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By R. C. Hubli

A panial equilibrium model? to simulate the dissolution of millerite (NiS) in aqueous solutions containing copper(II) chloride as the oxidizing species has been developed. The predominant copper(I) and copper(II) species are CuQ3 and CUO2 respectively. The model computes the initial concentrations of the species present in the aqueous phase under the specified input conditions, prior to the simulation of dissolution. During the dissolution of millerite, nickel enters the leach liquor as NiH and it has been found that the H+ decreases as a function of NiS dissolution. The simulation has been accomplished under conditions prevailing during actual dissolution, with only one mineral undergoing dissolution. The model can be applied for the simulation of co-dissolution of two or more sulfides. Under the given conditions, the precipitation of Cu1(OH»)O is negligible but loss of Cu(1l) could be significant if the initial H+ is lower than 0.03 M. The results of the simulation compare favorably with experimental observations.

Jan 1, 1996

By P. Curry, H. G. Stephenson, B. Van Den Bussche

"Three Sisters Resorts Inc. currently owns a2035 acre (824 ha) parcel of land, which previously belonged to Canmore Mines Ltd. Approximately 50% of these lands, that are slated for residential, resort and recreation development, have been undermined for coal in one or more seams.Norwest Mine Services has been contracted by the developer to assess and advise them on any past mining activity that may be potentially hazardous to their development and offer solutions to how these hazards may be mitigated or avoided.The following paper deals mainly with the procedures put in place and accepted by the approval authorities, and the Staged approach to the Investigative Procedure that Norwest follows in the mining assessment and mitigation work for Three Sisters."

Jan 1, 1996

By H. Eccles

BNFL, an internationally acclaimed company noted for its nuclear fuel cycle services and waste management technologies, collaborated with Viridian BioProcessing Ltd, a small company acknowledged for developing environmental biological processes, and an internationally recognised professor of biological sciences, to develop an unique bioremediation process for treating toxic, heavy metal contaminated land. This paper describes the process, with particular reference to the problem and scope of land contamination with toxic, heavy metals and the current available technologies. The process technologies are based on using indigenous, soil micro-organisms which can be stimulated to produce acid or sulphide ions to mobilise or precipitate the heavy metals respectively. Laboratory studies have indicated metal removal efficiencies of greater than 90 % can be achieved, whilst recovery efficiencies from the metal loaded leachate are even higher at approximately 95%.

Jan 1, 1996

By Kim Appleby

Epithermal gold-silver (lead-zinc-copper-manganese) mineralization on Misima Island is confined to steep and reactivated flat-lying normal faults in the upper plate of a major, shallowly dipping detachment fault. The hangingwall comprises an Eocene metavolcano-sedimentary sequence that has been extensively intruded byMiocene calc-alkaline granodiorite. It is unconformably overlain by Pliocene sedimentary and volcanic rocks. High-pressure amphibolite facies rocks dominate the footwall and have many characteristics of a metamorphic core complex. Mafic-alkalic lamprophyre dike swarms intrude the hangingwall and footwall sequences. Previous workers attributed the gold-silver mineralization on Misima to the intrusion of the porphyritic granodiorite (Williamson, 1984). This has been proposed for many tertiary gold deposits of the southwest Pacific(Sillitoe, 1989; Leach and Corbett, 1994).

Jan 1, 1996

By R. K. M. Bhandari

Geotechnical investigation for a LPG plant located in Assam state - an area of high seisimicty - revealed a layer of loose to medium silty sand susceptible to liquefaction at some depth below the finished ground surface. Liquefaction analyses were carried out using simplified Seed's approach as well as considering the progressive buildup of pore pressures with cyclic earthquake loading. Seismic settlements were computed for areas where the analysis indicated partial liquefaction. Pile foundations in areas where complete liquefaction was indicated, were treated with gravel drains to prevent buildup of pore pressures. The paper presents and discusses the liquefaction analyses, effect of non-liquefiable overburden soil on the liquefaction potential of the silty sand and the remedial measures that have been taken to ensure safety of the pile foundations in transmitting vertical and lateral loads.

Jan 1, 1996

By Virtanen M

Grinding has been one of the areas of major development at Outokumpu's concentrators. During its early years the company used entirely rod and hall mills, but due to the high costs of metallic grinding it began the testing of autogenous grinding as early as the 1950s. In the late-1970s, the company's own modification for two stage autogenous grinding was ready for industrial use. Surprisingly late, in the 80s - 90s, an interest rose to check also the effects of grinding methods on flotation results. This paper firstly gives a short history of the development work of Outokumpu type autogenous grinding, called 'Outogenius'. The effects of some grinding methods on the process results of two nickel ores are then reviewed. The tests to date show notable effects of grinding methods on flotation.

Jan 1, 1996

By M. Misra

The coral contaminated with plutonium at Johnston Atoll UA) was subjected to gravity and flotation separation processes at the Soil Washing Laboratory (SWL) and also at the Johnston Atoll UA) site. Tests were conducted with the contaminated coral fractions referred to as the "HP-l" ( hot particles) and the "sludge". The gravity process tested was centrifugal gravity separation and the flotation processes were conventional Denver mechanical flotation and tall column flotation. Flotation tests were conducted using both fresh and sea water. Industrial fatty acid (anionic collector) was chosen as collector to make plutonium-enriched particles hydrophobic. The use of flurosilicic acid and sodium silicate made the clean coral hydrophilic. The results show that each of the processed when tested with appropriate size fraction and operating conditions resulted in passing the success criteria. It was possible to obtain more than 80% weight of the original coral as "clean sand" having activity below the JA site "soil screening level" of 13.5 pCi/gm. The field tests spiked with plutonium particles showed remarkable success. The effect of depressants, flotation medium and the coral pretreatmentis described. Finally, a flowsheet developed by the University of Nevada, Reno to treat 8000 tons of HP-l pile presently stored at JA is presented.

Jan 1, 1996

By Lu S, Zhou S

The flash smelting technology employed in Jinchuan demands a better mineral processing concentrate with an MgO content below 6.5 per cent. Two ways for MgO removal have been investigated in detail based on properties and process mineralogical characteristics of the rich ores in the number one mining area in Jinchuan. The key to the first way is the use of a new flowsheet which has two-stage grinding and separation followed by single-stage regrinding and multi-stage cleaning for the rougher concentrate. The second approach utilises two novel reagents, AT-131 and AT-202, which have been developed recently. Excellent metallurgical performance has been obtained in a commercial test and a batch test, respectively. The MgO content of flotation concentrate can be reduced to about six per cent.

Jan 1, 1996

By G. E. McClelland

In recent years exploration and development of low-grade sulfide precious metal ore deposits has increased. Low- grade ores are usually processed using conventional heap leach cyanidation methods. The potential for acid mine drainage from spent sulfide ore heap leached residues remains a concern even though the processed residue is stacked on an impervious liner system. It is therefore of critical importance to evaluate methods for long term prevention of acid mine drainage from sulfide heap leachable ores during the precious metal recovery process rather than mitigation during the closure and reclamation phase. This paper discusses two simple AMD prevention options for the recovery process phase. Laboratory evaluations were made using a modified humidity cell kinetic AMD test method on two low-grade sulfide ores without addition of an alkaline component and on the same ores with natural limestone or acid neutralizing oxide ore blended with the feeds before kinetic testing. Laboratory results are discussed in detail and demonstrate that blending an acid neutralizing component with sulfide ore effectively prevents the production of acid from the processed residue.

Jan 1, 1996

By J. Gartelmann, B. Zaslavsky, Y. Vojta, D. J. Chaiko, W. Mego, A. N. Rollins

"Aqueous biphasic extraction (ABE) processes offer the potential for low-cost, highly selective separations. This countercurrent extraction technique involves selective partitioning of either dissolved solutes or ultrafine particulates between two immiscible aqueous phases. The extraction systems that we have studied are generated by combining an aqueous salt solution with an aqueous polymer solution.We have examined a wide range of applications for ABE, including the treatment of solid and liquid nuclear wastes, decontamination of soils, and processing of mineral ores. We have also conducted fundamental studies of solution microstructure using small angle neutron scattering (SANS). In this chapter we review the physicochemical fundamentals of aqueous biphase formation and discuss the development and scaleup of ABE processes for environmental remediation.IntroductionAqueous biphasic extraction (ABE) is a highly adaptable separation technique that can be used in a wide range of applications. We have been evaluating various types of ABE systems for possible applications in the treatment of solid radioactive wastes (1,2), liquid nuclear wastes (3,4), and contaminated soils (5-7), and in the removal of organics from aqueous salt solutions (8). We have also conducted fundamental studies of the solution microstructure of ABE systems using small angle neutron scattering (SANS) (9).The extraction systems are generated by combining an aqueous salt solution and an aqueous polymer solution. This produces two distinct liquid layers that are as immiscible as oil and water, yet each liquid layer contains at least 70 to 80 wt % water. The biphasic systems that we have been working with consist of immiscible polyethylene glycol (PEG) and salt solutions. Some inorganic salts that promote biphase formation with PEG solutions include the sodium/potassium salts of sulfate, carbonate, phosphate, and hydroxide (10)."

Jan 1, 1996

By V. M. Torres

Arapiraca ore deposit has a mixed chalcopyritelbornite mineralogy, with a copper head grade of 0.7%. The reserve size does no allow profitable exploration by grinding/flotation. The technical feasibility of exploring the reserve by heap leaching was studied. Preliminary agitation tests indicated 85% copper recovery. To simulate heap leaching, column tests were performed. The tests included different ore types and acid addition levels. Operating at pH range 1.6-1.8, 67% copper extraction was achieved. Also, it was found an empirical correlation between the operation pH range, copper extraction and acid consumption.

Jan 1, 1996

The Steering Committee for Minerals and Mining Policy convened two workshops during March 1996 to address the following topics: Business Environment- National and Provincial Powers, Administration and Regulation, Mineral Marketing, Beneficiation, Research and Development, Environmental Issues, Mining Impact on Surface Usage, Southern Africa Regional Issues. Human Resources: Elementary Residual Racism, Housing, Downscaling, Migrant Labour and Human Resource Development. Mineral Tenure: Mineral Rights, System of Access to Mineral Rights, Access to Exploration information, optimal Exploration, Trust Lands. Small-scale Mining. Development of Small-scale Mining, Artisanal Mining.

Jan 1, 1996

By Guo Xian Jian

In this paper, the effects of matte grade, flux grain size, blast flowrate and blast O2 content on the process of silica flux melting in a copper converter were investigated. The results showed that the blast flowrate and the blast 02 content were not significant factors in the melting process. However, with an increase in grain size of flux and grade of matte, the amount of the flux molten decreased. The data on the melt rate of process correspond well with the mathematical model which simulates the chemical reactions occurring at the interface. The kinetic equations of melting are as follow:

Jan 1, 1996

By Günter Petzow, Hans Leo Lukas, Hans Jürgen Seifert

"The CALPHAD method (CALculation of PHAse Diagrams) has been extensively developed in the last 25 years and became a useful tool in materials science. Thermodynamic descriptions for the functions of state of unary, binary and ternary phases are derived by the optimization of phase diagrams. These functions are stored in computerized thermochemical databases and can be combined to extrapolate to multi component systems. Depending on special demand, the actually most advantagous presentations of the calculated results can be chosen: tables or in a clear graphical form as phase diagrams, phase amount diagrams or volatility diagrams. The method will be desribed by the system Ti-Si-C-N-O including the ceramic subsystem Si3N4-SiC-TiCi,N1_1,-C-N-O which is very important for the development of ceramic composites. The calculations give the thermodynamic stabilities of the condensed phases as function of temperature, concentration and partial pressure of different gas species. Adjusting the sintering conditions to these results the formation of unfavourable compounds or liquid phases can be suppressed.IntroductionThe CALculation of PHAse Diagrams (CALPHAD-method) of multicomponent systems provides the possibility to plan experiments very efficiently and avoid the experimental trial and error approach for the development of materials. The main problem for best use of calculated results is their interpretation with regard to the specific applications under consideration. Tables give the exact quantitative data for the treated phenomena. However, most important to make best use of these thermodynamic data is their graphical representation especially designed for the solution of specific problems, scientific as well as application oriented. Only well chosen graphical representations support a comprehensive understanding of the thermodynamic interrelationships and the transfer to the problem."

Jan 1, 1996

The implementation of NAFTA in January of 1994 was expected to have small but beneficial effects for the Mexican economy, mostly through increased investment flows. Mexico's mining industry was especially likely to benefit, as mineral investment funds would be diverted to the now safer Mexico and away from similarly endowed but more risky Latin American mineral economies. The results of the past two years have shown that it is governments and macroeconomic factors that influence investment flows, rather than the fine-tuning of trade flows through so called "free-trade" agreements.

Jan 1, 1996

By G. T. Lineberry, W. J. Wiehagen

A paradigm shift As market economists, mine managers are interested in "staying in business" and even "prospering." Bottom-line results are the "order of the day." Concern for bottom-line results can invoke questions such as how much was produced, at what cost, and was anyone injured? While these questions will always carry everyday emphasis at the mine, they are fundamentally lacking in that they often appear, especially to lower levels of management and to the production worker, as pre-eminent concerns. Driven by market economics, many organizations have decentralized, outsourced, downsized, restructured and formed new coalitions. Investments in new technology and a concentration on productivity have been an essential part of these changes, contributing to improvements in both safety and efficiency. A reason for (and, perhaps a result of) these improvements has been the development of a highly experienced and flexible work force. This situation presents an interesting opportunity to modify a few paradigms about work life in general, and perhaps a few paradigms about how we invest in the miner, in particular. Studying these issues now night offer some interesting opportunities for the Future, as the foundations for the next generation of mine workers are laid. With the average "experienced" U.S. miner five to fifteen years from retirement, perhaps a key determinant of future success in the world market might be how well we make the transition from today's work force to the work force of tomorrow. We can ill afford to wait a few more years to tap into the special knowledge residing within a veteran mining work Force. The Work Crew Performance Model (WCPM) is one approach to defining, capturing and transferring this expertise. The WCPM suggests a paradigm shift, moving from a focus on products (quantity) to a focus on the process (quality). It also involves a slight change in the process -- a different way to think and work. Of great importance, it entails a belief and a commitment to people within the organization; a commitment to collect simple (but interesting) data; exploration for insightful ways to plot and integrate that data; and finally the search for creative methods to reinvest that knowledge back into the organization, that is, back into the work force. As a way of thinking, the WCPM subordinates information about how much is produced daily or how many were injured over a year's time to concern and detail for how the individual's and the work crew's performance contribute toward meeting organizational goals. Drawing upon the expertise within members of that work crew to address and solve operational problems is one approach for meeting organizational goals. This everyday focus on how we work is hypothesized by the WCPM to make the difference between a good section supervisor and the average one; an exemplar continuous-miner operator and the run-of-the-mill one; a mining crew that produces consistently high quantities, but, inadvertently, degrades the production of other units. The WCPM permits objective and reliable performance data to be collected. This data then can be used to define variability within tasks of work crew members; to relate observed variability to a cost consequence; and to more meaningfully analyze performance through the integration of traditional analytical tools, such as the production simulator, CONSIM, with a recommended behavioral approach, the WCPM. Basis for engineering test Most equipment selections and purchases involve a field trial test of the system. Technology is routinely bench tested at the manufacturer's facility, government agencies and the mine site. The WCPM suggests a similar, but more practical, method for testing the performance of a work system -a test for how technology is used (by people) at the work site. It implies learning from veteran mining personnel that have gone well "beyond the book." This approach to learning and to integrating training with everyday work life can help answer questions such as: What constitutes desirable perfor¬mance as, for examples, a shuttle-car operator, a miner operator or a bulldozer operator; what characterizes exem¬plary performance within the context of the work system, the technology and the work crew; how can investments in the worker he linked to measurable results within the organiza¬tion? This paper explores these questions and makes recom¬mendations for enhancing the cost-linkages between invest¬ments in people and the mine's monthly cost sheets.

Jan 1, 1996

By John A. Herbst

Plantwide control of mineral processing operations has long been sought for its potential benefits. These benefits include minute-to-minute optimization, reacting to disturbances in ore characteristics and equipment status as they happen and the coordination of all unit operations in pursuit of the highest performance level. However several difficult challenges have kept us from fully realizing those benefits. One of these challenges has been to provide fairly complete quantitative descriptions of Unit operations to account for critical interactions within and 'between unit operations. In some cases we understand the physics and chemistry very well and can incorporate that 'knowledge into phenomenological models. In other cases our knowledge is incomplete, so we must rely on other forms of knowledge such as fuzzy logic or neural nets. Another challenge to be met has been to simultaneously compute a large number of manipulated variables. In the past this challenge was met by optimizing only unit-by-unit, rather than on a global basis to significantly reduce the number of variables. In this paper, a procedure that globally optimizes one or two important variables is outlined. This procedure comes much closer to true plantwide optimizing control while remaining computationally feasible. Finally, another major challenge is to choose a meaningful global objective that can be calculated With the models and can be effectively optimized. Financial goals seems to be the objectives of choice. This paper discusses recent progress In overcoming the challenges and illustrates a promising approach which is being pursued at :Mexicana de Cobre's 'La Caridad copper ore concentrator. At M de C, advanced ,control strategies have been 'installed one at a time in the crushing, grinding and flotation sections. During this period, the throughput of La Caridad, Mexico's largest copper concentrator, 'increased from 76;000 tpd to 90,000 tpd. Plantwide integration is expected' to gain an additional 3% improvement in profitability.

Jan 1, 1996

By Baozhong Zhao

Laboratory experiments have been conducted on the removal of As, Sb and Bi from molten copper by SF 6 injection. The results showed that the impurities can be removed by SF6 injection in the? sequence of Sb >As >,Bi and the rate of Bi removal is affected significantly by the concentration levels of As and Sb in the copper melt. Analysis of the experimental data indicates that the impurity removal process is under chemical reaction control rather than by mass transfer of impurity through the molten copper phase. On the basis of experimental results, a kinetic model was developed and the order of chemical reaction and the volumetric chemical reaction rate coefficients of impurity removal were determined.

Jan 1, 1996

Detrital gold in the Greymouth-Hokitika area has been won from: (a) gravel of the Pliocene Old Man Group, (b) glacial outwash gravel of Middle and Late Quaternary age, (c) raised shoreline deposits of Middle and Late Quaternary age, (d) deposits resulting from the erosion of (a) to (c). The source of the gold was probably widely dispersed quartz veins in great thicknesses of greywacke and low-grade schist eroded from east of the Alpine Fault, with a contribution from veins in Greenland Group greywacke in the south. At times of high interglacial and post-glacial sea level, gold was concentrated along marine shorelines, and subsequent progressive uplift has resulted in a set of sub-parallel beach leads up to 100 m above present sea level. During glaciations, gold was concentrated in outwash streams close to moraines, especially where ice forming one moraine penetrated and destroyed an older one. Worked deposits in the Old Man Group may also be associated with glaciation. Apart from workings that are essentially extensions of past workings, significant new prospects may depend on inferences as to where prospective deposits are completely obscured by younger ones.

Jan 1, 1996

By Andrew G. Martin

In 1991, Modular Mining Systems began marketing a Slope Monitoring System (SMS) now installed at twelve mines. The SMS uses automated wire line extensometers to monitor field conditions frequently. Every few minutes, the slope displacement values and current temperature are transmitted to a central computer via a packet radio telemetry system. The desktop workstation receiving the data continuously provides updated displays of active slope monitors and generates audible and visual alarms if movement exceeds user specified thresholds. The computer system also generates numerous graphs and reports for quick analysis of slope stability. This work describes the functionality of the SMS, details improvements to the SMS hardware and software developed for several clients, outlines different installation techniques needed for wall rock and spoil monitoring, and interprets slope movement data using illustrations of stable and unstable conditions.

Jan 1, 1996