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By R. Halatchev

This paper treats the spatial aspect of mine sequence optimization, revealing it in the context of determining the optimum number of cutbacks of an openpit mine. Cutback mining is currently a dominant method in the mining of base and precious metals. It is based on a pseudo-economic discretization of the pit space using advanced pit design algorithms. The result of implementing such an approach of pit design is the generation of pit shells, which need to be grouped into an optimum number of cutbacks to maximize project value. In this paper, the development of a mathematical solution of this problem using combinatorial analysis is presented. The solution provides a multivariate investigation of the optimum mine sequence with the implementation of a method for production scheduling optimization that uses Net Present Value (NPV) as a criterion for assessing the economic efficiency of mine sequencing. A case study using the conditions of a hypothetical openpit gold mine is provided to illustrate the applicability of the approach. The results obtained reveal the complex nature of NPV variation as a function of the cutback geometry.

Jan 1, 2015

By Rick Piovesan, Pramod Rao, Nihal Bohra, Mark Wahler

"This paper discusses the approach followed for the geotechnical design of 355 mm and 457 mm diameter driven open-ended steel pipe piles used for a gas plant at a green field site in Pilbara region in Australia. The principal bearing layer at the site comprises of calcareous Red Bed soils and weak rock, which is the typical geology along a significant length of the northern Western Australian coastline with carbonate content up to 70%. The uncertainty associated with the mechanical behavior of the calcareous soils and cemented soils (weak rocks) presented design challenges in the selection of appropriate pile design method and design parameters for pile capacity estimation during Front End Engineering Design (FEED). The American Petroleum Institute (API)-based design methodology was adopted. The representative design parameters for the Red Bed weak rock were established by treating the weak rock as clay with undrained shear strength as one-half of the characteristic unconfined compressive strength (UCS) value. Both statically load tested and CAPWAP (Case Pile Analysis Wave Program) estimated ultimate axial pile capacities on 25 early pre-production indicator piles demonstrated that the API design methodology for siliceous soils provides reasonable prediction of axial pile capacity in the red bed soils/weak rock and no reduction to API computed axial capacity due to carbonate content is warranted. The results also demonstrated that penalizing axial pile capacity solely based on carbonate content is not appropriate.IntroductionA gas processing facility was proposed to commercialize the gas reserves located 130 km offshore from the north-west coast of Western Australia (WA). The project site is a green field site located in the Pilbara region along the northwest coast of WA. Specific information regarding the site has been withheld due to confidentiality reasons. The site layout is shown in Figure 1.The site comprises low-lying tidal flats, clay pans and sand dunes covered with low scrub. The onshore site levels vary from elevation 1 m to 10 m AHD (Australian Height Datum), with the largest proportion of the area (excluding sand dunes) between elevations of 1 m and 3 m.The onshore facilities are to comprise a liquefied natural gas (LNG) plant site, a construction camp, the land-based portion of the materials offloading facility (MOF), roadways, and borrow pit areas.The existing ground levels within the process train area, where pile load testing was performed, vary from over 7 m AHD where the summits and peaks of the central dune exist to typically 1 m to 2 m AHD towards the east and west edges of the dune. The proposed finished grade for the process train is set at 7 m AHD."

Jan 1, 2015

By João Veludo, Eduardo Júlio, Helen D. Robinson, Jesús E. Gómez

"Utilization of micropiles for structural retrofit requires connection of the micropiles to the footings of the existing structure. Almost ten years ago, an experimental research effort was carried out in the US to investigate the magnitude and mechanism of development of the bond strength between micropiles and existing concrete. The study resulted in important conclusions on the mechanism of connection capacity development and provided specific recommendations for practical design of micropile-to-footing connections. In the last five years, the original study was complemented by an intensive experimental effort in Portugal aimed at answering many of the questions still remaining on this topic. This paper is a summary of the knowledge that is presently available on the capacity of micropile-to-existing footing connections. It presents the results and observations of model tests performed in the US and Portugal, as well as some tests from actual construction sites. The paper presents clear evidence that friction may be the most important component of connection capacity. It also presents a clear correlation between confinement and connection capacity.IntroductionUtilization of micropiles for structural retrofit requires connection of the micropiles to the footings of the existing structure. This is often accomplished by drilling through the footing and developing the connection by direct bond between the micropile grout and the existing concrete. Almost ten years ago, an experimental research effort was carried out in the US to investigate the magnitude and mechanism of development of the bond strength between micropiles and existing concrete. Smooth and textured micropile inserts of varying lengths were tested to failure inside pre-drilled holes of varying diameters. That investigation led to several publications (Gomez et al. 2005, Wilder et al. 2005, Cadden 2009) on the mechanism of development of bond strength between micropiles and concrete, which included a chart for preliminary bond value selection depending on the diameter of the hole and texture of the micropile.An intensive testing program was carried out in Portugal in the last five years. The program focused on answering questions posed by the original investigation and on finding the relationship between connection capacity and level of confinement. Both investigations, and especially the testing performed in Portugal, provided an invaluable amount of information on the mechanisms of failure of micropile-to-footing connections. This information should be the basis for development of design procedures that, until now, were not available."

Jan 1, 2015

By Daniel W. Mageau, Larry W. Applegate, Aaron K. McCain

"An innovative method of ground freezing was successfully tested to create a “dry” excavation condition for a new building foundation at a site in downtown, Miami, Florida. The subsurface conditions in Miami generally consist of very porous, weak limestone and sand with groundwater near the surface. Water flow through these materials can be very high. Dewatering is extremely restricted in Miami so deep below-grade structures are rare and expensive. A new, innovative method to allow deep excavations in dry conditions without dewatering involves the creation of a thick, temporary, frozen soil plug below the planned excavation depth across the entire site to cut off vertical groundwater flow during construction. Frozen soil is impermeable and very strong and has long been used for temporary structural and water-tight shored walls. Using the same proven principals, frozen soil plugs are very effective at cutting off water from the bottom of the excavation as well as resisting upward buoyant forces. This new freezing method can be used for fairly deep excavations in new building construction supported on deep foundations. The building piles act as temporary anchors for the frozen plug to resist very high upward buoyant pressures until the permanent structural slab is completed.IntroductionUnlike other Cities, below grade basements are rare in Miami. The few basement foundations constructed have utilized a cumbersome and expensive method of excavation and shoring involving underwater excavation, tremie slabs, and commercial divers. The key issue for underground construction in this area of the country is the vertical flow of groundwater through the base of the excavation. To deal with this issue in the past, the contractor first installed all of the building piles and the perimeter shoring walls. Then, interior sheet pile walls are installed to create small manageable excavation pits. Each pit is then excavated through standing water “in-the-blind” and around the buildings support piles. The final excavation, interior struts, and inspection is performed by commercial divers. Finally a thick foundation tremie slab is poured under water. This method could be successful but proved to be time consuming and expensive. In addition, some building piles were occasionally damaged during the under-water construction process."

Jan 1, 2015

By Brandon Buschmeier, Frederic Masse

"Inclusions are a type of ground improvement that provide an improvement of a soil mass by insertion of a material with better characteristics than the surrounding soils. There are primarily two types of inclusions: “Soft” inclusions which are constructed of granular material (Stone Columns, Rammed Aggregate Piers, VibroPiers...), and “rigid” inclusions which are constructed of grout inserted with or without pressure (VibroConcrete Columns, Controlled Modulus Columns, Soil Mixing Columns).While the central principle of the inclusions is similar (i.e., overall improvement of characteristics of the soil mass below the structure), the load transfer mechanism is radically different for each technique. Therefore, the applicable design methodology is specific to the type of inclusions and there exists no universal method of design which spans across all inclusions.This paper will present an in-depth comparison between the standard design methods used for “soft” granular-type inclusions (Priebe modified, Balaam & Booker, Goughnour & Bayuk...) and the methods used for “rigid” inclusions which mainly rely on finite element analysis. The paper will explain why the design for soft inclusion methods cannot be applied to rigid inclusions and vice-versa. Each design method will be reviewed in detail to better emphasize its limitations and advantages.Two case histories will also be presented; one for each type of inclusions in order to illustrate the concepts developed in the first part of the paper.1 INTRODUCTION1.1 GENERAL OVERVIEW OF GROUND IMPROVEMENT WITH INCLUSIONSThe use of ground improvement methods to provide the appropriate amount of foundation support is a growing and constantly evolving industry. Traditional structural foundation methods including ‘shallow’ and ‘deep’ foundations do not adequately address the wide range of settlement tolerances, soil conditions, and loading considerations inherent to each unique potential project. In some instances, ‘shallow’ foundation solutions are simply not feasible due to soil and loading constraints. Furthermore, ‘deep’ foundation solutions are used to ‘bridge’ the soft compressible soils, ensuring that the entirety of the load in the structure is transmitted through individual elements into competent layers below the ground surface (bedrock, dense residual soils). Highly concentrated structural loads are transferred into the individual elements by means of direct contact requiring the use of structurally rigid surficial components (structural slabs, grade beams, and pile caps).Ground improvement bridges the gap between these two traditional methods, offering adequate foundation support while using more costeffective techniques and design methodologies. Inclusions are a type of ground improvement used to provide a reinforcement of the soil mass through the vertical insertion of a material with better characteristics than the surrounding soils. Much like deep foundations, inclusions are installed through soil layers with high compressibility and/or low bearing capacity and terminated in a suitable bearing stratum. However, unlike deep foundations, ground improvement inclusions rely on a distribution of load between the soil and the inclusions. By doing so, some of the structural load is applied directly to the soil in a proportion equal to its bearing capacity and compressibility limits, while the rest of the load is shed into the vertical inclusions down to the bearing stratum. Load sharing is a critical aspect in the performance and design of the various ground improvement methods."

Jan 1, 2015

By James L. Christensen, Gregory Sanchez, Michael P. Walker

The Fogg Museum expansion project required excavation and construction in a congested urban area in Cambridge, Massachusetts. A soldier pile tremie concrete (SPTC) wall provided the support of excavation and now serves as the permanent basement wall of the new expansion of the museum. The existing Fogg museum had a single basement level. The new expansion has a two-level basement for new exhibit space and an amphitheater. The east side of the site is about 20 feet above the basement level of the existing Fogg structure which resulted in a significant unbalanced load that needed to be resolved without damaging the original Fogg structure. The SPTC wall was supported with a combination of tiebacks and internal bracing. The final depth of the excavation was about 40 feet below street level. Strict movement control was imposed because the existing museum contained an Italian Renaissance-style courtyard. The southeast corner of the SPTC wall had to accommodate underpinning of an historic concrete ramp which was ultimately incorporated into the expansion. Challenges during construction included excavating the SPTC wall panels up to 12 feet into argillite bedrock which had occasional diabase dikes and sills. The following topics are discussed in more detail after a general project.

Jan 1, 2015

By Jacob A. Jordan, Rachel M. Garrett, W. Robert Thompson III, James C. Pegues

"Environmental control structures for an existing fossil-fuel power generating plant near Pascagoula, Mississippi faced several design and construction challenges due to space limitations. Conceptual design calculations indicated drilled shaft foundations would likely be needed to accommodate the higher lateral and compressive loads expected under some structures. A maximum drilled shaft diameter of 60-in was preferred due to various space constraints. Smaller diameter drilled shafts were deemed acceptable under structures with more moderate loading conditions. Furthermore, augercast piles were considered where lateral loading was not a governing design criterion.A series of SPT borings and CPT soundings revealed a subsurface profile consisting of soft to firm clays to depths of about 25 feet, underlain by fine to coarse sands. The apparent relative density of the sands was loose just below the clay, with increasing density noted with an increase in depth.Analysis of conventional drilled shafts indicated needed capacities could not be achieved unless shaft lengths exceeded 100 feet. Post-grouted drilled shafts were therefore evaluated to decrease shaft lengths by taking advantage of increased base capacity. Analyses showed the higher predicted capacities needed for some structures could be achieved with this approach. Final design for the project incorporated 90-ft long, 60-in diameter post-grouted drilled shafts; 60-ft long, 48-in diameter post-grouted drilled shafts; and 60-ft long, 48-in diameter conventional shafts. Both post-grouted and conventional trial shafts were installed as part of the detailed design phase of the project. Each trial shaft included CSL integrity testing and Osterberg-cell bi-directional load testing. Load test results revealed that additional base capacity was, in fact, achieved through the post grouting process. The 60-in diameter post-grouted production shafts and the 48-in diameter conventional production shafts have been installed at the site, with the project that would utilize the 48-in diameter post-grouted shafts deferred at this time."

Jan 1, 2015

By Pancho J. Garza, Keith H. Dahlen, Chris A. Labye

"Design for reconstruction of the East Flagstaff traffic interchange project located in Flagstaff, Arizona posed particular challenges. The proposed design included construction of a nearly 50-foot tall mechanically stabilized earth (MSE) wall given rightof- way constraints and soft subgrade soils. The tight right-of-way, approximately 15 feet in certain locations, adjacent to existing structures limited the number of viable remedial alternatives to provide grade separation at the proposed bridge abutment without significant settlement. Preliminary analyses indicated the existing subgrade soils - consisting primarily of relatively soft silts and clays with decomposed pumice - would settle approximately 12 to 14 inches resulting in unacceptable wall deformation. Stone columns placed via vibratory methods (vibro-replacement) consisting of circular excavations which penetrate to firm bearing soils and which are filled with crushed stone were selected to densify the existing subgrade soils. The implemented mitigation measures helped limit settlement to less than one inch and allow for successful construction of the project. The project history - including site constraints, subsurface conditions, evaluation of remedial alternatives, stone columns methodology, and effectiveness of ground improvements - will be discussed.IntroductionThis paper describes the subsurface investigation performed for the reconstruction of the Business Route 40 (B-40) (Country Club Drive) and United States (US) 89 Traffic Interchange (TI) located within the city limits of Flagstaff, Arizona. This project is currently referred to as the East Flagstaff TI. The Project Site Vicinity Map is shown below.The former B-40/US 89 TI was considered ineffective in handling the current and projected volumes of traffic which transition from northbound (NB) B-40 to US 89 (both directions), as well as from southbound (SB) US 89 to SB B-40. The intent of the project was to reconstruct the TI to better accommodate projected traffic volumes. The project eliminated the existing ramps from both NB B-40 to SB and NB US 89. The new interchange includes a Tee intersection from B-40 to US 89. In order to accommodate this alignment, the profile of US 89 was raised several feet (on nearly the same as existing horizontal alignment) to match the elevated profile of B-40. B-40 was shifted just west of its current alignment to accommodate construction of a new, wider bridge structure which spans over Industrial Drive, the Burlington Northern Santa Fe (BNSF) railway, and old Route 66. South of the new bridge, B-40 transitioned back to the existing alignment just north of the I-40/B-40 TI. Within the project limits, both US 89 and B-40 were widened to three travel lanes in each direction."

Jan 1, 2015

By Kevin Cunningham

"Litigation resulting from neighboring structures with settlement and/or lateral movement or improper pile design and faulty soils engineering analysis, are a multi-faceted opportunity for law firms. These types of claim scenarios are an attorney’s dream, and can obliterate a Deep Foundation Contractors profit and more importantly, can be avoided with a progressive approach to risk management in design and project management.The following (4) case studies will be examined and dissected to discern certain lessons learned for risk management solutions to avoid these deep foundation related challenges in the future.1) Pipe Flotation – Soil Conditions Not Anticipated in Specifications or Contract2) Easement Encroachment – Easement Dimensions Not Recognized Until Completion of Project3) Subjacent Lateral Support – Neighboring Structure Wooden Pile Unprotected Causing Structure to Settle4) Improper Pile Placement - Construction & Design Caused Retail Store to SettleSpecific Deep Foundation project challenges involving: buoyancy calculations regarding subsurface soil characteristics, design factors taking existing subsurface sewer line easements into account, structural instability as result of excavation causing exposure/heavy rainfall to existing wooden piles supporting adjoining building and improper pile location resulting from faulty pile design will be described with risk management recommendations to avoid these challenges in the future.From the very start of construction on any project deep foundation and excavating work poses numerous engineering and technical challenges for developers, contractors and engineers. Dealing with changing or hidden conditions is one of the most difficult challenges facing any contractor or engineer on a project. Relying on incomplete or inaccurate engineering reports is another common problem. Other challenges include dealing with technical errors or oversights that are deeply embedded in the project specifications or bid process.No matter what is the origin of the problem or how it manifests, deep foundation contractors, design professionals and engineers should be ever-mindful of good risk management practices that can prevent serious disputes that can result in costly litigation."

Jan 1, 2015

By William G. Ryan, David S. Graham, Dan A. Brown, Rich A. Lamb, Paul J. Axtell

"The St. Croix River Crossing project on the Minnesota-Wisconsin border has been in the process of planning and public debate for two decades, with several changes in alignment. During the course of the earlier planning process in 1995, a drilled shaft load test was performed to obtain preliminary design information. There were some difficulties in maintaining stability within the weak sandstone bearing formation, and the measured axial resistance was relatively low. Subsequent experience by the Minnesota Department of Transportation with similar weak sandstones on the I-35W project suggests that improved construction techniques using modern drilling fluids may offer opportunities for improved performance. During final design in 2012 a second load test program was performed of a full scale test shaft constructed using polymer drilling fluids. The stability of the socket excavation in the weak sandstone appeared to be greatly improved and the measured axial resistance significantly higher.This case history illustrates the excellent performance that drilled shafts can provide in even relatively weak sandstone bedrock as well as the profound influence on axial resistance associated with the construction techniques used. The improved resistance values obtained by the new load test with more recent construction technology allowed the foundation scheme to be substantially optimized with respect to the number and size of required drilled shafts, reducing the size, cost, and risk of the coffercells and footings.IntroductionThe Minnesota Department of Transportation (MnDOT) has awarded the first phase of a bridge construction project that will cross the St. Croix River between Oak Park Heights, MN and St Joseph, WI. The first phase construction contract involves building the river pier substructures including groups of drilled shafts beneath each tower leg. A general location of the bridge project is provided in Figure 1.Prior to award of the construction contract, two separate design-phase axial load tests were performed on non-production drilled shafts with rock sockets. Both tests were static, bottom-up tests using the Osterberg Cell (O-cell). The first test was performed in 1995 when final design and construction was thought to be imminent. After years of public debate and literally, an act of Congress, design of the project was finally restarted and a second load test performed in 2012. The 1995 test was conducted on the Minnesota bank approximately 900 ft southwest of the St. Croix River bank. The 2012 test was conducted in the river about 2,100 ft northeast of the1995 test location. A plan-view of the project indicating the test program locations relative to the bridge alignment is provided in Figure 2."

Jan 1, 2015

By Swaminathan Srinivasan, Aaron J. Muck

"When an opportunity arises to combine state-of-the-art concepts with advanced modeling tools, engineers need to take what they know and apply forward thinking to geotechnical solutions to promote the state-ofpractice. Such an opportunity was seized during the design and construction of the Great American Tower in Cincinnati, Ohio. The forty-one story Great American Tower at Queen City Square – currently the tallest building in Cincinnati – has not only changed the downtown skyline, it is also contributing to the advancement of the state-of-the-art use of auger cast-in-place (ACIP) piles as settlement reducers. Predicted settlements of a traditional mat foundation were excessive, and the costs and construction time associated with traditional ACIP piles extending to bedrock were not preferred. A mat supported on a limited number of ACIP piles, with the piles primarily acting as settlement reducers, was evaluated as the preferred foundation type.Promoting the unique soil-structure interaction of the foundation system with confidence required the use of sophisticated numerical modeling tools. Traditional standard penetration test boring data (SPT) was initially used to develop a numerical analysis of the soil-structure interaction using FLAC 3D software. The model was further modified with cone penetration (CPT) and pressuremeter testing (PMT), along with actual load test results on several ACIP pile elements of varying lengths, but all tipping above bedrock. Through a combined design team effort, and detailed numerical modeling analysis, ACIP piles were recommended for reducing mat foundation settlement. Instrumentation during and post-construction confirmed design assumptions and predictions. Integrating sound geotechnical concepts, and using advanced geotechnical analysis and design methods, traditional mat and ACIP pile foundations were successfully integrated into a unique foundation support system.INTRODUCTIONThe Great American Tower at Queen City Square in Cincinnati, Ohio is located within a region dissected by historical geologic deviances associated with the meander of the Ohio River and glacial progression/recession. Combining a challenging geology, with the development of a high-rise office building afforded the design team an opportunity to combine state-of-the-art soil-structure interaction concepts and method with traditional geotechnical engineering concepts. Such a combination required a variety of field tests, collaboration with the design team and owner, and geotechnical-structural modeling during the design phase. During construction, in addition to materials testing and observation, a variety of instrumentation systems were employed. Together, the data was used to corroborate the design model and make adjustments during construction and further substantiate design assumptions following construction."

Jan 1, 2015

By Artur R. P. Junior Sergio, Pedro A. Netto, N. Monteiro, Foluke S. de Assis, Frederico M. Margem

Synthetic fibers are being replaced gradually by natural materials such as lignocellulosic fibers. Compared to synthetic fibers, natural fibers have shown advantages in technical aspects such as environmental and economic. So there is a growing international interest in the use of those fibers. The banana fiber presents significant properties to be studied, but until now few thermal properties on banana fiber as reinforcement of polyester matrix were performed. The present work had as its objective to investigate, by photoacoustic spectroscopy and photothermal techniques the thermal properties of diffusivity, specific heat capacity and conductivity for polyester composites reinforced with banana fibers. In the polyester matrix will be added up to 30% in volume of continuous and aligned banana fibers. These values show that the incorporation of banana fibers in the polyester matrix changes its thermal properties.

Jan 1, 2015

By Junfu Chen, Jiann-Yang Hwang, Yong Zhou, Lijun Lu, Likun Lia, Jixiong Liu

The sheet-like NiS-ZnS heterostructured composites were prepared by the microwave hydrothermal. The fabrication of the heterojunctions broadened the range of light response of ZnS. The photoexcited electrons of ZnS migrated to the redox potential of NiS/Ni2S under visible light irradiation, which can facilitate the effective separation of photogenerated electrons and holes in space. The visible photocatalytic activity towards hydrogen production for NiS/ZnS nanosheet heterostructed composites without co-catalyst achieved 0.28 mmol h–1, and the quantum efficiency was up to 18.6% under the wavelength with 420 nm visible light irradiation.

Jan 1, 2015

By Zhen Zhang, Jiang Diao, Tao Zhang, Yi Ren, Lu Jiang, Xiao-Man Yan, Bing Xie

The precipitation behavior of phosphorus enrichment phase was investigated by slag modification with Al2O3. The mineral phase of the original slag and modified slags were measured by mineral phase microscope, SEM+EDS and XRD. The mechanism of Al2O3 modification was discussed according to the thermodynamic theory analysis software (Factsage version 6.3). The results show that the high phosphorus solid solution (nˊ2CaO·SiO2-3CaO·P2O5) was generated by the continuous reaction of nC2S-C3P (nˊ＜n) solid solution and Al2O3 under 1350℃. The amount of initially precipitated solid solution (nC2S-C3P) was reduced and even disappeared with the increasing of Al2O3. If the addition of Al2O3 is enough in the slag, the high phosphorus solid solution (nˊC2S-C3P) that generated by the above mentioned reaction will continue to react with Al2O3 to produce Ca2Al2SiO7 and even C3P, which was demonstrated that the addition of Al2O3 has a positive influence on the precipitation of phosphorus enrichment phase.

Jan 1, 2015

By Halvor Dalaker, Alain Marc Ferber, Thor Anders Aarhaug, Pål Tetlie

Off-gas monitoring of experimental reactors give little information about intermediate reaction products and reflect chemical equilibria at reduced gas temperatures. A reactor design with optical access was designed and tested in order to be able to qualify and quantify gaseous species from their emission spectra. By use of a sequence of sapphire, UV fused silica and IR transparent sapphire and CaF2 windows and lenses optical access to a hot, maximum 1800 °C, reaction zone was gained. A cooled area behind the reaction zone was used as a background in order to avoid signal saturation from reactor walls. In addition to molecular emission spectra, atomic emission lines are used to characterize stable gas constituents and radicals. The setup has been designed for the study of methane dehydrogenation experiments in order to investigate the carbon activity of reduction of oxide with methane, but has also been used to monitor gaseous silicon suboxide.

Jan 1, 2015

By Petrus Christiaan Pistorius, Ming Tang

Magnetite concentrate is pelletized and then hardened by elevated-temperature oxidation to hematite, to produce pellets for ironmaking. Previous work showed that the rate of oxidation is under mixed control of gaseous mass transfer of molecular oxygen through the pellet pores, and solid-state diffusion into the oxidizing grains. Because of the partially limiting role of solid-state diffusion, concentrate size distribution strongly affects pellet oxidation. Previously, a simple mixed-control model was formulated to describe isothermal oxidation. In that model, the main effect of concentrate size distribution was on the plateau level of oxidation which is reached at a given temperature. However, the extent of plateau oxidation increases with increased temperature, requiring a more complex model for non-isothermal oxidation. In this paper, predictions of the non-isothermal model confirm the strong effects of concentrate size distribution and oxygen enrichment. In particular, a greater fraction of coarse magnetite particles would be beneficial, decreasing the size of the macroscopic unoxidized pellet core.

Jan 1, 2015

By Honglei Zhang, Yue Wang, Guotao Xu, Li Liu

The influence of rich oxygen atmosphere on the properties and structure of castables used in the hot wind pipe of blast furnaces was analyzed. Results show that the cold compressive strength of castables is affected by the change of rich oxygen volume in the wind pipe, the bulk density decreases and apparent porosity of castables increases with the addition of rich oxygen in wind pipe. With the addition of rich oxygen, the velocity of heat transfer increase and result of the steel shell become over hot out of safe limit at the thin lining in hot wind pipe.

Jan 1, 2015

By Paul S. Korinko, Simona E. Hunyadi Murph

To address a radiological contamination event, a materials and process project was initiated. During the course of this project, processes and materials were developed that successfully captured zinc vapors physically and chemically, respectively. However, the physical traps were placed in an undesirable area and it was determined that the chemically captured zinc reactions was reversible. Consequently, advanced nanomaterials are being developed to capture zinc vapors. The current state of the art of the science and engineering of these materials and their efficacy for zinc capture and retention is discussed in this paper.

Jan 1, 2015

By Patrice Chartrand, Halvor Dalaker, Philippe Ouzilleau

A size-dependant thermodynamical model for the carbon-hydrogen previously developed by Ouzilleau et al. [1] has been expanded here to include chemisorption of methyl groups. Gibbsenergy minimalisation calculations using FACTSAGE software on this model indicates that hydrogen bonding through methyl groups is energetically favoured as an intermediate between bonding as monoatomic hydrogen to edge hexagons (which is more favourable) and as monoatomic hydrogen to corner hexagons (which is less favourable). The model has also been applied to methane decomposition and oxide reduction using natural gas. A C-H solid solution as a thermodynamic description of the solid carbon phase influences calculations of carbon activity in metastable methane, and gives different results than when using graphite.

Jan 1, 2015

By Shengli Wu, Jinming Zhu, Wei Huang, Xinliang Liu

The sinter of high basicity would interact with lump ores or acid pellets in the cohesive zone of blast furnace due to the difference of chemical composition and micro structures. The results of this work showed that the softening-melting properties of lump ores and acid pellet would be obviously improved by the high temperature interaction. However, the high temperature interaction index (INI) would be influenced by many factors, such as chemical composition, porosity, interaction interface and so on. The INI between sinter and porous limonite lump ore (L-2) was much higher than that of dense hematite lump ore (L-1) and acid pellet (P-1). In addition, though the softening and melting properties of L-2 were poorest in respective iron ores, the softening and melting properties of integrated burden B (consist of sinter and L-2) were not worse than other integrated burdens due to the strong high temperature interaction.

Jan 1, 2015