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By Alessandro Navarra, Roberto Parra, Boyd Davis, Frank Mucciardi

A smelter scheduling algorithm has been developed, which allocates the oxygen production between the smelting furnace and the converter aisle, so as to maximize copper throughput. The algorithm is intended for daily operation planning, controlling the sequencing of the converter cycles, and the oxygen drawn by these cycles. In some cases, it may be worthwhile to decrease converter oxygen allocation in favour of the smelting furnaces. Thus, a better utilization of the oxygen plant can increase primary copper throughput by several percentage points. This principle is demonstrated through sample computations. The approach presented in this paper can be incorporated into smelter management software.

Jan 1, 2015

By K R. Brentley

"Tshepong Mine, Harmony’s largest gold producing mine, is situated in the Free State portion of the Witwatersrand Basin, east of Odendaalsrus and north of Welkom, South Africa. The Basal reef is a narrow tabular conglomerate and is the main gold bearing ore body. The strata strikes mainly in a northsouth direction with an average dip of 22 degrees. Currently mining takes place at depths of between 1 690m and 2 150m below surface. The Basal reef unit consists of a conglomerate ranging between a few and 30cm in thickness. Some 80-90% of the gold occurs in the lower portion of the conglomerate. Directly above the conglomerate is a quartzite placer unit, the Basal quartzite, which is a clean, hard competent rock and varies in thickness between 50cm and 200cm. The Basal unit is overlain by the Khaki shale which can vary between 30cm and 500cm in width. It is weak and incompetent khaki coloured chloritic shale.A method of stoping, termed “undercut”, is practiced in order to remove the lower 15-20cm of the gold rich strata. The method entails removing this portion along with some 70-80cm of footwall host rock which is a strong competent quartzite. The hard competent quartzite overlying the conglomerate is left in-situ to form a competent hangingwall which can stabilize and prevent exposure of the weak Khakishale. This method of extraction was developed through trial and error and has been used reasonably successfully since its inception in the early 1960’s where the method was developed to extract the Basal reef at the Western Holdings Mines. Recently prospect drilling and a number of localised hangingwall failures indicated that the residual quartzite beam could be less than 60cm and in some instances as thin as 30cm in certain areas of the mine. The result of this is a less stable hangingwall which not only poses a safety risk to workers in these areas but also had the potential of locking up some 840 000 Tonnes of gold bearing ore. At the present gold price this amounts to revenue of approximately ZAR1.5 billion (U.S. $143 million).This paper discusses the method of “undercut stoping” and existing practices in place at Tshepong Mine. It also explores new initiatives such as the use of a simple freely-supported elastic beam solution to perform back analysis, on-site data capturing of beam thickness and support geometries in order to develop empirical design charts and numerical modelling to assist in the verification of the empirical design method."

Jan 1, 2015

By C. Samuelsson, H. Ahmed, B Björkman, A. Andersson

The cost of raw material and energy is a continuing driving force towards working with increasing the recycling of ore based steelmaking residues. In Sweden no on-site sinter plants are operated at the integrated steelworks. Instead, selected residues from the plant are incorporated in a cold bonded briquette product which is recycled to the process via the blast furnace (BF). Since the BF sludge is the major bleed of zinc out of the furnace it is required to be de-zinced prior to recycling in the briquette product. In the present work landfilled BF sludge has been characterized with respect to chemical composition, particle size distribution, X-ray diffraction (XRD), and scanning electron microscopy (SEM). The sludge was also subjected to laboratory scale hydrocyclone trials aiming at reducing the zinc content making the sludge viable for recycling. The results suggested that the sludge had been agglomerated prior to the characterization and hydrocyclone treatment. The zinc removal using the hydrocyclone was discussed.

Jan 1, 2015

By V. Labiouse, F. Orellana

"Hollow cylinder samples can be tested for both the characterization of rock properties and the physical modelling at reduced scale of engineering applications. Particularly, this type of experimental setup can be used to simulate different stress conditions around underground openings, as already developed in the petroleum engineering field e.g. to study the instabilities around deep wellbores during either drilling or the oil production phase. Some authors have also used this technique to successfully characterize the damaged zone around underground openings in the tunneling engineering field looking for an efficient design of their support.This article presents a new hollow cylinder testing device developed at the Rock Mechanics Laboratory of the Ecole Polytechnique Fédérale de Lausanne (EPFL), Switzerland. It allows a full and independent control of the confining pressure and pore water pressure conditions at both the inner and outer boundaries of Thick-Walled Hollow Cylindrical samples. In order to mimicking a tunnel excavation in a porous rock mass, after initial recovery of the in-situ stress and pore water pressure, the hollow cylinders are subjected to a decrease in the internal confining pressure. Moreover, X-Ray Computed Tomography scans of the specimens are performed through the testing cell before and after the mechanical unloading to monitor the displacements undergone and the sample damage. The equipment, testing procedure and data analysis techniques are briefly presented in the paper.The good performance of the apparatus has already been checked on weak rock specimens, among others on Boom and Opalinus Clay samples. In many configurations, the mechanical unloading is found to induce a Damaged Zone (DZ) around the central hole. Its geometry and extent show a great similarity with in-situ observations around tunnels driven in the Boom and Opalinus Clay formations. Such similarities contribute to increase confidence in the understanding and modelling of the ongoing processes."

Jan 1, 2015

By S. Bhattacharjee

"Rock failure process is generally recorded or measured using conventional sensors like strain gauges, seismic, micro-seismic, acoustic, electromagnetic and other techniques. The above sensors are either to be pasted on the surface of the rock sample or placed very near to it to capture the response of the sample with the increment of load. This requires precise tools to cut or polish the locations where sensors are to be placed. Moreover, deformation or acoustic or micro-seismic activities are recorded only at the locations where sensors are pasted.Recent development in Digital Image Correlation (DIC) technique has shown promise to measure deformation / strain at every location of the surface of a sample. In DIC, two images (reference and deformed) are taken within a small time interval of the same object are compared to estimate the change in reflectance as a function of displacement, velocity or rate of strain at each pixel while the object is undergoing through a loading process. In this study, extended digital image correlation (X-DIC) technique has been implemented using 4-noded quadrilateral elements with a discontinuity surface in the deformed image. The continuous and enriched displacements are estimated at each node.The X-DIC method is verified using numerically generated images. The study has been further extended to evaluate the performance of X-DIC method on deformation analysis of experimental samples under uni-axial loading condition. The results of this study show that X-DIC method is an effective tool for determination of displacements of the entire surface of a rock sample having a discrete crack or discontinuity in a non-contact manner. This method demonstrates the applicability to investigate rock failure mechanism for the entire sample in a laboratory set up as well as monitoring of pillar failure mechanism in underground mines."

Jan 1, 2015

By N. Ginouse, S. Reny

"In the mining industry time is critical as production depends on the speed of the mining cycle. During the mining process, the time required to re-open access for the next phase of an underground heading is a key point that strongly depends on the ability of the selected ground support technique to promptly ensure the safety of workers. Fiber reinforced dry-mix shotcrete has been proven to be an efficient and well adapted technique, able to produce a ground support material with the required energy absorption or flexural toughness in a single application phase. In this context, this paper demonstrates the possibility of significantly speeding up the mining process by using a new fiber reinforced dry-mix shotcrete. The new fiber reinforced dry-mix shotcrete is capable of developing flexural toughness in only 24 hours that is equivalent to what is typically achieved after 28 days using current fiber reinforced drymix shotcrete technology.INTRODUCTIONShotcrete is often used for ground support when using the drill and blast method or other tunnelling methods. But before re-opening access for the next phase of the underground heading, the applied shotcrete is required to reach a minimum compressive strength and in case of fiber reinforced shotcrete, a minimum flexural toughness (energy absorption) in order to ensure the safety of the workers going into the heading. Combined with bolts, the use of conventional fiber reinforced shotcrete becomes an interesting method for ground support as it is applied very soon after excavation and works to stabilize ground movements (Bernard E. S., 2009). In this case, the toughness development of fiber reinforced shotcrete becomes an important feature of the material when looking to speedup the mining cycle. However, early re-entry criteria in underground openings are difficult to ascertain as the load carrying capacity of fiber reinforced shotcrete is usually assessed after 7 or 28 days. For this reason, re-entry criteria varies from one mining area to another and are usually based on compressive strength requirements. For example, in northern Ontario, Canada, one of the current practices in the mining industry consists of allowing safe re-entry once fiber reinforced shotcrete has developed a compressive strength of higher than 4 MPa (Dufour, O’Donnell, & Ballou, 2003). Flexural toughness requirements on fiber reinforced shotcrete are also typically based on evaluation after 28 days."

Jan 1, 2015

By Iina Vaajamo, Jani Jansson, Lauri Pesonen

In pyrometallurgical operations, structural integrity of a high temperature furnace plays a crucial role in the overall safety, profitability and ecological footprint of the plant. Furnace integrity is related to how reliable a furnace is and it can be compromised, for example, by having poor operating and maintenance practices, an inefficient cooling system and flaws in the overall furnace design. These flaws and poor practices might lead to unexpected shutdowns, production losses, increased emissions, or worse. This paper presents the main factors to consider when engineering a furnace and developing its operating practices, while ensuring safe and reliable operations without compromising process efficiency and quality of the final products. In this respect, Outotec’s solutions for the cooling system and for automation systems like PROSCON, Process Advisor, Sentinel and our Smelting Information Management System, are also introduced.

Jan 1, 2015

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By Tom Snyder, John Brulia

PART 3 – UN Identifi cation Markings for the Highway Transportation in Commerce of Bulk Explosives, Oxidizers, and Combustible Liquids

Jan 1, 2015

By S. M. Rupprecht

"SynopsisOver the last decade in South Africa, there has been a significant increase in the number of mining operations, both open pit and underground, which use independent contractors to carry out mining activities. Often mine owners will choose the contractor option without fully understanding the consequences of undertaking this option. Traditionally, contract mining has come at a cost premium of about 15% to 20% compared to an owner mining scenario. However, due to the large number of junior mining companies entering the mining arena in South Africa contract mining rates have increased, with cost premiums as high as 50% being reported. This paper looks at the merits of owner mining versus contract mining and describes under what conditions it may be favourable to select the one option over the other. In addition, the methodology of entering into contract negotiations with the objective of establishing a fair and sustainable relationship is discussed.IntroductionOver the last decade in South Africa, there has been a significant increase in the number of mining operations, both open pit and underground, which use independent contractors to carry out mining activities. Surface mining, for example, may use contractors to conduct drilling and blasting operations or load and haul operations. Underground mining may contract out work such as shaft sinking, mining, support, construction work, cover drilling, sweeping and vampings. Common surface operations such as mineral beneficiation, waste disposal, security, and product transport may also be outsourced to contractors.Many companies have a business model that utilizes contractors for the entire mining cycle, maintaining a small head office to provide direction and control. The difficulty with this option is that often mining companies will choose the contractor option without fully understanding the implications."

Jan 1, 2015

By Q. G. Reynolds, R. T. Jones

The choice of furnace design parameters has a marked effect on the integrity of the furnace that is constructed. The design methodology for DC arc furnaces typically begins with the chemical reactions and feed materials that define the process. The specific energy requirement of the process, and the feedrates of the raw materials largely determine the power requirement for the furnace. A chosen value for the 'power intensity' sets the diameter of the furnace. Justification is provided for why this is a good choice of scale-up parameter. Equations are presented to quantify the resulting trade-off between thermal efficiency and the degree of error that can be tolerated in the balance between power and feedrate. This improved understanding should provide a better rationale for selecting an appropriate power intensity (or furnace diameter) for future furnaces.

Jan 1, 2015

By Mark McComb, Geoffrey R. Lane

"Over the years many differing approaches have been developed to clearly understand the nature, mode of occurrence, associations and deportment of both free-milling and refractory gold in a wide variety of differing geologic environments and plant products. Many approaches can be taken to characterize the ore which may occur as complex fine grained gold, ultra-fine grained gold, coarse nuggetty gold, complex Asrich refractory gold and double-refractory gold. The approach taken in assessing small drill core composites from Novo Resources Beaton Creek Paleoplacer gold project located in the Pilbara region of Australia was complicated by the nature of the ore, the small amount of sample available from current exploration work, and the gold grade and the grain size distribution. In this case the scope of the study was limited by sample availability although significant amounts of valuable information was also gained. This gold characterization study included the following elements:??Size fraction assays??Ore microscopy??Preparation of heavy mineral concentrates from sized fractions (screening) of crushed or milled head using heavy liquids and Superpan table.??Systematic scans of the heavy mineral concentrate, middling, and tailing fractions using TIMA Automated Scanning Electron Microscopy integrated with an Energy Dispersive Spectrometry to provide semi-quantitative elemental analysis of the individual grains found in the sample.The unique methodology employed to detail the gold deportment was the combination of the Tescan Integrated Mineral Analyser (TIMA) and the Oxford INCA GSR software. This technique not only allowed us to document the deportment of gold but recognize other associated minerals, which included gersdorffite, chalcopyrite, uraninite, coffinite, brannerite and several Rare Earth-bearing minerals.INTRODUCTIONGold deportment studies are commonly carried out on preliminary gold exploration projects in order to determine the various limitations, which may effect processing of the potential ore. This is often because it may be expected that there may be a refractory component to the gold, which may limit physical separation techniques and suggest more costly hydrometallurgical techniques. Often when carrying out gold deportment studies the mineralogical methods may be limited to assuming that the gold will be fine and easily found using standard techniques of optical microscopy or Scanning Electron Microscopy. This may not always be the case as various geological environments may pose their own individual problems to determining the deportment of the gold grains."

Jan 1, 2015

By M. Laliberte

"Gold-mine effluents are often characterized by high concentrations of copper, ammonia and cyanide derivatives (mostly cyanates and thiocyanates). While not acutely toxic to birds, this water can be acutely toxic to fishes and invertebrates. In many jurisdictions, the effluent requires further treatment in order to pass a mandatory requirement to be nonlethal to species like the rainbow trout (Oncorhynchus mykiss) or Daphnia magna. Using actual mine water, it has been demonstrated that aerated moving bed biofilm reactors will biodegrade the ammonia, cyanides, cyanates and thiocyanates, thereby removing the toxicity associated with these components. By removing copper by precipitation the water can be made to pass acute toxicity tests. Tests have demonstrated that the process is stable between 4 and 25°C, with no significant changes in the treated water composition. Once the biomass is acclimatized, the process is resistant to upsets and requires very little inputs except for phosphorus and air. Furthermore, it has been demonstrated that an anoxic reactor can be added downstream of the aerated reactors to remove nitrates if required.IntroductionThis paper will demonstrate that gold-mine effluents, which are toxic to fishes and invertebrates, can be made nontoxic by using a combination of chemical precipitation and biological oxidation.The typical composition of gold-mine effluents will first be described. The applicable legislation will then be introduced, with its requirement that the treated effluent be nontoxic. The toxicity of a typical untreated effluent will then be confirmed, and the sources of the toxicity identified. After that, a number of toxicity reduction treatment methods will be presented, and the selected method will be described.The lab tests that confirmed the efficiency of the treatment method will be presented, with three phases of testing as the understanding of the process gradually improved. Toxicity test results showing that the water is nontoxic after treatment through the temperature range will be presented."

Jan 1, 2015

By C. O’Hara, S. Roy, K. Swedburg, J. Katchen

"New Gold Inc.’s New Afton concentrator commenced operation in June 2012, producing a copper-gold-silver concentrate. During the first two years of operation, various optimization efforts have improved mill throughput, recoveries and concentrate grade. Daily mill throughput has increased 20% above the design rate. This was achieved through more consistent instantaneous feed rate and size distribution from the mine reclaim stockpile, higher pebble crusher reliability, changes to the SAG and ball mill grinding media sizes, larger SAG grate openings, reduced SAG discharge screen-deck aperture size and an increase in the maximum ball mill power draw limit. Metal recoveries at New Afton are primarily limited by liberation in the coarser size fractions; therefore, improving the grind size at a given mill throughput has been the main means of improving recovery. The average rougher flotation feed F80 size was reduced from 175µm in Q1 2013 to 165µm in Q1 2014, while the average operating mill throughput increased by 25%. Other flotation circuit changes focusing on recovery improvement include the addition of froth crowders to the rougher cells and the use of a stronger frother. The average concentrate grade increased from 22% Cu in Q1 2013 to 25% Cu in Q1 2014. This was achieved by redirecting the flash flotation concentrate stream to the regrind circuit and by the addition of lime to the cleaner circuit.This paper describes the above improvements made at the New Afton mill. The paper describes the objectives, timing and end result of each area of improvement.IntroductionThe New Afton Mine is situated approximately 10km west of Kamloops, British Columbia, 340km north-east of Vancouver. The mine has a moderate climate, access to transportation and electrical infrastructure, nearby fresh water supply, and close proximity to industrial and mining service businesses. The population of Kamloops is around 90,000 with most mine employees living in or around the city."

Jan 1, 2015

By William Gleason

"The Colorado School of Mines has used the Edgar Mine in Idaho Springs as an experimental mine to teach students since 1921. Since the school acquired the former gold, silver, lead and zinc mine, countless students have received hands-on engineering lessons on their way to earning mining engineering degrees. On Dec. 14, the House Subcommittee on Energy and Mineral Resources held a historic field hearing about the future of mining education in the United States in a classroom about 300 m (1,000 ft) inside the Edgar Mine. Representatives Doug Lamborn (R-CO), Rob Bishop (R-UT), Cresent Hardy (R-NV) and Ed Perlmutter (D-CO) were on hand for the first ever congressional hearing held in a mine where they heard testimony supporting the Mining School Enhancement Act, which was introduced to Congress by Hardy and Perlmutter on Oct. 9, 2015. The act, which is part of a larger mining development and reclamation reform package, seeks to address the absence of a viable pipeline necessary to replenish current faculty vacancies in United States Mining Schools. “What better place to hold a hearing to discuss the need for future mining engineering experts,” Subcommittee Chair Lamborn said in his opening statement. “It is a need felt by industry, states, the federal government as well as nonprofits.” The Mining School Enhancement Act would redirect millions of dollars in fees that are being collected from active mining operations to fund the research and educational programs at engineering schools with mining programs. Those fees now are being used in the form of grants awarded by the Surface Mining Control and Reclamation Act of 1977 (SMRCA)."

Jan 1, 2015

By A. O. Sfriso

"Numerical modelling is becoming universal in rock engineering practice. Most applications focus on the prediction of failure loads of 2D problems, where the numerical models are useful extensions to analytical methods and experience-based design criteria. For 3D problems and problems where the assessment of serviceability indicators – displacements, ground-structure response, etc. – are of importance, the selection of the constitutive models themselves and the implications of the selection of material parameters may have a very heavy impact on the reliability of the model outcome and its predictive capability.This paper overviews basic common aspects of constitutive equations used in practical rock engineering and summarizes some challenges that are frequently observed when reviewing numerical models performed for routine problems in rock engineering. INTRODUCTIONNumerical methodsFrom a philosophical perspective models, either analytical or numerical, are idealizations of a perceived reality. For us engineers, models are just tools we use to guide our judgement and understanding of the problem in hand. When dealing with problems in rock engineering, we resort to a wide range of techniques:1. Closed form solutions like confinement-convergence methods for circular tunnels: these methods satisfy equilibrium and compatibility requirements at the cost of a crude simplification of the material behavior and geometry;2. Limit analysis methods, like bearing capacity formulas: lower bound methods satisfy equilibrium but sacrifice compatibility, and upper bound methods do the opposite. Material behavior must be simple, geometry admits limited freedom;3. Limit equilibrium methods, like method of slices for slope stability: they satisfy restricted forms of equilibrium, do not satisfy compatibility requirements, require simple material behavior but have a much greater flexibility on geometry;4. Numerical methods, where a mesh is employed to discretize the problem geometry: when properly formulated, these methods satisfy equilibrium and compatibility requirements and give reasonable approximations to the behavior of very complex geometries and construction sequences. Very little restrictions remain on geometry and material behavior, but the cost of calibrating the material parameters can be very high."

Jan 1, 2015

By Syd Peng

"As the International Conference on Ground Control in Mining (ICGCM) enters its 35th year in 2015, it is time to look back and identify the areas that need to be emphasized and to look forward to see what areas need to be researched in the future. In the past three decades, ground control has made a tremendous advancement, and many case studies published in the 36 volumes of proceedings have demonstrated its important role in the daily mining operations. However, there is still plenty of room for improvements. This paper discusses the research needs in 12 subject areas, including mine geology, rock property, zones of disturbance in overburden, computer modeling, underground stress measurements, research method, roof bolting, coal pillars, failures, subsidence, shield supports, and coal bumps.INTRODUCTIONThe International Conference on Ground Control in Mining (ICGCM) was founded in 1981. Since then, 1,546 papers have been published in the 36 conference proceedings, including the three surface subsidence workshops held in the 1981, 1986, and 1992. All types of topical areas regarding mining, from geotechnical core loggings in the exploration phase through backfilling after mining to finally spoil piles stability on the surface, have been addressed. A review of these papers, and other related literature as well, indicate that ground control has developed to become an inseparable part of mine design and a problem-solving tool for safe production.After 34 years, it is time to look back and identify the areas that need to be emphasized and to look forward to see what areas need to be researched in the future. There is no doubt that the conference series has achieved the goal for which it was originally designed: to provide an annual forum for the exchange of information among the researchers, government regulators, equipment manufacturers, consultants, service providers, and—above all—mine operators. There have been many papers addressing the application of ground control techniques for successful mine design and safe production, and, without these papers, many projects would have failed. In fact, the conference emphasis on application types of papers may have steered too far toward the application side. A review of the conference papers shows that papers have been leaning mostly toward the applied side, leaving most, if not all, fundamental issues behind in nearly every topical area. This paper addresses research needs in 12 topical areas: mine geology, rock property, zones of disturbance in overburden, computer modeling, underground stress measurements, research method, roof bolting, coal pillars, failures, subsidence, shield supports, and coal bumps."

Jan 1, 2015

By Dale Ramsey

As someone who has enjoyed photography as a hobby for many years, aerial photography to me has always been an exciting way to give a different perspective to my images. Our industry is always in search of new technology for bet­ter and more cost effective methods to improve our trade and aerial photography is a great tool to improve project planning or document its progress. It has typically involved conventional aircraft both fixed wing and helicopters but neither method is always available or cost effective. The lat­est innovation since digital imaging is the development of Unmanned Aerial Vehicles (UAVs) or drones. But there is a lot of uncertainty with this amazing new technology’s fu­ture in the U.S. as the Federal Aviation Administration (FAA) is under review and development of UAV regulations for commercial use which are slated to be completed in 2015.

Jan 1, 2015

By A. J. Martin, M. J. Peoples, D. J. Adams, A. Opara

"The weathering of coal mine waste rock releases iron, calcium, sulfate and associated trace elements like selenium (Se). Nitrogen species are also found in association with coal-mining drainages mainly due to the leaching of residual blasting compounds. Elevated concentrations of Se are a ubiquitous occurrence in coal-mining environments in British Columbia. A major concern with waterborne Se in British Columbia is the potential for its bioaccumulation in aquatic food chains.Treatment to remove Se from coal-mining waste waters has proven to be challenging for conventional water-treatment technologies. Compounding this challenge, many streams are characterized by high flows and low selenium concentrations. Conventional membrane and ion exchange treatments produce concentrated brine streams that are difficult to treat or require disposal. Conventional biotreatment systems use excess nutrients to provide the required electrons to compensate for inefficient and variable electron availability, as well as to adjust reactor chemistry.This paper's electro-biochemical reactor (EBR) technology provides a controllable and consistent supply of useable electrons to the microbes directly at a low voltage potential (1-3 V) and low current. In this manner, the EBR technology overcomes the shortcomings found in conventional systems, as it reduces the required nutrient addition and provides a more controllable, efficient, economical and robust biotreatment system. Additionally, the EBR process does not produce excess solids or biomass; therefore, solids management post-treatment is not required.Laboratory EBR bench-scale and on-site pilot-scale systems were used to treat five British Columbia coal-mine waste waters; influent Se concentrations ranged from 35 µg/L to 531 µg/L. Se treatment targets for the tested waters ranged from 5 to 10 µg/L. Mean Se concentrations in EBR effluents ranged from 0.5 µg/L to 1.4 µg/L, while reducing sulfate concentrations. The test data demonstrate that the EBR technology is an effective Se removal option for British Columbia’s coal-mining waste waters.IntroductionSelenium in Mining. Selenium (Se) is a naturally occurring trace element, which is an essential nutrient in small amounts (Thompson and Robinson, 1980; Brown and Arthur, 2001). However, it is also toxic to aquatic life, birds, and humans at very low concentrations. A major concern with waterborne Se is the potential for its bioaccumulation in aquatic food chains, resulting in acute and/or chronic toxicity to fish, water birds and amphibians (Besser et al., 1996; Conley et al., 2009)."

Jan 1, 2015

By H. Huang, R. N. Gow

"The reactivity of an enargite mineral electrode was investigated spectroelectrochemically under conditions typically found in alkaline sulfide leach solutions, with pH 11-13 and Na2S additions of 50 and 250 gL-1. A bulk enargite electrode was cycled between 0 and -1,000 mV for each set of solution conditions. Raman spectroscopy was used to determine and compare surface formations against species in mass-balanced EH-pH diagrams generated using STABCAL. Previously, it was determined that arsenic could be selectively leached under alkaline conditions at an average solution potential of -300mV, across the pH range 11-13. Operating under such conditions allowed for the selective leaching of arsenic with elemental sulfur formation. From several of the voltammograms obtained during this current testing, the formation of elemental sulfur appeared at increasingly reducing conditions with increasing sulfide concentration. At high concentrations, copper started to dissolve, possibly as a bisulfide complex, reducing the selectivity of the leach, unlike previous studies. However, the presence of the higher sulfide concentration is also anticipated to prevent passivation by consuming any surface formation of elemental sulfur. This study provides insight into the operating parameters of alkaline sulfide leaching in regards to the selectivity of arsenic leaching, as well as guidance for control of reagents and solution potential and, of course, the need for water treatment afterwards.IntroductionEnvironmental limitations on the pyrometallurgical processing of arsenic-bearing concentrates have forced operations to consider other solutions. Attempts to hydrometallurgically process enargite (Cu3AsS4) fall into two categories: the co-dissolution of arsenic and copper under acidic conditions, and the selective leaching of arsenic under basic conditions. The authors believe that the selective leaching of arsenic is more amenable because it produces a solid copper phase, preferably chalcocite (Cu2S) or covellite (CuS) that could then be processed using conventional methods already in place in the copper and gold industries. Potential leaching methods include alkaline sulfide leaching (Achimovicovica et al., 1999; Anderson and Twidwell, 2008a,b; Tongamp et al., 2009 and 2010), hypochlorite leaching (Vinals et al., 2003; Curreli et al., 2005; Mihaljovic et al., 2007), ammoniacal leaching (Gajam and Raghavan, 1983), and acid leaching (Gow et al., 2014b) with or without fine grinding to mechanically activate the enargite surface and increase normally slow leach reaction kinetics (Achimovicova et al., 1999; Balaz et al., 2000; Balaz and Achimovicova, 2006). In this study, the reactivity of enargite under alkaline sulfide leach conditions was examined."

Jan 1, 2015