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By W. K. Tolley

The Bureau of Mines is investigating hydrometallurgical processing techniques to recycle metals from semiconductors and other advanced materials. Cadmium and tellurium were recovered from CdTe scrap produced in the manufacture of infrared optic devices. Sulfation, ferric chloride leaching, and oxygen-pressure leaching have been tested. Cadmium dissolution was achieved using oxygen-pressure leaching in dilute sulfuric acid. However, no satisfactory scheme for dissolution of the higher valued tellurium has been devised. Leaching the ground CdTe for 75 min at 110°C in 1.1M H2S0, under 120 psig 0, yielded 99.5% Cd extraction. Tellurium remained in the leach residue as TeO, and elemental tellurium; residual cadmium was less than 0.5%. The cadmium in the leach liquor was purified of coextracted metals such as gallium and iron by adjusting the pH. The cadmium was recovered as cadmium sulfate crystals by evaporating the solution. Recovery of by product metals, notably gallium, is possible.

Jan 1, 1991

By Roman Pyrih, Jim V. Rouse

Because cyanide is a naturally-occurring chemical, geochemical and biogeochemical mechanisms exist to retard or attenuate the movement of cyanide and its compounds in the subsurface and to degrade such compounds into low-hazard reaction products. The attenuation capacity of subsurface earth materials can be measured, predicted, and enhanced by simple and inexpensive procedures. The paper describes methods of testing the geochemical and biogeochemical attenuation capacity of the subsurface and offers general suggestions for methods of enhancing such capacity. It also presents examples of data which documents such attenuation.

Jan 1, 1991

By Lyman H. Hart

Michiquillay is a major copper deposit situated about 70 km (44 miles) northeast of Cajamarca in northern Peru (Fig. 1). It occurs largely in quartz monzonite in a shatter zone produced by the intersection of northwest- and northeast-trending fault systems. The geology is described by Hollister and Sirvas (1974). The ore deposit was drilled in 1963-1964 by Asarco, with results indicating a resource of 575 Mt (634 million st) averaging 0.72% Cu-0.03% Mo. A decision to bring the project to production has been deferred because world capacity to produce copper has been more than adequate to serve world requirements since 1964. The chain of events leading to the discovery of Michiquillay was set in motion by a decision by the management responsible for the Chilete mine to undertake an investigation of the surrounding area for a possible supplementary source of mill feed to bolster its decreasing lead-zinc reserves. Chilete, located 100 km (62 miles) inland from Pacasmayo, is the most northerly, important mining project in Peru, and little was known of the mineral potential north and east of that point. Relatively unimpressive reports of Colonial silver mining had attracted little investigation, and little was known of the regional geology. One study by Benavides (1956) had been made of the Cretaceous in the region of Cajamarca.

Jan 1, 1991

By D Vickers, N C. Fowke

The reduction of geological risk for planning of high production longwall faces is essential. Geological and geophysical techniques applied at Huntly West Mine before 1989 were unable to reduce the geological risk to an acceptable level. The success of a trial long-hole directional drilling programme at Huntly West Mine (Fowke et al, 1989) has encouraged the Coal Corporation of New Zealand to use the technology long-term, for seam definition. Initial drilling in 1989 completed a total of 3543 metres, with the longest borehole length being 369 metres (limited by number of rods available). A major re-interpretation of seam structure resulted from the drilling, which was able to fill in seam details between surface exploration boreholes. The undulating thick seam conditions at the mine require a refinement of drilling strategies used overseas. Long-hole directional drilling also displays potential for inseam gas drainage. Gas flows of the order of 1000 L/min were initially indicated in individual boreholes. Other gas parameters of the seam have been studied by Beamish et al (1991), and highlight the significance of the natural gas resource in the Huntly Coalfield.   The continued development of drilling technology will be of major benefit sustainable development, particularly in policy.

Jan 1, 1991

By Y. C. Kim

This paper describes the implementational aspects of a blast hole kriging system that has been developedfor the purpose of daily ore/waste control in an open pit mine. The primary goal of blast hole kriging is to improve the ore/waste delineation procedure. A complete computer program package called Blast Hole Kriging (BHK) System was developed for IBMIPC AT or XT computers, using the Fortran language and supplemented by a few assembly language routines for the bit- map manipulation. This paper emphasizes the practical implementation requirements of the system and discusses system design considerations.

Jan 1, 1991

By Yan. T. Y.

Uranium precipitation from an eluate using hydrogen peroxide has been studied in a laboratory continuous unit. The important process parameters were the dosage of H2O2, reaction pH and chloride ion concentration. In the process, the alkaline eluate is acidified to a pH of 2, then H2O2 at 110%-130% of the stoichiometric requirement is added, and finally NaOH is added to maintain a pH of 4 for one hour to complete the precipitation and settling. The chloride content in the system is controlled to 50g/L or below by rejecting part of the decant solution. The process has been successfully employed in commercial operations. The uranium recovery is complete, while the precipitate settles rapidly and can be processed to high purity yellow cake without filtration.

Jan 1, 1991

This paper reviews the current techniques employed in the prediction of subsidence and how they have been applied to partial extraction systems. The method using influence functions to describe the shape of the profile is investigated in detail and has been adopted to model the subsidence over workings in Huntly. It is compared with the profile methods developed in the United Kingdom and found to predict the subsidence profile more accurately than these methods.

Jan 1, 1991

By Churchill M

One of the significant changes which has occurred in the flotation sector of the minerals industry, over the last two decades, has been the successful development of the very large flotation machine. The last twenty years has seen the volume of the individual cell, available to the industry, increase by a factor of ten. Today, new mills, and existing mill modernization plans, can consider individual cell volumes as large as 85 m3 with the certainty that the metallurgical performance capability of the large machine is inherently as efficient as the smaller machine. The large flotation cell offers benefits to the user such as reduced floor space, lower total power, process control simplification, and reduced maintenance. However, the flotation machine size selection process, based on overall installation economics, must include such factors as process tonnage, flotation kinetics characteristics, and metallurgical performance objectives. This paper discusses the flotation machine size and circuit arrangement selection based on both metallurgical performance and economic considerations. A computer based flotation kinetic analysis technique, which has proven valuable in quantifying the metallurgical response of flotation circuits having different cell sizes and number, is utilized to illustrate the selection of cell size and arrangement best suited to a client's Requirement.

Jan 1, 1991

By Vincent Castronova, Jane Y. C. Ma, Joseph K. H. Ma, Chang-geng Mo, Carl J. Malanga

A group of bisbenzylisoquinoline (BBIQ) alkaloids has been shown to exhibit various degrees of effectiveness in preventing silicainduced fibrosis in animal models (1, 2). The capability of these drugs to interact with phosphatidycholine vesicles and rat alveolar macrophages was studied using fluorometric and equilibrium dialysis methods. The lipid binding affinity of these alkaloids was found to depend upon several structural factors including hydrophobic substitutions, the chiral configurations, and the double oxygen bridge-restricted conformation of the benzylisoquinoline moieties. Tetrandrine, which is highly effective in preventing fibrosis, showed strong binding to both lipid vesicles and alveolar macrophages. In contrast, curine and tubocurine, which have little or no effect on silicosis, exhibited only weak binding to lipid vesicles and almost no binding to cells. The moderate binding affinity of fangchinoline to vesicles and cells corresponded to a moderate effectiveness of the compound as an antifibrogenic agent. Methoxyadiantifoline, an alkaloid of unknown antifibrogenic potential, also exhibited high binding affinities for lipid and cells. In summary, this study indicates that alveolar macrophages exhibit large binding capacities for certain members of the BBIQ alkaloids. A positive correlation was observed between binding affinity to alveolar macrophages and the reported antifibrotic potency of these compounds, suggesting that the ability of these drugs to interact with alveolar macrophages may be a key step in inhibition of the progression of silica-induced pulmonary disease.

Jan 1, 1991

By Higuchi K

For the mechanisation or automation of mining, recognition of the shape of mined cavities is basic information. A three dimensional shape measuring system, developed and tested, includes an ultrasonic range finder which is attached to the tip of a serial link manipulator. The range finder can be moved to any position and direction in the operational space of the manipulator. The position of a point on the surface of the object is obtained from the position of the range finder, the direction of the beam of the ultrasonic waves and the measuring distance of the range finder.To avoid collision between the sensor and the object, the manipulator is controlled to trace the surface of the object For the tracing control, another ultrasonic range finder is employed. The test results show that the developed system has high performance.

Jan 1, 1991

By Charles Vaught

The U.S. Bureau of Mines evaluated the self-contained self-rescuer (SCSR) donning proficiency of 243 miners. These workers were from eight underground coal mines in the eastern United States. The objectives of the study were (1) to gather information on skill levels, since all miners in the study had prior instruction and opportunity to practice donning the apparatus, and (2) to summarize a quality control procedure useful in conducting periodic evaluations of donning proficiency. The sampling procedure used proved to be both reasonable and efficient in gathering information on training effectiveness_ It also provided a good statistical base for making informed site-specific decisions regarding SCSR training needs. Results from the observed samples at each of the eight mines indicate a wide variability across sites. The rate at which miners failed to isolate their lungs varied from 33 to 40.0 pct. Concomitantly, proficiency rates (miners either performing adequately or demonstrating a perfect 3+3 sequence) ranged from 13.3 to 63.3 pct.

Jan 1, 1991

Use controlled blasting techniques to reduce blast-produced overbreak damage to underground mine ribs and back for both safer working conditions and improvements in productivity. The Problem Blasting is used in metal and non-metal underground mine slopes, drifts and crosscuts to fracture rock to be excavated and further processed. Standard blasting also produces fractures in the rock beyond the desired excavation area. This is sometimes evident by rough surfaces, undercutting and other signs of excessive damage. This damage contributes to rockfalls in the mines, a major cause of injuries and fatalities, and equipment damage. A variety of controlled blasting techniques has been developed for civil engineering projects where long-term stability is essential. For several reasons, these methods arc not widely used in mining. For example, these methods incur additional costs and time; there is little need to maintain stable openings over long periods of lime; and there is the perception (hat corrective remedial techniques, such as rock bolting, are more practical. Basically the benefits of these methods are not demonstrably clear for application in underground mines.

Jan 1, 1991

By R. P. King

The central idea presented in this paper is straight forward. Some fairly obscure mathematical techniques are presented from the fields of integral geometry and stereology and these techniques are shown to provide workable quantitative relationships from which the liberation spectrum of an ore after comminution can be determined. The experimental data that is required can be obtained very accurately and conveniently by image analysis of polished sections of the original ore. This quantitative mineralogical analysis provides a bridge that can link the worlds of the mineralogist and the mineral process engineer. This paper has been written to introduce this quantitative approach to a wider audience in the hope that the approach will be used more widely and that the basic linear intercept analysis data will be measured for a wider range of mineralogical textures. This could lead to a more comprehensive characterization of typical mineral ores that will be of considerable use in practical mineral processing.

Jan 1, 1991

By David A. Larson

The future exploitation of crust deposits will require a dependable characterization system. The U.S. Department of the Interior, Bureau of Mines (Bureau) initiated research to develop a new sampling dredge by conducting a series of cutting and physical property tests on previously collected cobalt-rich manganese crust and substrate samples. Using the engineering parameters derived from these tests, a large, heavy dredge was designed and tested. This heavy dredge was capable of fragmenting and collecting in situ crust, but it created handling problems for the research vessel, thus an aggressive cutting, light-weight dredge was conceived and fabricated. The light-weight dredge is capable of fragmenting and collecting crust and some talus. This dredge can be used on flat or rough seabed terrains. It can be easily retrieved from hang ups and reset to sample again.

Jan 1, 1991

By Wang Hong Qu

This paper observes the shape of throw explosion crater its ejecta locus of internal medium and the process of distance along with slope's angle developing. It was discovered that initial velocity is inversely proportional to slope's angle. The velocity of surface distribution at the lower half crater of explosion is larger than at upper one. It carries the relevant calculated formula and physical process of explosion crater forming under the inclined boundary conditions, and some important law. It proved that the gravity influence is very distinct for the blast action in the little resistance line.

Jan 1, 1991

By P. A. Botha

Most sinter producers prefer to use a range of iron ores with the aim to optimize their sinter blends. ISCOR is however limited to the use of ore from two deposits, namely Sishen and Thabazimbi. Only sinter produced from Sishen ore is described in this report. The Sishen iron ore deposit provides high-grade hematite ore with a mean iron content of 65 per cent. Three major ore types are developed: massive, laminated and conglomeratic. The main ore mineral is hematite with minor to trace amounts of quartz, mica, phosphates and, in places, carbonates. A sinter product is characterized by its mineralogical composition and metallurgical properties. The production rate also plays an important role in the economic evaluation of sinter quality. Sinter-pot tests were conducted with varying basicities, given as the ratio of CaO to SiO:< and coke content. The results of these tests were characterized by mineralogical and metallurgical methods. Basicity of a sinter mix directly influences the mineralogical composition and metallurgical properties. The content of calcium ferrite and calcium silicate increases with increasing basicity, thereby increasing the reducibility and cold strength of the sinter product. Experiments performed during this study provided a model for the optimization of the sinter mix with respect to its mineralogical and metallurgical parameters.

Jan 1, 1991

By J. D. Morgan

In the first half of the year, lessening of cold war tensions was welcome. But Iraq&apos;s invasion of Kuwait in the second half led to the Persian Gulf War in January and February 1991. This caused an oil shock that dampened the economy. So the US gross national product rose only 0.9% to $5,463 billion (US billion = 109). The buildup of military forces in the Persian Gulf area focused greater attention not only on petroleum but also on other strategic materials. The Department of Defense continued to review stockpile goals and to upgrade several mineral materials. In addition, the Bureau of Mines continued to maintain the standby Emergency Minerals Administration. The Defense Production Act, which authorizes priorities, alloca¬tions and supply expansion, lapsed on Oct. 20. So the Selective Service Act of 1967 became the authority for assuring that orders of the armed forces and defense atomic-energy programs were given priority treatment. Consumer demand strongly affects mining worldwide. US citizens carry significant debt, and large stocks of housing and consumer goods are already in place. Some 250 million persons have 188 million licensed motor vehicles and 100 million dwelling units. Consequently, new car production fell 11 %, to 6.1 million units. Truck and bus production fell 8%, to 3.7 million units and new private housing starts fell 13% to 1.2 million units.

Jan 1, 1991

By David M. Parkes, George E. Davies

"Mathematically, the proposed formula is: ""Human Effectiveness + Technological Improvement = Success in the Nineties"". A brief review is made of geology, level of technology, management and labour situations, and range of production costs in coal producing countries. This comparison shows keen competition for Canadian coals, especially from the People&apos;s Republic of China, South Africa and Australia. Domestic competition comes from nuclear energy, hydro-electric generation, natural gas (if permitted) and eastern United States coal.The huge increase in the size and power of surface mining equipment in the last forty years led to modern large-scale open pit mining. While conventional truck and shovel operations will continue to be widely used, more continuous mining and conveying systems will be installed as pits become deeper and haul distances longer. Computer systems will become more sophisticated and their applications more widespread, leading to higher productivity and closer control of all operations and equipment performances and to partial or complete automation of certain operations.The underground revival will be driven by a new generation of mining people, cooperating to produce over 3 million t/y from 300 m longwall faces retreating over 3 km resulting in mine productivities of over 40 tonnes per man shift, as is already achieved in several mines throughout the world. Continuous operation using on-line control system will assist in consistent production with availabilities over 75%."

Jan 1, 1991

By H. Demirel

This paper deals with concentration of hematitic-limonitic iron ores. The ore sample obtained from Karakuz (Turkey) contain:. about 40-46 I Fe. First, a low intensity magnetic separation process was employed to separate the strongly magnetic particles cf "-10+2 mm" and "-2+0.075 mm" size fractions and magnetic concentrates with 59.1 % Fe aid % 58.0 Fe were obtained respectively. The non-magnetics of both fractions were then fed to a nigh intensity permanent magnetic separator. The Fe contents of "-10+2 nun" and "2+0.075 mm" size fractions were increased from 28.2 to 51.13 and from 35.4 7. to 43.25 respectively after single pass. Easing on these results, it was concluded that the high intensity permanent magnetic separator could he used as a pre-concentrator f.7.1- hematitic-limonitic Karakuz iron ore.

Jan 1, 1991

By Frédéric Flament, Mary Goldman, Gille Barbery

"Pilot plant testwork on autogenous and semi-autogenous grinding was conducted at the Centre des Recherches Minérales du Québec (CRM) to investigate the effect of ball addition, solids concentration in the feed, specific energy consumption and feed size distribution.A mathematical model that incorporates breakage and surface mechanisms of loss of mass was developed to predict load size distribution of autogenous and semi-autogeneous mills. An empirical model was used to predict product size distribution of autogenous and semi-autogeneous mills.IntroductionAutogenous (AG) and semi-autogenous (SAG) grinding circuits offer potential capital and operating cost savings when compared with conventional grinding. Empirical relationships have been developed to calculate specific power consumption for SAG mills using pilot plant test results (Mular et al., 1989; Barrett and Allan, 1986). Empirical models can be obtained from plant practice data but are applicable only to the particular ore and set of operating conditions used in the model. Grinding mechanisms have to be taken into account in order to develop a model that can be applied to different ores and mills.In AG and SAG, the ore itself acts as grinding media, with the finer sizes being crushed by the coarser ones. Surface mechanisms of loss of mass, in which the inner core of the particle remains intact, also take place. In SAG milling, the effect of balls also has to be taken into account. The role of each one of these mechanisms changes with particle size and the model has to account for such changes."

Jan 1, 1991