., 2012). The predicted no-effect concentrations (PNEC) are 12.7 mg Mo/L and 1.92 mg Mo/L correspondingly for freshwater and marine water (Heijerick et al., 2012a). When sulfates present in drinking water in excess of 250 mg/L they cause a cathartic action (especially in children) in the presence of sodium and magnesium, and when the concentration exceeds 600 mg/L, diarrhea. When sulfate-rich effluents are discharged into the environment, they may increase the acidity of water bodies and soils (Guimarães and Leão, 2014). Because of the adverse effects to human health and the environment, limits are set for SO42- concentrations in waters and wastewaters in the range of 250 / 500 mg/L."

Jan 1, 2018

By Saveliy F. Kaplan, Valeriy N. Tsyplakov, Vasily N. Kovalev, Igor A. Agapov, Nikolai V. Vorob’ev-Desyatovskii

"Based on the experiments, a possibility of successful processing of double-refractory gold sulphide concentrates with a high content of natural organic carbon, which has a high sorption capacity toward gold chloride complexes, has been demonstrated. The proposed approach involves deep burnout of sorption-active organic carbon in an autoclave at a higher temperature and a longer retention time. INTRODUCTION It is known that one of the reasons why gold-bearing ores and concentrates are refractory is the occurrence of fine gold in sulphides (usually in pyrite and arsenopyrite) in ores and concentrates. In addition, refractory gold-bearing ores and concentrates also contain an organic carbonaceous material, which has a sorption capacity towards gold chloride complex, making the ore or concentrate even more refractory. In pressure oxidation, metallic gold is oxidized by Fe (III) aqua-ions and complex Au(Cl)4- ions are formed at temperatures over 180°C, in the presence of chlorides contained in ores. Complex gold anion is adsorbed on the organic carbon surface and then reduced to Au0; the chloride ion is regenerated and gold, adsorbed on organic carbon microparticles, is ultimately transferred to tailings (preg-robbing). Currently, there are several suggestions how to suppress preg-robbing (Simmons, 1998, Pyke, 1999, Rees, van Deventer, 2000, Zhao Jun-wei, 2008). It can be done by reducing the organic carbon content by processing (flotation, etc.),reducing chloride ion concentration by preliminary washing of concentrates in thickeners, reducing the adsorption capacity of organic carbonaceous material by introducing some organic substances that are strongly adsorbed on its surface (blanking agents), and reducing the redox potential of the slurry liquids by introducing neutralizing agents (limestone)."

Jan 1, 2018

By Y. Tang

"Rare earth elements (REEs) have many key applications in traditional and advanced technologies. A shortage of several critical REEs is expected due to the discrepancy between the availability of REEs from REE deposits and the REE demand from the market. REE recovery and separation from secondary resources such as uranium wastes and recycled materials might help balance the shortfall in a cost-effective way. This paper presents data concerning the recovery of heavy REEs (HREEs) from uranium raffinate. It also discusses the design, commissioning, and operation of a solvent extraction pilot plant for the separation of REEs.RÉSUMÉ Les éléments des terres rares (ÉTR) trouvent de nombreuses applications importantes dans les technologies classiques et de pointe. On prévoit une pénurie de plusieurs ÉTR critiques en raison des divergences constatées entre la disponibilité des ÉTR provenant de gisement d’éléments des terres rares, et la demande d’ÉTR sur le marché. La récupération et la séparation des ÉTR à partir de ressources secondaires telles que les déchets générés par le traitement du minerai d’uranium et les matériaux recyclés pourraient contribuer à équilibrer cette pénurie de manière rentable. Cet article présente des données relatives à la récupération des ÉTR lourds (HREE, de l’anglais heavy REEs) à partir de raffinat d’uranium. Il aborde également la question de la conception, de la mise en service et de l’exploitation d’une usine pilote d’extraction par solvants pour la séparation des ÉTR INTRODUCTIONSignificant amounts of strategic specialty heavy rare earth elements (HREEs) are present in waste streams in Saskatchewan uranium operations. Selective precipitation including neutralization, oxalate, and double-salt precipitation, as well as sulfide precipitation, ion exchange (IX), and solvent extraction (SX) are commonly used technologies for the recovery and purification of rare earth element (REE) solutions. REE oxalate precipitation can effectively remove Fe, Al, Ca, Si, and other impurities by taking advantage of the solubility difference between REE oxalates and impurities in the acidic solution (Xu, 2005)."

Jan 1, 2018

By Shahid Islam, Lucian Bogdan

Deep and large diameter drilled shafts use mostly bundles of Grade 60 (415 MPa) reinforcing bars as longitudinal reinforcement with rebar splices to make it longer. Lower Grade steel requires large number of bars which result in rebar congestion and difficulty in placing concrete. This leads to increased labor cost for fabrication and installation. By utilizing larger size and higher strength threadbar, the congestion of rebar can be reduced significantly and bundling of bars can be avoided. The lap splices are replaced with simple threaded couplers and end hooks are replaced with end terminators. Threadbar conforms to ASTM A615-15 and can be epoxy coated if required for corrosion protection. This paper describes an attractive value engineering of replacing Grade 60 (415 MPa) bundle of rebars with larger diameter Grade 75 (515 MPa), Grade 80 (550 MPa) and Grade 100 (690 MPa) threaded bars and threaded couplers in some specific drilled shaft projects in the USA. INTRODUCTION A drilled shaft which may also be referred to as drilled piers, caissons, cast-in-drilled-hole piles and bored piles is the key element to the foundation of massive structure. They are used for tall buildings, bridges and foundations for other applications such as retaining walls, sound walls, signs, or high mast lighting. Drilled shaft foundations are typically 3 to 12 feet (0.9m to 3.7m) in diameter cast-in-place deep foundation elements constructed in a drilled hole that is stabilized to allow controlled placement of reinforcing steel and concrete. Drilled shafts for transportation structures are commonly used to depths of up to 200 ft (61m) in the USA. Drilled shafts can be installed in a variety of soil and rock profiles, and are most efficiently utilized where a strong bearing layer is present. The reinforcing cage is typically lowered into position within the hole and then concrete placed through the center of the shaft, flowing from bottom to top through the reinforcement to fill the hole.

Jan 1, 2018

By V. V. Zakopaylo, M. V. Lukyantseva, V. A. Ignatkina, V. A. Bocharov, L. C. Khachatryan, D. M. Altynamanov, A. A. Kayumov, R. H. Sharipov

"This research was aimed to explain the reasons of low floatability of tennantite from refractory pyrite ores of non-ferrous metals and to create a reagent regime for selective increasing a recovery of copper sulfide minerals from arsenic-containing copper pyrite ore. ?opper-zinc ore of the Uzelga deposit has 89% of pyrite, some part as melnikovite; copper is assayed as 3.58% of tennantite and 0.25% of chalcopyrite; there is 2.19% sphalerite. Sulfide minerals are very finely disseminated. Tennantite is genetically related to primary copper sulfides. Graphene was identified on the surface of tennantite by a transmission electron microscopy (TEM) method. The recovery of tennantite was rose up by using the collector M-TF. M-TF is the mixture of diisobutylditiophosphate (DTF) and O-isopropyl-N-methyl (ethyl) (TC) in the certain ratio. M-TF change up a kinetic of copper sulfide flotation in a slightly alkaline medium, but pyrite has slowly floatability at this moment. A depressing effect of thiosulfate ions in a liquid phase of pulp flotation tennantite from pyrite ore has been established. A copper recovery up 14.2% (from 67.7 to 82.0%) into a copper concentrate level off copper grade of 18.65% (butkx) and 18.68% (M-TF) has been increased by the new technology with M-TF compared to a standard technology with butkx. A main copper recovery up to 50 % in an inter-cycle copper concentrate assaying 19-21% Cu in case of using M-TF was gotten. A zinc concentrate with recovery of 50% and a zinc assay of 41.76% by a standard flow sheet with butyl xanthate was obtained. A zinc recovery of 70.3% with a zinc grade of 44.17% by the M-TF technology was achieved.INTRODUCTION The pyrite copper-zinc ores of the Urals region are considered refractory. The distinctive features of these ores include a high content of pyrite (90-95%), the presence of arsenopyrite and arsenical pyrite, and the simultaneous presence of chalcopyrite, bornite, tennantite with the predominance of the latter (Andreasen et al.,2008;.Dobrotsvetov, 2009; Chanturiya et al. 2016). The flotation properties of tennantite differ from those of chalcopyrite (Xumeng Chen, Yongjun Peng, Dee Bradshaw. 2014), which is the reason why a comprehensive study was under taken of the flotation activity of tennantite and a process for its recovery was developed. The proposed agent treatment and flotation process make it possible to produce salable copper and zinc concentrates."

Jan 1, 2018

By Jogeshwar P. Singh, Aser I. Abbas, Mohamed Ashour

The presented methodology predicts the pile head response (i.e. pile head load - displacement curve) and develops the load transfer (t-z) curve of piles in sandy soils under tension forces based on soil/pile properties and soil-pile interaction. The proposed approach improves the prediction of the t-z curve in sandy soils compared to current practice. The method employs a nonlinear soil constitutive model to calculate the mobilized shear stress/strain in soil at the soil-pile interface induced by pile upward displacement. The approach accounts for the influence of the pile slenderness ratio on the predicted t-z curve and is validated through comparisons with measured pile head response and t-z curves from full-scale pile load tests. INTRODUCTION Piles may be subjected to axial uplift forces due to either static loading or cyclic loading. The majority of methods are only concerned with the pile ultimate tensile capacity. However, the mobilized pile stiffness (i.e., pile-head load-displacement relationship) is essential to determine the interaction between the foundation and the superstructure and consequently the performance of the whole structure. Methods that assess the pile ultimate tensile capacity usually assume the failure surface at the soil-pile interface and estimate the local side shear resistance using a lateral earth pressure approach. The Naval Facilities Engineering Command (NAVFAC 1986) and the US Army Corps of Engineers (USACE 1991) employed Eq. 1 to assess the ultimate shear stress (τ) developed at the soil-pile interface.

Jan 1, 2018

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018

By A. Lewis

"Thiol collectors including the xanthates and dithiophosphates have dominated the sulfide mineral processing industry for over a century. Tecflote represents completely different chemistry, without sulfur or phosphorus, and will float all sulfides and associated precious metals. As these collectors are surfactant in nature, they comprise a head group which binds to mineral surfaces, a spacer and a long hydrophobic tail. The modification of the spacer behind the head group allows for collector optimisation for different sulfide ore types and process conditions.The Tecflote surfactants have been designed to be either very selective against pyrite at the natural pH of the ore (pH 7-9) or to float all sulfides including pyrite. Depending on the ore type and the process flow sheet, the use of lime can be maintained, reduced or completely eliminated.Tecflote can be used either as a rougher collector giving good recovery and grade for the sulfide minerals or it can be used to target valuable minerals after regrind and through cleaner flotation. It has repeatedly shown to be very effective at holding onto gold through the cleaner steps. The low solubility has a significant impact on the mechanism and surface activity of the collector, resulting in a very different flotation response compared to conventional thiol collectors.INTRODUCTIONXanthate was first made in 1882 by Zeise and first used in flotation in 1924 (Keller, 2018). In 1946 Keller patented thionocarbamate as a collector, which was produced by Dow Chemicals (Keller, 2018). Later it was replaced by Dow product Z-200, while dialkylthionocarbamate was discovered by Harris et al. (Harris, 1954. No significant chemistry change to collectors has occurred since they were introduced in the mid-20th century and now that the feed grades have been declining over the last decades creating a need to find more selective collectors to extract difficult and complex ores and pushing the industry to look at other reagents."

Jan 1, 2018

By S. J. Prout, J. M. Lang, D. Lascelles, K. Sarinas

"There is a growing demand for ore characterization methods to support metallurgical development programs from a true geometallurgical perspective. Today, there are multiple automated mineral analysis systems on the market, many of which are based on conventional mineral liberation data. However, liberation data can be limited when assessing the floatability of a mineral to predict its recovery as it doesn’t consider the surface area available for collector absorption and bubble attachment; whereas mineral exposure measurements can. Using the First-Order Rate equation to predict the recovery versus time of variously exposed particles, a model has been developed to predict the recovery of copper sulphides at a particular grind size. This model provides the opportunity for the prediction of copper recovery and grade from multiple, small-scale samples. These predicted values can be imported into resource modeling software, and guide the domaining of geometallurgical units within the ore body. Data has been analyzed from various global copper porphyry systems and compared with actual flotation testwork.IntroductionAs part of the development of a mining project, resource estimation primarily focuses on the definition of the quantity and grade of the ore in the deposit; as the project evolves from preliminary economic assessment through to feasibility, the geological model is usually further populated with hardness and recovery data.The CIM Definition Standards (2011) identifies measured mineral resource as the part of a mineral resource for which quantity, grade or quality, densities, shape, and physical characteristics are estimated with confidence sufficient to allow the application of “modifying factors” to support detailed mine planning and final evaluation of the economic viability of the deposit as an asset. The modifying factors include, but are not restricted to, mining, processing, metallurgical, infrastructure, economic, marketing, legal, environmental, social and governmental factors.With market fluctuations, many investors in the mining industry have become more and more risk averse which has increased the demand for more reliable data to support these modifying factors. This has led to the widespread use of geometallurgy and statistical analysis to better inform the resource estimation. Geometallurgy is used to characterize ore variability and is especially useful for highly variable or strongly zoned deposits, several close deposits that will be milled together, projects requiring complex or new metallurgical approaches, brownfields or sight-of-mine exploration, expansion projects that exploit new, deeper or adjacent reserves, and projects with significant legacy drill core that are being re-evaluated due to new economic circumstances."

Jan 1, 2018